Digital Commons Network^™

Generation Of Carbon Dioxide And Mobilization Of Antimony Trioxide By Fungal Decomposition Of Building Materials, John D. Krause

USF Tampa Graduate Theses and Dissertations

Fungal contamination of buildings poses numerous challenges to researchers, building owners and occupants. Public health agencies promote prevention and remediation of mold and water damage, but lack sensitive methods to detect hidden mold growth and a complete understanding of the biological mechanisms that make occupying moldy buildings a hazard. The wide spread use of the fire retardant antimony trioxide (Sb₂O₃) on building materials and furnishings makes it inevitable that mold growth on treated materials will occur in some buildings with water damage. Several authors have speculation that microbial growth on materials treated with antimony trioxide could …

Effect Of Chromium Vi On The Production And Behavior Of Lytechinus Variegatus (Echinodermata: Echiniodea), Jennifer Rhora

USF Tampa Graduate Theses and Dissertations

Small amounts of chromium (VI) are carcinogenic in mammals. Concentrations of Cr in marine algae and seagrasses range from 0.06-7.17 /g DW and 0.1-30.6 g/g DW respectively. To test for an effect of these concentrations, production (change in organic material), righting response, feeding rates, absorption efficiency and fecal production were measured in Lytechinus variegatus from Sarasota fed prepared diets containing 0, 4.1, and 32g Cr/ g DW and individuals from Ft. DeSoto fed diets containing 0, 41 and 82g Cr/ g DW. The urchins were fed for 4-5 weeks, with weekly measurements of their feeding rates, absorption efficiency and fecal …

Seasonal And Spatial Trends Of Karenia Brevis Blooms And Associated Parameters Along The 10-Meter Isobath Of The West Florida Shelf, Elizabeth Singh

USF Tampa Graduate Theses and Dissertations

Karenia brevis is a toxic marine dinoflagellate species that blooms almost every year in the Gulf of Mexico. These blooms have had devastating effects on local economies, as well as on the fauna of the area. The ECOHAB:Florida project was founded to study the population dynamics and trophic impacts of K. brevis. The project included a series of monthly hydrographic offshore research cruises, as well as monthly surveys of a transect along the 10-meter isobath of the West Florida Shelf. This study focused on data from the alongshore transect over a three-year period (1999-2001). Physical parameters (temperature, salinity, and …

Bottom-Up And Top-Down Effects On Insects Herbivores Along A Natural Salinity Gradient In A Florida Salt Marsh, Maria Teresa Albarracin

USF Tampa Graduate Theses and Dissertations

I compared the strength of bottom- up and top-down effects on insect herbivores along a natural salinity gradient in salt marsh communities in West - Central, Florida. I used a 2x2 factorial design with plots divided into four different treatments: 1) fertilizer applied to increase plant quality 2) sticky traps added to remove natural enemies (parasitoids) 3) fertilizer applied and sticky traps added and 4) control plots. These plots were placed on 7 different sites containing the salt marsh plant Borrichia frutescens along a natural stress salinity gradient. In each plot I determined the abundance of the sap sucker Pissonotus …

An Investigation Of Tio2-Znfe2O4 Nanocomposites For Visible Light Photocatalysis, Jeremy Wade

USF Tampa Graduate Theses and Dissertations

Environmental pollution on a global scale is expected to be the greatest problem that chemical scientists will face in the 21st century, and an increasing number of these scientists are looking to new photocatalytic systems for the solution. Existing photocatalytic systems are effective for the decomposition of many unwanted organics through the use of efficient semiconductor photocatalysts activated by ultra-violet (UV) irradiation. The demand for visible light activated photocatalytic systems is increasing rapidly. Currently, however, the efficiency and availability of photocatalysts which can be activated effectively by the solar spectrum and especially indoor lighting is severely limited.

