Digital Commons Network^™

Pollutants And Foraminiferal Assemblages In Torrecillas Lagoon: An Environmental Micropaleontology Approach, Michael Martinez-Colon

USF Tampa Graduate Theses and Dissertations

Torrecillas Lagoon in the North Coast of Puerto Rico has experienced extensive anthropogenic influence over the past 400 years. Elevated concentrations of Potential Toxic Elements (PTEs) have been reported in surficial sediments. The main goal of this dissertation was to implement in Puerto Rico the use of benthic foraminifers as a bioindicators of PTEs and to compare the impact of Cu(II) on field samples with results of experimental work using cultures.

Analyses included geochemical assessment for bulk and carbonate- soluble bioavailable concentrations of PTEs in surface, core and pore-water samples, as well as analyses of grain-size, Percent Total Organic Carbon …

Statistical Analysis And Modeling Health Data: A Longitudinal Study, Bhikhari Prasad Tharu

USF Tampa Graduate Theses and Dissertations

Lung cancer has been considered one of the leading causes of deaths while cancer re- mains the second most common cause of deaths in the USA. Understanding the behavior of a disease over time could yield important information to make decisions about the disease. Statistical models could provide crucial clues and help to make a decision about the dis- ease, budget allocation, evaluation, and implement prevention. Longitudinal trend analysis of the diseases helps to understand long term effects and nature. Cholesterol level is one of the most contributing risk factors for Coronary Heart Disease. Studying cholesterol statistically helps to know …

Alumni Narratives On Computational Geology (Spring 1997 – Fall 2013), Victor J. Ricchezza

USF Tampa Graduate Theses and Dissertations

Recent meetings and publications have discussed what geoscience undergraduates should learn for professional success, and among other items, have identified several quantitative skills and habits of mind as being necessary for geoscience students; many of these items are commonly associated with Quantitative Literacy (QL). The Computational Geology course in the geology department has been evolving at USF for 20 years. The course teaches QL in a geologic setting independent of specific core geology topics. This course has long preceded the national acknowledgment of the need for what it teaches within the field. As the first of a series of related …

Determining The Effectiveness Of Soil Treatment On Plant Stress Using Smart-Phone Cameras, Anurag Panwar

USF Tampa Graduate Theses and Dissertations

Plants are vital to the health of our biosphere, and effectively sustaining their growth is fundamental to the existence of life on this planet. A critical aspect, which decides the sustainability of plant growth is the quality of soil. All other things being fixed, the quality of soil greatly impacts the plant stress, which in turn impacts overall health. Although plant stress manifests in many ways, one of the clearest indicators are colors of the leaves. In this thesis, we conducted an experimental study in a greenhouse for detecting plant stress caused by nutrient deficienceies in soil using smartphone cameras, …

Investigating Parameter Recovery And Item Information For Triplet Multidimensional Forced Choice Measure: An Application Of The Ggum-Rank Model, Philseok Lee

USF Tampa Graduate Theses and Dissertations

To control various response biases and rater errors in noncognitive assessment, multidimensional forced choice (MFC) measures have been proposed as an alternative to single-statement Likert-type scales. Historically, MFC measures have been criticized because conventional scoring methods can lead to ipsativity problems that render scores unsuitable for inter-individual comparisons. However, with the recent advent of classical test theory and item response theory scoring methods that yield normative information, MFC measures are surging in popularity and becoming important components of personnel and educational assessment systems. This dissertation presents developments concerning a GGUM-based MFC model henceforth referred to as the GGUM-RANK. Markov Chain …

Community College Student-Athletes' Perspectives On The Transfer Process To A Four-Year Institution, Jodie Kim Heinicka Libadisos

USF Tampa Graduate Theses and Dissertations

There is a population of student-athletes who are in need of deeper understanding and additional support. Community college transfer student-athletes face different challenges than their non-athlete and non-transfer peers. Given these differences, this qualitative study was focused on understanding the experiences and perceptions of community college transfer student-athletes. More specifically, this study aimed to describe the preparation to transfer, the transfer process, and the recommendations for successful transfer as each relates to academics, athletics, and personal factors. For this qualitative study, data were collected through individual interviews, a focus group, as well as observation and reflection. Fourteen themes emerged through …

