Digital Commons Network^™

Screening Soybean Genotypes For High Temperature Tolerance By In Vitro Pollen Germination, Pollen Tube Length And Physiological Techniques, Mohammed A. Salem

Theses and Dissertations

We are now witnessing changing environmental conditions and these changes will likely continue into the coming decades due to projected increases in temperatures on the earth surface. Recent model projections suggest that the global mean surface air temperatures will increase by 1.4 to 5.8 °C by 2100. The consequences of these high temperatures include reductions in crop yields. Soybean is one of the major crops grown in the US, where high temperatures (>35 °C) during reproductive growth decreased yield. Two experiments were conducted to determine the effects of temperature on soybean pollen germination properties and identify responses to temperature …

Mechanical And Physical Properties Of Preservative-Treated Strandboard, John Warren Kirkpatrick

Theses and Dissertations

The purpose of this research was to quantify properties of strandboard panels manufactured with various preservatives at loading levels effective against native termites. Panels were manufactured using nine different formulations. The method of preservative addition was also examined for some preservative formulations, increasing the total number of preservative treatments to twelve. Panels were manufactured with one target retention for each preservative treatment. An effective preservative loading relative to termites was established by previous studies or referencing current standards. Mechanical testing performed included static bending and internal bond. Physical testing included water absorption, thickness swell, and linear expansion. Few treatments met …

Theatre Arts Assessment In New Jersey High Schools, Julie Lawrence

Theses and Dissertations

Core Curriculum Content Standards and State Frameworks have outlined what needs to be taught in public high school arts programs, but how will teachers and administrators evaluate student achievement in the creative fields? Investigation of recent brain-based research and information on metacognition as they relate to the arts will be discussed in this project. Viable assessment tools for high school theatre arts programs that reflect recent research in metacognition will be included in this thesis.

Paleoenvironmental Reconstruction Of The Late Cretaceous Eastern Gulf Coastal Plain In Georgia And Alabama, Tracy L. Hall

Theses and Dissertations

The present study reconstructs the regional paleoenvironment (particularly paleoclimate) of the Late Cretaceous Eastern Gulf Coastal Plain of Georgia and Alabama using paleobotanical, paleoecological and geochemical methods in order to evaluate the Late Cretaceous climate of the Southeastern United States, and to add to the body of paleoclimate data for that time. Paleobotanical analysis indicates a terrestrial mean annual temperature (MAT) of about 27°C during the Late Cretaceous, which is considerably warmer than modern terrestrial MAT. Stable oxygen isotope data from molluscan carbonate indicate mean sea surface temperature (SST) of 26.8 °C for the Santonian, 23.5°C for the early Campanian, …

Factors Associated With Parenting Stress And Self-Competence In Single And Married Mothers Of Preschool-Aged Children, Erin Tentis

Theses and Dissertations

This study examined the differences between married and single mothers in parenting stress and parenting self-competence. Fifty married and 45 single mothers of children aged 3- 4- or 5-years old participated in this study. Each mother completed a packet of questionnaires that included a demographics form, the Parenting Stress Index - Short Form, the Parenting Sense of Competence scale, the Daily Hassles subscale of the Hassles and Uplifts Scale, the Social Provisions Scale, the Colorado Child Temperament Inventory, and the Child Behavior Questionnaire.

Results indicated that married and single mothers do not differ in the extent to which they feel …

Analysis Of Qa/Qc Protocols And Value Of Data To The Development Of Reference Criteria In The Georgia Ecoregions Project, Tracy Jo Ferring

Theses and Dissertations

The concept of Measurements Quality Objectives (MQOs), in bioassessment programs is a useful tool in evaluating the consistency of data and limiting variability and potential sources of measurement error. Typical evaluations of data repeatability and/or data quality center on the use of a series of calculations that quantify variability between measures. These calculations provided some indication of not only the quality of the data collected, but also acted as a measure of how representative the biological data were to each ecoregion. The evaluation of the Quality Control data for this project provides a framework for data users and water resource …

Preliminary Design Approach For Prosthetic Ankle Joints Using Compliant Mechanisms, Jason Matthew Wiersdorf

Theses and Dissertations

The objective of this thesis is to develop design approaches and models for prosthetic ankle joints using kinematic models of the human ankle and compliant mechanisms technology. Compliant mechanisms offer several potential design advantages over traditional rigid-body designs including high reliability and low cost. These design advantages are ideal for use in prosthetics. Some prosthetic ankle/foot systems currently on the market have multiple degrees of freedom yet are expensive. Additionally, even though these systems have multiple degrees of freedom, none of them are designed after the actual movements of the biological ankle. In this thesis a two, single degree-of-freedom hinge …

