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Preparation And Spectra Of Some New Alkyl Ammonium Salts Of The Tetrachlorocuprate (Ii) Ion., Paul Douglas Griffin

Masters Theses

"Several compounds containing the complex tetrachlorocuprate(II) anion, CuCl₄⁼, and various alkyl or aryl cations were prepared. These include bis(methylammonium)tetrachlorocuprate(II), bis(isopropylammoniumtetrachlorocuprate(II), 1,3-propanediammoniumtetrachlorocuprate(II), bis(furfuryl-ammonium)tetrachlorocuprate(II), and a series of ethylene ammonium salts. Some unsuccessful and difficult preparations are described. Spectra were taken in acetone, 4-butyrolactone, and methanoleaf An explanation of the effects of various solvents on the absorption spectrum and structure of the complex ion is given"--Abstract, page ii.

Stress Analysis Of A Wall Footing Subjected To External Vertical Loads And Overturning Moments By The Finite Element Method, Adil Godiwalla

Masters Theses

"This investigation pertains to the stress analysis by the finite element method of a wall footing subjected to external vertical loads and external overturning moments. This problem has been reduced to a two-dimensional stress analysis problem by taking a unit length of the wall. A rectangular plate - element is used throughout this investigation. The development of the matrix equations is shown and the solution is performed by digital computer. Stresses in the horizontal direction show essentially linear variation which is in agreement with simple structural theory, while stresses in the vertical direction show severe perturbation near the column load. …

Vapor Pressure And Evaporation Coefficient Of Cadmium Oxide, R. Tom Coyle Jr.

Masters Theses

"Knudsen effusion experiments were carried out on CdO in fused silica crucibles at temperatures of 918°K, 1008°K with orifice areas from 2.742x10^-3 cm² to 30.52x10^-2 cm². The experiments were made in a molybdenum-wire, resistance-heated vacuum furnace. Several orifice areas were used at each temperature and reciprocal pressure versus orifice area plots were made. These plots yielded an upper limit to the evaporation coefficient of. 4.15x10^-2. An equilibrium constant for the vaporization reaction

CdO(s) = Cd(g) + 1/20₂ (g)

of

log Keq = 11.12 - 1.952x10⁴/T.

was obtained. Second and third …

Comparative Analysis Of Polynomial Root Finding Techniques, Charles Ray O'Daniel

Masters Theses

"The purpose of this study was to investigate and recommend various methods instrumental in finding the roots of a polynomial p(x) = 0. Many different methods are present today, and each has its advantages and disadvantages.

Through thorough investigation, the author has ascertained the key methods to be the method of Bisection, the Newton-Raphson method, and the Bairstow method. Special support in the form of algebraic theorems on the locations and kind of roots are extremely helpful. This combination of theorems and methods provides assurance, speed, and the ability to obtain complex roots.

The Bisnewbar method developed by this author …

Gap-Graded Gravel For Asphaltic Paving Mixtures, Ernest Harrington Martin

Masters Theses

"The objective of this investigation was to determine if naturally occurring gap-graded gravel can produce asphaltic mixtures meeting minimum requirements for satisfactory pavement behavior.

Ten gap-graded mixes were blended by eliminating certain intermediate sized fractions or combination of fractions from the gradation of a control mix. The weight of the fractions eliminated was distributed to either the coarser or finer aggregate fractions.

All specimens were prepared and tested in strict accordance with procedures set forth in ASTM Designation D1559, "Resistance to Plastic Flow of Bituminous Mixtures Using Marshall Apparatus."

The physical properties compared and analyzed were (1) unit weight, (2) …

Dynamic Response Of A Simply Supported Beam To An Accelerating Point Load, Joseph Victor Cusumano

Masters Theses

"An analysis based on linear theory is presented for determining the dynamic response of a simply supported beam on an elastic foundation acted upon by a moving time dependent point force with axial forces included. This thesis extends the present theory to include an analysis of a point force accelerating uniformly across the beam. In particular, it is shown that the customary resonance conditions which are prevalent for a point force moving with uniform velocity no longer exist for the case of a point force accelerating uniformly across the beam.

The basic problem and its solution are presented for a …

Stresses In A Thick Spherical Shell, David Wayne Moore

Masters Theses

"This thesis reports a method to evaluate the stresses in a segment of a thick spherical shell. In the numerical examples loads due to thermal expansion as the shell is constrained at the free edge and a dead load acting vertically downward were considered for a shell assumed pinned but free to rotate and for a shell assumed completely fixed at the edge. A concrete shell was specifically studied but the method would also apply to a shell of any homogeneous, isotropic material"--Abstract, page i.

Convective Heat Transfer In Small Cylindrical Enclosures Heated From Below, Donald Wayne Land

Masters Theses

"Free convection in enclosed air spaces is often of prime importance in the design and analysis of panels utilizing the insulating properties of air and other gases. Previous investigations were performed on very thin air layers.

