Digital Commons Network^™

Crystal Engineering Of Multi-Component Crystal Forms: The Opportunities And Challenges In Design, Heather Dawn Marie Clarke

USF Tampa Graduate Theses and Dissertations

There is heightened interest to diversify the range of crystal forms exhibited by active pharmaceutical ingredients (APIs) in the pharmaceutical industry. The crystal form can be regarded as the Achilles' heel in the development of an API as it directly impacts the physicochemical properties, performance and safety of the API. This is of critical importance since the crystal form is the preferred method of oral drug delivery by industry and regulatory bodies. The ability to rationally design materials is a lucrative avenue towards the synthesis of functional molecular solids with customized physicochemical properties such as solubility, bioavailability and stability. Pharmaceutical …

Functional Magnetic Nanoparticles, James Gass

USF Tampa Graduate Theses and Dissertations

Nanoparticle system research and characterization is the focal point of this research and dissertation. In the research presented here, magnetite, cobalt, and ferrite nanoparticle systems have been explored in regard to their magnetocaloric effect (MCE) properties, as well as for use in polymer composites. Both areas of study have potential applications across a wide variety of interdisciplinary fields.

Magnetite nanoparticles have been successfully dispersed in a polymer. The surface chemistry of the magnetic nanoparticle proves critical to obtaining a homogenous and well separated high density dispersion in PMMA. Theoretical studies found in the literature have indicated that surface interface energy …

Temporal And Spatial Analysis Of Monogenetic Volcanic Fields, Koji Kiyosugi

USF Tampa Graduate Theses and Dissertations

Achieving an understanding of the nature of monogenetic volcanic fields depends on identification of the spatial and temporal patterns of volcanism in these fields, and their relationships to structures mapped in the shallow crust and inferred in the deep crust and mantle through interpretation of geochemical, radiometric and geophysical data.

We investigate the spatial and temporal distributions of volcanism in the Abu Monogenetic Volcano Group, Southwest Japan. E-W elongated volcano distribution, which is identified by a nonparametric kernel method, is found to be consistent with the spatial extent of P-wave velocity anomalies in the lower crust and upper mantle, supporting …

Understanding Operating Speed Variation Of Multilane Highways With New Access Density Definition And Simulation Outputs, Bing Huang

USF Tampa Graduate Theses and Dissertations

Traffic speed is generally considered a core issue in roadway safety. Previous studies show that faster travel is not necessarily associated with an increased risk of being involved in a crash. When vehicles travel at the same speed in the same direction (even high speeds, as on interstates), they are not passing one another and cannot collide as long as they maintain the same speed. Conversely, the frequency of crashes increases when vehicles are traveling at different rates of speed. There is no doubt that the greater speed variation is, the greater the number of interactions among vehicles is, resulting …

Algorithms For Visual Maritime Surveillance With Rapidly Moving Camera, Sergiy Fefilatyev

USF Tampa Graduate Theses and Dissertations

Visual surveillance in the maritime domain has been explored for more than a decade. Although it has produced a number of working systems and resulted in a mature technology, surveillance has been restricted to the port facilities or areas close to the coastline assuming a fixed-camera scenario. This dissertation presents several contributions in the domain of maritime surveillance. First, a novel algorithm for open-sea visual maritime surveillance is introduced. We explore a challenging situation with a camera mounted on a buoy or other floating platform. The developed algorithm detects, localizes, and tracks ships in the field of view of the …

Low Level Exposure To Air Pollution And Risk Of Adverse Birth Outcomes In Hillsborough County, Florida, Maria B. Mainolfi

USF Tampa Graduate Theses and Dissertations

In this retrospective cohort from 2002 through 2007, 104,003 singleton live births in Hillsborough County, Florida were analyzed to elucidate the relationship between feto-infant morbidity outcomes and prenatal exposure to six criteria air pollutants. This study is based on three linked databases: The Florida Hospital Discharge database; The vital statistics records of singleton live births; Air Pollution meteorological data from the Environmental Protection Agency. There are six common air pollutants, particulate matter 2.5 (PM2.5), particulate matter 10 (PM10), ground-level ozone (O3), carbon monoxide (CO), nitrogen (NOx), and lead (Pb). These pollutants are harmful to human health and the environment. The …

