Digital Commons Network^™

Microwave-Assisted Green Synthesis Of Spiroindolinopyranopyrazoles, Esther Owusu

Theses and Dissertations

Green Chemistry, usually known as sustainable chemistry, is widely implemented worldwide to safeguard human health and the environment. Recent investigations in organic synthesis and chemical transformation have demonstrated that green chemistry techniques are significantly reducing both chemical waste and reaction time. In order to fulfill this ecological requirement, it is crucial to lessen the utilization of perilous solvents and noxious chemicals, while also creating innovative reaction methods that decrease the production of trash. The implementation of such methodologies can greatly enhance the field of green chemistry. A more environmentally friendly synthetic method was utilized to generate spiro chemicals and their …

Patterns Of Interactions In Human-Machine Teams, Kazuhiko Momose

Theses and Dissertations

Increasingly capable machines, including Artificial Intelligence (AI) agents are playing a more important role in a wide range of applications, including human daily activities and safety-critical systems. They can benefit even more when humans and such machines agents work together as a team by leveraging each other's strengths and complementing each other to enhance overall performance. To design high-performing teams, it is critical to analyze the team dynamics and understand how humans and machines interact with each other. Collaboration, Coordination, and Cooperation (3Cs) are terms typically used to describe the behavior of teams. However, these terms tend to be used …

Psychology Graduate Student Experiences, Social Support, And Mental Health, Kathryn Lang

Theses and Dissertations

Graduate school is a highly stressful experience for many psychology students. Accordingly, graduate psychology programs need to identify and minimize unnecessary sources of stress on their students. Despite the importance of this topic, there is little research on factors that increase psychology graduate students’ stress. The present study determined how a student’s financial difficulties, quality of their social support, quality of their faculty support, number of adverse experiences they had in their program, the impact of a student’s negative experience in their program; and the population size of the location of their program affect a student’s mental health, perceived progress …

Developing Inclusive Practices Through Peer Coaching In College Science Teaching, Briana Miller

Theses and Dissertations

Historically underrepresented students pursuing STEM majors encounter systemic barriers. Students are more likely to experience success when faculty implement inclusive practices. Faculty often lack the pedagogical training necessary to adopt inclusive practices, further perpetuating inequities. To eliminate barriers and offer equitable opportunities for success in STEM majors, this case study explores the implementation of peer coaching and Culturally Relevant Science Teaching (CRST) in college level science teaching, focusing on the experiences of three participating faculty. Through a year-long professional development (PD) cycle, three science faculty members from a small liberal arts college engaged in reflective practices aimed at improving their …

Causes Of The Morphological Distinctiveness Of Ahuna Mons And Differences In Cryovolcanic Styles On Ceres And The Inner Uranian Satellites Miranda And Ariel, Caleb Strom

Theses and Dissertations

Ahuna Mons is one of the most distinctive features on the dwarf planet (1) Ceres and shows evidence of cryovolcanic activity on a main belt object in the geologically recent past. Ahuna Mons is unusual, however, in that it has a higher aspect ratio and sharper features than other candidate domes on Ceres. It also stands apart from cryovolcanic features identified on other suspected cryovolcanic worlds like Miranda and Ariel, where cryovolcanism is associated with double ridges and potential plume activity. In this work, dome age, based on crater counting, and aspect ratio are compared through correlative analysis to investigate …

Investigation Of Gas Injection Eor In Conventional And Unconventional Reservoirs Based On Laboratory Experiments And Field Pilot Tests, Jin Zhao

Theses and Dissertations

Currently, fossil fuels (including oil, natural gas, and coal) are still the dominant energy sources in the United States. However, their extraction and utilization generate a significant volume of carbon dioxide (CO2) and associated gases, such as methane (CH4), ethane (C2H6), propane (C3H8), etc. Injecting these gases back into deep oil reservoirs offers a practical means to enhance oil recovery while reducing air pollution. The target formations are usually characterized by good porosity and permeability to ensure sufficient injectivity and storage capacity. However, recent unconventional reservoir development indicated that tight formations could also be potential targets for enhanced oil recovery …

Learning-Based Feature Identification For Rendezvous And Capture Of Non-Cooperative Space Objects, Trupti Mahendrakar