This thesis presents the results of an experimental investigation to determine the heat transfer by convection and conduction through air layers with relative sizes in terms of length/diameter ratios of one-fourth to one.

Eight cylindrical samples were tested. Four had inside diameters of 2.0 inches, and the others were 2.75 inches in diameter. Heat was transferred across the air layers by both conduction and …

A Study Of The Complexes Of Diketocyclobutenediol, Stewart Michael Condren

Masters Theses

"In this study of the complexes of diketocyclobutenediol, squaric acid, the following original compounds were prepared: zirconyl squarate, indium (III) squarate; titanium (III) squarate, ruthenium (III) squarate, tungsten (VI) squarate, vanadium (III) squarate, and niobium (V) squarate, where squarate refers to the dianion of diketocyclobutenediol. Metal analyses were made on all of these except the ruthenium. However, only three of these metal analyses, namely those for titanium (III) squarate, indium (III) squarate, and zirconyl squarate, warrented [sic] further investigation. Carbon and hydrogen analyses were then made for these three compounds. From the percentage compositions, possible structures were proposed.

The tungsten, …

A Study Of Selected Audio-Visual Materials Used In South-Eastern Illinois Secondary School Drafting Programs, Robert L. Trueblood

Masters Theses

No abstract provided by author.

Foreign And American Students Opinions Of Social, Political And Religious Attitudes In The American Culture, Robert K. Luther

Masters Theses

No abstract provided.

Guidance Activities For The Elementary Teacher, Sherry Blew

Masters Theses

No abstract provided.

A Survey Of Entry Jobs And Entry Requirements In Primary Metal And Fabricated Metal Firms In Rock Falls And Sterling, Illinois, E. Kenton Peak

Masters Theses

No abstract provided.

Comparison Of General Athletic Ability Of Four Groups Of College Athletes As Measured By Cozens' Test Of General Athletic Ability For College Men, Theodore James Schmitz

Masters Theses

No abstract provided.

Two Operas Of Benjamin Britten: An Analysis Of Style, Richard O. Scott

Masters Theses

No abstract provided.

Studies On The Effects Of Toxic Materials On The Respiration Rate Of Tubificidae, Richard A. Sikora

Masters Theses

A study was made to determine the effect of lead, nickel and pentachlorophenol, at varying pH levels, on the respiration rate of this family of aquatic oligochaetes. Respiration was measured as the ul. of oxygen consumer per mg. of live tissue per hour of exposure.

Worms were found to decrease their rate of respiration in the presence of lead nitrate. This was demonstrated at three pH levels: 6.5, 7.5 and 8.5. It was concluded that this drop was due to the action of lead on the enzymes of the metabolic systems and on the characteristic of lead which stimulates the …

A Rhetorical Analysis Of John F. Kennedy's "Inaugural Address" Of January 29, 1961, Marjorie T. Hutton

Masters Theses

No abstract provided.

A Comparative Study Of The Concept Of Man As Revealed In The Works Of Certain Contemporary Painters, Larry S. Barnfield

Masters Theses

No abstract provided.

A Ten Year Educational Plan For Paris Union District #95, Paris, Illinois, Joseph A. Doglio

Masters Theses

No abstract provided.

A Determination Of The Rate Of Evaporation Of Zinc At Atmospheric Pressure., Yu Ming Su

Masters Theses

"Measurements of evaporation rates of zinc in three different residual gases, e.g., argon, carbon monoxide, and hydrogen at one atmosphere pressure, were made. It was found that the rate of evaporation of zinc in one atmosphere of argon was almost the same as that in carbon monoxide, while the rate in hydrogen was almost twice the rate in argon or carbon monoxide. Measurements of evaporation rate of zinc in one atmosphere of argon-oxygen mixtures were also made. The evaporation rate was considerably reduced because the formation of the oxide film retards the zinc vapor escaping from the evaporating surface"--Abstract, page …

The Design Of A Drum Memory System, Frederick W. Lynch

Masters Theses

"Three methods for obtaining an auxiliary memory for an SCC-650 (Scientific Control Corporation) digital computer are presented. A logic design is then developed on the basis of using the drum and write circuits from an available IBM-650 digital computer and constructing the remaining logic functions. The results of the logic design are the transfer equations necessary to implement the memory system"--Abstract, page ii.