Florida Fishery-Wide Reproductive Indices Of Stone Crab, Menippe Mercenaria, And Their Application To Stock Assessment And Management, Claire Elizabeth Crowley

USF Tampa Graduate Theses and Dissertations

The stone crab, Menippe mercenaria, supported the third most valuable fishery in Florida in 2016. Declining catch per unit effort (CPUE) and overall negative trend in landings since 2000 have raised concerns among fisherman, researchers, and fishery managers about the resiliency of the fishery. The Florida Fish and Wildlife Research Institute estimated that the Florida stone crab fishery has been overexploited since 1997. Overexploited fisheries, such as the commercial stone crab fishery, risk induced changes in life history parameters, such as age at maturation and reproductive output. In turn, these population-level changes have the potential to reduce the spawning …

Plant Species Richness And Species Area Relationships In A Florida Sandhill, Monica Ruth Downer

USF Tampa Graduate Theses and Dissertations

Pine sandhill are integral pyrogenic communities in the southeastern United States. Though once widespread, habitat destruction, fire suppression and fragmentation have reduced the population to nearly 3%. It is important to learn as much as possible about these unique areas in order to implement best management practices to conserve and restore the existing populations of these communities.

Fire is central to the maintenance of pine sandhill communities and two conceptual hypothesis regarding burn frequency have come to light in maintaining the unique species composition and richness of these areas. The first is the Intermediate Disturbance Hypothesis which suggests that intermediate …

Detecting Surface Oil Using Unsupervised Learning Techniques On Modis Satellite Data, Joshua Kidd

USF Tampa Graduate Theses and Dissertations

The release of crude oil or other petroleum based products into marine habitats can have a devastating impact on the environment as well as the local economies that rely on these waters for commercial fishing and tourism. The Deepwater Horizon catastrophe that started on April 20th 2010 leaked an estimated 4.4 million barrels of crude oil into the Gulf of Mexico over a 3 month period threatening thousands of species and crippling the gulf coast. The National Oceanic and Atmospheric Administration (NOAA) used several satellite remote sensing technologies to manually track and predict the extent and location of oil on …

Member Perceptions Of Informal Science Institutions Graduate Certificate Program: Case Study Of A Community Of Practice, Lois A. Ball

USF Tampa Graduate Theses and Dissertations

Abstract

This research attempted to understand the experiences of a cohort of informal and formal science educators and informal science institution (ISI) community representatives during and after completion of a pilot graduate certificate program. Informal science educators (ISEs) find limited opportunities for professional development and support which influence their contributions to America's science literacy and school science education. This emergent design nested case study described how an innovative program provided professional development and enabled growth in participants' abilities to contribute to science literacy. Data were collected through interviews, participant observations, and class artifacts. The program by design and constituency was …

The Impacts Of Population Density, And State & National Litter Prevention Programs On Marine Debris, Melissa Rose Brogle

USF Tampa Graduate Theses and Dissertations

Marine debris is improperly disposed of solid waste, also called litter, which is deposited in the marine environment (NOAA, 2010). Litter prevention techniques such as fines, cleanups, incentives, and others, can help to decrease litter, and ultimately decrease marine debris. This research analyzed 2000 and 2010 International Coastal Cleanup (ICC) data obtained from The Ocean Conservancy to ascertain whether certain litter prevention techniques did reduce amounts and types of marine debris found in coastal areas. The litter prevention techniques analyzed included state bottle bills, voluntary monofilament fishing line recycling programs, and the Keep America Beautiful (KAB) cigarette butt litter prevention …

Development Of A Tool For Pressure Ulcer Risk Assessment And Preventive Interventions In Ancillary Services Patients, Monica Shutts Messer

USF Tampa Graduate Theses and Dissertations

The incidence of nosocomial pressure ulcers has continued to increase in U.S. hospitals over the past 15 years despite the implementation of national preventive guidelines and the wide-spread use of validated risk assessment tools. The majority of preventive efforts and tools have been focused primarily on patients who are bed-ridden or immobile for extended periods. What has not been well studied or identified is the potential risk for pressure injury to patients undergoing diagnostic procedures in hospital ancillary units where extrinsic risk factors such as high interface pressures on procedure tables and friction and shear from positioning and transport can …

