Digital Commons Network^™

Water Management Capabilities Of Bio-Inspired Flow Field Configurations For Polymer Electrolyte Membrane Fuel Cells, Nicholas Warren Freer

Masters Theses

"Fuel cells have received an increasing amount of attention over the past decade for their power production capabilities. Polymer electrolyte membrane (PEM) fuel cells in particular are researched because of their high power density, large range of operating conditions, green products, and ease of scalability. PEM fuel cells do have a number of issues that reduce their overall performance. These issues include variations in reactant distribution, materials issues for the bipolar plate, and flooding caused by poor water management. Variations in the reactant distribution causes lower overall power output due to regions of low reactant density. This means that optimizing …

Green Roof Water Quality Impacts And Physicochemical Stability, Grace Ella Harper

Masters Theses

"Green roofs can provide environmental benefits and conserve energy; this research evaluated green roof stormwater management, nutrient loading, and erosion prevention for two green roof media. During a pilot study, the runoff quantity and composition from green roof material was evaluated continuously under field conditions for two different media, both tested under planted and unplanted conditions. Water quantity results show over a 40% reduction in runoff from just the growing media and over 60% reduction in runoff with established plants in green roof media over the eight month study. Previous studies have reported a "first flush" of excess nutrients but …

A Computational Study Of Driven Micro-Cavities In Supersonic Flat Plate Flow, Thomas Ryan Rehmeier

Masters Theses

"Driven micro-cavities embedded in the wall beneath turbulent supersonic boundary layers are analyzed using two-dimensional computational fluid dynamics. This concept is a passive flow control technique in which very small cavities formed by arrays of thin vertical walls are oriented transverse to the flow direction and underlie the boundary layer. The purpose is to reduce or eliminate skin friction drag. Various micro-cavity configurations were analyzed at locations (0.1 m and 1 m) downstream of the leading edges of flat plates, for free-stream Mach numbers of 1.2, 2.0, and 3.0. Results focus on net drag reduction achieved, cavity flow-field effects, perforation …

Production Of 1,3-Propanediol From Glycerol Under Haloalkaline Conditions By Halanaerobium Hydrogeniformans, Daniel William Roush

Masters Theses

"With increased demands around the world to make modern lifestyles more environmentally friendly, the chemical commodity market has rapidly shifted. Through new technologies in chemical production, certain high value products have oversaturated the market and have become high-volume, low value waste products. The expansion of biodiesel production offers a prime example; high volumes of glycerol byproduct from this process have shifted glycerol from a high priced commodity to a common waste product. A number of microorganisms are known to synthesize the polymeric precursor 1,3-propanediol from glycerol; however, crude glycerol from biodiesel production creates a harsh environment for most microbes, and …

Wetting And Drying Cycles And The Fungal Communities On Leaf Litter In Streams, Kele Qwinn Thrailkill

Masters Theses

"Leaf litter is a major source of energy for streams in deciduous forests. Fungi play a critical role by converting the leaves into nutritional material for the rest of the food web. The breakdown of leaf litter and associated biota, including invertebrates and fungi, have been proposed as measures of stream health in systems affected by anthropogenic activity. Rates of leaf breakdown can be depressed in streams affected by acidity, metals, organic contaminants, and other stressors. Climate change may lead to alterations in stream hydrology such that streams experience more frequent floods as well as drying episodes. Fungal communities can …

Insufficient Ct Data Reconstruction Based On Directional Total Variation (Dtv) Regularized Maximum Likelihood Expectation Maximization (Mlem) Method, Fahima Fahmida Islam

Masters Theses

"Sparse tomography is an efficient technique which saves time as well as minimizes cost. However, due to few angular data it implies the image reconstruction problem as ill-posed. In the ill posed problem, even with exact data constraints, the inversion cannot be uniquely performed. Therefore, selection of suitable method to optimize the reconstruction problems plays an important role in sparse data CT. Use of regularization function is a well-known method to control the artifacts in limited angle data acquisition. In this work, we propose directional total variation regularized ordered subset (OS) type image reconstruction method for neutron limited data CT. …

Role Of Nicotine In Oxidative Stress, Rakesh Kacham

Masters Theses

"Nicotine, a major alkaloid, is present in tobacco products as well as in smaller amounts in potatoes, tomatoes, and eggplants. Although it is the addictive compound in cigarettes, nicotine is believed to play a protective role in neurodegenerative disorders such as Parkinson's disease. Researchers have found that the short-term administration of nicotine may help improve the memory process by reducing oxidative stress in the brain. Our studies have shown that, by blocking Fenton's reaction, nicotine is able to inhibit free radical generation, so this research has focused on the antioxidant properties of nicotine. The cell lines of the alveoli, blood …

Kinetics Of Human And Bovine Insulin Amyloid Fibril Formation In The Presence Of Solid/Liquid Interfaces, Paulina Barranco Morales

