Digital Commons Network^™

Electrode Engineering To Minimize Degradation In Lithium-Sulfur Batteries, Saheed Adewale Lateef

Theses and Dissertations

Lithium-Sulfur (Li-S) batteries have recently received significant attention as a potential candidate for next-generation energy storage technology. This is due to its high theoretical capacity (1675 mAh/g) which can provide theoretical energy density of 2500 Wh/kg as compared to 400 Wh/kg of the current Lithium-ion batteries. Moreover, the earth-abundant sulfur element as well as its environmental friendliness endows unique advantages on the cost and environmental impact. However, there are several roadblocks that need to be addressed for commercial adoption of Li-S batteries, such as: (i) poor conductivity of sulfur and its discharged product; (ii) solubility of lithium polysulfides and their …

The Moderating Effects Of Community Involvement On The Association Between Witnessed Community Violence And Mental Health Outcomes Among Black Adolescents, Curtisha Tamara Shacklewood

Theses and Dissertations

Black youth and adolescents are at a disproportionately high risk for experiencing community violence exposure (CVE) and the potential influence it may have on psychological functioning. Research posits that Black youth who experience community violence are at a significantly higher risk of experiencing elevated internalizing symptoms (e.g., depression) and externalizing symptoms (e.g., delinquency). Previous research has utilized the ecological model to investigate interpersonal protective factors that potentially buffer the effects of CVE, including parental support and family characteristics. However, there is little research that explores community-level factors, such as community activities (e.g., youth activities and parental perception of collective efficacy) …

Leveraging After School Programs As Resources To Support Adolescent Health And Wellbeing Within Underserved Communities: A Qualitative Study, Olivia Staples

Theses and Dissertations

Over the past decade, youth have shown a consistent rise in stress, major depression, anxiety, and suicide, with underserved youth (low-income, minoritized communities) at greatest risk of exposure to chronic stress, related outcomes, and less access to health services (APA, 2017). Afterschool programs (ASPs), which serve as important resources in underserved communities, can be a critical support for youth health and well-being (Afterschool Alliance, 2019). However, few studies have examined ways in which ASPs address the challenges underserved youth face across their ecosystem to promote youth resilience (Jones & Deutsch, 2011). Using qualitative interview data from staff and youth across …

Stem Integration In The Classroom: An Exploratory Case-Study On Teachers Defining Their Stem Identity And Role As A Stem Educator, Tawana Guillaume

Theses and Dissertations

The push for inclusion of science, technology, engineering, and mathematics (STEM) as a meta-discipline in K-12 education is recognition that the challenges faced by society require technology skills, interdisciplinary problem-solving, and an increased number of people entering STEM professions (Dare et al., 2014; English, 2016; Fan et al., 2021; Holstein & Keene, 2013; Roehrig et al., 2012, 2021; Sanders, 2008). The dissertation in practice explored STEM teacher identity and conceptions of STEM as a function of STEM professional experience outside of the field of education. The exploratory casestudy sought to identify the relationship between STEM career-based experiences – specifically the …

Improved Extraction And Detection Of Disinfection Byproducts, Impacts Of Wildland-Urban Interface Wildfires On Drinking Water, And Change In Disinfection Byproducts Over Time In Chlorinated Vs. Chloraminated Distribution Systems, Patrick Thomas Justen

Theses and Dissertations

Drinking water disinfection is critical to prevent the occurrence of waterborne pathogens in drinking water. However, disinfection causes the unintended formation of disinfection byproducts (DBPs) through the reaction of disinfectants (e.g., chlorine, chloramine) with natural organic matter (NOM), algal matter, or anthropogenic pollutants present in source waters. Exposure to DBPs is associated with increased bladder cancer, colorectal cancer, miscarriage, and birth defects. The U.S. EPA currently regulates eleven DBPs in drinking water—four trihalomethanes, five haloacetic acids, bromate, and chlorite. However, research shows that DBP related toxicity in drinking water is driven mainly by other, non-regulated DBPs, particularly iodinated DBPs and …

​​​Creating A Resident And Fellow Scholarly Activity Tracking Tool In A Large Academic Health System: A Dissertation In Practice​, Elyse Anne Wieszczecinski

Theses and Dissertations

Documenting and reviewing resident and fellow scholarly activity within a sponsoring institution can be a laborious task. With multiple lines of information coming from a wide variety of sources, this problem of practice implemented the Information Systems Success Model to help develop a database by which this information can be collected in a way that is efficient while maintaining the need for a user-friendly product. While other healthcare entities have also incorporated this model into their scholarly activity collection, these are still individual needs of the sponsoring institution and its constituents to consider when adapting the strategy. Using an improvement …