Theses and Dissertations

In recent years, On-Orbit Servicing (OOS) and Active Debris Removal (ADR) have attracted increasing interest due to growing concerns about space debris. This debris poses a significant risk to spacecraft, as collisions can catastrophically end missions and potentially trigger a cascading chain reaction of more debris. Space debris ranges from tiny paint chips to large non-functional spacecraft and even launch vehicle components. One way to mitigate the formation of additional space debris is to reduce the total number of large non-cooperative resident space objects present in operational orbits. This can be achieved through two approaches: de-orbiting these objects as part …

A Comparative Analysis Of Early Algebraic Thinking Activities From U.S. And Singapore Primary Textbooks, Christian Joel Hernandez

Theses and Dissertations

Many studies highlight the challenges students face when transitioning to algebra at the secondary level. Introducing algebraic concepts and fostering algebraic thinking at the primary level can help mitigate these difficulties. Prior to formal algebra instruction, early algebra can be cultivated as a mode of thinking known as algebraic thinking. Several international curricula, such as Singapore Math, incorporate early algebraic thinking into the early stages of schooling. Singapore Math, renowned for its high performance in international assessments, has been widely adopted by schools seeking to replicate its success.

This study compares two primary-level mathematics curricula—CCSSM-aligned textbooks and Singapore Math—specifically focusing …

Synthesis Of Photocleavable Molecules For Neurological Applications, Nishal Madujith Egodawaththa Arachchilage Don

Theses and Dissertations

In recent biomedical research, the precise control of molecular dynamics through light activation has emerged as a powerful tool, particularly in the field of neurobiology. This approach involves the use of photocleavable cages or photoprotective groups (PPGs) that are chemically tethered to biologically active molecules such as neurotransmitters or calcium chelators. These cages remain inert until exposed to specific wavelengths of light, typically in the visible range, triggering the release of the active compound with high spatiotemporal precision.

For neurotransmitter systems, such as glutamate (Glu), which plays a critical role in synaptic transmission and memory formation, researchers have developed novel …

Novel, Ultra-Fast Electrochemical Sensors For The Enhanced Detection Of Neurotransmitters And Toxic Heavy Metals In Aqueous Solutions, Noel Manring

Theses and Dissertations

Neurodegenerative diseases (NDDs) are a growing global health concern, affecting millions of people worldwide. NDDs arise from the progressive loss of neuronal cell function, ultimately leading to cell death. Abnormal levels of neurotransmitters, the chemical messengers in the brain, have also been linked to NDDs. Despite various treatments and medications aimed at alleviating physical and mental symptoms, there is currently no cure or means to halt disease progression. While the exact pathogenesis of NDDs remain poorly understood, cognitive decline is largely attributed to brain volume reduction, particularly in the hippocampus. Clinical studies suggest that environmental factors, such as exposure to …

Machine Learning Methods For Quantification Of Glacier Variations Through Satellite Imagery, Robert D. Breininger

Theses and Dissertations

Glaciers around the world have experienced a trend of recession within the past century. Quantification of glacier variations using satellite imagery is of great interest due to the importance of glaciers as freshwater resources and as indicators of climate change. The potential methods to quantify glacier variations with increasing complexity include detecting the terminus location, quantifying the glacier surface area, and measuring glacier volume. Although there are methods in literature designed purposefully for glacier area segmentation that have achieved acceptable results, they are often localized to the region where their training data were acquired and further rely on training sets …

Theoretical Advancements In Hawkes Processes And Their Practical Applications, Xi Zhang

Theses and Dissertations

Hawkes self-exciting point processes have been widely used in fields such as seismology, finance and social media analysis. Despite decades of research focusing on these processes, several key aspects remain under-explored. These include broadly applicable methods for model evaluation and selection, intuitive nonparametric inference approaches akin to kernel density estimation for probability density functions, and strategies to enhance the performance of generative point process models in predictive tasks. In this dissertation, first, we extend the time-rescaling theorem, which is traditionally limited to non-terminating processes with complete observations, to accommodate terminating processes and incomplete observations as well. This extension allows for …

Advancing Biofabrication Methodologies To Develop Biomimetic Tissue Scaffolds For Musculoskeletal Applications, Nashaita Yezdi Patrawalla