Development And Application Of An F/M Based Anaerobic Digestion Model And The Rt-Ribosyn Molecular Biology Method, Matthew Raymond Cutter

USF Tampa Graduate Theses and Dissertations

A simple anaerobic digestion model has been developed for a continuously-stirred tank reactor (CSTR), which links the specific biogas production rate to the food/microorganism ratio (F/M). The model treats the various microbial populations involved in the sequential biological processes involved in anaerobic digestion as a composite and links the entire biomass specific growth rate directly to the specific biogas production rate. The model was calibrated by determining the specific gas production rate for a range of F/M values using a municipal wastewater seed sludge. The model predictions for steady-state biogas production rates were compared to observed biogas production and volatile …

Self-Assembly Of Self-Similar Structures By Active Tiles, Daria Karpenko

USF Tampa Graduate Theses and Dissertations

The natural capacity of DNA for molecular self-assembly has already been exploited to create DNA based tiles which can self-assemble into nano-scale arrays and carry out nano-scale computation. Thus far, however, all such self-assembly has been passive, in the sense that the binding capacities of a tile are never altered throughout the assembly. The idea of active tiles, tiles that can send signals to each other and activate latent binding sites, has been proposed but never incorporated into a formal model. Here, I present an extension of the existent abstract tile assembly model by defining an active tile assembly and …

Investigation And Synthesis Of Novel Graphene-Based Nanocomposites For Hydrogen Storage, Anthony Joseph D'Angelo

USF Tampa Graduate Theses and Dissertations

It is of great interest to develop and utilize a high surface area material with optimized hydrogen sorption properties. The need for a renewable energy source to replace automobile gasoline has become more critical in the past decade. Hydrogen is a viable fuel source for automobile usage; however, the question of how hydrogen will be safely and efficiently stored still remains. Critical factors for optimum hydrogen storage include ambient conditions and low activation temperature for adsorption and desorption phenomena. In order for optimum hydrogen adsorption to be achieved, the properties of (1) high surface area, (2) optimum hydrogen adsorption energy, …

Multidimensional Spectroscopy Of Semiconductor Quantum Dots, Jason Michael Bylsma

USF Tampa Graduate Theses and Dissertations

The coherent properties of semiconductor nanostructures are inherently difficult to measure and one-dimensional spectroscopies are often unable to separate inhomogeneous and homogeneous linewidths. We have refined and improved a method of performing multidimensional Fourier transform spectroscopy based on four-wave

mixing (FWM) experiments in the box geometry. We have modified our system with broadband beamsplitters in all interferometer arms, high-resolution translation stages and the ability to work in reflection geometry. By improving the phase-stability of our setup and scanning pulse delays with sub-optical cycle precision, we are able to

reproduce 2DFT spectra of GaAs multiple quantum wells. With the FWM signal …

A Principled Approach To Policy Composition For Runtime Enforcement Mechanisms, Zachary Negual Carter

USF Tampa Graduate Theses and Dissertations

Runtime enforcement mechanisms are an important and well-employed method for ensuring an execution only exhibits acceptable behavior, as dictated by a security policy. Wherever interaction occurs between two or more parties that do not completely trust each other, it is most often the case that a runtime enforcement mechanism is between them in some form, monitoring the exchange. Considering the ubiquity of such scenarios in the computing world, there has been an increased effort to build formal models of runtime monitors that closely capture their capabilities so that their effectiveness can be analysed more precisely. While models have grown more …

Examining The Economic Costs And Sources Of Potable And Nonpotable Water In Northern Mexico, Kathryn Marie Marlor

USF Tampa Graduate Theses and Dissertations

Water availability and the cost of different water sources have been studied at great length. However, information is still needed to determine the policy directions to be undertaken by nations that have not yet achieved universal coverage of an improved water source. To further examine differences in water availability and pricing in the context of the developing world, three communities in Northern Mexico were surveyed to determine the differences in water distribution schemes and associated costs between rural and urban centers. It was observed that rural communities without a piped water supply paid 13 percent more for potable water supplies …