Coefficients Of The Characteristic Polynomial Of A Hypergraph And Their Combinatorial Properties, Utku Okur

Theses and Dissertations

We investigate the combinatorial properties of the characteristic polynomial $\phi_\mathcal{H}\ev{t}$ of a hypergraph $\mathcal{H}$, in particular, its coefficients. Due to a classical result of Jacobi, the generating function of closed walks at a vertex $u$ in a graph $G$ is determined by the rational function $\phi_{G-u}(t) / \phi_G(t)$. The connection between closed walks of $G$ and its characteristic polynomial has a known elegant proof via an application of Viennot's Heaps of Pieces framework, where cycles are taken as pieces and the concurrence relation is sharing a vertex. Here, we prove a bijection between heaps with a unique maximal piece containing …

Inspiring Girls To Fill The Blank Space In Stem: The Impact Of An After-School Coding And Robotics Club On Elementary Female Students' Engagement And Self-Efficacy In Computer Science, Lisa Guenther Wilbanks

Theses and Dissertations

The purpose of this action research was to describe how participation in an after-school coding and robotics program influenced elementary female students’ engagement and self-efficacy in computer science. According to a 2023 report from the National Science Foundation, in 2020 women earned only 21% of computer science degrees and 24% of engineering undergraduate degrees in the United States. As two of the fastest growing fields, the lack of female perspectives and experiences will continue to limit innovation in these areas. Studies show that gender gaps in engagement and self-efficacy in STEM begin long before students enter college and the workforce, …

Adipokines Mediate Fat-To-Ovary Communication To Regulate Oogenesis, Adipocyte Size, And Lipid Storage In Drosophila Melanogaster, Chad Herbert Simmons

Theses and Dissertations

Humans have complex signaling pathways that allow them to store and expend energy based on nutritional quality and availability. Inter-organ signaling is used to communicate nutrient availability between organs based on nutritional needs and the rate of cellular division. Our main overarching question is to investigate how fat-derived signals affect adipocyte morphology and the maintenance of stem cells in the ovary. While signaling pathways, like insulin and mTOR, and some adipokines that are involved in inter-organ nutrient sensing have been identified, the exact nutrient reliant mechanisms of stem cell maintenance are not completely understood. Using Drosophila melanogaster as a model, …

Thesis: Comparing Functional And Effective Brain Connectivity Metrics For Eeg, Diksha Srishyla

Theses and Dissertations

Background:Brain connectivity measures have been used to study communication between brain regions using electroencephalography (EEG). Functional and effective connectivity estimate the synchronization and the flow of information between regions, respectively. However, findings from studies using different measures to investigate similar connections do not converge. To guide the selection of functional and effective connectivity measures in future studies, we systematically compared a set of measures in the context of resting state EEG. We examined four functional connectivity metrics (coherence (Coh), the imaginary part of coherence (imCoh), the corrected imaginary part of phase lagged value (ciPLV), the debiased weighted phase-locking index (dwPLI)) …

Ai-Driven Autonomous Manufacturing: A Novel Taxonomy, Vision-Guided Planning, And Diversity-Aware Active Learning Frameworks, Ibrahim Yousif

Theses and Dissertations

Manufacturers face two opposing challenges: the escalating demand for customized products and the pressure to reduce lead times. Current manufacturing equipment, although reliable, operates at the limits of its technology and lacks adaptability to dynamic environments. This trade-off has been described as the optimal degree of automation, a threshold beyond which further automation incurs more cost than benefit. Smart manufacturing has introduced adaptive, data-driven systems, but many deployments still lack the contextual adaptability and autonomous decision-making required to handle unplanned disruptions. This underscores the need for intelligent, autonomous systems capable of real-time adaptation without costly reconfiguration, minimizing human intervention during …

Towards Accurate First-Principles Modeling In Heterogenous Catalysis: Ethane Dehydrogenation And Hydrogenolysis Over Pt Catalysts, Mubarak Ayo Bello

Theses and Dissertations

First-principles modeling has become central to heterogeneous catalysis research, offering mechanistic insight and guiding catalyst design, yet conventional approaches often struggle to accurately describe complex catalytic systems due to methodological uncertainties, simplified assumptions, and the structural diversity of nanoparticle catalysts. This dissertation addresses these challenges using ethane dehydrogenation (EDH) and hydrogenolysis (EH) over platinum catalysts as model systems. The first study benchmarks density functional theory (DFT) functionals against the random phase approximation (RPA) for the EDH network on Pt(111), identifying cost-effective functionals and demonstrating the efficiency of BEEF-vdW ensembles for capturing functional uncertainty. The second study (addressed in prior work) …