Correlogram Method For Comparing Bio-Sequences, Gandhali P. Samant

Theses and Dissertations

Sequence comparison is one of the most primitive operations used in bio-informatics. It is used as a basis for many other complex manipulations in the field of Computational Molecular Biology. Many methods and algorithms were developed to compare and align sequences effectively. Most of these methods use linear comparison and some standard scoring schemes to calculate the similarity between sequences. We described an alternative approach to compare sequences based on the correlogram method. This method has already been used in the past for comparing images. By using the correlogram method, a sequence is projected on a 3-D space and the …

White Beauty: The Portrayal Of Minorities In Teen Beauty Magazines, Micaela Choo Banks

Theses and Dissertations

This content analysis examines the representations of minorities in the two most popular teen beauty magazines: Seventeen and YM. Nine issues for 2003 constituted the sample frame yielding a total of 620 advertisements containing human models. After setting up a theoretical framework of the new racism and White beauty, this study investigates the portrayals of minority models. Overall, when compared with earlier studies the number of minority models used in mainstream magazine advertising rose and the portrayals of minority models in prominent roles increased. Yet, the subtle nature of the new racism was reinforced in the following findings: Prominent …

Assessment Of Chenopodium Quinoa Willd. Genetic Diversity In The Usda And Cip-Fao Collections Using Ssr?S And Snp?S, Shawn A. Christensen

Theses and Dissertations

Quinoa (Chenopodium quinoa Willd.) is a staple grain for the indigenous people of the Andean region of South America with excellent nutritional qualities, including protein content. The objective of this study is to report on the development of fluorescence-tagged simple sequence repeats (SSRs) and single nucleotide polymorphisms (SNPs) to (1) genetically characterize the inherent diversity of 152 accessions of C. quinoa; (2) determine to what degree the CIP-FAO collection represents the range of genetic diversity in quinoa; and (3) test four hypotheses regarding quinoa?s center of diversity, Highland and Lowland clustering patterns, origin of Lowland varieties, and the …

Gender Issues In Islamic Schools: A Case Study Of Two Schools In The United States, Hilda Yacoub Sabbah

Theses and Dissertations

This study sought to explore and explain how boys, girls, teachers, and principals "do gender" in Islamic schools in the United States. The goal is to seek plausible explanations of how boys and girls interact formally and informally during the day, how they create differences, and how they interact with teachers and principals. This descriptive study utilized a case study design. The education of girls is very important for their individual growth and development, as well as for the welfare of both the Islamic and American societies and nations. Therefore, scholars and educators should work together to solve problems interfering …

The Role Of Phosducin-Like Protein And The Cytosolic Chaperonin Cct In G Beta Gamma Dimer Assembly, Ting Hu

Theses and Dissertations

Phosducin-like protein (PhLP), a G protein beta gamma subunit dimer binder and G protein signaling regulator, was suggested to regulate the activity of cytosolic chaperonin CCT by their high affinity interaction. In the present study, the three-dimensional structure of PhLP:CCT complex has been solved by cryoelectron microscopy. PhLP was found to bind only one of the chaperonin rings with both N- and C-terminal domains. It spans the central folding cavity of CCT and interacts with two opposite sides of the top apical region, inducing the constraining of the entry of the folding cavity. These findings support a putative role of …

Palladium-Imidazolium Carbene Catalyzed Heck Coupling Reactions And Synthesis Of A Novel Class Of Fluoroanthracenylmethyl Ptc Catalysts, Jiuqing Zhang

Theses and Dissertations

Palladium catalyzed Heck coupling with aryl and alkenyl halides has become a powerful means of carbon-carbon bond formation. This standard synthetic method has been developed to a high level of utility using various catalysts, conditions and substrates. Yet significant drawbacks remain, including poor reactivity, the need for high temperatures and base, limited substrate generality, and selectivity. Mixed products often suffer from olefin migration following insertion. N-Heterocyclic carbenes (NHC) have proven to be electron-rich donors which provide higher stability and reactivity than phosphines. In a previous paper reported by our research group the imidazolium-palladium carbene has proven to be highly efficient …

Modeling Distributions Of Test Scores With Mixtures Of Beta Distributions, Jingyu Feng