Design And Construction Of Functional Metal-Metalloporphyrin Frameworks, Le Meng

USF Tampa Graduate Theses and Dissertations

Porous metal-organic frameworks are a new type of functional materials with potential applications for gas storage, gas separation, catalysis, biomedical and chemical sensors. This thesis describes several porous metal-metalloporphyrin frameworks (MMPFs), which were synthesized with a series of transition metals and 5,15-bis(3,5-dicarboxyphenyl)-10,20-bis(2,6-dibromophenyl)porphine. Among these MMPFs, the cobalt MMPF (CoBrPTC) has a fcu structure, which represents the first porphyrin-based MOF with this topology. CoBrPTC was evaluated as heterogeneous catalyst and demonstrated interesting catalytic performances.

Willingness-To-Pay For Maintenance And Improvements To Existing Sanitation Infrastructure: Assessing Community-Led Total Sanitation In Mopti, Mali, Justin Vern Meeks

USF Tampa Graduate Theses and Dissertations

In recent years, much focus has been put on the sustainability of water and sanitation development projects. Experts in this field have found that many of the projects of the past have failed to achieve sustainability because of a lack of demand for water and sanitation interventions at a grassroots level. For years projects looked to create this demand through various subsidy schemes, with the "software" of behavior change and education taking a backseat to the "hardware" of infrastructure provision. Community-Led Total Sanitation (CLTS) is a fairly new way of looking at the issues of increasing basic sanitation coverage, promoting …

Developing Predictive Models For Lung Tumor Analysis, Satrajit Basu

USF Tampa Graduate Theses and Dissertations

A CT-scan of lungs has become ubiquitous as a thoracic diagnostic tool. Thus, using CT-scan images in developing predictive models for tumor types and survival time of patients afflicted with Non-Small Cell Lung Cancer (NSCLC) would provide a novel approach to non-invasive tumor analysis. It can provide an alternative to histopathological techniques such as needle biopsy. Two major tumor analysis problems were addressed in course of this study, tumor type classification and survival time prediction. CT-scan images of 109 patients with NSCLC were used in this study. The first involved classifying tumor types into two major classes of non-small cell …

Speaker Recognition Using Shifted Mfcc, Rishiraj Mukherjee

USF Tampa Graduate Theses and Dissertations

Speaker Recognition is the art of recognizing a speaker from a given database using speech as the only input. In this thesis we will be discussing a novel approach to detect speakers. Here we will introduce the concept of shifted MFCC to add improvement over the performance from previous work which has shown quite a decent amount of accuracy of about 95% at best. We will be talking about adding different parameters which also contributed in improving the efficiency of speaker recognition. Also we will be testing our algorithm on Text dependent speech data and Text Independent speech data. Our …

Evidence For Viral Infection In The Copepods Labidocera Aestiva And Acartia Tonsa In Tampa Bay, Florida, Darren Stephenson Dunlap

USF Tampa Graduate Theses and Dissertations

Mesozooplankton are of critical importance to marine food webs by transferring energy from the microbial food web to higher trophic levels and depositing energy to the deeper ocean layers through fecal deposition. While decades of research have shown that viruses have significant impacts in the oceans, and infect a wide range of organisms from bacteria to whales, there is still little known about the impacts of viruses on the mesozooplankton community. As copepods are the most abundant mesozooplankton group, this study sought to characterize the viruses present in natural populations of the calanoid copepods Acartia tonsa and Labidocera aestiva in …

Development Of An Integrated Process Model For Algae Growth In A Photobioreactor, Mehregan Jalalizadeh

USF Tampa Graduate Theses and Dissertations

While understanding the kinetics of algae growth plays an important role in improving algae cultivation technology, none of the existing kinetic models are able to describe algae growth when more than three growth limiting factors are involved. A model was developed in this study to describe algae growth in a photobioreactor. Two expressions were proposed based on the Monod model to relate the specific growth rate of algae to the concentration of nitrogen, phosphorus, inorganic carbon and light intensity in the culture media. Algal biomass concentration as a function of time was calculated by solving mass and energy balances around …

Overcoming Limitations Of Serial Audio Search, Isabela Cordeiro Ribeiro Moura Hidalgo

USF Tampa Graduate Theses and Dissertations

The typical approach for finding audio recordings, such as music and sound effects, in a database is to enter some textual information into a search field. The results appear summarized in a list of textual descriptions of the audio files along with a function for playing back the recordings. Exploring such a list sequentially is a time-consuming and tedious way to search for sounds. This research evaluates whether searching for audio information can become more effective with a user interface capable of presenting multiple audio streams simultaneously.

