Digital Commons Network^™

Assessment Of High-Performance Steels Through Additive Manufacturing And Ultrasonic Impact Peening, Md Touhidul Islam Rimon

Theses and Dissertations

This abstract focuses on the treatment of three distinct materials: 17-4 PH stainless steel, a nickelbased super alloy, and AISI 4140 stainless steel. The treatment process involves a combination of laser deposition and ultrasonic impact peening.

The study explores the effects of this treatment on the mechanical and microstructural properties of the mentioned materials. Laser deposition is utilized to enhance surface characteristics, such as hardness, wear resistance, and corrosion resistance. Nickel-based super alloys are known for their exceptional high-temperature strength and corrosion resistance, making them suitable for demanding applications in aerospace and power generation industries. AISI 4140 stainless steel is …

Dodea K-12 Student Perceptions Toward Adjusting To Math Curricula Discrepancies Among Base Schools, Jackie Zuiderhof

Theses and Dissertations

Students who are affiliated with the United States Armed Forces will transition every two to four years depending on their parents’ career. The students who move may have educational gaps in mathematics because of a United States Armed Forces move occurring in the middle of a school year. The problem of practice addresses the educational gaps that former students and teachers perceive occurring related to content knowledge and procedural fluency. The researcher used a mixed methods study to ask close-ended quantitative questions and open-ended qualitative questions. The research was conducted on the web-based platform of Facebook. The results of the …

“You Have To First Recognize That There’S A Problem Before You Can Enact Change”: A Mixed-Methods Study Of General And Special Education Co-Teachers’ Critical Consciousness And Agency In Enacting Socially Just Inclusive Practices, Latifa Sebti

Theses and Dissertations

Inclusive education transcends the physical integration of students with disabilities in inclusive classrooms, demanding a commitment toward socially just inclusive practices. The purpose of this exploratory mixed-methods study is to investigate inclusive co-teachers' critical consciousness and agency in socially just inclusive practices, specifically for students of color with disabilities. The quantitative phase, with a survey of 241 teachers, revealed a structural equation model showing relationships between critical awareness about intersectionality, attitudes toward inclusion, self-efficacy in inclusive teaching, agency, and critical action. The open-ended responses indicated two teacher profiles based on their level of critical consciousness. The qualitative phase included interviews …

An Investigation Of The Interactions Of Gradient Coherence And Network Pruning In Neural Networks, Zachary Yauney

Theses and Dissertations

We investigate the coherent gradient hypothesis and show that the coherence measurements are different on real and random data regardless of the network's initialization. We introduce "diffs," an attempt at an element-wise approximation at coherence, and investigate their properties. We study how coherence is affected by increasing the width of simple fully-connected networks. We then prune those fully-connected networks and find that sparse networks outperform dense networks with the same number of nonzero parameters. In addition, we show that it is possible to increase the performance of a sparse network by scaling the size of the dense parent network it …

The Advancement Of Experimental And Computation Tools For The Study Of Molten Salt Chemistry To Facilitate The Extraction Of Strategic Elements In Nuclear Applications, Michael Stoddard

Theses and Dissertations

Nuclear energy presents environmental benefits, yet the challenge of radioactive waste management persists. Advanced solutions, such as Molten Salt Reactors (MSRs), require a more profound understanding of molten salt chemistry. This research aims to develop tools, including a depletion simulator, molten salt electrochemical simulator, and a fluoride-based thermodynamic reference electrode for electrochemical purification. The computationally inexpensive depletion simulator allows for exploration into extraction and processing strategies for molten salt reactors. An illustrative case study on Mo-99 production from MSRs demonstrates the practical application of the theoretical framework, emphasizing the need for optimization in extraction effectiveness and separation difficulty. The electrochemical …

Trip - Transformer Interatomic Potential Predicts Realistic Energy Surface Using Physical Bias, Bryce Eric Hedelius

Theses and Dissertations

Accurate interatomic energies and forces enable high-quality molecular dynamics simulations, torsion scans, potential energy surface mapping, and geometry optimization. Machine learning algorithms have enabled rapid estimates of energies and forces with high accuracy. Further development of machine learning algorithms holds promise for producing general potentials that support dozens of atomic species. I present my own Transformer Interatomic Potential (TrIP): a chemically sound potential based on the SE(3)-Transformer. TrIP's species-agnostic architecture--using continuous atomic representation and homogenous graph convolutions--encourages parameter sharing between atomic species for more general representations of chemical environments, keeps a reasonable number of parameters, serves as a form of …