Theses and Dissertations

Test score distributions are used to make important instructional decisions about students. The test scores usually do not follow a normal distribution. In some cases, the scores appear to follow a bimodal distribution that can be modeled with a mixture of beta distributions. This bimodality may be due different levels of students' ability. The purpose of this study was to develop and apply statistical techniques for fitting beta mixtures and detecting bimodality in test score distributions. Maximum likelihood and Bayesian methods were used to estimate the five parameters of the beta mixture distribution for scores in four quizzes in a …

The Frequency And Severity Of Problem Behaviors Among Individuals With Autism, Traumatic Brain Injury, And Mental Retardation From The Utah Dspd Dataset, Melanie Kay Arp

Theses and Dissertations

The study reports on analyses of data collected from the Inventory for Client and Agency Planning (ICAP) for 5,859 children with Autism (n = 511), Traumatic Brain Injury (TBI, n = 522), or Mental Retardation (MR, n = 4826) whose legal guardians applied for support services through the Utah Department of Services for People with Disabilities (DSPD). Results indicate that the least to most frequent problem behaviors were (a) destructive to property, (b) hurtful to self, (c) hurtful to others, (d) socially offensive, (e) unusual habits, (f) withdrawal, (g) uncooperative, and (h) disruptive behaviors. The degree of severity varied from …

Facilitating Communication About Death Between Mothers And Adolescent Sons Using Fictional Children's Literature, Deon G. Leavy

Theses and Dissertations

Most children will experience the death of a loved one in their lifetime and will need to develop healthy grieving patterns. Communication between parents and children is a key ingredient in facilitating this development. Current opinions about bibliotherapy, using a book to assist in healing, suggest that books provide understanding about grief and death and open channels of communication. Although the use of bibliotherapy is gaining popularity, little research exists about its efficacy. Utilizing the book The Bridge to Terabithia, this study evaluated the facilitation of communication about death between 19 dyads of mother and adolescent sons. Their answers and …

Total Syntheses Of (+)-Geldanamycin, (-)-Ragaglitazar, And (+)-Kurasoin A And Phase-Transfer-Catalyzed Asymmetric Alkylation, Erik J. Hicken

Theses and Dissertations

Geldanamycin possesses various biological activities as seen in the NCI 60 cell line panel (13 nM avg., 70 nM SKBr-3 cells). The predominant mode of action providing these unique results arises from the ability of geldanamycin (GA) to bind to the chaperone heat shock protein 90 (Hsp90). Despite its complicated functionality, the first total synthesis of GA was accomplished, which included two new reactions developed specifically to address the stereochemical features. The final step in the synthesis of GA was a demethylation-oxidation sequence to generate the desired para-quinone. This step could only be accomplished with HNO3/AcOH, producing GA in …

Development Of Biological Reference Conditions Of Wadeable Streams In The Major Ecoregions And Subecoregions Of Georgia, Duncan L. Hughes

Theses and Dissertations

One bioassessment tool available to resource managers to indicate NPS impairment of wadeable streams and rivers are multi-metric invertebrate indices. Such indices are assembled from metrics in broad categories that represent different aspects of community structure and function (e.g. richness, composition, tolerance/intolerance, feeding group, and habit). Indices must incorporate suites of metrics that are ecologically relevant, quantifiable, non-redundant, and that best individually discriminate between reference sites and impaired sites. More than 240 wadeable streams in Georgia were sampled during the September thru February index period using RBP protocols during three successive sample seasons (1999-2003). Ecoregional reference (minimally impaired) sites, as …

Specific Heat And Thermodynamic Properties Of Metallic Systems: Instrumentation And Analysis, Brian E. Lang

Theses and Dissertations

A small-scale adiabatic calorimeter has been constructed as part of a larger project to study nano-particles and to facilitate specific heat measurements on samples where it is difficult to obtain enough material to run on the current large-scale adiabatic apparatus. This calorimeter is designed to measure sample sizes of less than 0.8 cc over a temperature range from 13 K to 350 K. Specific heat results on copper, sapphire, and benzoic acid show the accuracy of the measurements to be better than ±0.4% for temperatures higher than 50 K. The reproducibility of these measurements is generally better than ±0.25%. Experimental …

Historical Land Cover Impacts On Water Quality In The Provo River Watershed, 1975 - 2002, Fredric James Donaldson

Theses and Dissertations

The Provo River watershed has experienced land cover change over the past several decades. Land cover influences water quality inasmuch as land cover determines the type and quantity of non-point source (NPS) pollutants that may enter the water. This study examines the historical impacts of land cover changes on water quality in the Provo River using remote sensing and statistical analysis. Statistical correlations and linear regressions were used to study the relationship between various land cover types and water quality variables for six years between 1975 and 2002. This thesis supports research finding myriad impacts of urban land cover on …

