Digital Commons Network^™

Device Physics Of Solution Processable Solar Cells, Jason Erik Lewis

USF Tampa Graduate Theses and Dissertations

This Ph.D work reports the studies of photovoltaic devices produced by solution processable methods. Two material systems are of interest: one is based on organic semiconductors, and another on organic/inorganic hybrid composites. Specifically, organic photovoltaic (OPV) devices are made using photoactive materials consisted of a p-conjugated polymer [Poly(3-hexylthiophene), or P3HT] and fullerene derivative [phenyl-C60-butric acid methyl ester, or PCBM] in a bulk heterojunction (BHJ) structure of donor/acceptor network. On the other hand, hybrid photovoltaic (HPV) devices are made from blend of quantum dots and p-conjugated polymers. The QD material presented here are of the lead sulfide (PbS), and lead selenide …

Performance Assessment Of Predicted Heat Strain In High Heat Stress, Ronald Eugene Long

USF Tampa Graduate Theses and Dissertations

Heat stress is a common physical agent associated with many occupations. The most commonly used method of assessing heat stress exposure is an empirical method using the Wet Bulb Globe Temperature Index but his method is limited in its ability to parse out individual contributors to the heat stress. The International Organization for Standardization (ISO) published a rational model called Predicted Heat Strain (PHS) in 2004, and rational methods have the advantage of separating out the individual pathways for heat exchange. The objective of this research was a performance assessment of the current PHS model. This experimental design consisted of …

Assessing Relational Networks: An Evaluation Of Derived Relational Responding With Children With Asd And Typically Developing Children, Gianna Delayce Lozano

USF Tampa Graduate Theses and Dissertations

The way in which humans engage in conversation and social interactions is largely due to their ability to form relationships between a wide variety of stimuli. Two people are able to communicate fluently and effectively because each has the capacity to derive meaning during social interactions. Forming relationships is an effortless process that humans engage in daily, however for those individuals with developmental disabilities, the ability to form relationships between various stimuli based on arbitrary properties does not appear to happen in the natural course of development. The purpose of this study was to assess the ability of children to …

The Search For The Missing Mantles Of Differentiated Asteroids: Evidence From Taxonomic A-Class Asteroids And Olivine-Dominated Achondrite Meteorites, Michael Peter Lucas

USF Tampa Graduate Theses and Dissertations

The apparent rarity of taxonomic A-class asteroids poses a significant paradox for understanding asteroid differentiation and the dynamical evolution of the early solar system. Based on results from asteroid taxonomic surveys, and on the abundances and mineralogy of different achondrite meteorites, it appears that olivine-dominated mantle remnants are missing from both the asteroid population and in meteorite collections. Several scenarios to explain this paradox have been proposed: (1) olivine mantle material has been stripped away by collisions and only remains as small fragments (< ~5 km), (2) A-class asteroids are abundant but have been altered in some way masking their presence, or (3) differentiated asteroids did not form thick olivine-rich mantles.

We have approached these questions through the collection of taxonomic and observational data on known A-class …

Saved By The (Alexander Graham) Bell: An Analysis Of Synchronous Communication And Student Satisfaction / Retention Rates In The First Year Online Composition Classroom, Jennifer Jane Lynch

USF Tampa Graduate Theses and Dissertations

Online first-year writing courses, with all of their promise, still maintain alarmingly low retention and student satisfaction rates, driving online curriculum designers to take another look at ways to increase both retention and satisfaction. To replicate the high rates of face-to-face classes, we must revisit and revise our approach to communication in the first-year writing online classroom. Think about it: The online classroom has abandoned a mainstay in education for thousands of years - synchronous communication. Why have we been so quick to dispose of it? Are we now paying the price?

This research will provide additional value to the …

Crystal Engineering Of Pharmaceutical Cocrystals, Sreya Mukherjee

USF Tampa Graduate Theses and Dissertations

Pharmaceutical cocrystals use principles of crystal engineering for the design of crystalline forms of drugs and can improve their solubility, bioavailability, stability and other important properties without changing the efficacy of the drug. Herein reported are pharmaceutical cocrystals of two API's, caffeine and Pentoxifylline.

