Digital Commons Network^™

Synthesis And Characterization Of Biomimetic Dinuclear And Tetranuclear Copper Complexes, Syed Rahmath Ullah Joy

Masters Theses

Seven new copper(II) complexes were prepared from the condensation reaction of 4-tert-butyl-2,6-diformylphenol with two equivalents of bis(pyrazolyl)ethanamine or 3,5-dimethyl-bis(pyrazolyl)ethanamine moieties in the presence of two equivalents of various copper(II) starting materials having different counter ions (i.e. acetate - AcO^-, perchlorate - CIO₄^-, tetrafluoroborate - BF₄^-, nitrate - NO₃^-, and chloride - Cl^-). The resulting copper(II) complexes were characterized in solid state by single crystal X-ray crystallography, and in solution by UV-Vis and ESI/MS spectroscopies.

X-ray crystallographic studies showed that in solid state two types of …

Pd-Based Photocatalysts For Sonogashira C-C Cross-Coupling Reactions, Komadhie Charuka Dissanayake

Masters Theses

Sonogashira C-C cross-coupling reaction has been heavily used for its simplicity, flexibility and value. Although the original Sonogashira C-C cross coupling reaction conditions entail the use of 0.5 mol% of Pd catalyst, 2 mol% of Cul as co-catalyst at room temperature, the experimental conditions used in laboratories to prepare some compounds vary substantially, especially with respect to the reaction time, temperature and loading amount of the catalysts. The most significant drawback of the conventional Sonogashira reaction is the use of Cul as it leads to the formation of homocoupling product when the reaction is exposed to air or oxidizing agents. …

Solidification Rate Detection Through Solid-Liquid Interface Tracking, Wei Luo

Masters Theses

”Studying the melt pool dynamics in laser powder bed fusion (LPBF) additive manufacturing is vital to predict the microstructure of the built part. High-speed synchrotron hard X-ray imaging is an advanced technique to monitor the LPBF process in situ and in real time. However, it is very challenging to track the solid-liquid interface due to the low image contrast, high image noise and unstable intensity of the image sequences.

In this paper, we propose an solid-liquid interface detector with human interaction to track the interface to compute the solidification rate of the melt pool. The proposed method includes six independent …

Efficient Implementation Of Ieee 802.11i Wi-Fi Security (Wpa2-Psk) Standard Using Fpga, Atal Bajracharya

Masters Theses

The rationale behind the thesis was to design efficient implementations of cryptography algorithms used for Wi-Fi Security as per IEEE 802.11i Wi-Fi Security (WPA2-PSK) standard. The focus was on software implementation of Password-Based Key Derivation Function 2 (PBKDF2) using Keyed-Hash Message Authentication Code (HMAC)-SHA1, which is used for authentication, and, hardware implementation of AES-256 cipher, which is used for data confidentiality.

In this thesis, PBKDF2 based on HMAC-SHA1 was implemented on software using C programming language, and, AES-256 was implemented on hardware using Verilog HDL. The overall implementation was designed and tested on Nexys4 FPGA board. The performance of the …

Proppant Transport With Varying Injection Points And Its Impact On Proppant Development Inside A Fracture, Shail Janakbhai Soni

Masters Theses

"This study presents experimental work which examines the effect of perforation placement and density on proppant placement within a hydraulic fracture. The study also investigates the effect of proppant angularity.

Experiments were conducted with ceramic proppant injected in a fracture slot model consisting of three injection points at the bottom, middle and top of the fracture slot, and two outlets, at the bottom and top of the fracture model. The effect of single point injection height was investigated by injecting solely at the bottom, middle or top of the apparatus, for both bottom and top outlet conditions. Multiple injection points …

Numerical Modeling Of Capillary-Driven Flow In Open Microchannels: An Implication Of Optimized Wicking Fabric Design, Mehrad Gholizadeh Ansari