The purpose of …

Development And Characterization Of Carbon Nanotubes For Sensor Applications, Jessica Eileen Otto

USF Tampa Graduate Theses and Dissertations

The aim of this research was to develop, characterize, and analyze carbon nanotubes as biosensors. In particular, pH and lactate molecules were targeted in this study. The reason these analytes were chosen was twofold. Firstly, when hydrogen ions and lactate are excreted in abnormal amounts in human sweat, they may be an indicator of a separate health problem. Thus, there is a clinical need for such biosensor applications. Secondly, pH and lactate detection represent two different types of electrochemical sensing techniques.

The carbon nanotubes used in this research were single walled and existed in bundles. They were further functionalized with …

Neurochemical Analysis Of Cocaine In Adolescence And Adulthood, Kirstie Helen Stansfield

USF Tampa Graduate Theses and Dissertations

Adolescence is a time of high risk behavior and increased exploration. This developmental period is marked by a greater probability to initiate drug use and is associated with an increased risk to develop addiction and dependency in adulthood. Human adolescents are predisposed toward an increased likelihood of risk taking behaviors (Zuckerman M, 1986), including drug use or initiation. The purpose of this study was to examine differences in developmental risk taking behaviors and neurochemical responsivity to cocaine based on these behavioral characteristics. Adolescent and adult animals were exposed to a novel stimulus in a familiar environment to assess impulsivity, novelty …

The Impact Of Structural Adjustment On Health, Education And Employment: A Case Study On Sierra Leone, Rashida Strober

USF Tampa Graduate Theses and Dissertations

Since their inception in African countries, structural adjustment has tended to cause more harm than help. This thesis aims to answer the question, in what ways have structural adjustment policies impacted Africa in general and Sierra Leone in particular? This question is highly relevant when it is considered that Africa is one of the poorest regions in the world and has experiences much conflict and suffering. In addition, much is known about the impact of structural adjustment in many African countries. However, little has been written on the impact of structural adjustment in Sierra Leone, especially in terms of the …

County Level Predictors Of Homicide And Suicide In The State Of Florida, Kelly K. Browning

USF Tampa Graduate Theses and Dissertations

The present study expands the range of theoretical perspectives and empirical questions that have occupied the recent literature on homicide and suicide. The study examines county-level predictors for homicide and suicide in all sixty-seven counties in Florida. The current examination identifies which county-level variables are most closely related to each other, which variables explain the greatest amount of differences within the Florida counties, as well as which variables are most significantly correlated with the homicide and sucide rate by county. Additionally, the variables included in the present research are driven by the theorectical perspectives of social disorganization and anomie/strain theory. …

The Effects Of A Parent Intervention On The Phonological Awareness Skills Of Kindergarten Students, Andrea Ofiara

USF Tampa Graduate Theses and Dissertations

This study examined the efficacy of the Sound Foundations program, implemented by parents, for increasing phonological awareness (PA). Three kindergarten students identified with PA deficits and their mothers served as participants. Parents implemented Sound Foundations twice per week for five and a half weeks. The effects of the intervention were evaluated using a multiple baseline across participants design. PA was measured using the Phoneme Segmentation Fluency measure of the Dynamic Indicators of Basic Early Literacy Skills. Results showed that two students showed increases over time in phonemes per minute after the parent intervention. A third student did not show substantial …

The Effects Of The Presence Of A Dog On The Social Interactions Of Children With Developmental Disabilities, Stephanie Walters

USF Tampa Graduate Theses and Dissertations

The effects of the presence of a dog on the social interactions between children with developmental disabilities and their teacher were analyzed in this study. We examined whether the presentation of a dog would improve the social interactions of three children with developmental disabilities. A baseline condition consisting of the child and teacher in the presence of three toys, one of which was a toy dog was followed by an intervention in which a real dog was added to the sessions. A multiple baseline design across participants was employed to assess experimental changes in interactions during the intervention condition.