The Journey Toward Ascension: Understanding The Narratives Of Latinx Women In K-12 School Principalship, Manuela Jimenez

Theses and Dissertations

This study explored the unique leadership journeys of Latinx women holding principal positions in K-12 schools across New Jersey. The research findings revealed that these women's career paths were significantly influenced by their social identity characteristics, specifically as female Latinx individuals. The study serves as a crucial reminder to challenge and eliminate negative perceptions and biases towards Latina school principals and their leadership growth and methodologies. The study focused on the leadership journeys of Latinx women holding principal positions in K-12 schools in New Jersey. The findings also showed that their career paths were aided by their social identity characteristics …

Towards A Practical Method For Monitoring Kinetic Processes In Polymers With Low-Frequency Raman Spectroscopy, Robert Vito Chimenti

Theses and Dissertations

Unlike liquids and crystalline solids, glassy materials exist in a constant state of structural nonequilibrium. Therefore, a comprehensive understanding of material kinetics is critical for understanding the structure-property-processing relationships of polymeric materials. Amorphous materials universally display low-frequency Raman features related to the phonon density of states resulting in a broad disorder band for Raman shifts below 100 cm-1, which is related to the conformational entropy and the modulus. This disorder band is dominated by the Boson peak, a feature due to phonon scattering because of disorder and can be related to the transverse sound velocity of the material, and a …

Development Of Bifunctional Electrocatalyst For The Electrically Rechargeable Zinc Air Batteries, Thiruvenkatam S

Theses and Dissertations

The spontaneous reaction between zinc and oxygen in an alkaline medium is exploited in non-rechargeable aqueous zinc-air batteries (ZABs) to generate useful electricity. The primary ZAB has a rich history as it was used in tramways, railway signalling and it is being used in hearing aids, pacemakers, etc. The success of primary ZABs led to the development of two types of rechargeable ZAB, namely, mechanically rechargeable ZAB (mrZAB) and electrically rechargeable ZAB (erZAB). In mrZABs, the exhausted anode and electrolyte are replaced periodically. Whereas the chemistry of primary ZAB is reversed using suitable electrocatalysts in erZABs. Electrocatalysts used in erZABs …

Automating Verification Of Bpmn Workflow Functional Correctness Using Model Checking, Bryce Mckay Pierson

Theses and Dissertations

Many critical systems industry-wide demand fail-safe process execution. Many of these systems are beginning to use low-code or no-code (LC/NC) solutions to their problems. Mechanisms for verifying the integrity of LC/NC solutions are extremely limited in comparison to traditional code. One solution exhaustively searches the execution state space for undesirable behavior, but it requires expertise in model checking and extensive manual labor. Additionally, error output from that method is exclusively text-based and demands time and familiarity to comprehend. We introduce a tool for automating model checking of LC/NC solutions. Participation in the automation process requires very little knowledge of the …

"Pasted Up And Printed Out": Watchmen As Ontographic Network, Thomas B. De Groff

Theses and Dissertations

This thesis explores Alan Moore and Dave Gibbons' 1986-87 comic book series Watchmen according to its network structure, paying particular attention to page layout and the establishment of or deviation from the nine-panel "waffle iron" grid. This reading aims to better understand the comic book form, connecting the work of comics theorist Theirry Groensteen to certain elements of actor-network theory and Ian Bogost's notion of the ontograph--a map of being that emphasizes the interobjectivity of networked nodes. This thesis explores the ontographic nature of the comic book form more generally before tracing the meta-textual ontograph in Watchmen. The thesis then …

Head Tail Open: Open Tailed Classification Of Imbalanced Document Data, Chetan Joshi

Theses and Dissertations

Deep learning models for scanned document image classification and form understand- ing have made significant progress in the last few years. High accuracy can be achieved by a model with the help of copious amounts of labelled training data for closed-world classification. However, very little work has been done in the domain of fine-grained and head-tailed(class imbalance with some classes having high numbers of data points and some having a low number of data points) open-world classification for documents. Our proposed method achieves a better classification results than the baseline of the head-tail-novel/open dataset. Our techniques include separating the head-tail …