Hearing The Difference: Just Intonation Techniques Utilizing Distortion Product Otoacoustic Emissions In Viola Performance, Calj Green Umezono

Theses and Dissertations

Difference tones, also known as distortion product otoacoustic emissions, are the result of active phenomena in the human cochlea during the conversion of sound waves into bioelectrical signals. Difference tones make it possible to explore alternative musical tuning systems beyond the twelve-tone, equally tempered regime. Musicians have investigated difference tones since the 18th Century in Euro-American musical contexts, but their application has so far been limited in scope. Advances in science, technology, and music theory from the late 19th Century through the early 21st Century have given present-day violists the opportunity to more fully understand the virtues of difference tones …

Machine-Learning-Assisted Discovery Of Lattice Dynamics Signatures Of Sodium Superionic Conductors, Ogheneyoma Maxwell Aghoghovbia

Theses and Dissertations

Sodium superionic conductors are key to the development of all-solid-state sodium batteries. Discovery of new superionic conductors has traditionally relied on insights from material defect chemistry and the transition/hopping theory, while the role of lattice vibrations, i.e., phonons, remains underexplored. We identify key lattice dynamics signatures that govern ionic conductivity by analyzing the phonon mean squared displacement (MSD) of Na⁺ ions. By high-throughput screening of a dataset of 3903 Na-containing structures, we establish a strong positive correlation between phonon MSD and diffusion coefficients, providing a quantitative correlation between lattice dynamics and ion transport. To accelerate this discovery, we incorporate …

Multi-Perspective Feature Learning For Facial Expression Recognition In The Wild, Xiangyu Hu

Theses and Dissertations

With the rapid progress of deep learning, Facial Expression Recognition (FER) has seen substantial improvements in performance, particularly “in the wild” meaning real world conditions. Despite these advances, most existing methods extract features from facial images as the sole emotional cues, which limits the model’s ability to capture the full complexity of human emotional expressions.

In reality, facial expressions are composed of diverse and multi-perspective information, including appearance-based cues and geometric structural deformations due to activations of facial muscles. Depending exclusively on one type of representation may fail to exploit the complementary nature of these cues, an issue that becomes …

New Approaches On Source Coding For Quantum Stochastic Sources And Implementation Of Quantum Fanout Gate, Rabins Wosti

Theses and Dissertations

The accurate computation of advanced quantum algorithms like Shor’s integer factorization, quantum phase estimation (QPE), and the quantum Fourier transform (QFT) requires quantum circuits of considerable size and depth. It is difficult to achieve reliable computation with deep quantum circuits due to the limited coherence times of the current noisy quantum devices. The quantum fanout gate is known to be a powerful primitive for reducing the depth of many quantum circuits (Høyer and Špalek 2003; Gottesman and Chuang 1999). Shallow or constant-depth quantum circuits are desirable for both near-term and fault-tolerant quantum computations as they reduce noise and allow faster …

The Church As An Ecological And Cultural Anchor: Examining Its Role In Gifted Education, Advanced Academic Access, And Educational Equity, Matrissa Bennett

Theses and Dissertations

This action research study examines the role of the Black church as an ecological and cultural anchor in addressing the inequities of gifted education and expanding access to advanced academic opportunities for Black students. The study is grounded in Bronfenbrenner’s ecological systems theory, critical race theory, and racial and ethnical socialization, and it explores how the Black church can support student development, empower parental advocacy, and partner with schools to promote educational equity. Conducted at Mountain Valley Baptist Church in South Carolina, the interventions included student mentoring, goal setting sessions, academic enrichment, emotional support initiatives, a parent workshop, and a …

Developing A Dynamic Bilingual Space In An Early Childhood Korean Heritage Language Classroom Through Multimodal Translanguaging Pedagogy, Kyungjin Hwang

Theses and Dissertations

Drawing on translanguaging theory and multimodal literacy, this dissertation examines how a multimodal translanguaging pedagogy can create a dynamic bilingual space in a Korean heritage language classroom in the southeastern United States. Using a teacher-research design and thematic analysis of classroom video recordings and student artifacts, the study explored ten instructional modules with Korean-American children aged five to six. It first identified the core components of the pedagogy, its framework, curriculum content, and teacher strategies, and then analyzed how children flexibly used Korean and English across modes such as speaking, writing, and drawing. Findings revealed diverse translanguaging forms and functions. …