Polymer Microchips For Capillary Electrophoresis And Electric Field Gradient Focusing Of Biomolecules, Ryan Thomas Kelly

Theses and Dissertations

Polymeric materials have seen increasing use as microfluidic device substrates due to their low cost and the simplicity of templated fabrication procedures. I showed that poly(methyl methacrylate) (PMMA) microdevices could be enclosed in a boiling water bath, which allowed the seal to form more quickly than in conventional approaches, and enabled microchannels to remain hydrated throughout the bonding process. Microchip capillary electrophoresis (µ-CE) devices were fabricated using water-based enclosure, and a mixture of fluorescently labeled amino acids was separated in 30 s in these microchips. To create more robust capillary electrophoresis (CE) microdevices with improved separation performance, phase-changing sacrificial materials …

Geologic Map Of The Golden Throne Quadrangle, Wayne And Garfield Counties, Utah, Daniel H. Martin

Theses and Dissertations

The Golden Throne Quadrangle is located within Capitol Reef National Park, south-central Utah. Geologic mapping of this 1:24,000 scale 7.5 minute quadrangle began in 2003 as the National Parks Service desired to have geologic maps at this scale produced within the park. Stratigraphically, ten bedrock formations and ten Quaternary deposits are exposed within the Golden Throne Quadrangle. Geologic formations range in age from Permian to Jurassic. This map contains details not included on previous geologic maps including; the members of the Carmel, Chinle, and Moenkopi Formations. Additionally, the Page Sandstone is herein mapped as an independent unit. Structurally the Golden …

Structure Elucidation Of Bioactive Compounds Isolated From Endophytes Of Alstonia Scholaris And Acmena Graveolens, Nicholas James Hundley

Theses and Dissertations

Alstonia scholaris is an evergreen tree native to Southeast Asia and Australia. It is commonly used as a medicinal plant throughout these regions. In the present study, an endophyte of the genus Xylaria was isolated from a stem of Alstonia scholaris, its mycelia and exudate extracted, and the extract assayed for growth inhibition of HeLa cancer cells in vitro. Several known compounds were isolated and identified based on NMR, infrared, and mass spectral data. The compounds identified are 19,20-epoxycytochalasin C; 19,20epoxycytochalasin D; and xylobovide. Two other compounds, fusaric acid and dehydrofusaric acid, were discovered in an endophyte of the Hypocreales …

An Acyl Radical Cascade Model For The Total Synthesis Of Lyconadin A, Seth W. Grant

Theses and Dissertations

Lyconadin A (1) is a structurally unique Lycopodium alkaloid with antitumor properties, isolated from the club moss Lycopodium complanatum. We are developing a synthetic route to 1 based on a novel 7-exo-trig/6-exo-trig acyl radical cascade cyclization. The synthesis of model acyl radical cascade precursor 23 will be presented. Key features of this synthesis include the suppression of competing elimination during the alkylation of a hindered phenethyl bromide and the use of a lactone as a precursor to a compound bearing two differentially protected primary alcohols. An account of our studies on the model acyl radical cascade cyclization (23 to 24 …

Protein Impregnated Polymer (Pip) Film Infrared Sensor Using Suspended Microelectromechanical Systems (Mems) Pixels, Tetsuo Kaieda

Theses and Dissertations

The Air Force Research Laboratory Materials and Manufacturing Directorate have developed a novel protein impregnated polymer (PIP) suspension that changes resistivity as a function of absorbed infrared radiation. Due to this property, the PIP is a potential material for use as an uncooled bolometer, or thermal sensor. In this research, a thermally-isolated pixel design, sensor characterization methods, and sensor fabrication and processing steps were developed. To create a microbolometer, the PIP was applied to two prototype micro-electro-mechanical systems (MEMS) surface micro-machined structures. The first is a raised cantilever pixel array that uses residual stress polysilicon and metal film arms to …

Establishment Of A System Operating Characteristic For Autonomous Wide Area Search Vehicles, Brian A. Kish