Theses and Dissertations

Musculoskeletal injuries impose a significant global burden, affecting millions and generating an economic toll exceeding $14 billion. Tissue engineering has gained traction as a promising strategy offering potential for functional restoration of damaged musculoskeletal tissues. This research aims to advance biofabrication techniques for generation of biomimetic tissue scaffolds, by optimizing scaffold design and modulating fabrication process parameters to generate scaffolds for musculoskeletal regeneration with application-specific tailored properties. In this realm, collagen-based biomaterials have been extensively investigated for tendon and ligamentous applications, and in combination with bioceramics incorporated into the collagen framework to produce composite scaffolds that better recapitulate the native …

Morphometric Based Roughness Estimates For Wind Loading Applications In The Coastal Transition Zone, Hadley Rose Besing

Theses and Dissertations

This project was developed to support the Florida Tech Wireless Sensor Network System (WSNS) hurricane research team in determining wind loads during high-impact wind events. The WSNS team objectives included estimating the critical pressure (𝐶_p) from observed 3-s gusts during high impact weather events (tropical cyclones). The field work was conducted at a single-story residential home in Satellite Beach, FL approximately 400 m from the coast. During data collection periods, more than 1-million 20-second LiDAR wind profiles were observed.

The bulk roughness at the test residence is characterized utilizing an existing morphometric technique with geometry that is derived …

Heterogeneous Collaborative Robotics: Multi-Robot Navigation In Dynamic Environments, Tyler Nicholas Raettig

Theses and Dissertations

Abstract: The challenges of multi-robot navigation in dynamic environments, focusing on uncertainties in obstacle complexities, partial observation, and the transition of policies from simulations to the real world. The proposed approach utilizes a deep reinforcement learning (DRL) framework enabling a Light Detection and Ranging (LiDAR)-equipped robot to communicate with a camera-equipped robot to achieve optimal paths despite their different sensors. The key contributions include the development of a cooperative architecture for information exchange between robots, a DRL-based framework for learning navigation policies, and a training mechanism based on dynamic randomization for enhanced real-world adaptability. Experimental validation using Gazebo simulations demonstrates …

Mathematical Model For Helically Propagating Spatially Multiplexed Mimo Channels Inside Single Core Optical Fibers, Ibrahim Barka

Theses and Dissertations

It all started when our curiosity was sparked by observing light beams from a Multi-Channel Laser Source precisely coupled into a single-core optical fiber positioned on an optical bench in the lab. The multiplexed light beams, characterized by different spatial azimuthal angles, were guided by the fiber, tracing helical paths and producing a bright central spot with concentric rings depending on the launched angles, a phenomenon we came to call Spatial Domain Multiplexing (SDM). Conventional concepts of hybrid and LP modes couldn’t fully explain the behavior of SDM modes, leading us to the question of the types of field configurations …

Decoding Neural Networks: An Information-Theoretic Guide To Interpretability, Error Analysis And Efficiency, Mackenzie J. Meni

Theses and Dissertations

This dissertation addresses critical challenges in neural network design by leveraging entropy-based techniques to improve model efficiency, interpretability, and bias reduction. Focusing on the unique demands of computer vision applications, particularly object detection and classification for real-time systems, this work introduces a series of innovative methods centered on information theory. At the core of these methods is the Probabilistic Explanations of Entropic Knowledge (PEEK) framework, a tool developed to analyze and visualize entropy distributions across feature maps. PEEK offers insights into information flow within neural networks, making it possible to pinpoint layers that contribute meaningfully to decision-making or identify those …

Intent Visualization In Human-Agent Teams, Rahul Tushar Mehta

Theses and Dissertations

Despite advances in autonomous systems, effective collaboration between humans and intelligent agents remains a significant challenge, particularly in shared-control scenarios. This study investigates how intent visualization affects human-agent collaboration in telecollaboration scenarios, examining its impact on team performance, operator trust, and workload. Using a custom simulation environment and Wizard-of-Oz methodology, we conducted an experiment with 13 participants who completed exploration tasks under two conditions: a baseline interface and an enhanced interface with intent visualization. Results showed that while intent visualization did not significantly improve objective performance metrics, it led to a 22.6\% increase in explicit disagreements between operators and the …