Development And Evaluation Of Full Performance-Based Procedures For The Estimation Of Liquefaction-Induced Building Settlement In A Non-Free-Field Condition Using Cumulative Absolute Velocity, Dallin Nathan Smith

Theses and Dissertations

Liquefaction induced settlement is an earthquake hazard engineers face when developing infrastructure. Current methods for estimating liquefaction induced settlement are done in a free field condition. This assumption is not an accurate way to describe the soil because in most cases the soil will bear some kind of infrastructure. Evaluation of liquefaction induced settlement in a non-free-field condition is a more appropriate way. Using the Bullock et al. CAV model, Bullock et al liquefaction induced settlement model, and probabilistic seismic hazard software from the USGS, a full performance-based procedure for the estimation of liquefaction-induced building settlement in the non-free-field condition …

Unique K3 Surfaces With Purely Non-Symplectic Automorphism: Insights From Weighted Projective Spaceunique K3 Surfaces With Purely Non-Symplectic Automorphism:\\Insights From Weighted Projective Space, Elizabeth Melville

Theses and Dissertations

K3 surfaces have garnered attention across various fields, from optics and dynamics to high energy physics, making them a subject of extensive study for many decades. Recent work by mathematicians, including Brandhorst [1], has focused on non-symplectic automorphisms, aiming to categorize K3 surfaces that admit such automorphisms. Brandhorst made a list of unique K3 surfaces with purely non-symplectic automorphisms and established specific criteria for a K3 surface to be isomorphic to one on his list. This thesis aims to provide an alternative representation of select K3 surfaces from Brandhorst's list. While Brandhorst predominantly characterizes these surfaces as elliptic K3 surfaces, …

Transferable User-Friendly Machine Learning For Normal Boiling Point Prediction, Frank Tafadzwa Mtetwa

Theses and Dissertations

The estimation of thermophysical properties of chemical compounds holds considerable importance across a multitude of fields, ranging from material science to process design. Among these properties, the normal boiling point (NBP) stands out as a pivotal parameter in scientific and engineering contexts, as it elucidates the state of a substance under standard conditions commonly encountered in nature. Additionally, NBP is extensively documented in various reference materials and databases. Given its paramount importance and widespread availability, prediction methodologies for other properties such as critical temperature, liquid density, vapor pressure, surface tension, liquid viscosity, liquid thermal conductivity, and flash point often rely …

Catchment Water Storage Mediates River Flow Sensitivity To Climate Change, Brian Charles Brown

Theses and Dissertations

As patterns of precipitation and evapotranspiration change, human water security and aquatic ecosystem health depend on understanding how catchment characteristics interact with climate to control river flow. We tested factors that mediate sensitivity of river flow to fluctuations in climate using a set of 1,148 data-rich, climate diverse catchments in various parts of the world from 2001-2020. We extrapolated these results to an additional 2,012 catchments with sparser data. Using features such as vegetation, land use, hydrology, and local climate, we found that catchments with high aridity to runoff ratios (Fuh's parameter) had 380% higher runoff sensitivity to fluctuations in …

The Evaluation Of Non-Specific Risk Indicators In Improving Detection Of Psychosis-Spectrum Liability, Thomas W. O'Kane

Theses and Dissertations

Psychosis-spectrum disorders remain a leading cause of disability for both individuals and society, with early identification and prevention efforts representing a promising avenue of research for addressing these concerns. One potential impediment to improving early risk identification is the historical focus on indicators thought to be exclusive to the psychosis-spectrum. This focus often comes at the expense of non-specific risk factors (e.g., disrupted sleep, adverse childhood experiences) which contribute to the risk of developing psychosis as well as other mental illnesses. Research suggests the inclusion of these non-specific factors may improve our ability to identify those at risk. The present …

Methods For Finding Best Coset Codes For Physical-Layer Security, Andrew Glenn Swain

Theses and Dissertations

Finding best coset codes for secrecy over the binary erasure wiretap channel remains a difficult problem. Greater understanding of the structure of coset codes is necessary to reduce the problem space in which we search for these best codes. This dissertation presents new necessary conditions for a code to be best, including a condition that states that a code must maximize the minimum distance of both itself and its dual. It introduces and evaluates the accuracy of new heuristics to approximate the code's equivocation based on a code's weight enumerator polynomial. We also present a new tool for visualizing the …

