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On The Number Of Colors In Quandle Knot Colorings, Jeremy William Kerr

USF Tampa Graduate Theses and Dissertations

A major question in Knot Theory concerns the process of trying to determine when two knots are different. A knot invariant is a quantity (number, polynomial, group, etc.) that does not change by continuous deformation of the knot. One of the simplest invariant of knots is colorability. In this thesis, we study Fox colorings of knots and knots that are colored by linear Alexander quandles. In recent years, there has been an interest in reducing Fox colorings to a minimum number of colors. We prove that any Fox coloring of a 13-colorable knot has a diagram that uses exactly five …

Cement Heat Of Hydration And Thermal Control, Ahmadreza Sedaghat

USF Tampa Graduate Theses and Dissertations

Heat of hydration is a property of Portland cement and a direct result of the chemical reaction between cement and water. The amount of heat released is dependent upon the cement mineralogical composition, curing temperature, water to cement ratio, and cement fineness. High temperature resulting from heat of hydration (thereon referred to as HOH) of cement can affect the hydration process, and consequently the kinetics of development of the mechanical properties of concrete. One of the main reasons triggering the interest in HOH of cement is its implication in thermal cracking of concrete. The high temperature gradient between the inner …

Modeling The Construction And Evolution Of Distributed Volcanic Fields On Earth And Mars, Jacob Armstrong Richardson

USF Tampa Graduate Theses and Dissertations

Magmatism is a dominant process on Earth and Mars that has significantly modified and evolved the lithospheres of each planet by delivering magma to shallow depths and to the surface. Two common modes of volcanism are present on both Earth and Mars: central-vent dominated volcanism that creates large edifices from concentrating magma in chambers before eruptions and distributed volcanism that creates many smaller edifices on the surface through the independent ascent of individual magmatic dikes. In regions of distributed volcanism, clusters of volcanoes develop over thousands to millions of years. This dissertation explores the geology of distributed volcanism on Earth …

West Florida Shelf Connectivity: An Exploratory Study, Amanda Sue Reinert

USF Tampa Graduate Theses and Dissertations

This Thesis explores the connectiveness of the West Florida Shelf’s various areas of economic and ecological importance by considering five case studies of varying dynamic forcing influences and time. The advection of water about the shelf moves nutrients and has a direct impact on the shelf’s ecology and the determination of whether or not the shelf will be oligotrophic at any given time or location. The case studies are analyzed both quantitatively and qualitatively after quasi-isopycnal particle trajectory calculations are completed for each. The findings support a combination of local and deep-ocean forcing being ideal for the maximum advection and …

Modified Yttrium Hydroxide/Mc Nylon Nanocomposites And Scaling Effects In Multilayer Polyethylene Films, Jia Chen

USF Tampa Graduate Theses and Dissertations

In this thesis, monomer casting (MC) nylon was synthesized. MC nylon could replace nonferrous metals in certain applications, including gears, wheels, and other moving parts. However, compared with metals, MC nylon products have poor strength and stiffness, and crack easily, especially at low temperatures. In addition, the dimensional stability of MC nylon is poor, especially in the large casting nylon products, causing significant internal stresses due to shrinkage. Thus, MC nylon cracks easily when cast and molded. The yttrium hydroxide particles were modified by stearic acid and dispersed in the caprolactam. The polymerization time was short due to fast anionic …

Characterization Of Bacterial Diversity In Cold-Water Anthothelidae Corals, Stephanie Nichole Lawler

USF Tampa Graduate Theses and Dissertations

Cold-water corals, similar to tropical corals, contain a diverse and complex microbial landscape. Comprised of vital microscopic organisms (i.e. bacteria, viruses, archaea), the coral microbiome is a driving factor in the proliferation and survival of the coral host. Bacteria provide essential biological functions within coral holobionts, facilitating increased nutrient utilization and production of antimicrobial compounds. To date, few cold-water octocoral species have been analyzed to explore the diversity and abundance of their microbial associates. For this study, 23 samples of the family Anthothelidae were collected from Norfolk (n = 12) and Baltimore Canyons (n = 11) from the western Atlantic …

Modeling The Extent Of Virus Removal In Waste Stabilization Ponds To Support Reuse Of Wastewater, Kelly James Vannoy

