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Masters Theses

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Dynamic Response Of A Simply Supported Beam To An Accelerating Point Load, Joseph Victor Cusumano Jan 1967

Dynamic Response Of A Simply Supported Beam To An Accelerating Point Load, Joseph Victor Cusumano

Masters Theses

"An analysis based on linear theory is presented for determining the dynamic response of a simply supported beam on an elastic foundation acted upon by a moving time dependent point force with axial forces included. This thesis extends the present theory to include an analysis of a point force accelerating uniformly across the beam. In particular, it is shown that the customary resonance conditions which are prevalent for a point force moving with uniform velocity no longer exist for the case of a point force accelerating uniformly across the beam.

The basic problem and its solution are presented for a …


Mechanisms Of Base-Catalyzed Reactions: Part Iii: The Acidities Of Some Hydroxylic Compounds In T-Butyl Alcohol., Charles Frederick Seger Jan 1967

Mechanisms Of Base-Catalyzed Reactions: Part Iii: The Acidities Of Some Hydroxylic Compounds In T-Butyl Alcohol., Charles Frederick Seger

Masters Theses

"The KHA of water and five alcohols were determined in t̲-butyl alcohol employing sodium and potassium t̲-butoxides. The order of acidity is methanol>water>ethanol> 2-propanol~cyclohexanol>methanol. It was also shown that potassium t̲-butoxide was twice as strong a base as sodium t̲-butoxide. A spectrophotometric method was employed with p-nitroaniline as the indicator. Calculations were made employing the methods of Stearns and Wheland and of Hine and Hine"--Abstract, page iii.


Determining The Transfer Matrices Of Tapered Multiwire Transmission Lines, Clyde A. Vandivort Jan 1967

Determining The Transfer Matrices Of Tapered Multiwire Transmission Lines, Clyde A. Vandivort

Masters Theses

"The advent of monolithic and integrated microelectronic circuits has aroused interest in passive multilayered thin film networks. The basic thin film network is shown in Figure 1. This structure consists of alternate resistive and dielectric layers sandwiched together. Such devices are referred to as distributed parameter RC networks. The reduction of volume and increased reliability offered by thin film devices has caused considerable effort to be extended in the analysis of their characteristics....

The incremental equivalent circuit given in Figure 2 stems directly from the above physical parameters and is the circuit used as a basis for the analysis that …


Basic Iron (Iii) Alkanoate Complexes, Young Hee Kim Jan 1967

Basic Iron (Iii) Alkanoate Complexes, Young Hee Kim

Masters Theses

"Much information appears in the literature concerning the preparation, properties and structure of the basic iron (III) acetates...This study was initiated to prepare a number of the basic trinuclear iron (III) alkanoate complexes and to investigate the possibility of a common structure for all of these as suggested by the work of Orgel. The structural investigation was done on the basis of stoichiometric relationships, infrared spectra and magnetic moments"--Abstract, pages ii-iii.


Construction Of A Laboratory Type, Convertible Excitation Argon Laser, Arthur P. Reckinger Jan 1967

Construction Of A Laboratory Type, Convertible Excitation Argon Laser, Arthur P. Reckinger

Masters Theses

"The purpose of this thesis is to describe the construction of a general purpose, convertable [sic] excitation, laboratory type, argon laser. Quartz tubing was used in the final model while attempts to use alumina were made during earlier work. The final model has total optical power output of 230 mw at a discharge current of 29 amperes in the dc excitation mode. Provision was also made to utilize RF or pulsed excitation. The device is built so that several values of optical transmittance are available with a wide range of mirror placement"--Abstract, page ii.


Scanning Properties Of Unsymmetrically Loaded Aperture Arrays, Gary Dean Brunner Jan 1967

Scanning Properties Of Unsymmetrically Loaded Aperture Arrays, Gary Dean Brunner

Masters Theses

"Radiation patterns resulting from an array of waveguide-fed apertures, filled with assymmetrically [sic] cut dielectric inserts, in an infinite ground plane were investigated. The results of Blumberg and Hemmen concerning single apertures were applied to a two-aperture array, with emphasis upon obtaining an array capable of scanning in the far field through changes in the permittivity of the assymmetrically [sic] cut dielectric inserts. Scanning was shown to be possible with up to a 60⁰ scan angle with a "push-pull" method of varying permittivities, in which the permittivity of one insert is raised while the other is lowered. The aperture field …


Noble Gases In The Earth And Its Atmosphere, Robert Anthony Canalas Jan 1967

Noble Gases In The Earth And Its Atmosphere, Robert Anthony Canalas

Masters Theses

"Abundance of noble gases extracted from Fig Tree Shale exhibit a marked deviation from the gas content of eclogitic rocks purported to be mantle material. The abundances of the heavy noble gases in shale were found to exceed the highest known meteoritic values. The abundances of the lighter noble gases were found to be comparable to the abundances of these gases in typical chondrites.