All …

Giving Voice To Parents Of Young Children With Challenging Behavior, Jonathan Worcester

USF Tampa Graduate Theses and Dissertations

In recent years, there has been increased interest in the science of child development, particularly relative to early childhood (i.e., birth to 5 years) and children with challenging behavior. A broad interest in brain-behavior relationships and prevention services for young children has led to a renewed interest in the developmental significance of early life experiences (National Research Council and Institute of Medicine, 2000). Armed with an increasingly large body of neuroscience research, researchers have begun to examine the efficacy of prevention services and supports for young children and families, particularly those with challenging behavior (i.e., behaviors that interfere with optimal …

Loving Loving? Problematizing Pedagogies Of Care And Chéla Sandoval’S Love As A Hermeneutic, Allison Brimmer

USF Tampa Graduate Theses and Dissertations

My thesis project is an argument for and an investigation into the complex dynamics of what I term a critical, feminist, anti-racist pedagogy. Drawing from scholarly work in the fields of feminist theory, cultural studies, whiteness studies, and rhetoric and composition, in what follows I argue for a “blurring” of the traditional reason-emotion split that, I believe, continues to stifle learners in today’s U.S. educational system. I then offer a pedagogical theory that rejects or “blurs” this split, acknowledges and examines the affective realm, and is fueled by the more holistic notion and theory of “love as a hermeneutic” put …

School-Based Mental Health Services Delivered By School Psychologists, Emily Luis

USF Tampa Graduate Theses and Dissertations

This study involved analyses of an existing database conducted for the purposes of identifying and understanding factors that are associated with the delivery of school-based mental health services by school psychologists. The study examined the average number of hours per week in which school psychologists engage in mental health services and the types of mental health services in which they engage. Factors such as training, desire to deliver mental health services, time available and support for mental health services were investigated. The database that served as the basis for these analyses had been created by mailing a survey to 1000 …

Racial Disparities In Breast Cancer Surgical Treatment And Radiation Therapy Use, Tracey Lynn Koehlmoos

USF Tampa Graduate Theses and Dissertations

This study explores the relationship between race and surgical treatment and radiation therapy use for localized breast cancer patients in the state of Florida in 2001. The study will be useful in raising awareness of the relationship between Black race and appropriate breast cancer treatment within the Florida Cancer Data System. The Healthy People 2010 initiatives call to eliminate racial disparities and the high placement of breast cancer on the national research agenda make this study timely and insightful for health policymakers, clinicians and other health researchers. Also, the study evaluates the effect of other health system and patient related …

Supercritical Carbon Dioxide Aided Preparation Of Nickel Oxide/Alumina Aerogel Catalyst, Haitao Li

USF Tampa Graduate Theses and Dissertations

The strength, thermal stability, pore structure and morphology are keys to success for wider deployment of aerogels. Furthermore, co or subsequent functionalization of the surfaces are equally, if not more important. This study addresses these issues through a new method. The path involves successful use of surfactant templating, supercritical extraction and drying, and supercritical fluid aided functionalization of the surface. Alumina support and alumina supported nickel catalyst particles are used to evaluate the approach. Initially thermally stable surfactant alumina was synthesized. The surfactant template was removed completely with the aid of a supercritical solvent mixture. Surfactant-templated alumina aerogel showed remarkable …

Voices From A Marginalized Population: Life Histories Of Individuals With Physical Impairments, James Peter Marsh

USF Tampa Graduate Theses and Dissertations

Individuals with physical impairments have been marginalized and discriminated against since the social identification of these individuals occurred as a sub-group within society. While much has been done to resolve prejudice against individuals with physical impairments, more needs to be done to decrease, or at least deter, discrimination and prejudice against individuals who have been marginalized. The purpose of this study is to give four individuals with physical impairments the opportunity to tell their stories. Through the telling of these stories, I believe others can identify with these individuals, and thereby, help decrease discrimination against individuals with physical impairments.

Life …

The Impact Of Victim-Offender Familial Relationships On Capital Sentencing Outcomes, Katharine D. Evans

USF Tampa Graduate Theses and Dissertations

This study is an investigation of whether familial relationships among offenders and their victims affect capital sentencing. Using a sample of capital cases from North Carolina restricted to familial homicides, logistic regression models are used while controlling for legal and extra-legal factors that influence decision outcomes. Such models of capital sentencing are developed to (1) determine whether familial-victim cases have unique correlates; and (2) whether there are variations in the effects of these correlates across gender. Contradictory to these hypotheses, results suggest that acquaintance and stranger relationships are less likely to receive a capital outcome when compared to familial relationships. …