Shutdown Reactivity Worth Of Reactor Control Rods By A Subcritical Multiplication Method, Leslie Roger Conner

Masters Theses

"Two modified subcritical multiplication methods for measuring the reactivity worth of control elements were developed and investigated. The first involved the calibration of a subcritical count interval by the asymptotic period method. The second involved the calibration of a subcritical count interval by a rod interchange with the reactor regulating rod which had previously been calibrated by the asymptotic period method. The accuracy of these methods is relatively poor. this inaccuracy is due to shadowing effects and to the spatial harmonics which exist in the core. An investigation of the spatial harmonics to determine the best location for the neutron …

The Design And Construction Of An Apparatus For The Plane Wave Analysis Of Mufflers, Stephen Philip Buckley

Masters Theses

"In the following report, a method for evaluating the attenuation characteristics of a general muffler as well as the design, construction and use of the associated apparatus are described. The method combines accepted plane wave theory and experimental techniques into a relatively straightforward approach to the analysis of acoustic filters. Equations are developed to cover the frequency range between 300 and 4000 cycles per second. Deviations from these equations extend the use of the equipment to low frequencies without the need for unduly long and cumbersome apparatus. This method, which may be called the standing wave method, utilizes a standing …

Synthesis Of Filters Using Distributed Rc Networks, Mario Nader Nader

Masters Theses

"This paper deals with the problem of realizing filter and delay functions by means of distributed RC devices. The method is made possible through the use of a distributed RC network which possesses rational admittance parameters. The technique of approximating transfer functions using polynomial factors that are ration in e[superscript (a square root of s] is explained. These factors are used to approximate the magnitude and phase characteristics for a low-pass filter. This filter is then realized using the admittance functions studied by Wyndrum, the "s->W" transformation, and Richard's theorem. Those factors are then used to approximate high-pass and …

A Study Of The Afterglow Of An R-F Excited Mercury Discharge, James A. Aubrecht

Masters Theses

"The short duration afterglow of an r-f discharge in mercury has been examined versus ground state mercury atom density and r-f power. The intensity of the 5771, 5462, 4360, 4079, 4047, 3907, 3651/56, 3342, and 3127/32Å atomic mercury lines were observed to decay as a function of time after the shut off of the active discharge. At temperatures below 333⁰K, all atomic lines decayed exponentially, and no molecular emission was observed. From 333⁰K to 423⁰K, the atomic lines were observed to decay rapidly initially, then exhibit an enhancement effect in intensity which was produced by metastable atom collisions, and finally, …

Estimation Of Regional Trends In Gravity Using Gram Orthogonal Polynomials, Stanley Dean Thompson

Masters Theses

"A computer program is presented which estimates the trend in a rectangular array of gravity measurements. It is assumed that the regional trend of gravity may be estimated by a low-order polynomial. The method of least-squares is applied to solve for the low-order polynomial which best approximates this trend. Gram orthogonal polynomials are used in the solution of this least-squares surface fit. The program is tested on a known polynomial and on some hypothetical Bouguer gravity data and found to approximate the ʺregional trend of gravity in these cases. The importance of eliminating any significant noise in the observations before …

Negative Resistance In Cadmium Sulfide., John William Mohr

Masters Theses

"A light-sensitive, negative-resistance phenomenon has been observed in a special two-terminal CdS device fabricated from selected single crystals. The device differs from those used in previous investigations in that one end of the device was masked to keep out visible light and that the phenomenon was observed at room temperature. A method is described which enables the phenomenon to be observed on a reproducible basis. It was found that the CdS single crystal must have a relatively high density of traps. Possible mechanisms which may contribute to the phenomenon are discussed"--Abstract, page ii.

Scanning Properties Of Unsymmetrically Loaded Aperture Arrays, Gary Dean Brunner

Masters Theses

"Radiation patterns resulting from an array of waveguide-fed apertures, filled with assymmetrically [sic] cut dielectric inserts, in an infinite ground plane were investigated. The results of Blumberg and Hemmen concerning single apertures were applied to a two-aperture array, with emphasis upon obtaining an array capable of scanning in the far field through changes in the permittivity of the assymmetrically [sic] cut dielectric inserts. Scanning was shown to be possible with up to a 60⁰ scan angle with a "push-pull" method of varying permittivities, in which the permittivity of one insert is raised while the other is lowered. The aperture field …

Annealing Characteristics Of Neutron Irradiated Silicon Transistors, Joseph Robert Chott

Masters Theses

"When a transistor is subjected to neutron irradiation, a component of base current proportional to neutron fluence is induced. From the effects of annealing on the base and collector currents, the conclusion was drawn that there is an apparent difference in the annealing characteristics between the neutral and the space-charge regions of the semiconductor device. This study of the anomalous annealing indicates that the neutron-induced component of base current is a result of one, or a combination, of the following mechanisms: a quasi-tunneling recombination phenomena in the emitter-base space-charge region, or an influence of the p-n junction electric field on …

The Measurement Of Explosively Induced Stresses In Rock-Like Materials With A Capacitive Transducer, Vincent Paul Crane

Masters Theses

"A capacitive transducer was developed for measuring the free surface motion in Hydrostone blocks loaded by an explosive plane wave generator approximately one foot from the specimen. The charge to specimen distance was adjusted to produce a single spall, the position of the fracture being noted on the recovered specimen. The longitudinal wave velocity in each specimen was determined by the ultrasonic pulse technique before each shot. From the above measurements the stress, strain and strain rate at the point of fracture were determined. An attempt was made to determine the actual fracture time with imbedded [sic] conductive graphite rods, …