The Design And Testing Of A Novel Batch Photocatalytic Reactor And Photocatalyst, Shawn Sasser

USF Tampa Graduate Theses and Dissertations

With an ever-increasing human population, the importance in having sustainable energy resources is becoming increasingly evident, as the current energy habits have brought about massive atmospheric pollution in the form of CO₂ emissions, resulting in a rise in the average global temperature. To battle the effects of climate change, many alternative energy resources have been investigated. Among these, photocatalytic conversion of CO₂ to renewable hydrocarbon fuels such as methane and methanol is one of the most desirable, as it provides the opportunity to utilize the sun’s energy to convert CO₂ to renewable fuels. The work in this …

Statistical Modeling Of Carbon Dioxide And Cluster Analysis Of Time Dependent Information: Lag Target Time Series Clustering, Multi-Factor Time Series Clustering, And Multi-Level Time Series Clustering, Doo Young Kim

USF Tampa Graduate Theses and Dissertations

The current study consists of three major parts. Statistical modeling, the connection between statistical modeling and cluster analysis, and proposing new methods to cluster time dependent information.

First, we perform a statistical modeling of the Carbon Dioxide (CO₂) emission in South Korea in order to identify the attributable variables including interaction effects. One of the hot issues in the earth in 21st century is Global warming which is caused by the marriage between atmospheric temperature and CO₂ in the atmosphere. When we confront this global problem, we first need to verify what causes the problem then we …

Applications Of Satellite Geodesy In Environmental And Climate Change, Qian Yang

USF Tampa Graduate Theses and Dissertations

Satellite geodesy plays an important role in earth observation. This dissertation presents three applications of satellite geodesy in environmental and climate change. Three satellite geodesy techniques are used: high-precision Global Positioning System (GPS), the Gravity Recovery and Climate Experiment (GRACE) and Interferometric Synthetic Aperture Radar (InSAR). In the first study, I use coastal uplift observed by GPS to study the annual changes in mass loss of the Greenland ice sheet. The data show both spatial and temporal variations of coastal ice mass loss and suggest that a combination of warm atmospheric and oceanic condition drove these variations. In the second …

Nano-Photonic Waveguides For Chemical And Biomedical Sensing, Surya Venkatasekhar Cheemalapati

USF Tampa Graduate Theses and Dissertations

In this dissertation, advances in the fields of Photonics, and Plasmonics, and specifically, single cell analysis and waveguide sensing will be addressed. The first part of the dissertation is on Finite Difference Time Domain (FDTD) optimization and experimental demonstration of a nano-scale instrument that allows sensing at the cellular and subcellular levels. A new design of plasmonic coupler into a nanoscale waveguide is proposed and optimized using FDTD simulations. Following this, a subcellular nanoendoscope that can locally excite fluorescence in labelled cell organelles and collect the emitted fluorescent light for detailed spectrum analysis is fabricated and tested. The nanoendoscope has …

Time Dependent Kernel Density Estimation: A New Parameter Estimation Algorithm, Applications In Time Series Classification And Clustering, Xing Wang

USF Tampa Graduate Theses and Dissertations

The Time Dependent Kernel Density Estimation (TDKDE) developed by Harvey & Oryshchenko (2012) is a kernel density estimation adjusted by the Exponentially Weighted Moving Average (EWMA) weighting scheme. The Maximum Likelihood Estimation (MLE) procedure for estimating the parameters proposed by Harvey & Oryshchenko (2012) is easy to apply but has two inherent problems. In this study, we evaluate the performances of the probability density estimation in terms of the uniformity of Probability Integral Transforms (PITs) on various kernel functions combined with different preset numbers. Furthermore, we develop a new estimation algorithm which can be conducted using Artificial Neural Networks to …

An Integrative Model Of Situation Awareness, Andrew Thurston

USF Tampa Graduate Theses and Dissertations

In aviation safety incident reports, lack of situation awareness (SA) is often attributed as the cause of negative safety outcomes, such as accidents. While the predominant model of SA has identified three components of SA, perception, comprehension, and projection, assumptions of their relationships with each other and external criteria are yet tested empirically. Specifically, SA theory suggests comprehension SA fully mediates the relationship between perception and projection SA. Additionally, research on the relationships between individual differences and SA is lacking. The purpose of the current study is to test a comprehensive model of SA which simultaneously examines the described mediation, …