USF Tampa Graduate Theses and Dissertations

Waste stabilization ponds (WSPs) are one of the most prevalent types of domestic wastewater treatment technologies employed worldwide, and global stressors such as urbanization, population growth, climate change, and water scarcity have increased the demand for reusing treated wastewater. The safe reuse of treated wastewater in agriculture can ease water scarcity, aid in food production, and reduce environmental degradation from the discharge of wastewater effluent to surface waters. The ability to predict virus concentrations in wastewater effluent is an important criterion for determining whether wastewater is suitable for discharge to the environment or for reuse in agriculture. However, many uncertainties …

Exciton Dynamics And Many Body Interactions In Layered Semiconducting Materials Revealed With Non-Linear Coherent Spectroscopy, Prasenjit Dey

USF Tampa Graduate Theses and Dissertations

Atomically thin, semiconducting transition metal dichalogenides (TMDs), a special class of layered semiconductors, that can be shaped as a perfect two dimensional material, have garnered a lot of attention owing to their fascinating electronic properties which are achievable at the extreme nanoscale. In contrast to graphene, the most celebrated two-dimensional (2D) material thus far; TMDs exhibit a direct band gap in the monolayer regime. The presence of a non-zero bandgap along with the broken inversion symmetry in the monolayer limit brands semiconducting TMDs as the perfect candidate for future optoelectronic and valleytronics-based device application. These remarkable discoveries demand exploration of …

Analysis And Processing Of Human Electroretinogram, Abdulrahman Mohammad Alaql

USF Tampa Graduate Theses and Dissertations

Electroretinagram (ERG) is the recording of electrical activity of retinal cells elicited by light stimulation, which has been widely used to help diagnose different types of retinal dysfunctions. The ERG response signal is a short non-stationary signal that contains overlapping components. Different Digital Signal Processing (DSP) techniques are investigated using MATLAB to study the time-frequency responses of the ERG signal such as Short Time Fourier Transform (STFT), Continuous Wavelet Transform (CWT) and Discrete Wavelet Transform (DWT). The Photopic ERG signal was processed and analyzed in this thesis and the results of each technique have been investigated in detail. The Photopic …

Motivation Of Adult, Auditioned Community Choirs: Implications Toward Lifelong Learning, David James Redman

USF Tampa Graduate Theses and Dissertations

Knowledge of motivation factors can assist conductors and music educators at all levels in planning and implementation of musical goals. The purpose of this study was to identify motivational factors to join the choir and maintain membership in the choir as well as the role of stress/anxiety in maintaining choral membership. In addition, the role of musicianship was evaluated in terms of music aptitude and vocal ability. Participants (N=135) from four adult, auditioned community choirs participated in this study. Data was collected using Advanced Measures of Music Audiation, Singing Coach, measure of vocal ability and a questionnaire relating to topics …

A Comparison Of Educational "Value-Added" Methodologies For Classifying Teacher Effectiveness: Value Tables Vs. Covariate Regression, Theodore J. Dwyer

USF Tampa Graduate Theses and Dissertations

There is a great deal of concern regarding teacher impacts on student achievement being used as a substantial portion of a teacher’s performance evaluation. This study investigated the degree of concordance and discordance between mathematics teacher ranking using value tables and covariate regression, which have both been used as measures for teacher effectiveness. The researcher examined teacher rankings, before and after the state recommended classification, using correlational techniques, comparison matrices, and visual examination for value-added scores derived from the value table versus the covariate regression approach. Examination demonstrated strong correlations between the initial rankings (r = .77 to .98) …

Production Of Biodiesel From Soybean Oil Using Supercritical Methanol, Shriyash Rajendra Deshpande

USF Tampa Graduate Theses and Dissertations

The slow yet steady expansion of the global economies, has led to an increased demand for energy and fuel, which would eventually lead to shortage of fossil fuel resources in the near future. Consequently, researchers have been investigating other fuels like biodiesel. Biodiesel refers to the monoalkyl esters which can be derived from a wide range of sources like vegetable oils, animal fats, algae lipids and waste greases. Currently, biodiesel is largely produced by the conventional route, using an acid, a base or an enzyme catalyst. Drawbacks associated with this route result in higher production costs and longer processing times. …

Incongruous Conceptions: Owen Jones’S Plans, Elevations, Sections And Details Of The Alhambra And British Views Of Spain, Andrea Marie Johnson