Theses and Dissertations

The optimal employment of autonomous search and destroy vehicles is addressed. The results apply to air, land, or water vehicles with 1, k, or infinite warheads. The specific scenarios considered involve an air vehicle searching a battle space for stationary targets in the presence of false targets. Encounters are modeled with uniform, Poisson, and normal distributions. Linear and circular search patterns are examined. All relevant parameters are extracted from intelligence information, the sensor performance specification, and the air vehicle performance specification. Analytic system effectiveness measures are derived using applied probability theory. The effectiveness measures derived in this dissertation handle time-varying …

Combat Identification With Sequential Observations, Rejection Option, And Out-Of-Library Targets, Timothy W. Albrecht

Theses and Dissertations

This research extends a mathematical framework to select the optimal sensor ensemble and fusion method across multiple decision thresholds subject to warfighter constraints for a combat identification (CID) system. The formulation includes treatment of exemplars from target classes on which the CID system classifiers are not trained (out-of-library classes) and enables the warfighter to optimize a CID system without explicit enumeration of classifier error costs. A time-series classifier design methodology is developed and applied, yielding a multi-variate Gaussian hidden Markov model (HMM). The extended CID framework is used to compete the HMM-based CID system against a template-based CID system. The …

Effect Of Melatonin And Dopamine In Site Specific Phosphorylation Of Phosducin In Intact Retina, Arinzechukwu Okere Nkemdirim

Theses and Dissertations

Phosducin (Pdc) is a 28 kDa binding partner for the G protein beta gamma subunit dimer (G-beta-gamma) found abundantly in the photoreceptor cells of the retina and pineal gland. In the retina, light-dependent changes in cAMP and Ca2+ control the phosphorylation of Pdc at serine 73 and 54, respectively, which in turn controls the binding of Pdc to G protein beta gamma subunit dimer . G protein beta gamma subunit dimer binding has been proposed to facilitate light-driven transport of G protein beta gamma subunit dimer from the site of phototransduction in the outer segment of the photoreceptor cell to …

The Effect Of A Lingual Magnet On Fricative Production: An Acoustic Evaluation Of Placement And Adaptation, Andrea Lynn Weaver

Theses and Dissertations

Much of speech kinematics research is conducted by attaching a device to the articulators. However very little research has been conducted to determine what influence these devices may have on the perceptual and acoustic characteristics of speech. This study examined the effect of placing a small magnet on the tongue of ten normal adult speakers while reading a sentence containing /s/ and "sh" in initial, medial and final position. Two different placements of 10 and 15 mm from the tip of the tongue were analyzed. Data were taken before magnet placement, immediately after magnet placement, after 5 minutes of conversation, …

Generation Of Biomarkers From Anthrax Spores By Catalysis And Analytical Pyrolysis, Phillip R. Smith

Theses and Dissertations

Anthrax spores, in weaponized form, are dangerous biological warfare agents. Handheld technology for the rapid detection of anthrax is greatly needed to improve national security. Methods to detect anthrax spores are diverse, with most taking at least an hour for positive identification. A viable option for rapid detection is analytical pyrolysis (AP), which produces chemicals containing taxonomical information (biomarkers). AP methods are reviewed and critically analyzed to show that reproducible detection of anthrax spores in a rapid manner (< 5 min) with a handheld device is not currently possible. A promising alternative to AP is the use of a catalyst to produce biomarkers from anthrax spores with improved selectivity and reproducibility. Catalytic materials having promise for this include platinum, nickel, and superacids. Experiments evaluating several of these materials are described. A biomarker mass spectral library was created, based on information available in the scientific literature, to facilitate analysis and identification of the biomarkers produced experimentally. The RAMFAC algorithm was used to deconvolute chromatographic peaks to produce clean mass spectra and match them against entries in the biomarker library. While the library is not complete, its use with the RAMFAC algorithm enabled detection of many important biomarkers in experiments involving catalytic breakdown of anthrax spores. Experimental results from preliminary tests of several catalysts are presented and discussed. Addition of catalysts in the form of platinum nanoclusters and superacids to bacterial spores in a commercial pyrolyzer effected an increase in the amount of biomarkers produced at mild conditions over traditional pyrolysis methods. Electroformed nickel mesh, on the other hand, demonstrated low catalytic activity for the production of biomarkers, likely due to poor contact of the spores with the mesh. Biomarkers similar to those published in the literature were observed, including dipicolinic acid, picolinic acid, propionamide, acetamide, diketopiperazines, fatty acids, furfuryl alcohol, and DNA bases. A statistically designed factorial study was used to determine the importance of temperature, spore loading, and nanocluster loading on the production of three important biomarkers. The relative importance of these variables differs for each of the three important biomarkers, suggesting they are produced by different reaction mechanisms.