Gamma Aapeptides As Host Defense Peptide Mimics, Yaqiong Li

USF Tampa Graduate Theses and Dissertations

There has been increasing concern regarding the emergence of multi-drug resistant pathogens. The resistance develops when pathogens, especially bacteria, are frequently exposed to conventional antibiotics, as they are heavily used in both human and livestock. This is due to the high target specificity of conventional antibiotics, which places pathogens in high selective pressures and eventually results in drug resistant by mutations. To address this issue, global actions and cooperation are needed. At the same time, new technologies and strategies need to be developed. Host defense peptides (HDPs) are widely found in the innate immune system. They show both direct antimicrobial …

Morphodynamics Of Egmont Key At The Mouth Of Tampa Bay: West-Central Florida, Zachary James Tyler

USF Tampa Graduate Theses and Dissertations

Egmont Key, located at the mouth of Tampa Bay, is part of a dynamic system with many interrelated natural and anthropogenic factors influencing its morphodynamics. This study started in August 2012. During the 3-year period until August 2015, 28 beach profile transects were established and surveyed 10 times. Seventeen historical aerial images from 1942 to 2013 were geo-rectified and analyzed. Three hundred and fourteen sediment samples were procured from the navigation channel dredge area and the beach nourishment area and analyzed for grain size. A numerical wave model was established to simulate the nearshore wave field. The overall goals of …

Stoicism In Descartes, Pascal, And Spinoza: Examining Neostoicism’S Influence In The Seventeenth Century, Daniel Collette

USF Tampa Graduate Theses and Dissertations

My dissertation focuses on the moral philosophy of Descartes, Pascal, and Spinoza in the context of the revival of Stoicism within the seventeenth century. There are many misinterpretations about early modern ethical theories due to a lack of proper awareness of Stoicism in the early modern period. My project rectifies this by highlighting understated Stoic themes in these early modern texts that offer new clarity to their morality. Although these three philosophers hold very different metaphysical commitments, each embraces a different aspect of Stoicism, letting it influence but not define his work. By addressing the Stoic themes on the morality …

Predictors Of Adult Community College Students' Intent To Transfer From The Community College With The Associate In Science, Associate In Applied Science, Or Associate In Arts Degree To A Public University In Florida, Anthony Gemart Hill

USF Tampa Graduate Theses and Dissertations

The purpose of this study was to examine the predictors and pre-transfer navigation experiences of community college students enrolled in Associate of Arts (AA), Associate in Science (AS), or Associate in Applied Science (AAS) degrees with transfer intent to Florida’s public universities. The population included adult students aged 26 and above enrolled in Florida state/community college AA, AS, or AAS programs. One hundred and seventy-five students from two community colleges participated in this study with a response rate of 10%. The valid data set included 101 respondents, AA (n =17), AS (n =76), AAS (n =4), other …

Chiral Boro-Phosphates In Asymmetric Catalysis: 1,4-Reduction Of Enones And Reductive Aldol, Susana Sorina Lopez

USF Tampa Graduate Theses and Dissertations

The biological activity of the pharmaceutical drugs often depends on how it fits with a receptor making stereochemistry a key component. Selective reactions can limit or avoid the mixture of enantiomers obtained. One such reaction is the selective reduction of a carbon-carbon double bond in the presence of a carbonyl. Although efficient, current asymmetric synthesis methods have limitations such as harsh reaction conditions, the high costs of chiral catalysts and the toxicity of the metal-based catalysts. Catalysts derived from small organic molecules have become an attractive alternative which have been explored more rigorously in recent years. Using a BINOL-derived boro-phosphate …

Renewable Energy Investment Planning And Policy Design, Alireza Ghalebani

USF Tampa Graduate Theses and Dissertations

In this dissertation, we leverage predictive and prescriptive analytics to develop decision support systems to promote the use of renewable energy in society. Since electricity from renewable energy sources is still relatively expensive, there are variety of financial incentive programs available in different regions. Our research focuses on financial incentive programs and tackles two main problem: 1) how to optimally design and control hybrid renewable energy systems for residential and commercial buildings given the capacity based and performance based incentives, and 2) how to develop a model-based system for policy makers for designing optimal financial incentive programs to promote investment …