Research has indicated that caffeine has the ability to reverse AB; plaque deposition in the brain (believed to be the primary cause of Alzheimer's pathogenesis) and thus revert memory and improve cognitive impairment. But owing to the fast absorption rate and short half life, a controlled release formulation of caffeine would be clinically beneficial. Thus, novel …

Guided By The Spirit: Understanding Student Behavior And Theological Philosophy Through The Lens Of Secondary Catholic School Teachers, Angela Marie Mucci

USF Tampa Graduate Theses and Dissertations

The purpose of this study was to examine how secondary Catholic school teachers perceived problem behavior exhibited by students with or without disabilities based on their theological philosophy. Using the methods identified in grounded theory, seven secondary Catholic school teachers were interviewed to gain an understanding of the extent to which a theological philosophy was reflected in their perceptions, responses, and policies towards behavior challenges/problems. In order to conceptualize and contextualize the notion of a "theological philosophy," this study utilized three tenets of Catholic Social Teaching (dignity of the human person, common good, and preferential option for the poor and …

Numeracy, Cancer Risk Perceptions, And Self-Protective Behaviors Among U.S. Adults, Teri Malo

USF Tampa Graduate Theses and Dissertations

Individuals have become more involved in health-related decisions, in part due to an unprecedented access to information that can be used to enhance both physical and mental health. Much of this health-related information is presented in a numerical format; unfortunately, research suggests many Americans may not possess the literacy skills necessary to comprehend numerical health-related information. More research needs to be conducted to examine numeracy and its role in cancer risk perceptions, and how those risk perceptions relate to cancer self-protective behaviors. The purpose of the current study was to: (a) examine socio-demographic variables associated with numeracy, (b) determine which …

Framing 10/12 And 3/11 In American And European News, Andrea Lypka

USF Tampa Graduate Theses and Dissertations

This media analysis of the incidents in Bali in 2002 (10/12) and Madrid in 2004 (3/11) reveals the black and white portrayal of these attacks in western news through the localization of international terrorism occurrences, pro-government perspective, and internalization of U.S. policies. The Old Europe and New Europe debate further fractures the European press. Such rhetoric perpetuates the "us versus them" schism by contrasting the goals of the alleged perpetrators with the western values of democracy and freedom. Governmental sources remain central news sources during these crises. In addition, 9/11, war on terrorism, and fear from further attacks dominate news …

The Role Of Microvascular Complications In The Relationship Between Glycemic Control And Depressive Symptomatology In Patients With Type 1 Diabetes: A Mediational Study, Laura Lynn Mayhew

USF Tampa Graduate Theses and Dissertations

People with diabetes are at double the risk of developing depression. Depression is associated with increased morbidity and mortality in people with diabetes. Levels of A1c have been linked to microvascular complications (e.g., retinopathy, nephropathy, and neuropathy) as well as depression. The interrelationship between A1c, microvascular complications, and depression has not previously been investigated in a comprehensive model, and a better understanding of the nature of these associations is needed. Preliminary analyses test the assumption that A1c mediates the relationship between group assignment in the Diabetes Control and Complications Trial (DCCT) and microvascular complications. The primary purpose of the study …

Impacts Of Artificial Reefs On Surrounding Ecosystems, Sarine Manoukian

USF Tampa Graduate Theses and Dissertations

Artificial reefs are becoming a popular biological and management component in shallow water environments characterized by soft seabed, representing both important marine habitats and tools to manage coastal fisheries and resources. An artificial reef in the marine environment acts as an open system with exchange of material and energy, altering the physical and biological characteristics of the surrounding area. Reef stability will depend on the balance of scour, settlement, and burial resulting from ocean conditions over time. Because of the unstable nature of sediments, they require a detailed and systematic investigation.

Acoustic systems like high-frequency multibeam sonar are efficient tools …

The Influence Of Meteorological Parameters On Rainfall And Severe Weather In Pinellas County, Fl, Cristina A. Mazza

USF Tampa Graduate Theses and Dissertations

Pinellas County is located on a peninsula in Florida that experiences daily patterns of sea breeze associated rainfall mainly during the summer months of June through August. Previously, rainfall patterns, amounts and timing and severe weather in Pinellas County have not been examined considering dominant wind flow patterns, sea breeze circulations and other atmospheric variables. To improve forecasting of local mesoscale phenomena, this project examined the rainfall patterns, amounts and timing and severe weather occurrences that occur as a result of sea breezes and associated prevailing wind regimes within Pinellas County for the months of June, July and August for …

Advanced Signal Processing Techniques For Single Trial Electroencephalography Signal Classification For Brain Computer Interface Applications, Kun Li