Temperature gradient analyses show that excess heavy gases are released at low temperatures. This is interpreted to indicate a preferential adsorption of the heavy noble gases on fine-grained sediments when these gases were being released from …


A Subsurface Geologic Study Of Petroleum Possibilities In The Pennsylvanian Rocks Of Concho County, Texas, Gregory Paul Kraus Jan 1967

A Subsurface Geologic Study Of Petroleum Possibilities In The Pennsylvanian Rocks Of Concho County, Texas, Gregory Paul Kraus

Masters Theses

"During early Pennsylvanian time the area now occupied by Concho County was a portion of the Texas peninsula, a broad, low arch with a karst topography developing on its exposed Ellenburger surface. A mid-Pennsylvanian marine transgression inundated the arch and it became an area of clear, shallow water deposition favorable to limestone development. Local sedimentation during Strawn time was largely controlled by its position relative to the Llano uplift and surrounding basins. A variety of subsurface maps were constructed for this study essentially utilizing electric log data. The results indicate that limestones of the Strawn platform facies rapidly change in …


The Relation Of Heat Transfer To Mass Transfer In Vaporization Through Porous Membranes., Chung-Liang Yeh Jan 1967

The Relation Of Heat Transfer To Mass Transfer In Vaporization Through Porous Membranes., Chung-Liang Yeh

Masters Theses

"The object of this investigation was to study the mass and heat transport phenomena through porous, water-repellent membranes. The investigation concerned the rate of vaporization of salt water at a porous membrane surface, mass transfer of vapor through the pores of the membrane, condensation of vapor on the other surface of the membrane in contact with a coolant (fresh water), and the undesired heat transfer by conduction through the membrane. The water-repellent membrane separated the two liquid phases by surface tension forces and provided a vapor phase in its pores. Membranes made of fiberglass and Teflon had been found suitable …


Mass Transfer From A Torus Shaped Body, Kamalesh Suryakant Desai Jan 1967

Mass Transfer From A Torus Shaped Body, Kamalesh Suryakant Desai

Masters Theses

"A mathematical model for molecular diffusion in a torus was derived. Handlos and Baron have assumed a system of tori in their eddy diffusion model for liquid-liquid extraction from droplets. However, the effect of torus curvature was neglected in their studies. Since they assumed the torus could be represented by an infinite cylinder. In this study, the effect of torus curvature was considered on the concentration profile and the fraction of the solute extracted. The partial differential equation describing the model consists of three independent variables, and a finite difference technique was employed for the solution of the mathematical model. …


Plastic Deformation Of Thin Plates With A Spherical Indenter, Benjamin Jen-An Chang Jan 1967

Plastic Deformation Of Thin Plates With A Spherical Indenter, Benjamin Jen-An Chang

Masters Theses

"A method of determining the stress distribution in a thin plate deformed with a spherical indenter is presented in this report. The analysis is formulated in cylindrical coordinates and utilizes the basic principles of plasticity (von Mises yield criteria, Luwig stress-strain equation, Hencky Deformation theory, etc.). The problem is solved through the utility of a displacement function that, by virtue of its definition, automatically assures that the condition of volume constancy is satisfied. The boundary conditions are selected on the basis of having average, or integrated, effects corresponding to the physical constraints of the problem. Numerical integration is introduced to …


An X-Ray Study Of The Lead Titanate-Bismuth Chromate System, Tsen-Tsou Shih Jan 1967

An X-Ray Study Of The Lead Titanate-Bismuth Chromate System, Tsen-Tsou Shih

Masters Theses

"The lead titanate-bismuth chromate system was studied employing x-ray diffraction techniques at both room and high temperatures. Samples were prepared by sintering stoichiometric mixtures of the corresponding oxides followed by air quenching. Bismuth chromate was prepared by resintering and air quenching for four times. The results of the analyses show the structure of BiCrO₃ to be tetragonal with 8 molecules per unit cell. Solid solutions exist over the range 100 to 35 mole percent PbTiO₃ of the binary system, although small amounts of other phases are present in some regions. X-ray data at room temperature indicate the tetragonal perovskite structure …


A Shunt-Feed Antenna System On A Small Supersonic Aircraft, Larry Joseph Nanney Jan 1967

A Shunt-Feed Antenna System On A Small Supersonic Aircraft, Larry Joseph Nanney

Masters Theses

"A technique was developed which successfully predicted the reactance of a shunt cavity exciting the air frame of a small supersonic aircraft as an antenna. This was possible by the use of the wire above a ground place approximation which closely defined the characteristic impedance of the shunt fed cavity. A correlation was made between the maximum values of parallel resistance of the shunt fed cavity and the length of the air frame or portions of the air frame, which at this point were found to be a quarter wavelength in length. Measurements of the impedance of the shunt-feed system …


Digital Filter Design And Evaluation, David Alvarado MaguiñA Jan 1967

Digital Filter Design And Evaluation, David Alvarado MaguiñA

Masters Theses

"This thesis is concerned with the application of two digital filter design techniques to the Pade approximate continuous filters. The (m, n) Pade approximant has a numerator polynomial of degree n in s and a denominator of degree n in s. The (n-1, n) approximates are desirable for linear phase low pass filters, pulse delay circuits without initial condition errors, and pulse forming networks. A collection of plots is shown to demonstrate the quality of the approximations in the frequency domain, as far as amplitude and phase are concerned. These low pass approximants are normalized to a cut-off frequency of …