Leibniz's More Fundamental Ontology: From Overshadowed Individuals To Metaphysical Atoms, Marin Lucio Mare

USF Tampa Graduate Theses and Dissertations

I aim to offer an innovative interpretation of Leibniz’s philosophy, first by examining how the various views that make up his ontology of individual substance involve a persistent rejection of atomism in natural philosophy and secondly, by exploring the significance of this rejection in the larger context of Seventeenth-century physics. My thesis is structured as a developmental story, each chapter analyzing the discontinuities or changes Leibniz makes to his views on individuation and atomism from his early to late years. The goal is to illuminate underrepresented views on individuals and atoms throughout Leibniz’s works and thus bring a clearer understanding …

Assessing Property Value Impacts Of Access To Bus Rapid Transit (Brt): Case Study Of The Cleveland Healthline, Victoria A. Perk

USF Tampa Graduate Theses and Dissertations

The nation’s economy depends heavily on mobility of goods and people. As communities look to improve mobility, many options can be considered, including roadway improvements, congestion-pricing options such as dynamic tolling and toll lanes, and public transit. Investment in public transit services can come in the form of increased and enhanced bus services, including bus rapid transit (BRT), as well as rail transit investments. As BRT continues to grow in popularity in the United States, a better understanding of the mode’s impacts on land uses and economic development is needed. One method of assessing the mode’s impacts is by examining …

The Role Of Social Ties In Dynamic Networks, Xiang Zuo

USF Tampa Graduate Theses and Dissertations

Social networks are everywhere, from face-to-face activities to online social networks such as Flickr, YouTube and Facebook. In social networks, ties (relationships) are connections between people. The change of social relationships over time consequently leads to the evolution of the social network structure. At the same time, ties serve as carriers to transfer pieces of information from one person to another.

Studying social ties is critical to understanding the fundamental processes behind the network. Although many studies on social networks have been carried out over the last many decades, most of the work either used small in-lab datasets, or focused …

“It’S Not Pixie Dust”: An Exploratory Qualitative Case Study Of A School-Based Multimodal Tablet Initiative, Erin Elizabeth Margarella

USF Tampa Graduate Theses and Dissertations

This dissertation presents findings from a qualitative case study of three English teachers representing varying levels of comfort with technology and years of teaching experience at St. Patrick Catholic High School. This research was motivated by two questions: (1) What are three literacy educators’ perceptions of a multimodal tablet initiative at a Catholic High School? (2) How is information regarding the use of iPad technology for literacy disseminated to three High School English teachers within a Catholic School system? Data was collected over a twelve-week period during the first academic year of implementation of a school-based multimodal tablet (iPad) initiative. …

Mining Dynamic Recurrences In Nonlinear And Nonstationary Systems For Feature Extraction, Process Monitoring And Fault Diagnosis, Yun Chen

USF Tampa Graduate Theses and Dissertations

Real-time sensing brings the proliferation of big data that contains rich information of complex systems. It is well known that real-world systems show high levels of nonlinear and nonstationary behaviors in the presence of extraneous noise. This brings significant challenges for human experts to visually inspect the integrity and performance of complex systems from the collected data. My research goal is to develop innovative methodologies for modeling and optimizing complex systems, and create enabling technologies for real-world applications. Specifically, my research focuses on Mining Dynamic Recurrences in Nonlinear and Nonstationary Systems for Feature Extraction, Process Monitoring and Fault Diagnosis. …

Design Exploration And Application Of Reversible Circuits In Emerging Technologies, Saurabh Kotiyal

USF Tampa Graduate Theses and Dissertations

The reversible logic has promising applications in emerging computing paradigms, such as quantum computing, quantum dot cellular automata, optical computing, etc. In reversible logic gates, there is a unique one-to-one mapping between the inputs and outputs. To generate a useful gate function, the reversible gates require some constant ancillary inputs called ancilla inputs. Also to maintain the reversibility of the circuits some additional unused outputs are required that are referred to as the garbage outputs. The number of ancilla inputs, the number of garbage outputs and quantum cost plays an important role in the evaluation of reversible circuits. Thus minimizing …

Motivation For Mathematics: The Development And Initial Validation Of An Abbreviated Instrument, Kenneth Lee Butler