USF Tampa Graduate Theses and Dissertations

Brain Computer Interface (BCI) is a direct communication channel between brain and computer. It allows the users to control the environment without the need to control muscle activity [1-2]. P300-Speller is a well known and widely used BCI system that was developed by Farwell and Donchin in 1988 [3]. The accuracy level of the P300-BCI Speller as measured by the percent of communicated characters correctly identified by the system depends on the ability to detect the P300 event related potential (ERP) component among the ongoing electroencephalography (EEG) signal. Different techniques have been tested to reduce the number of trials needed …

Design And Synthesis Of Beta-Hairpin Peptidomimetics For Modulating Integrin Mediated Cell Adhesion, Abeta Fibrillogenesis And P53-Mdm2 Protein-Protein Interactions, Priyesh Jain

USF Tampa Graduate Theses and Dissertations

Inhibiting therapeutically important protein-protein interactions has been a tremendous challenge for medicinal chemists. The folded 3D structures of peptides and proteins, mainly comprise secondary structural elements i.e α-helices and β-sheet have created an opportunity to design small molecules and peptidomimetic inhibitors of protein-protein interaction (PPI). Hence, information about the formation and stabilization of these secondary structures is vital for designing future drugs. In this dissertation, several cyclic beta-hairpin peptidomimetics that mimic the recognition surface have been designed and synthesized as inhibitors for different targets such as integrin mediated extracellular matrix -cell adhesion in multiple myeloma, p53-MDM2 PPI, amyloid beta fibrillogenesis …

Evaluation Of Common Inherited Variants In Mitochondrial-Related And Microrna-Related Genes As Novel Risk Factors For Ovarian Cancer, Jennifer Permuth Wey

USF Tampa Graduate Theses and Dissertations

Epithelial ovarian cancer (EOC) is a leading cause of morbidity and mortality among women in the United States, and the etiology is incompletely understood. Common, low penetrant genetic variants such as single nucleotide polymorphisms (SNPs) likely contribute to a significant proportion of EOC. We examined whether SNPs in two understudied yet biologically important types of genes, mitochondrial-related and miRNA-related genes, may contribute to EOC susceptibility using data from a large, homogeneous study population of 1,815 EOC cases and 1,900 controls (frequency-matched on age-group and race/ethnicity) genotyped through stage 1 of an ongoing genome-wide association study. Inter-individual variation in genes involved …

Epidemiological Study Of Contributing Factors In The Development Of Peptic Ulcer And Gastric Cancer Initiated By Helicobacter Pylori Infection In India, Rahul Suresh Mhaskar

USF Tampa Graduate Theses and Dissertations

Background: Helicobacter pylori (H. pylori) infection is a significant risk factor for peptic ulcer (PU) and gastric cancer (GC). Apart from the virulent CagA genotype of H. pylori environmental and dietary factors influence disease outcomes. There have been no studies addressing these factors in Western India. Hence, we conducted a case control study enrolling PU, GC patients and controls at Pune, India.

Methods: Risk factors for PU and H. pylori infection were assessed in participant interview. H. pylori status was assessed from stool by monoclonal antigen detection. To understand treatment effect, we followed 100 H. pylori positive patients.

Results: We …

Antecedents And Consequences Of Channel Alienation: An Empirical Investigation Within Franchised Channels Of Distribution, Ivan Lapuka

USF Tampa Graduate Theses and Dissertations

Investigating an important overlooked phase of interorganizational relationship evolution, which is currently hypothesized to progress through five stages of awareness, exploration, expansion, commitment, and dissolution, this dissertation proposes that in the long road between commitment and dissolution, the quintessential interfirm relationship is likely to be characterized by aprolonged period of relationship alienation, which then becomes the immediate precursor to the dissolution stage.

The dissertation utilizes social learning theory, behavior constraint theory, and alienation theory to explain apathetic behaviors of franchisees. The principal proposition is that certain characteristics of the franchise system’s operating environment inadvertently condition franchisee estrangement and failure, and …

Comparison Of Safety Performance By Design Types At Freeway Diverge Areas And Exit Ramp Sections, Hongyun Chen

USF Tampa Graduate Theses and Dissertations

The primary objective of the study is to evaluate the safety performance of different freeway exit types used in current practical designs. More specific, the research objectives include the following two parts: 1) to compare the safety performance of different design types at freeway diverge areas and exit ramp sections; and 2) to identify the impact factors contributing to the crashes happening at these two specific segments.