Masters Theses

"The purpose of this thesis was to study the rate and extent of aggregation of human and bovine insulin in bulk and in the presence of either polystyrene microspheres with different surface chemistries or liposomes of different composition. Insulin aggregation was followed by turbidimetry, Fourier transform infrared spectroscopy (FTIR), and dynamic light scattering. The Congo red assay was used to corroborate the presence of amyloid deposits and transmission electron microscopy (TEM) was used to analyze the morphology of the amyloid deposits. Our results show that not all the surfaces shortened the lag time. On the other hand, most surfaces had …

Protein Aggregation At Solid/Liquid Interfaces: A Monte Carlo Study With Explicit And Implicit Solvent Effects, Rehman Fazeem

Masters Theses

"Metropolis Monte Carlo (MC) simulations were performed with positively charged peptides in aqueous solution to study changes in peptide conformations at solid/liquid interface, and its effects on protein aggregation. Intermediate-resolution diblock model peptide, comprising of 10 units of ALA (non-polar) and LYS (polar) amino acid residues, was used for the simulations. In the first approach to modeling, solvent effects were considered explicitly. The explicit model was then used to study two peptide molecules, in helical structure, at solid/liquid interface. In order to increase the number of peptide molecules in the simulation box, with reduced computational cost, an implicit solvent model …

A Study Of Clustering Rssi And Lqi From Wireless Network Communications, Yanwen Wang

Masters Theses

"In today's information world, different wireless sensor network topologies are permitted to exist in the same geographical region. For example, a city contains thousands of enterprise networks; a school might include different wireless network topologies used by students and faculties respectively. Even within a building, there might be multiple companies that use their own wireless networks. These networks might cause interference to other networks. How to detect, determine and locate the unknown wireless topologies in the same geographical area becomes quite significant in the wireless industry, especially in military use, such as spy-nodes detection and communication orientation systems. In this …

Broad-Spectrum Antibacterial Properties Of Metal-Ion Doped Borate Bioactive Glasses For Clinical Applications, Megan Ottomeyer

Masters Theses

"Bioactive glasses with antimicrobial properties can be implemented as coatings on medical devices and implants, as well as a treatment for tissue repair and prevention of common hospital-acquired infections such as MRSA A borate-containing glass, B3, is also undergoing clinical trials to assess wound-healing properties. The sensitivities of various bacteria to B3, B3-Ag, B3-Ga, and B3-I bioactive glasses were tested. In addition, the mechanism of action for the glasses was studied by spectroscopic enzyme kinetics experiments, Live-Dead staining fluorescence microscopy, and luminescence assays using two gene fusion strains of Escherichia coli.

It was found that gram-positive bacteria were more …

Freeze Tolerance Conferred By Transgenic Expression Of Late Embryogenesis Abundant Protein In Insect Cells, Alyssa N. Walser

Masters Theses

Anhydrobiotic organisms such as the brine shrimp Artemia franciscana have developed strategies to survive and thrive under conditions of limited water availability. One strategy is the accumulation of late embryo genesis abundant (LEA) proteins. Cells of Drosophila melanogaster (Kc167), which had previously been genetically modified to express a group 1 LEA protein (LEA1.3) found in A. franciscana, were used to test the impact of water stress due to freezing to -80°C. Two different freezing devices were used to determine the impact of the freezing protocol on the viability of cells after freezing and thawing. The first method used a 12-well …

Seventy Years Of The African American Male Experience At Eastern Illinois University, Rovion D. Reed

Masters Theses

Using qualitative methodology the researcher analyzed the lived experiences of seven African American men who attended Eastern Illinois University over the past seven decades including one who is currently enrolled. Data was collected by conducting archival research as well and semi-structured interviews. Overall participants reported having good experiences at Eastern Illinois University. The participants' experiences were categorized into seven themes including faculty or staff relations, race relations, intra-racial relations, campus involvement, mentoring, campus climate, and Black Greek organizations. In addition, minor themes were also discovered including only-ness, lowered expectations, positive influence of student organizations, and sense of care from mentors.

Separating The Whites From The Chaff: Whiteness, Blackness, Racial Exclusion In The Midwest Agrarian Mind, Philip Mohr

Masters Theses

This thesis approaches the construction of race through the vantage of one agrarian magazine, the Prairie Farmer. It analyzes the rhetoric of the people who wrote for this magazine to distinguish changing attitudes toward whiteness and blackness in the rural and agricultural Midwest from the end of the Civil War to the Great Migration. While whiteness was equated with what the Prairie Farmer saw as the active, progressive farmer, blackness was associated with stupidity, laziness, and threat to property. From this, the thesis argues we can build a base of knowledge from which to analyze the roots of racism …

Demographics Of A Commercially Exploited Population Of Flathead Catfish (Pylodictis Olivaris) In The Wabash River, Cassi Jo Moody-Carpenter