Masters Theses

"The use of microfluidics to transfer fluids without applying any exterior energy source is a promising technology in different fields of science and engineering due to their compactness, simplicity and cost-effective design. In geotechnical engineering, to increase the soil's strength, hydrophilic wicking fibers as type of microfluidics have been employed to transport and drain water out of soil spontaneously by taking advantage of natural capillary force without using any pumps or other auxiliary devices. The objective of this study is to understand the scientific mechanisms of the capability for wicking fiber to drain both gravity and capillary water out of …

Analysis And Mitigation Of Parallel-Plate Noise For High-Isolation Applications, Zachary Joel Legenzoff

Masters Theses

"Achieving highs levels of isolation between different functionalities in a PCB can be challenging. One of the major issues is that vertically adjacent planes or area fills in a PCB can form a parallel-plate waveguide with no cutoff frequency and serve as an efficient coupling mechanism between interconnects. Due to the finite size of the conductors, reflections off the edges of these parallel-plate cavities can result in the formation of standing-wave patterns with very high field strengths, resulting in high coupling at certain frequencies. This noise coupling mechanism can be suppressed by connecting the parallel plates together with an adequate …

An Analysis Of Extended Strings Of Hits And Misses In A Mental Telepathy Task, Gregory R. Peck

Masters Theses

The current study was designed to reanalyze archival data from the Eastern Illinois University parapsychology lab to determine the frequency of strings of hits and misses. Four datasets were included in the analyses, comprising a total of 348 participants. It was hypothesized that there would be more strings of hits and/or misses than expected by chance; there would be a difference between the number of strings of hits and the number of strings of misses; and participant scores on a 7-point belief in psi scale would be related to the frequency of hits and misses. Results indicated that no significant …

An Analysis Of The Meaning, Barriers, And Value Of Developmental Education For First-Generation Minority Students At A Community College, Molly Murphy

Masters Theses

This qualitative, phenomenological study was designed to learn more about how first-generation, minority community college students perceive the meaning, barriers, and value of developmental education. Five participants were interviewed in a semi-structured format. The results provided nuanced and personal accounts from students who revealed that developmental education affects their feelings of self-efficacy, that systemic financial challenges are consistent barriers to success, and that the connections between teachers and their students, or lack thereof, are perceived to have an impact on the usefulness of developmental education. Finally, results indicated the importance of working with students individually to understand how their ethnic …

Understanding The Transition To College For Students With Learning Disabilities, Breanna Rehor

Masters Theses

This study sought to investigate the transition to college for students with learning disabilities at a mid-size Midwestern university. A qualitative approach was used to provide insight in student's perspectives on the transition from high school to college. Three undergraduate students with learning disabilities were individually interviewed to gain understanding of the transition to college. The results demonstrated a critical need for institutions to address the transition to college for students with learning disabilities and create incentives that guide support for student success. Students utilizing various support systems like academic student services, and peers. The transitions to college for students …

Defense In Depth Network Perimeter Security, Anuoluwapo Ope Fatokun

Masters Theses

Defense in depth network perimeter security has always be a topic of discussion for a long time as an efficient way of mitigating cyber-attacks. While there are no 100% mitigating method against cyber-attacks, a layered defense in depth network perimeter security can be used to mitigate against cyber-attacks. Research have shown a massive growth in cyber-crimes and there are limited number of cyber security expert to counter this attacks. EIU as an institution is taking up the responsibility of producing cyber security graduates with the new Master of Science in Cyber Security program that started in Fall 2017.

This research …

Construct Validity Of The Learning-To-Learn Scales (Ltls) With A Preschool And Kindergarten Sample, Kassandra Jane Charles

Masters Theses

Learning behaviors, "observable behavior patterns that children display as they approach and undertake school learning tasks" (Yen, Konold, and McDermott, 2004, p. 159) and "the degree to which children adopt beneficial approaches to learning" (Rikoon, McDermott, & Fantuzzo, 2012, p. 273) have been shown to account for a substantial amount of variance in academic achievement and add predictive validity for future academic achievement. Prediction of academic achievement is vital when making individual decisions concerning academic placement, diagnosis, early intervention, and student selection (Yen, Konold, & McDermott, 2004). The current study assessed the concurrent criterion validity of the Learning-to-Learn Scales (LTLS) …