The study area includes four subjects, the freeway widely-spaced diverge areas; the freeway closely-spaced diverge areas; the left-side off-ramps and the exit ramp sections. For the freeway diverge areas, design types were defined …

Before The Storm: Evacuation Intention And Audience Segmentation, Homer J. Rice

USF Tampa Graduate Theses and Dissertations

The purpose of this study was to describe the predictors of evacuation intention among coastal residents in the State of Florida and to determine if there are meaningful segments of the population who intend to evacuate when told to do so by governmental officials because of a major hurricane. In the America’s and the Caribbean, 75,000 deaths have been attributed to hurricanes in the 20

th century. A well planned evacuation can reduce injury and death, yet many people do not have an evacuation plan and do not intend to evacuate when told to do so. The study used secondary …

Modern Variation In Predation Intensity: Constraints On Assessing Predator-Prey Relationships In Paleoecologic Reconstructions, James Funderburk

USF Tampa Graduate Theses and Dissertations

The complex interaction between predators and their prey is rarely preserved in the fossil record. However, predation of marine mollusks by drilling gastropods leaves a diagnostic hole in the shell of the prey, possibly allowing for quantitative analysis of this ecological interaction. Drilling frequency, as measured in marine mollusks both in the Modern and fossil record, has been heralded as a potential opportunity to quantify these ecological interactions and use these values in the testing of hypotheses.

This study employed the collection, tallying, and analysis of bulk samples derived from shelly deposits on 45 Modern beaches along the contiguous coast …

Comparative Study Of Intentional Communities, Jessica Merrick

USF Tampa Graduate Theses and Dissertations

Moving to Florida to retire has become commonplace among American elders, though we have seldom addressed how lesbians and gay men navigate sexual identity in retirement. I undertake ethnography of three suburban, retirement-aged residential communities in Florida in which lesbians and gay men make community in order to understand how identities are produced by and within communities, the significance of suburban gay communities in the post-gay community era, and how residents from each community engage dominant discourse. Sanctuary Cove

1 is a ―gay and lesbian‖ retirement community; Bayside Park is a ―women‘s-only‖ (lesbian) community; and Heritage Estates is a heteronormative …

Educators’ Beliefs About And Approaches To The Evaluation Of Student Writing, Vanessa Minick

USF Tampa Graduate Theses and Dissertations

The overarching purpose of this study was to describe educators’ beliefs about the evaluation of student writing. The inquiry was guided by the following research questions: (a) what are the differences in the ways in which educators approach evaluating student writing? (b) how do educators evaluate the effectiveness of their evaluation methods for judging the quality of students’ writing samples? and (c) what factors impact the evaluation decisions of educators? The following variables were considered: public and private school settings, evaluation methods, and educators’ beliefs about evaluating writing. In order to gain perspective of the current status of the methods …

Hydrologic Controls On Salinity In Mangroves And Lagoons, Christina Elaine Stringer

USF Tampa Graduate Theses and Dissertations

This dissertation explores the hydrologic controls on salinity within mangroves and lagoons at sites in Florida and Mexico. The main objective of this research is to better understand hydrologic controls on mangrove ecosystem structure and develop ideas that will be useful to land managers attempting to regulate and conserve these critical habitats. This study was conducted at sites in Ft. Pierce, FL and Costalegre on the central Pacific coast of Mexico.

We examined controls on water levels and salinity in a mangrove on a carbonate barrier island along the Indian River Lagoon, east-central Florida. Spectral analysis of water levels showed …

Evaluation Of Deep Geologic Units In Florida For Potential Use In Carbon Dioxide Sequestration, Tina Roberts-Ashby

USF Tampa Graduate Theses and Dissertations

Concerns about elevated atmospheric carbon dioxide (CO

2

) and the effect on

global climate have created proposals for the reduction of carbon emissions from large

stationary sources, such as power plants. Carbon dioxide capture and sequestration

(CCS) in deep geologic units is being considered by Florida electric-utilities. Carbon

dioxide-enhanced oil recovery (CO

2

-EOR) is a form of CCS that could offset some of the

costs associated with geologic sequestration. Two potential reservoirs for geologic

sequestration were evaluated in south-central and southern Florida: the Paleocene