Masters Theses

Flathead catfish, Pylodictis olivaris, are a popular game and commercial fish in the Midwestern United States. In the lower 322 km of the Wabash River, flathead catfish are commercially and recreationally harvested by Illinois and Indiana fishers. Current management regulations are different between the two states; Illinois and Indiana have minimum length limits of 381 and 254 mm, respectively. Indiana has proposed changing their minimum length limit to 381 mm and allowing only one fish> 889 mm to be harvested per day. My study examined the current status of flathead catfish in the Wabash River to determine a standardized …

Eccentric Resistance Training And Blood Flow Restriction, Zachary Pope

Masters Theses

The purpose of this study was to compare the muscular strength and hypertrophic response following a four week training intervention involving resistance exercise utilizing only eccentric muscle contractions with, or without blood flow restriction (BFR), as well as a control group maintaining their current training regimen. Sixteen young male volunteers were recruited to participate in this study. Prior to the training intervention, subjects attended three sessions in order to obtain demographic information (age, height, body mass) and familiarize each of the participants with the testing and training equipment. After the familiarization session, muscular strength was assessed via elbow flexion one …

Chemical Transformations Of Arylsulfonamide Molecular Crystals, Rajan Giri

Masters Theses

The pursuit of chemical specificity and efficiency of chemical reaction in molecular crystals has attracted considerable attention over the last decade. The successful control of molecular alignment prior to such transformations continues to provide opportunities for near quantitative yields of new materials. This thesis reports the predictable self-assembly of aryl sulfonamide materials constructed from cinnamic acid and phenylpentadienoic acid fragments capable of forming supramolecular dimers that undergo unique photocyclization reactions. Use of racemic and enantiopure single-component building-blocks provides access to enantiocontrolled [2+2] photodimerized products.

Solid-state reaction precursors were prepared using conventional solution-based synthetic organic techniques. Component chirality (racemic or homochiral) …

Determination Of Structural Stabilities Of Metal-Free Porphyrin Cytochrome C, Zinc Cytochrome C, And Cobalt Cytochrome C, Usha K. Tottempudi

Masters Theses

No abstract provided.

Dietary Iron Intake And Knowledge Of Iron Deficiency And Iron Deficiency Anemia Among Recreational Female Marathon Runners, Jamie Merritt

Masters Theses

No abstract provided.

Using Field Studies To Meet The Next Generation Science Standards, Amy Brown

Masters Theses

New science standards, the Next Generation Science Standards (NGSS), recently have been released which require students to use modeling and other process skills and cross-cutting concepts to show understanding of core concepts. Understanding by design approach was used to develop an ecology curriculum in line with the NGSS framework, using field studies to involve students in real science. A schoolyard habitat area on Neoga School District property was used for the field studies. Students were assessed with pre- and post-tests, traditional classroom grades on labs and projects and the Modified ATSI and Children's Science Curiosity Scale. All students showed significant …

Juvenile Delinquency: A Comparative Analysis Between Divorced And Married Homes, Cristina R. Prestin-Latham

Masters Theses

The purpose of this research was to determine if children being raised in divorced homes are more likely to be juvenile delinquents that children being raised in married homes. Additionally, this study sought to determine if the age of the child during the divorce further contributes to the likelihood of delinquent behavior. The majority of previous studies indicate children from divorced homes are more prone to juvenile delinquency than children from married homes. The sample in this study consisted of 544 participants. Using a self-reporting, anonymous questionnaire, participants were asked questions about their childhood home structure and their adolescent delinquent …

Cellular And Molecular Mechanisms Underlying The Interaction Of Apoe And Estrogen In Olfactory Neuronal Growth-Potential Relevance To Alzheimer's Disease, Minh Luong

Masters Theses

In recent years, there have been many studies looking at estrogen therapy (ET) as a treatment for Alzheimer's disease. Literature review suggests a close relationship between estrogen and apolipoprotein E (apoE) in the central nervous system. The mechanism underlying the interaction of apoE genotype with estrogen in the nervous system is not yet known. Therefore, the objectives of this research are 1) to determine the effects of estradiol treatment on basal cell proliferation and neuronal differentiation and 2) to identify the estrogen receptor subtype (ERα and ERβ) that mediates the increase of apoE levels, neurite outgrowth and neuronal numbers.

Results …

A Thermal Conversion Efficiency Study On Biomass Gasification Of Arundo Donax And Woodchips, Wei Wang

Masters Theses

The threat of energy depletion and greenhouse gas effect prove that fossil fuels are no longer sustainable for wide use. Thus, looking for alternative energy resources that are sustainable for use, environmentally friendly as well as regionally available is a challenge for current researchers. Biomass gasification is a process that turns solid biomass into combustible syn-gas. The identification of appropriate fuel sources for biomass gasification facilities in a particular region is significant from both energy and economic efficiency perspective.