Improving Robustness Of Learning-Based Approaches In Autonomous Systems And Engineering Education, Godwyll Aikins

Theses and Dissertations

This dissertation advances the development of robust learning-based approaches across two complementary domains: engineering education and autonomous systems. Through four studies, this research addresses critical challenges in preparing data-proficient engineers and developing reliable autonomous systems that can operate under uncertainty and incomplete information. The engineering education study examines how mechanical and aerospace engineering undergraduates conceptualize and develop data proficiency skills essential for modern engineering practice. Through interviews with 27 students, the research employs the How People Learn framework to analyze student perspectives on information literacy, data interpretation, and computational thinking. The findings inform pedagogical strategies for developing data proficiency in …

The Design And Implementation Of A Modular Tissue Engineering Test Bed To Pursue An Alternate Pathway Of Cell Culture Based Research, Ryley Patrick Griffin

Theses and Dissertations

The development of a Modular Automated Tissue Engineering Test Bed (MATETB) is the next step in the development of cheap and easily available in vitro cell regulatory systems for both academic and industrial purposes. This project outlined the framework and requirements for a device that could automatically regulate and collect data on a cell culture through the manipulation of its liquid environment. From this framework, a prototype was built. The device would fulfill cell culture needs while collecting data automatically and allowing for live viewing and imaging of cells. The device was comprised of a mechanical skeleton (MS), an environmental …

End-To-End Learning For A Low-Cost Robotics Arm, Abhishek Chothani

Theses and Dissertations

Robotic manipulation is a cornerstone of automation, with the ultimate goal of developing versatile systems capable of executing a wide range of real-world tasks autonomously. Traditional robotics approaches, while reliable and widely adopted in industrial settings, often struggle with adaptability, perception, and dynamic task execution. This thesis explores the evolution from classical robotics techniques to modern learning-based approaches, leveraging advancements in artificial intelligence to overcome these limitations.

Initially, the thesis presents a pick-and-place pipeline built using the Drake robotics framework and the KUKA iiwa robotic arm. This system employs a pseudoinverse controller for inverse kinematics to perform structured tasks like …

“How Can I Teach When I Was Not Taught How?”: Teacher Education For Mother Tongue Instruction For Stem In Southwest Nigeria, Motunrayo Adeosun

Theses and Dissertations

In this qualitative study, the experiences, training, and challenges of teachers in primary schools in a community in southwest Nigeria were explored. The purpose of this study was to identify the experiences of teachers about their training for mother tongue instruction and how they teach pupils with the mother tongue or local language of the community, the challenges faced by teachers in teaching with the mother tongue, and the strategies used by teachers to overcome the challenges. This study found that teachers received no training and there is no curriculum for the training of teachers to teach in the mother …

The Positivity Principle: Investigating A School Administrator Training Series Designed To Promote Systemic Positivity, Catherine Gillach

Theses and Dissertations

Education has historically been recognized as a stressful profession, yet the Covid-19 pandemic (2020) paired with intensified socio-political influences have exacerbated educator stress, anxiety, and negativity, prematurely pushing more career educators to leave the profession. Teacher and principal pre-service preparation programs largely neglect to train educators in strategies for personally managing negative stressors, and negativity mitigation strategies are often overlooked as a critical facet of school climate and culture. Therefore, the purpose of this dissertation in practice was to examine the degree to which a school administrator training series could stimulate personal and systemic positivity within participants’ schools in a …

Investigating The Relationship Between Teachers’ State Evaluation Rating And Their Classroom-Based Assessment Practices And Systems, Christopher Jones

Theses and Dissertations

This quantitative research study investigates the relationship between teachers’ evaluation rating and their classroom-based assessment practices using a survey approach. Four middle schools consisting of 39 (grades six through eight) teachers in the Southwestern U.S. participated in the study. Research has shown that when teachers regularly use a system of evidence-based classroom assessment practices, student achievement increases. The problem addressed within this investigation is that students nationwide are performing at lower proficiency rates in math and English Language Arts than previously seen. Results from this study indicate that even teachers rated “highly effective” on evaluations are not employing evidence-based assessment …

Investigation Of The Existence Of Vertically Oriented Ice Crystals In Winter Storms, Kendra R. Sand