High Resistivity Zinc Stannate As A Buffer Layer In Cds/Cdte Solar Cells, Sudhakar R. Gayam

USF Tampa Graduate Theses and Dissertations

The electrical conductivity of transparent conducting oxides is well exploited in front surface electrodes for solar cells where high transmission is also important. Fluorine doped tin oxide (SnO₂: F) is the most popular choice of front contacts for CdTe solar cells. In this thesis, Cd₂SnO₄ and Zn₂SnO₄ thin films are investigated focusing on their electrical and optical properties and used them in solar cells. Processing for these materials is optimized for optimum solar cell performance.

Cd₂SnO₄ thin films are deposited by co-sputtering of CdO and SnO₂ targets in …

Self-Guided Micro Vehicle: An Autonomous Vehicle With Gps Navigation And 802.11b Communications, Roberto J. Guerra

USF Tampa Graduate Theses and Dissertations

To facilitate the learning of automatic navigation systems by engineering students an easy to obtain platform is useful. The topic of this thesis is the design and implementation of a basic self-guided vehicle that can be programmed and expanded by anyone possessing basic experience with the C programming language. The Self-Guided Micro Vehicle, (SGMV), uses off-the-shelf easy to obtain parts such as a toy R/C truck and the Handyboard to maximize availability of this technology to students.

This thesis divides the SGMV design process by functionality. It starts by documenting the locomotion system, which was a modified R/C toy truck. …

Opportunistic Maintenance Policy Of A Multi-Unit System Under Transient State, Sulabh Jain

USF Tampa Graduate Theses and Dissertations

Most modern systems are equipped with very complex, expensive, and high technology components whose maintenance costs have become an increasingly large portion of the total operating cost of these systems. Thus, the efficacy of the maintenance policy for these and related systems has become a major concern to both manufacturing and design engineers. Different kinds of maintenance strategies have been proposed to solve the problem. While some of these have proven effective, there is yet no definitive approach that has been found that support the maintainability requirements of transient systems or systems that exhibit transient behavior. Transient behavior is the …

Re-Engineering Graduate Medical Education: An Analysis Of The Contribution Of Residents To Teaching Hospitals Utilizing A Model Of An Internal Medicine Residency Program, Ian M. Elius

USF Tampa Graduate Theses and Dissertations

According to the Institute of Medicine (IOM), the U.S. health care delivery system does not provide consistent, high-quality medical care to all people all the time. As a significant component of the health care delivery system, the state of Graduate Medical Education in the United States has prompted much analysis in recent years due to the general view that desired and actua l outcomes are increasingly at variance with each other. One area of focus has been the implications of change for provider credentialing and funding of graduate medical education.

With this research we test the hypothesis that residents perform …

An Integrated Optimal Design Method For Utility Power Distribution Systems, Ralph E. Fehr

USF Tampa Graduate Theses and Dissertations

This dissertation presents a comprehensive and integrated design methodology to optimize both the electrical and the economic performance of a utility power distribution system. The proposal is structured to facilitate its adoption and incorporation into the existing utility infrastructure by allowing the various portions of the new design to be implemented gradually into the existing infrastructure without the need to abandon the portions of the existing system that are performing satisfactorily.

The topology of the substation plays a vital role in determining both the reliability and the economy of the distribution system. The ring bus topology is offered as the …

Hope And Quality Of Life In Hospice Patients With Cancer, Cynthia Brown

USF Tampa Graduate Theses and Dissertations

Hope is considered to have a positive influence upon health. Cancer patients may enter hospice care after a rigorous course of medical treatment, having hoped for a cure or long remission. While the hope for cure is important, hope is no less important at the end of life when the goal of care is quality of life. This study examined the relationship between hope and quality of life in hospice patients with cancer.