A Photo Illicit Study Of Black Women's Sense Of Belonging At A Predominately White Institution, Kayla Alexandria Slusher

Masters Theses

This qualitative study sought to examine how Black women define and create their sense of belonging while attending a predominately White institution using a photovoice approach. The women took photographs of spaces that they frequently occupy and then engaged in a face-to-face interview to discuss the photographs. The researcher also investigated four Black women, ranging from junior to graduate level, to identify how they developed a sense of belonging at the research site institution. Results of the study showed that a feeling of comfort was most important when identifying belongingness in a space. The participants were able to create a …

Representation Of The Titanic In Children's Literature, Charity Rose Huwe

Masters Theses

State and national education initiatives are the driving force behind increased exploration of diverse texts, namely informational texts. Trade books offer opportunity for interdisciplinary units to develop through the rise of informational text use in both English/language arts and history/social studies. Primary source documents serve as a liaison to filing gaps in the information left out from textbooks and trade books. A more thorough understanding of historical figures and events are a result of such analysis. The initiatives do not dictate specific curricular material; teachers use their discretion when choosing available trade books, primary documents, and other curricular resources. In …

Impact Of Temperature Increase On Freshwater Fish Species: Energetics And Muscle Mechanics Of Two Centrarchids, Israt Jahan

Masters Theses

Fishes have evolved physiologically to live within a specific range of environmental variation and existence outside of that range can be stressful or fatal. These ranges can coincide for fishes that evolved in similar habitats. This study investigates physiological processes limiting thermal tolerance, specifically how changes in water temperature affect the swimming energetics and muscle mechanics in largemouth bass (Micropterus salmoides) and bluegill (Lepomis macrochirus). I focused on the impact of temperature change at the muscle level in these two species and the capacity to adapt to rapid changes in the environment. Fish were housed at …

Examining 8th Grade Students Disciplinary Literacy Of Science Material, Chelsie P. Doughty

Masters Theses

Education standards are shifting to reflect a skills-based, rather than a content-centered, curriculum that focuses on students being literate across all disciplines. This study focuses on the skills of critical thinking, close reading, and text-based writing as it applies to the scientific and historical disciplines. Eighth grade students engaged in a text-based writing assignment that required evaluation of multiple sources to support their claims. Student responses were analyzed textually and verbally as it related to the content. Findings included the ability to identify students' struggles and successes with close reading, writing claims, evaluating evidence for importance, and connecting documents to …

The Transcriptional Response Of Trametes Versicolor To Growth On Maple Chips And Miscanthus Straw, Maha Alanazi

Masters Theses

This thesis research explored the transcriptional response of Trametes versicolor, a white-rot fungus, in response to fundamentally different types of lignocellulosic biomass (miscanthus and maple) and rich medium (malt extract agar). After five weeks of growth by the fungus on the biomass, the fungal RNA was extracted from three biological replicates per biomass type and mRNA was sequenced (approximately 30 million reads per sample). The reads were processed using ArrayStar to covert to RPKM and annotated using JGI's T. versicolor GO annotation file along with NCBI's BLAST. Comparisons were made between average gene expression of the fungus grown on …

Development And Monte Carlo Validation Of A Finite Element Reactor Analysis Framework, Wayne J. Brewster

Masters Theses

"This study presents the development and Monte Carlo validation of a continuous Galerkin finite element reactor analysis framework. In its current state, the framework acts as an interface between the mesh preparation software GMSH and the sparse linear solvers in MATLAB, for the discretization and approximation of 1-D, 2-D, and 3-D linear partial differential equations. Validity of the framework is assessed from the following two benchmarking activities: the 2-D IAEA PWR benchmark; and the 2-D Missouri Science and Technology Reactor benchmark proposed within this study. The 2-D IAEA PWR multi-group diffusion benchmark is conducted with the following discretization schemes: linear, …

Precise Energy Efficient Scheduling Of Mixed-Criticality Tasks & Sustainable Mixed-Criticality Scheduling, Sai Sruti

Masters Theses

"In this thesis, the imprecise mixed-criticality model (IMC) is extended to precise scheduling of tasks, and integrated with the dynamic voltage and frequency scaling (DVFS) technique to enable energy minimization. The challenge in precise scheduling of MC systems is to simultaneously guarantee the timing correctness for all tasks, hi and lo, under both pessimistic and optimistic (less pessimistic) assumptions. To the best of knowledge this is the first work to address the integration of DVFS energy conserving techniques with precise scheduling of lo-tasks of the MC model.