A prototype audio player was developed with a user interface suitable for both …

An Ecological Assessment Of A Juvenile Estuarine Sportfish, Common Snook (Centropomus Undecimalis), In A Tidal Tributary Of Tampa Bay, Florida, Adam Benjamin Brame

USF Tampa Graduate Theses and Dissertations

The common snook, Centropomus undecimalis, is an estuarine dependent sport fish that relies upon subtidal wetlands as nursery habitat. Despite the economic and recreational significance of this species, there are portions of its life history and biology that are poorly understood, particularly its early life history. Understanding juvenile snook use of wetland habitats is crucial given the rapid loss and degradation of these areas to anthropogenic impacts. Young-of-the-year snook were collected in pond and creek habitats of a single wetland system to assess early life ecology and habitat use. Proxies of habitat quality were used to determine which habitats …

A Novel Ultrasonic Method To Quantify Bolt Tension, Jairo Andres Martinez Garcia

USF Tampa Graduate Theses and Dissertations

The threaded fasteners are one of the most versatile methods for assembly of structural components. For example, in bridges large bolts are used to fix base columns and small bolts are used to support access ladders. Naturally not all bolts are critical for the operation of the structure. Fasteners loaded with small forces and present in large quantities do not receive the same treatment as the critical bolts. Typical maintenance operations such tension measurements, internal stress checking or monitoring of crack development are not practical due to cost and time constrains. Although failure of a single non-critical fastener is not …

Removal Of Bisphenol A Model Compounds And Related Substances Using Octolig®, Rachael Josephine Alessio

USF Tampa Graduate Theses and Dissertations

Bisphenol A used in the production of polycarbonate plastics and epoxy resins is ubiquitous in the environment. The raw material is released to the environment during the manufacturing process and by leaching from consumer products. Recent studies are suggesting that low-dose amounts of Bisphenol A may have adverse health effects on humans. The possibility of removing Bisphenol A from natural water sources or from solvents used to extract the material from consumer products before they enter the market has been studied. The use of model compounds and related substances (4-isopropylphenol, 4-(t-butyl) phenol, and nitrophenols) have been used to study their …

Compound-Specific Stable Isotopic Analysis Of Protein Amino Acids: Ecological Applications In Modern And Ancient Systems, Greg Ellis

USF Tampa Graduate Theses and Dissertations

Stable isotopic analysis of the major biochemically important elements is an increasingly utilized tool in the study of ecology. Patterns of isotopic fractionation in carbon and nitrogen are used to determine trophic linkages, nutrient pathways, and sources of primary production in numerous contexts. Traditional techniques rely on measurements made of bulk samples such as tissue, but emerging methods using individual chemical compounds provide a means of achieving deeper understanding in a variety of inquiries.

Amino acids, as the building blocks of proteins, are the dominant nitrogen-bearing biomolecules and are a major constituent of all life. Patterns of isotopic fractionation during …

Synthesis And Characterization Of Nanocomposites For Electrochemical Capacitors, Farah Alvi

USF Tampa Graduate Theses and Dissertations

Presently there are deep concerns over the environmental consequences and the consumption of non-renewable energy sources, with the accelerated greenhouse effect, triggered enormous interest in the use of renewable energy sources e.g., solar, hydropower, wind and geothermal. However the intermittent nature of harvesting renewable energy sources has recently gained considerable attention in the alternative reliable, cost effective, and environmentally friendly energy storage devices. The supercapacitor and lithium ion batteries are considered more efficient electrical energy storage devices than conventional energy storage systems.

Both devices have many useful and important applications; they could be an excellent source for high power and …