USF Tampa Graduate Theses and Dissertations

This thesis analyzes Plans, Elevations, Sections, and Details of the Alhambra (1836-1842) by British Architect Owen Jones in relation to British conceptions of Spain in the nineteenth century. Although modern scholars often view Jones’s work as an accurate visual account of the Alhambra, I argue that his work is not only interested in accuracy, but it is also a re-presentation of the fourteen-century monument based on Jones’s ideologies and creative faculties. Instead of viewing the Alhambra through a culturally sensitive, historical lens, Jones treated it as an Imaginary Geography, as Edward Said called it, through which he could promote his …

Leonard Systems And Their Friends, Jonathan Spiewak

USF Tampa Graduate Theses and Dissertations

Let $V$ be a finite-dimensional vector space over a field $\mathbb{K}$, and let

\text{End}$(V)$ be the set of all $\mathbb{K}$-linear transformations from $V$ to $V$.

A {\em Leonard system} on $V$ is a sequence

\[(\A ;\B; \lbrace E_i\rbrace_{i=0}^d; \lbrace E^*_i\rbrace_{i=0}^d),\]

where

$\A$ and $\B $ are multiplicity-free elements of \text{End}$(V)$;

$\lbrace E_i\rbrace_{i=0}^d$ and $\lbrace E^*_i\rbrace_{i=0}^d$

are orderings of the primitive idempotents of $\A $ and $\B$, respectively; and

for $0\leq i, j\leq d$, the expressions $E_i\B E_j$ and $E^*_i\A E^*_j$ are zero when $\vert i-j\vert > 1$ and

nonzero when $\vert i-j \vert = 1$.

%

Leonard systems arise in connection …

Enhancement Of Supercapacitor Energy Storage By Leakage Reduction And Electrode Modification, Tete Tevi

USF Tampa Graduate Theses and Dissertations

Supercapacitors have emerged in recent years as a promising energy storage technology. The main mechanism of energy storage is based on electrostatic separation of charges in a region at the electrode-electrolyte interface called double layer. Various electrode materials including carbon and conducting polymers have been used in supercapacitors. Also, supercapacitors offer high life cycle and high power density among electrochemical energy storage devices. Despite their interesting features, supercapacitors present some disadvantages that limit their competitivity with other storage devices in some applications. One of those drawbacks is high self-discharge or leakage. The leakage occurs when electrons cross the double layer …

Chemical Investigation Of Antarctic Marine Organisms & Their Role In Modern Drug Discovery, Jacqueline Lee Fries

USF Tampa Graduate Theses and Dissertations

The chemicals produced by biological systems, whether proteins, peptides, or terpenes, will always provide an intriguing topic for researchers. Invisibly controlling every aspect of nature, these molecules are responsible for life, evolution, and death. Specifically, here is described the secondary metabolites produced by Antarctic marine organisms as well as others, and how they are used to defend or attract other animals while potentially providing health benefits to mankind. This is done through collection, extraction, and separation of individual specimens. The respective mixtures of compounds after isolation are then analyzed via spectroscopic methods such as nuclear magnetic resonance spectroscopy, mass spectrometry, …

Label Noise Cleaning Using Support Vector Machines, Rajmadhan Ekambaram

USF Tampa Graduate Theses and Dissertations

Mislabeled examples affect the performance of supervised learning algorithms. Two novel approaches to this problem are presented in this Thesis. Both methods build on the hypothesis that the large margin and the soft margin principles of support vector machines provide the characteristics to select mislabeled examples. Extensive experimental results on several datasets support this hypothesis. The support vectors of the one-class and two-class SVM classifiers captures around 85% and 99% of the randomly generated label noise examples (10% of the training data) on two character recognition datasets. The numbers of examples that need to be reviewed can be reduced by …

Design, Synthesis And Screening Of Peptidomimetics For Anticancer And Antiviral Drug Candidates, Yi Liang

USF Tampa Graduate Theses and Dissertations

The high demand of novel peptide and peptidomimetics based on the amount of genomic and proteomic data need be matched by synthesis and screening. The design and synthesis of peptide and peptidomimetics are so important because the peptide and protein-protein interaction play a key role in molecule recognition and signaling. The modified peptides have better stability and pharmacokinetic properties which may be guided by rational design and molecular modeling. Now many organic and medicinal chemists have chosen peptide and peptidomimetics as potential drug candidates for many targets.