USF Tampa Graduate Theses and Dissertations

This study outlines the development and initial validation of an abbreviated instrument intended to measure motivation for mathematics of university students in developmental algebra courses. I look across many of the predominant theories on motivation with the aim of representing several of these theories as latent constructs in a single instrument that is short enough to be administered in a reasonable amount of time, but inclusive enough that it could incorporate subscales representing multiple distinct latent factors. This study answers a call by researchers expressing a need to investigate relationships between disparate theories on motivation and is a response to …

Exploring The Relationship Between Severity Of Illness And Human Milk Volume In Very Low Birth Weight And Extremely Low Birth Weight Infants Over Six Weeks, Shannon Leigh Morse

USF Tampa Graduate Theses and Dissertations

Very low birth weight and extremely low birth weight neonates have tremendous risk of mortality. This is a grave concern; however, survival alone is not the goal of neonatal intensive care. Survival, along with a reduction or elimination of life long morbidity is the aim of neonatal intensive care.

Human milk is known as the best nutrition for babies and a growing body of evidence supports that human milk is critical in helping these fragile neonates mitigate the overwhelming risks they face. Therefore, the purpose of this study was to examine the relationship between neonatal severity of illness and human …

Co(Ii)-Based Metalloradical Catalysis For Asymmetric Radical Cyclopropanation, Qigan Cheng

USF Tampa Graduate Theses and Dissertations

Metal-catalyzed cyclopropanation of olefins with diazo reagents is one of the most general and efficient method to prepare cyclopropanes. The resulting cyclopropyl units are found as a basic structural element in a wide range of naturally occurring compounds and biologically active compounds, and can serve as versatile synthetic intermediates in the synthesis of multifunctionalized cycloalkanes and acyclic compounds. Since Co(II) complexes of D₂-symmetric chiral amidoporphyrins [Co(D₂-Por*)] were first introduced in 2004, Co(II)-metalloradical catalysis (MRC) have emerged as a new platform for asymmetric cyclopropanation. These metalloradical catalysts have been shown to be highly effective for asymmetric intermolecular …

The Use Of Synthetic Mixture Based Libraries To Identify Hit Compounds For Eskape Pathogens, Leishmaniasis, And Inhibitors Of Palmitoylation, Marcello Giulianotti

USF Tampa Graduate Theses and Dissertations

The goal of this work is to demonstrate the utility of using systematically formatted mixture based libraries as part of the drug discovery processes. While there are a number of different valid approaches for identifying hit and tool compounds, systematically formatted mixture based libraries, such as those described in this study, offer the ability to develop a significant amount of structure activity relationship data from the testing of very few samples. In support of this claim a review of recent developments in the area of systematically formatted mixture based libraries as well as three case studies are presented. The three …

Evaluation Of Pulmonary Function Among Workers Engaged In The Manufacture Of Hydraulic Fracking Ceramic Proppant, Humairat H. Rahman

USF Tampa Graduate Theses and Dissertations

Workers involved in hydraulic fracking processes are exposed to various types of chemicals and dusts in their workplaces, such as proppants, which hold open the fissures created in the fracking process. Recently, ceramic proppants have been developed that may be less hazardous to workers than traditional proppants. Pulmonary function testing of workers producing ceramic proppant was used to assess the potential inhalation hazards of ceramic proppant. Male workers (n = 100) from a producer of ceramic proppant were evaluated with pulmonary function test data collected and evaluated using The American Thoracic Society (ATS) acceptability criteria. A comparison group was selected …

Reflections On Global Competence By Four Design Educators, Philip A. Bulone

USF Tampa Graduate Theses and Dissertations

This inquiry investigated four design educators’ perspectives and beliefs of global competence teaching and learning, and aimed to inform effective global competence curricula planning and instruction across disciplines. The literature uncovered multiple reasons to warrant design educator reflections: (a) similarities among global competence and design thinking characteristics, (b) design education accreditation emphasis on globally oriented standards, and (c) design thinking as a resource to improve practices across disciplines. Accordingly, the inquiry employed a qualitative design and a multiple case-study approach. Data collection methods included: (a) interviews, (b) image artifacts, and (c) researcher reflective memos. A comparative analysis used systematic coding …