Investigating The Influence Of Instructional Strategies On The Development Of Procedural And Conceptual Knowledge In Advanced Algebra Ii Students, Maura Frances Yinger

Theses and Dissertations

This mixed-methods action research study investigated the influence of instructional strategies shown to improve students’ procedural and conceptual understanding in a rational expressions and equations unit in Advanced Algebra II. The instructional strategies used in the study include comparing, self-explaining, and exploring before instruction. The students (N=27) completed a pre-test and a post-test, both of which were followed by questions asking students to justify their responses on two questions. All students also responded to six digital self-explanation journal prompts. Randomly selected students were placed into three homogenous groups to participate in performance task observations. Analysis of the data …

Eeg And Media Multitasking: Adhd As A Moderating Factor, Xiaoying Guo

Theses and Dissertations

Media use has become an integral part of everyday life. It has risen dramatically over the past century with the advent of television, computers, and digital platforms, and more recently, it has been characterized by individuals using multiple devices simultaneously (Bushman & Anderson, 2001; Nielsen Media Research, 1998; Rideout & Robb, 2019, 2021). Media multitasking (MMT) has been linked to cognitive control challenges and attentional difficulties. This study examined EEG workload (Fz theta/Pz alpha ratio), survey accuracy, and ADHD traits (ASRS v1.1) in 33 adult participants across baseline and single-versus dual-media conditions. Results indicated that mental workload was significantly higher …

Exploring The Diversity And Biology Of Unique Giant Broad Host Range Bacteriophages In Natural Environments, Tannaz Mohammadi

Theses and Dissertations

Microbial interactions within the rhizosphere play a crucial role in shaping bacterial community diversity and function. To explore these dynamics, we isolated 21 bacterial strains from soil and plant root samples collected near Rocky Branch Creek on the University of South Carolina campus. Our findings revealed that a significant proportion of these bacteria are lysogenic for CbK-like phages belonging to the Dolichocephalovirinae subfamily. Additionally, we isolated free bacteriophages directly from the same soil samples and found them to be closely related to those harbored within lysogenic bacteria. Surprisingly, despite predictions of a narrow host range, most of these phages, both …

Unveiling Caulocovert: Conserved Phage And Gene Transfer Agent In Caulobacter, Talia Neco

Theses and Dissertations

Bacteriophage play an important role in bacterial evolution, population control, and horizontal gene transfer within microbial ecosystems. This study focuses on the discovery and characterization of Caulocovert, an active bacteriophage identified in multiple Caulobacter strains. Using genome annotation tools such as Artemis and Mauve, we identified multiple key phage genes, including the major capsid protein, head-tail connector, portal protein, and major tail protein. These phage genes are present in CB13 and several other strains, such as C. vibriodies CB15 and CB2, C. segnis CBR1, Caulobacter sp. FWC26, and the distantly related Caulobacter sp. D5 strain. The location of these genes …

The Impact Of Project-Based Learning On Future First Generation College Students’ Oral Communication Skills, Presentation Skills, Confidence Levels, And College And Career Readiness, Mandana Marashi

Theses and Dissertations

The purpose of this action research was to evaluate the impact of a project-based learning innovation course on high school students’ oral communication, presentation skills, confidence levels, and college and career readiness in a college and career readiness program housed at a university in the Mid-Atlantic region. Effective oral communication and presentation skills have been continuously emphasized by national organizations and employers to be critical skills for success in students’ academic and professional lives. However, teaching oral communication and presentation skills to high school students has been neglected, which has negatively affected students’ college and career readiness, particularly for students …

Journey To Proficiency: The Impact Of Explicit Problem-Solving Instruction In A Fifth-Grade Math Classroom, Brittany J. Terry

Theses and Dissertations

This action research study examined the impact of explicit problem-solving instruction on fifth-grade students’ mathematics proficiency and attitudes across skill levels. At the outset, students relied on rote procedures rather than conceptual reasoning, limiting their ability to apply skills in new contexts or understand why procedures work. Grounded in constructivist and sociocultural learning theories, the study aimed to move students beyond procedural fluency through explicit instruction of problem-solving strategies, modeling, guided practice, collaboration, and reflection. Over 8 weeks, 32 students participated in daily lessons. Findings from pre–post assessments, interviews, and portfolios indicate that explicit problem-solving instruction supported measurable growth in …