Thirty-one patients with cancer, who were alert, oriented, living with a caregiver, and aware of their diagnosis were sampled from a hospice program. The instruments used were …

The Relationship Between Caregiving And Bereavement: A Series Of Three Studies, Allison Burton

USF Tampa Graduate Theses and Dissertations

Spousal bereavement has been consistently demonstrated in the literature to be one of the most highly stressful experiences in an individual’s lifetime. In addition many deaths in the United States are preceded by a period of caregiving, which is also believed to be highly stressful and have a profound impact on bereavement. However the literature has been inconsistent as to the exact nature of the relationship between caregiving and bereavement and there has been some debate as to whether or not positive and negative affect variables are mutually exclusive.

This dissertation sought to further address the issue of the relationship …

The Impact Of Privatization Of Primary Care Programs In Large County Health Departments In Florida, Arlesia Lynn Brock

USF Tampa Graduate Theses and Dissertations

Since the mid-1970s, top managers, politicians, and officials in both public and private institutions have promoted contracting-out services (privatization) as a means of increasing efficiency, flexibility, and quality. The privatization trend has occurred in many public sector organizations particularly in city services and prisons. Public health services are not immune to this trend. Today many county health departments have contracted the provision of public health services like womens health, primary care, and laboratory services. However, very few studies have analyzed the impact of these privatizations on cost, access, and health outcomes. Proponents favoring the private provision of these services argue …

The Assessment Of Appearance Factors Related To Intentional Uv Exposure, Guy Cafri

USF Tampa Graduate Theses and Dissertations

Understanding the motives for sunbathing and indoor tanning is an extremely important public health issue. Skin cancer rates have increased dramatically in recent years and UV exposure via sunbathing and utilization of sun lamps and tanning beds are considered important risk factors. Motives for sunbathing and tanning salon use have been thought to be related to appearance concerns, yet little research has examined the specific tan appearance attitudes that may contribute to use of these behaviors. Two studies were conducted with the aim of assessing distinct attitudes related to a tan appearance. In the first study items were created based …

Distribution Of Clionid Sponges In The Florida Keys National Marine Sanctuary (Fknms), 2001-2003, Michael K. Callahan

USF Tampa Graduate Theses and Dissertations

In 2001, the Coral Reef Evaluation and Monitoring Program (CREMP) began monitoring the abundance and area covered by three clionid sponges (Cliona delitrix, C. lampa, and C. caribbaea). Subsequently, monitoring has been conducted annually at all 40 CREMP sites throughout the Florida Keys National Marine Sanctuary (FKNMS) and the Dry Tortugas. Between 2001 and 2002, mean clionid area decreased significantly from 7.6 cm2 /m2 to 4.6 cm2 /m2 (Wilcoxon; p= 0.035). Between 2002 and 2003, the decline to 4.5 cm2 /m2 was not significant. Approximately 80% of all clionid colonies recorded at the CREMP stations covered less than 50 cm2 …

Mapping The Major Axis Of Tephra Dispersion With A Mesoscale Atmospheric Model: Cerro Negro Volcano, Nicaragua, Marc A. Byrne

USF Tampa Graduate Theses and Dissertations

Models of tephra fallout are used to assess volcanic hazards in advance of eruptions and in near-real-time. Current models often approximate the wind field using simplistic assumptions of the atmosphere that cannot account for typical variations in wind velocity that occur in time and three-dimensional space. Here, a widely used mesoscale atmospheric model is used to improve forecasts of the location of the major axis of dispersion for erupting plumes. The Pennsylvania State University-National Center for Atmospheric Research fifth-generation Mesoscale Model (MM5) specializes in atmospheric prediction for regions on the order of ten to hundreds of kilometers on a side. …

Eros, Paideia And Arête: The Lesson Of Plato’S Symposium, Jason St. John Oliver Campbell

USF Tampa Graduate Theses and Dissertations

Commentators of Plato’s Symposium rarely recognize the importance of traditional Greek conceptions of Eros, paideia and arête in understanding Plato’s critique of the various educational models presented in the dialogue. I will show how Plato contests these models by proposing that education should consist of philosophy. On this interpretation, ancient Greek pedagogy culminates in a philosophical education. For this new form of education, the dialogical model supplants the traditional practices of kléos and poetic mimēsis, inextricably bound to archaia paideia and traditional forms of education. Plato’s Socrates is searching for knowledge and immortality through an application of the philosophical method, …