In this dissertation, research efforts in design and synthesis of cyclic peptides with …

Modeling Food Security, Energy, And Climate And Cultural Impacts Of A Process: The Case Study Of Shea Butter In Sub-Saharan Africa, Colleen Claire Naughton

USF Tampa Graduate Theses and Dissertations

Millions of people in the world, particularly women and people in sub-Saharan Africa, suffer from hunger and poverty. Three of the major 2015-2030 United Nation’s Sustainable Development Goals (SDGs) aim to eliminate hunger through food security and sustainable agriculture, eradicate poverty, and achieve gender equality through women’s empowerment. Shea trees and their associated fruit and butter can play a major role in each of these three SDGs for women and their families throughout sub-Saharan Africa. Shea trees are located over a wide expanse stretching more than 5,000 kilometers across over eighteen countries in sub-Saharan Africa. These trees produce fruit that …

An Investigation Of The Effects Of Chemical And Physical Weathering On Submerged Karst Surfaces, Bryan Charles Booth

USF Tampa Graduate Theses and Dissertations

Reports an investigation of the effects of chemical and physical weathering on submerged karst surfaces that pairs laboratory studies with computer modeling studies. The first study attempts to quantify the production of carbonate fines; soluble sediments produced by the incomplete dissolution of karst minerals during chemical weathering. Results show carbonate fine production in relation to dissolutional action; Chalk: 42.8%; Coquina: 2.6%; Dolomite: 3.1%; Gray Limestone: 4.8%; Ocala Limestone: 3.1%; Shell Limestone: 6.1%; Travertine: 8.6%. Due to the use of hydrochloric acid as opposed to carbonic acid these results may not be fully valid for application to natural speleogenic processes. The …

Synthesis Of Agents For The Treatment And Analysis Of Tropical Diseases, Jeanine Yacoub

USF Tampa Graduate Theses and Dissertations

Toxoplasmosis is an opportunistic disease caused by the protozoan parasite Toxoplasma gondii. The parasite is usually staved off by a healthy immune system and remains dormant in the body. In immunocompromised patients, the parasite can become active and spread throughout the body causing symptoms such as encephalitis, cognitive disorders, seizures, and death. Combination drug therapy is the usual treatment for toxoplasmosis; however, patients suffer from problems of intolerance, allergic reactions, and cytotoxicity. In an effort to identify new drug targets for toxoplasmosis, a series of compounds have been synthesized that can be used as tools to probe the unique …

Florida's Bright Futures Scholarship Program: The Effects Of Losing Merit-Based Financial Aid On Persistence, Robert Laws Liddell

USF Tampa Graduate Theses and Dissertations

College completion agendas necessarily presume year-to-year student persistence. Institutional efforts to retain admitted students has emerged for a variety of reasons, some intrinsic and others extrinsic. Some of these reasons include (1) financial exigency as institutions strive to retain tuition-paying students or meet prescribed enrollment and retention criteria currently used in performance funding strategies; (2) reputation enhancement as institutions attempt to ascend annual publications such as the U.S. News & World Report which rely on retention rates as one of several indicators used to measure institutional quality; (3) gaining a perceived advantage in admissions, marketing, and fundraising as persistence rates …

Ammonium Removal From High Strength Wastewater Using A Hybrid Ion Exchange Biological Process, Veronica Ester Aponte-Morales

USF Tampa Graduate Theses and Dissertations

Anaerobic digestion (AD) has been shown to be an effective technique for energy recovery and stabilization of livestock wastes, municipal sludges and industrial wastewaters. However, further treatment is required to remove nitrogen from AD effluents to avoid detriments to surface and ground waters. The high free ammonia (FA) concentrations present in AD effluents can inhibit nitrification processes in conventional biological nitrogen removal (BNR) systems. The overall goal of this research was to develop a process for removal of nitrogen from AD swine waste (ADSW) effluent. The proposed solution was to incorporate particulate chabazite, which has a high cation exchange capacity, …

Multiple Scales Of Beach Morphodynamic Processes: Measurements And Modelling, Jun Cheng

USF Tampa Graduate Theses and Dissertations

Multiple scales of beach morphodynamic processes ranging from those of wave-breaking induced turbulence, individual wave, storm, seasonal, to inter-annual are examined in this dissertation based on both laboratory and field data. These processes were simulated using process-based numerical models and data-driven models.