Planning, Outcomes, Oversight: A Linguistic Analysis Of New Jersey Statutes And Reports From 1970 To 1999, Sharon E. Mccann

Theses and Dissertations

Between the decades of 1970 through 1999, there were major shifts in higher education in New Jersey. Utilizing a grounded theory approach this dissertation created a database of legislation, hearings transcripts, and education reports. Searching this database for commonly used terminology, this dissertation was seeking a pattern in language use that could demonstrate the incursion of neoliberal economic terminology into the way high education was discussed during these years. A grounded theory exploration, this dissertation does not claim to have achieved a proven connection between the language shift and decisions made by education leadership. All it can demonstrate is that …

To Decipher Genomic Evolution Of Dengue Virus And To Probe The Activation Mechanism Of A Her2 Directed Chimeric Antigen Receptor Toward Computer Aided Drug Design (Cadd), Mariya Hryb

Theses and Dissertations

This study encompasses three significant chapters focusing on diverse yet interconnected aspects of pharmaceutical research. Chapter 1 delves into the complexities of drug development, emphasizing the challenges and the pressing need for advanced technologies to streamline the process. Computational methods like Computer-Aided Drug Design (CADD) extend their scope beyond small molecules, aiding in the design of intricate biomolecules vital for biomedical advancements, especially in immunotherapy. Chapter 2 introduces the Near-Neutral Balanced Selectionist Theory (NNBST) validated through analysis of Dengue virus evolution. The unique features observed align with NNBST, surpassing existing theories. This approach offers a deeper understanding of viral evolution …

The Generation Of Terahertz Light And Its Applications In The Study Of Vibrational Motion, Aldair Alejandro

Theses and Dissertations

Terahertz (THz) spectroscopy is a powerful tool that uses ultrashort pulses of light to study the properties of materials on picosecond time scales. THz light can be generated through a variety of methods. In our lab, we generate THz through the process of optical rectification in nonlinear optical (NLO) organic crystals. THz light can be used to study several phenomena in materials, such as spin precession, electron acceleration, vibrational and rotational motion. The work presented in this dissertation is divided into two parts: (1) the generation of THz light and (2) applications of THz light. The first portion of this …

Tunable Dual-Phase Dual-Drug Delivery System Using A Plga Microparticle/Pva Hydrogel Composite, Timothy John Eck

Theses and Dissertations

Current drug-eluting coatings have demonstrated controlled long-term, sustained release but have only tried to mitigate short-term burst release as a negative side effect. For applications like wound healing, there is a need for a drug-eluting coating which is adjustable in both short- and long-term release, independent of each other. We present a tunable dual-phase dual-drug delivery coating composed of drug-loaded polymer microparticles and drug-loaded hydrogel which can control short term and long term release individually in this study. This coating was created using lidocaine and dexamethasone encapsulated in poly(D,L-lactide-co-glycolide) particles combined with lidocaine- and dexamethasone-loaded poly(vinyl alcohol) hydrogel. Hydrogel drug …

Multifunctional And Moisture Tolerant Zinc-Based Mono- And Bi-Metallic Metal-Organic Framework (Mof) Thin Films, Emmanuel Agbata

Theses and Dissertations

Many applications of metal-organic frameworks (MOFs) are highly dependent on their structures. The type and consistency of structure inform their properties. Zinc-based MOFs are applicable in different fields because of the low toxicity of zinc materials and are therefore also useful for catalysis. While MOF-5, a zinc-based MOF with carboxylate linkers is moisture intolerant, a variant of this is moisture tolerant. The introduction of a nitrogen-based linker in the zinc MOF which renders the structure moisture-tolerant. This material has not been explored as much, despite its multifunctional properties. Furthermore, the growth of Zn-based bimetallics of this MOF has not yet …

Modified Coulomb Approach For Squat Silos, Mitchell Cade South

Theses and Dissertations

Traditional methods for calculating lateral pressures in silos, such as Janssen's Method and Coulomb's Method, have limitations due to the underlying assumptions of each methodology. This research investigates an approach which adapts Coulomb's Method to account for the cylindrical geometry of silos. The Silo Wedge Method (SWM) distinguishes between two cases based on the aspect ratio (height/diameter) of the silo. Comparative analysis reveals that the SWM accurately matches Coulomb's Method for linear retaining walls when the silo aspect ratio approaches zero. As the aspect ratio increases above 0.25, the SWM exhibits behavior similar to Janssen's Method. This suggests a potential …