Journey Toward Collective Efficacy: ​The Impact Of Lesson Study In A Professional Learning Community, Julia Rose Pabst

Theses and Dissertations

This mixed methods action research study investigated the impact of a lesson study protocol on elementary teachers’ confidence through the implementation of the Three Read Close Reading Protocol (3RCRP), a research-based reading comprehension strategy. This study, grounded in Bandura’s Social Cognitive Theory, explored how collaborative and practice-based professional learning could bridge the gap between pedagogical knowledge and classroom practice to enhance teacher self-efficacy. The primary research questions focused on how participation in a lesson study influenced teachers’ self-efficacy and which aspects of the protocol were perceived as most influential. Four participants and one participant-observer engaged in a series of Professional …

The Impact Of Incorporating Crp And Growth Mindset Into The Learning Environment For Increasing Student Enrollment In Advanced Mathematics Courses, Srinivas Akella

Theses and Dissertations

This mixed-methods action research study explored the impact of incorporating Culturally Relevant Pedagogy (CRP), goal setting, and growth mindset strategies into the learning environment of an advanced mathematics course. The overall goal was to increase enrollment of underrepresented student groups in advanced mathematics courses at a small rural high school in Georgia. The problem of practice addressed in this study is the underrepresentation of African American students in advanced-level mathematics courses, such as Precalculus and Calculus, due to structural, cultural, and psychological barriers. Despite the importance of advanced mathematics for college readiness and access to STEM careers, students from underserved …

The Role Of Prelimbic Projections To The Rostromedial Tegmnetal Nucleus In Cue Discrimination, Emma Lane Carlson

Theses and Dissertations

Maladaptive decision-making, such as persistent reward seeking despite negative consequences, is a hallmark of substance use disorder (SUD) and related psychiatric conditions. These behaviors are thought to arise from impairments in aversive learning and disrupted neural signaling that normally supports behavioral inhibition. The prelimbic cortex (PL) plays a critical role in encoding cue–outcome associations and exerting top-down control over behavior, while the rostromedial tegmental nucleus (RMTg) serves as a GABAergic inhibitor of midbrain dopamine neurons in response to aversive stimuli. Although both structures have been implicated in reward and avoidance processes, little is known about how direct PL-RMTg projections contribute …

Enhancing Teacher Self-Efficacy In Ngss Storyline Implementation: A Mixed Methods Action Research Study On Professional Development In Middle School Science Education, Dena Spickard Fender

Theses and Dissertations

This mixed-methods action research study examined how professional development (PD) influences middle school science teachers’ self-efficacy in implementing the Next Generation Science Standards (NGSS) Storyline curriculum. The study also explored which aspects of PD are most effective in supporting teachers at different career stages. Teacher self-efficacy is a critical factor in the successful adoption of reform-based science instruction, yet limited research has investigated how PD can be differentiated to address the needs of novice, intermediate, and veteran educators in underperforming schools.

A convergent mixed-methods design was employed to collect both quantitative and qualitative data. The Science Teaching Efficacy Belief Instrument-A …

Integrity On The Line: An Action Research Investigation Into Cheating Behaviors Among Honors Students, Latasha Arda Smart

Theses and Dissertations

Academic dishonesty remains a persistent issue in education, undermining both learning and institutional integrity. While it has been extensively researched in general contexts, little is known about its occurrence in high-achieving settings such as honors classes, where students are frequently under increased performance pressure. This action research study investigated the prevalence, causes, and consequences of cheating behaviors among honors students at a rural high school.

The study centered on Ajzen’s Theory of Planned Behavior, Bandura’s Social Cognitive Theory, and Merton's Strain Theory. Data were collected using a qualitative case study design, which included semi-structured interviews with students, teachers, and administrators, …

The Processing Of Emotional Prosody And Semantics In Native And Non-Native Chinese Speakers, Cheng Xiao

Theses and Dissertations

Emotional information in spoken language is conveyed through both semantic and prosodic cues. While listeners interpret the meaning of utterances (what is said), they also detect the speaker’s emotional prosody (how it is said). For non-native speakers, processing these two types of information simultaneously can be challenging, particularly in a tonal language such as Mandarin Chinese, where the same acoustic feature (i.e., pitch) encodes both lexical semantics and emotional prosody. This dissertation reports a series of behavioral and fMRI experiments investigating how native and non-native Chinese speakers perceive and process emotional prosody and semantics in words and sentences. Behaviorally, results …