In this thesis, the utilization based schedulability tests and sufficient conditions for such …

Developing A Methodology For Estimating The Growth Of Radiated Emission From Multi-Modular Systems, Kaustav Ghosh

Masters Theses

"The large multiscale problems are commonly faced in real-world applications such as analysis of electromagnetic interference for a printed circuit board installed on a large platform with connected cables, wires and other high speed interfaces. EMI problems are not uncommon in high speed systems which involve multiple modules of complex hardware. As the system clock frequency and data rate increases, so does the challenges in controlling the EMI in such systems. The costs to prototype and to develop networking equipment are growing as a result of increasing complexities and densities. EMC regulations require radiated emission testing to be done in …

Data Analysis Of Low-Salinity Waterflooding To Enhance The Oil Recovery In Sandstone Reservoirs, Nadia Ariani

Masters Theses

"The lack of a single reasonable general mechanism to describe how low-salinity waterflooding can improve oil recovery in both laboratory and field pilot projects has increased the interests of many researchers and stakeholders. There has not been observed the relationship of formation brine salinity and injected brine salinity to see how much salinity is reduced to produce the maximum enhanced oil recovery by LSWF. There is no guidance in what EOR stage the LSWF is best implemented. This work collects data from various published literature to develop a comprehensive data set regarding low-salinity waterflooding in sandstone reservoirs. The LSWF mechanisms …

De-Embedding Method Comparisons And Physics Based Circuit Model For High Frequency D-Probe, Yuan Chen

Masters Theses

"In section 1, the procedures of 1X-Reflect smart fixture de-embedding (SFD), 1-port auto fixture removal (AFR), and 2X-Thru SFD are compared from various perspectives: test fixture design, the de-embedding procedure, and de-embedded results. The accuracy of fixture characterization and the de-embedded result is the key figure of merit (FOM) in each de-embedding method. Full wave models are built to evaluate the FOM of the three methods, by comparing the scattering parameters (S-parameters) and time domain reflectometer (TDR). A test coupon for measuring USB-C cables is adopted to serve as a manufactured validation purpose.

In section 2, a physics-based circuit model …

An Integrated Method For Understanding The Fluid Flow Behavior And Forecasting Well Deliverability In Gas Condensate Reservoirs With Water Aquifer Drive, Abdulaziz Mustafa Em. Ellafi

Masters Theses

"Gas condensate reservoirs constitute a significant portion of global hydrocarbon reserves. In these reservoirs, as bottomhole pressure falls below the dew point, liquid develops in the pore space. This results in the formation of a liquid bank near the wellbore region that decreases gas mobility, which then reduces gas inflow. Some gas condensate reservoirs have bottom aquifer drive, which also negatively impacts gas production. This research used a field case study to demonstrate an integrated workflow for forecasting well deliverability in a gas condensate field in Libya. The workflow began with the interpretation of open-hole log data to identify the …

Battery Optimization In Microgrids Using Markov Decision Process Integrated With Load And Solar Forecasting, Prateek Jain

Masters Theses

"Rising climatic concerns call for unconventional/renewable energy sources which reduce the carbon footprint. Microgrids that integrate a variety of renewable energy resources play a key role in utilizing these energy resources in a more efficient and environmentally friendly manner. Battery systems effectively help to utilize these energy resources more efficiently. This research work presents a framework based on Markov Decision Process (MDP) integrated with load and solar forecasting to derive an optimal charging/discharging action of Battery with rolling horizon implementation. The load forecasting regression models are discussed and developed. Also, various solar forecasting models like clear sky, multi-regression and Non-Linear …