At a microscale, separating turbulence from orbital motion under breaking waves in the surf zone is essential to understanding wave-energy dissipation. Velocity data under monochromatic and random waves in the large-scale sediment transport facility (LSTF) were analyzed. Moving averaging provides a simple method for extracting turbulence from velocity measurements under random breaking waves collected at a reasonably high …

Risk And Resiliency Factors At School Entry: Relations To Academic And Behavioral Outcomes In Early Adolescence, Krystle Kuzia Preece

USF Tampa Graduate Theses and Dissertations

The purpose of this study was to examine how early academic and behavioral variables in kindergarten (i.e., academic performance, first time kindergarten status, early school-related emotional adaptation, prosocial behavior, externalizing behaviors, and internalizing behaviors) were related to academic and behavioral outcomes in eighth grade (i.e., academic performance, retention, suspension, externalizing behaviors, internalizing behaviors, and having an educational/mental health diagnosis). Archival data from the Early Childhood Longitudinal Study—Kindergarten Cohort (ECLS-K) database that included approximately 5,700 participants from across the U.S., were examined to answer three research questions: (1) How are early academic and behavioral variables related to each other among youth …

Multidimensional Waveform Shaping In Multicarrier Systems, Ertugrul Guvenkaya

USF Tampa Graduate Theses and Dissertations

Constantly increasing demand for wireless communications in various applications has always led to new ways of modulating the radio frequency (RF) carrier signal by advancing waveform structure throughout generations. Although communication data rates are limited by the theoretical capacity, specific signaling designs for the signal that experiences natural and artificial effects in the transmission medium such as multipath fading channel, hardware impairments and multiuser environment promised better solutions in providing improved wireless access to various type of users and networks. Besides communication capacity, broadcasting nature of radio signals poses the information security as another main concern in wireless communications. In …

Developing Differentiated Reading Instruction Online For Gifted Third Graders: A Design Experiment, Beth E. Jordan

USF Tampa Graduate Theses and Dissertations

The high stakes on standardized testing in the United States of America’s education system pressures teachers to ensure every child meets minimum standards. Teachers report this pressure motivates them to focus the majority of their time on struggling students. Combined with lack of training and resources, intellectually gifted students may remain under-challenged in a regular elementary classroom. To address the problem, the researcher continued the development of an online instructional environment, which teachers may use to extend and enrich the regular language arts curriculum for intellectually gifted students. The researcher conducted a formative design experiment “to create a viable theory-driven …

Neurophysiological Activity Related To Speech Production: An Erp Investigation, Adithya Chandregowda

USF Tampa Graduate Theses and Dissertations

The event related potential (ERP) technique is enjoying widespread application in neurophysiological research due to its fine temporal resolution. Of relevance to this study are ERPs related to voluntary movements. The precision with which movement related processes could be recorded using the ERP technique was demonstrated by Gilden, Vaughan and Costa (1966) and Kutas and Donchin (1974, 1977, and 1980) who found that the readiness potential (RP) immediately preceding hand movement was larger over the hemisphere contralateral to the responding hand. Given that left hemisphere controls right hand movements and vice versa, their findings confirmed that the lateralized readiness potential …

The Relationship Of Childhood Stress To Adult Health And Mortality Among Individuals From Two U.S. Documented Skeletal Collections, Late 19Th To Early 20Th Centuries, Rhonda Coolidge

USF Tampa Graduate Theses and Dissertations

Although the association between social inequality and poor adult health is well established, the mechanisms by which inequality is translated into poor adult health are less clear. Increasingly, evidence suggests that many adult health problems and health disparities have their origins in early life; the developmental origins of health and disease (DOHaD) hypothesis provides an explanatory mechanism linking adverse early life conditions with permanent structural or functional changes that increase the risk for disease. This hypothesis is consistent with bioarchaeological research noting reduced lifespan among individuals exhibiting signs of childhood stress.

The principal aim of this dissertation is to contribute …

Optical Communication Using Hybrid Micro Electro Mechanical Structures (Mems) And Commercial Corner Cube Retroreflector (Ccr), Sunny Kedia

USF Tampa Graduate Theses and Dissertations

This dissertation presents a free-space, long-range, passive optical communication system that uses electrostatically modulated microelectromechanical systems (MEMS) structures coupled with a glass total internal reflection (TIR)-type corner cube retroreflector (CCR) as a non-emitting data transmitter. A CCR consists of three mirrors orthogonal to each other, so that the incident beam is reflected back to the incident beam, source. The operational concept is to have a MEMS modulator fusion with TIR CCR, such that the modulators are working periodically to disrupt the evanescent waves at the air interface of one of the three back glass faces of a TIR CCR. The …