Cedar Keys Formation/Upper Cretaceous Lawson Formation (CKLIZ) and the Lower

Cretaceous Sunniland Formation along …

Selected Students’, Parents’, And Graduate Student Tutors’ Experiences And Perceptions In A Community Of Interest Summer Literacy Camp, Kim G. Thomas

USF Tampa Graduate Theses and Dissertations

In this qualitative case study, I examined a local summer literacy camp in which

graduate student tutors tutored elementary and middle school students in reading and

writing. I focused the study on the primary stakeholders in the summer literacy camp:

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ts, and the course instructor/camp director because

their voices are limited in the current literature. In this Community of Interest Summer

Literacy Camp, the graduate student tutors moved from a position of fear and trepidation

to a position of empowerment in which they hoped to make changes in their classrooms,

schools, and communities. The tutees learned to appreciate the …

Libs And Lite Emission Based Laser Remote Sensing Of Chemical Species And Enhanced Modeling Of Atmospheric Absorption, Dzianis V. Pliutau

USF Tampa Graduate Theses and Dissertations

Laser-Induced Breakdown spectroscopy (LIBS) and Laser-Induced Thermal Emission (LITE) emission based laser remote sensing were investigated with the application to the remote measurements of trace chemical species. In particular, UVvisible LIBS and Mid-IR LITE systems were developed and measurements of remote targets and chemical surfaces were studied. The propagation through the atmosphere of the multi-wavelength backscattered LIBS and LITE optical spectrum with atmospheric absorption effects on the returned lidar signal was investigated. An enhanced model of the atmospheric effects on emission-based laser-remote sensing was developed and found to be consistent and in agreement with our experimental results.

LITE measurements were …

Linking Soil Loss To Sediment Delivery In Two Estuaries In Puerto Rico, Nekesha Bernadette Williams

USF Tampa Graduate Theses and Dissertations

Enhanced soil loss from the watershed is a major environmental issue. Increased soil loss from a watershed can potentially increase sediment delivery and loading to aquatic ecosystems such as rivers and estuaries. An increase in sediment delivery and loading to freshwater and transitional marine ecosystems can impact water quality and supply specifically by: (1) reducing water clarity, (2) transporting nutrient and pollutant laden sediments and (3) reducing the storage capacity of reservoirs. To address these broader environmental impacts of increased sediment delivery and loading to aquatic ecosystems it is imperative that potential source areas of sediments available for transport are …

The Interaction Between Urban Form And Transit Travel, Sisinnio Concas

USF Tampa Graduate Theses and Dissertations

This study presents an analytical model of the interaction between urban form and the demand for transit travel, in which residential location, transit demand, and the spatial dispersion of non-work activities are endogenously determined. In this model, travel demand is considered a derived demand brought about by the necessity to engage in out-ofhome activities whose geographical extent is affected by urban form. In a departure from the urban monocentric model, residential location is defined as a job-residence pair in an urban area in which jobs, residences, and non-work activities are dispersed. Transit demand is then determined by residential location, work …

Technology Integration For Preservice Science Teacher Educators, Nina C. Stokes

USF Tampa Graduate Theses and Dissertations

The current state of technology integration in science teacher education programs is examined with a view to providing science teacher educators with practical information and diverse examples of technologies they can model in their own courses. Motivators and barriers to technology integration and use are discussed, and recommendations for choosing and evaluating science technologies made. A brief history of how computers, related communication technologies, and science teacher education reform "fit" together is provided. Multiple interpretations of what is meant by "technology" and associated terms (distance learning, online courses, Web-enhanced courses, simulations, authentic data sets etc.) are included to set the …

Antarctic Tunicates And Endophytic Fungi: Chemical Investigation And Synthesis, Matthew D. Lebar

USF Tampa Graduate Theses and Dissertations

Drug discovery is reliant on new developments in natural product chemistry as well as advances in chemical synthesis. The interconnectivity and interdependence of natural and synthetic investigation in drug discovery is evident. The chemical exploration reported herein elaborates the relationship between natural product chemistry and chemical synthesis. Of particular interest are chemicals from organisms residing in less accessible environments, particularly Antarctica and endophytic microbial communities. Degradation via reductive ozonolysis of palmerolide A, a macrocyclic polyketide isolated from the Antarctic tunicate

Synoicum adareanum, and subsequent synthetic preparation of the resulting polyols (1,2,6-hexanetriol and 1,2,3,6-hexanetetraol) led to a revision in the …