Development Of Zr(Iv) Mof-Enabled Nerve Agent Electrochemical Hydrolysis Sensors, Tyler James Marlar

Theses and Dissertations

Nerve agents are acetylcholinesterase inhibitors and among the most toxic chemical warfare agents ever synthesized. Detection of these chemicals is critical for the protection of populations and strategic resources. G-series nerve agents are volatile compounds. V-series nerve agents are persistent phosphonothioate compounds. Persistent nerve agents do not readily volatilize and can contaminate environmental resources for extended periods. While nerve agents are inherently non-electroactive, they can be hydrolyzed to electroactive products compatible with electrochemical sensing. Zr(IV) MOFs are next-generation nanoporous materials, which have been shown to rapidly catalyze nerve agent hydrolysis. In this work, the catalytic processes of MOF-808, a specific …

Studio As Laboratory: Prioritizing Artistic Fluency Through The Morphogenesis Of Paper, Jeannette Lina Neal

Theses and Dissertations

This paper describes a curriculum designed to examine relationships between artistic fluency in middle school art classrooms, and a robust year-long paper curriculum. A sustained focus with one material, such as paper, combined with relevant artists and investigative skills activities was designed to increase artistic fluency during a time when students often experience a decline in identity and confidence. Concerns with the U-curve theory suggest that many factors affect the continuity of art during these crucial years of school. Educational standards of the Reggio Emilia Approach can be applied to secondary education, encouraging both students and educator to create dynamic …

Developing An Artistic Self In Preservice Elementary Teachers: A Studio Art Curriculum To Promote Art Integration, Karilee D. Park

Theses and Dissertations

With the continual use of standardized testing, teaching art in schools, particularly elementary schools, often falls to generalist teachers with little to no experience in art. While art can be integrated into daily curriculum for deeper and lasting learning, without the proper training or support, generalist teachers are left to implement art as they encountered it in the past, if at all. Artistic anxiety and culturally misappropriated artistic experiences result in the arts being used inefficiently or avoided completely. Creating a curriculum for preservice elementary generalist teachers, I explored art integration through developing artistic confidence, skill, and identity for 16 …

Investigating The Antibacterial Properties Of Nanostructured Aluminum Surface, Quinshell Smith

Theses and Dissertations

Bacterial infections are a major public health concern. Bacterial infection can occur in any part of the body and can also cause the body to respond to its presence. Bacteria can be transferred to humans through water, food, air, and living vectors. The modes of transmission for bacterial infections are vectors, airborne, physical contact, and droplets. Current preventative measures have been put in place to combat this issue. These preventative measures include immunization of both animals and humans, personal hygiene measures, biocidal agents, and essential oils. Bacterial resistance has occurred due to these preventative measures being misused and overused. Bacteria …

General Non-Destructive Evaluation For Friction Stir Welding, Johnathon Bryce Hunt

Theses and Dissertations

Friction stir welding (FSW) is an advantageous solid state joining method for many different engineering designs. It was invented in 1991 by TWI and since that time a tremendous amount of research has been executed to understand and implement FSW in a myriad of materials in numerous industries such as aerospace, ship building, train, automotive, energy, agriculture and others. Most industries have strict weld inspection processes to validate a weld before it is put into service. One of the main weld characteristics that is measured is the size of any subsurface volumetric voids. The current standard to test friction stir …

Time-Dependent Strain-Resistance Relationships In Silicone Nanocomposite Sensors, Alex Mikal Wonnacott

Theses and Dissertations

Flexible high-deflection strain gauges have been demonstrated as cost-effective and accessible sensors for capturing human biomechanical deformations. However, the interpretation of these sensors is notably more complex compared to conventional strain gauges, partially owing to the viscoelastic nature of the strain gauges. On top of the non-linear viscoelastic behavior, dynamic resistance response is even more difficult to capture due to spikes in resistance during strain changes. This research examines the relationships between stress, strain, and resistance in nanocomposite sensors during dynamic strain situations. Under the assumption that both macroscopic stress and resistance are governed by microscopic stress concentrations at the …