This research developed three methods to calculate thermal conversion efficiency for biomass gasification using a downdraft laboratory scale gasification system. These …

Survey Of Medicinal Herbs Of Central Illinois Prairie And Woodlands, Debra Ann Welch

Masters Theses

Illinois has been named the "Prairie State" for good reason. When the pioneers discovered a vast sea of grasses and forbs, they thought the prairie infertile. However, they soon found out that the blacksoil prairie was composed of a rich diversity of plant species that could provide much of the medical and nutritional needs of everyday life. The medicinal uses of many prairie species have not only been tested throughout history, but today modern science has also discovered their therapeutic importance.

The purpose of this study was to survey prairie species growing in the central Illinois counties of Coles and …

Molecular Mechanisms Involved In Anhydrobiosis Of Insect Cells, Diyagama Arachchi Ralalage Dilini Sewwandi Samarajeewa

Masters Theses

Animals possessing tolerance to extreme water stress are termed anhydrobiotes. Many desiccation tolerant organisms respond to water stress by intracellular accumulation of selected sugars such as trehalose and larger macromolecules such as Late Embryogenesis Abundant (LEA) proteins and thereby maintain the cell viability. Evidence indicates that the presence of trehalose and Late Embryogenesis Abundant (LEA) proteins may work synergistically to confer cellular protection during drying in eukaryotic cells. We evaluated any increase in cellular desiccation tolerance by expressing different LEA proteins in a non-desiccation tolerant insect cell line Drosophila melanogaster (fruit fly) (Kc167 cells) in the presence of trehalose.

Transgenic …

Examining The Relationship Between Environmental Policy And Economic Competitiveness In The United States And The European Union, Scott A. Trail

Masters Theses

In sum, when considering the findings of all three chapters of this thesis cumulatively, several implications are worth noting in regards to the relationship between environmental policy and economic competitiveness. First, the notion that adopting stringent environmental standards will impede on a state's ability to remain economically competitive was shown to be the exception, rather than the rule in all of the cases surveyed in this thesis. Moreover, the cumulative research throughout this thesis has shown the depth of complexity that exists between environmental and economic policy networks. Each chapter illustrated how the general relationship between government and private interests …

Direct Analysis Of Hops By Leaf Spray And Paper Spray Mass Spectrometry, Kari Blain

Masters Theses

The objective of this research is to develop a new and innovative method of hops analysis, which is much faster than standard testing methods, as well as reduce the amount of consumables and solvent used. A detailed discussion on the development of an ambient ionization mass spectrometry method called paper spray (PS-MS) and leaf spray (LS-MS) mass spectrometry will be presented. This research investigates the use of PS-MS and LS-MS techniques to determine the α- and β- acids present in hops. PS-MS and LS-MS provide a fast way to analyze hops samples by delivering data as rapidly as a UV-Vis …

Scopolamine-Induced Dry Eye Model In Female Rats, Ryan Alderson

Masters Theses

The objective of this study will be to establish, validate, and characterize a dry eye model in female rats induced by continuous systemic administration of scopolamine via Alzet® osmotic pumps for 28 days. This study will use female rats as a model for dry eye and will be implanted with osmotic pumps that will continuously distribute scopolamine or saline systemically over 28 days. Scopolamine will be used to induce the dry eye condition and saline will be used as a negative control. The clinical signs of dry eye will be evaluated by tear volume measurements with sterilized phenol-red thread (FCI …

"His Head Rolled Forth Onto The Floor:" Women, The Abject, And The Male Gaze In Old English Poetry, Jaime Michelle Myers

Masters Theses

Old English poetry features several female characters who challenge androcentric authority by violently killing men. I argue in this thesis that three of these women—Modthryth, Grendel’s mother, and Judith—are linked together by their rejection or reversal of the male gaze. In their forceful refusal to be visually objectified, each character is portrayed as abject—outside of normal and outcast from community. They cause disorder, illustrate the fragility of androcentric control, and force a confrontation with death. In so doing, they create ambiguity and, at times, reverse the subject/object and masculine/feminine gender binaries.

Assessing The Impacts Of Dams On Nutrient And Sediment Loading In The Kalamazoo River Using The Soil And Water Assessment Tool (Swat), Daniel Henry Serfas

Masters Theses

The Soil and Water Assessment Tool (SWAT) was applied to the Kalamazoo River Watershed in order to evaluate the impacts that several dams within a superfund site "Area of Concern" have on the sediment, nutrients, and streamflow of the system. It was hypothesized that the SWAT model could be used to recreate the watershed in hopes of estimating the amounts of nitrogen, phosphorus, and sediment that would result from the removal of the dams. The model would then be used to evaluate dam removal scenarios to come up with a best management practice (BMP).

The model was calibrated, however, during …