Theses and Dissertations

The existence of vertically oriented ice crystals is investigated in winter storms, as observed through remote sensing and analyzed during the NASA Earth Venture Investigation of Microphysics and Precipitation for Atlantic Coast-Threatening Snowstorms (IMPACTS) field campaign field campaign. The primary objective was to determine if a preferred angle of ice crystal orientation could be identified in situ using contemporary airborne sampling instruments. Additionally, the study sought to explore potential correlations between the vertical orientation of ice crystals and electric field anomalies at cloud top, as well as the relationship between crystal orientation and particle concentration. To achieve these objectives, Two-Dimensional …

An Analysis Of Curricular Complexity Patterns In Undergraduate Mechanical Engineering Programs Using Federally Reported Data, Shane Schellpfeffer

Theses and Dissertations

With the recent development of curricular analytics tools designed to quantify the structure of a curriculum (Heileman, Abdallah, et al., 2018), some institutions of higher education are examining their curricula to find ways that these pathways to graduation can be improved (McMurtrie, 2021). The tools used to analyze curricula were created to address an issue of importance in the field of undergraduate engineering, that issue being the decreasing enrollment trend over the past two decades. The decrease in undergraduate engineering graduates in programs across the United States led to conversations in both academia and industry regarding potential solutions for this …

Barriers To Faculty Adoption Of Assessment: A Case Study In Engineering, Melodie A. R. Williams

Theses and Dissertations

This case study at an undergraduate teaching-focused engineering program in a small faith-based liberal arts university is designed to evaluate tools for assessing the engineering accreditor ABET’s Student Outcome Five – teamwork skills of engineering students. This evaluation would set the foundation for developing an assessment program that meets the needs of faculty, administrators, and accreditors. Activity theory is used as the theoretical framework for the study. A literature review lays the foundation for a novel conceptual framework asserting “faculty resistance” is actually “systemic friction.” The methodology is described, including data collection procedures, data analysis methods, and the approaches to …

Redefining Research Impact: Developing And Evaluating Modified H-Indexes For Comprehensive Academic Assessment, Nash Mayhue Minton

Theses and Dissertations

In academic research, the h-index has gained prominence as a useful metric for gauging the impact and productivity of researchers. This thesis seeks to provide a general overview of the h-index by providing information on the positive applications that the h-index utilizes, as well as the faults and limitations that diminish its utility. This thesis aims to combat the bias of hyper-authorship, which inherently inflates researchers' h-indexes by disproportionately attributing credit to individuals in multi-author publications, as well as provide other indices that could prove to be a possible replacement index or to be used as a basis for creating …

Soil Biogeography And Community Assembly In Polar Regions, Jesse Jorna

Theses and Dissertations

The polar regions provide community ecologists with natural microcosms, that include reduced species diversity, steep environmental gradients and limited human perturbance. Soil biodiversity in the polar regions is poorly understood, and the driving forces behind community compositions can range in scale from glacial forces 20,000 years ago to the impact of a researcher's footstep. Here, we present the results of an investigation of the driving factors behind biodiversity in Arctic and Antarctic soils, with specific attention to the role of community assembly processes. We suggest a framework for investigating the effects of inter-bacterial community processes like facilitation and argue for …

Enhancing Muscle Health And Modulating Immune Response With Galectin-1 In Lgmd2b/R2 Models, Stefannia Esparza Pulido

Theses and Dissertations

Limb-Girdle Muscular Dystrophy Type 2B/R2 (LGMD2B/R2) is a type of dysferlinopathy, a progressive muscle-wasting disorder caused by mutations in the dysferlin gene. Hallmarks of the disease include chronic inflammation, impaired muscle regeneration, and eventual muscle degeneration. Currently, no FDA-approved therapies are available for dysferlinopathies. Recombinant human Galectin-1 (rHsGal-1) has shown multiple roles in maintaining skeletal muscle homeostasis, promoting muscle repair, enhancing myogenesis, and modulating inflammation by downregulating the NF-κB pathway. The ability of rHsGal-1 to modulate the immune response is particularly promising for therapeutic applications in patients with LGMD2B/R2. In this study, we evaluated the effects of rHsGal-1 in a …