Cloud Transactions And Caching For Improved Performance In Clouds And Dtns, Dileep Mardham

Masters Theses

"In distributed transactional systems deployed over some massively decentralized cloud servers, access policies are typically replicated. Interdependencies ad inconsistencies among policies need to be addressed as they can affect performance, throughput and accuracy. Several stringent levels of policy consistency constraints and enforcement approaches to guarantee the trustworthiness of transactions on cloud servers are proposed. We define a look-up table to store policy versions and the concept of "Tree-Based Consistency" approach to maintain a tree structure of the servers. By integrating look-up table and the consistency tree based approach, we propose an enhanced version of Two-phase validation commit (2PVC) protocol integrated …

Nonlinear Finite Element Analysis Of Concrete Columns Subjected To Complex Loading, Adam Christopher Morgan

Masters Theses

"This study details the development and implementation of a finite element model within a commercial finite element code, Abaqus CAE, for the analysis of reinforced concrete (RC) bridge columns containing interlocking spirals subjected to combined loading conditions including axial, shear, bending, and torsional loads, including the post-peak response. The model is a first of its kind attempt at simulating the response of RC columns with continuous spiral transverse reinforcement and subjected to combined loading conditions including torsion. The model is utilized to determine the quasi-static load-deformation response under various proportions of the input loads and displacements. The resulting quasi-static load-deformations, …

Transmission Line Inspection Using Suspended Robot: Cost Effective Analysis And Operational Routing Identification, Balaji Rathinam Nagarajan

Masters Theses

"High voltage transmission lines form a crucial part of the energy infrastructure of a country. Effective maintenance is required to maintain its reliability and reduce the probability of the occurrence of the outage. Conventionally, the routine inspection of the transmission line was conducted by linemen with the assistance of hot stick and helicopter, which is considered dangerous, time-consuming, and expensive.

In this thesis, we focus on the initial study of seeking the state of the art robotics technology to by largely replace human beings in transmission line inspection. The existing robotics technologies that are interested by utility companies, as well …

Controlling Phase Fractions Of 304l-Ss In Selective Laser Melting Using Cooling Rate, Eberechukwu Anthony Okoro

Masters Theses

"This study examines the thermal profile and the ferrite-austenite phase fractions upon heating and cooling of 304- stainless steel powder via Selective Laser Melting (SLM). Experiments were performed to validate the ABAQUS finite element model, while the phase transformation simulation was performed using MatCalc and ThermoCalc. A correlation between the thermo-mechanical changes in ABAQUS and the microstructural changes from MatCalc was obtained by matching their cooling rates. The result indicates that cooling rate has a significant effect on the phase fractions of FCC and BCC formed in 304L stainless steel via the SLM process. The results also indicate that for …

Cyber-Physical Security Of An Electric Microgrid, Prashanth Palaniswamy

Masters Theses

"Cyber-physical systems (CPSs) are physical systems that are controlled or monitored by computer-based systems. CPSs are a combination of computation, networking, and physical processes. As CPSs are a combination of various diverse components, they are vulnerable to several security threats. Moreover, there are many different security domains (not just high/low, nor necessarily hierarchical). This paper utilizes previously developed multiple security domain nondeducibility (MSDND) to uncover potential integrity vulnerabilities in an electric microgrid. Invariants are manually generated using the insights obtained through MSDND analysis and use linear regression to automate the generation of invariants. The vulnerabilities are then mitigated, to the …

Fuel Burnup Simulation And Analysis Of The Missouri S&T Reactor, Joshua Hinkle Rhodes

Masters Theses

"The purpose of this work is to simulate the fuel burnup of the Missouri S&T Reactor. This work was accomplished using the Monte Carlo software MCNP. The primary core configurations of MSTR were modeled and the power history was used to determine the input parameters for the burnup simulation. These simulations were run to determine the burnup for each fuel element used in the core of MSTR.

With these simulations, the new predicted isotopic compositions were added into the model. New core configurations were determined, and the burnup corrected model was used to predict the excess reactivity and control rod …