Analog Simulation Of A Plug Flow Tubular Reactor, Jon Douglas Carson Jan 1967

Analog Simulation Of A Plug Flow Tubular Reactor, Jon Douglas Carson

Masters Theses

"This thesis stresses the importance of analog and digital computers in the field of reaction kinetics. The analog computer is used to simulate a chemical reaction, the hydrolysis of acetic anhydride. The hydrolysis reaction takes place in a tubular reactor. The reactor is 3/4 inch in diameter and 20 feet long. These reactor dimensions allow the reaction system to approach plug flow, if the reactants flow through the reactor at turbulent flow rates. The physical, reactor, system is used to obtain experimental data for the hydrolysis reaction. The data is obtained at reactor temperatures between 75 and 100°F. Feed concentrations …


A Report Of Early Professional Experiences, Joy Rogers Dec 1966

A Report Of Early Professional Experiences, Joy Rogers

Masters Theses

No abstract provided.


Budget Effects On Defense Planning, Charles Ventura Nov 1966

Budget Effects On Defense Planning, Charles Ventura

Masters Theses

Preface

The Department of Defense (DOD) program budget was developed to link defense planning to defense spending. The budget is designed to reflect total program costs. Military managers require such costs in order to make optimum allocation of resources. The program budget has been a useful tool in bringing uniformity to military plans but its effectiveness, the author contends, has been limited because it contains inaccurate cost data.

The author intends to prove that incorrect financial information is included in the budget because some resource expenditures cannot be accurately traced. The same resource is "common" to several different weapon systems. …


The Study Of The Metal Complexes Of Alpha Aminohydroxamic Acids, Richard N. Nipe Nov 1966

The Study Of The Metal Complexes Of Alpha Aminohydroxamic Acids, Richard N. Nipe

Masters Theses

Introduction

The objectives of this investigation were to develop: 1) compounds similar to hydroxy urea, a compound known to have anti-tumor activity, 2) a method to prepare α-aminohydroxamic acids and to study the complexes of these compounds with several metal ions, 3) computer programs to determine the pK's1 of the hydroxamic acids and the stepwise stability constants2 for the ligands and several metal ions.

The values obtained for the stability constants were compared with values for the stability constants of acetohydroxamic acid and α-aminocarboxylic acids in an attempt to find which in the ligand formed bonds with the …


Dogmatism And Decision-Making In A Variable Risk Situation, Robert E. Jones Sep 1966

Dogmatism And Decision-Making In A Variable Risk Situation, Robert E. Jones

Masters Theses

No abstract provided.


Game Theory And Power Politics, Michael Decker Sep 1966

Game Theory And Power Politics, Michael Decker

Masters Theses

Preface

The contemporary argument over method reaches into all the traditional diversions of social science, of which political science is no exception. Such names as structure-functionalism, decision theory, systems analysis, behavioralism, and game theory have become commonplace identifications of political methodologies in the twentieth century. And if one consideration has generated this plethora of seemingly novel approaches to the study of politics, it is an epistemological one. Indeed, the argument seems to center around determining that kind of intellectual behavior which will best enable the student to understand political events.

...

It is proposed in what follows that, in the …


Discrepancies Between Historical Accounting Data And The Theoretical Data Requirements For Economical Order Quantity Application, James Edward Joyce Aug 1966

Discrepancies Between Historical Accounting Data And The Theoretical Data Requirements For Economical Order Quantity Application, James Edward Joyce

Masters Theses

No abstract provided.


The Application Of The Verwey-Overbeek Theory To The Relative Sediment Volume Of Kaolin-Water Dispersions, James E. Kline Aug 1966

The Application Of The Verwey-Overbeek Theory To The Relative Sediment Volume Of Kaolin-Water Dispersions, James E. Kline

Masters Theses

Introduction

This paper describes an investigation intended to: 1. observe the effect of electrolyte concentration on the stability of kaolin-water systems, 2. evaluate the relative sediment volume measurement as a tool for determining the stability of such systems, 3. assess the applicability of the Verwey-Overbeek theory of stability of lyophobic colloids for predicting the observed effects, and 4. determine if any correlation exists between the effects predicted by the theory and observed through the relative sediment volume measurement.

The relative sediment volume measurement will be shown to be dependent upon the efficiency of packing of the pigment particles, which in …


A Comparative Approach Into The Differentiation Of Two Strains Of Staphylococci, Walter D. Hoeksema Aug 1966

A Comparative Approach Into The Differentiation Of Two Strains Of Staphylococci, Walter D. Hoeksema

Masters Theses

Introduction

The purpose of this investigation was to differentiate Staphylococcus aureus phage type 42D from Staphylococcus epidermidis.

The investigation involved four approaches to this differentiation. The first was a selective screening technique on specific media to point out physical and biochemical characteristics and to demonstrate the presence of specific enzymes. The second was a drug survey which was used to show basic susceptibility and resistance to ten different antibiotics. The third was ultra-violet irradiation which was used to discern susceptibility and resistance to the soft rays of this spectrum segment. The fourth was a chromatographic procedure using labeled carbon which …


A Technique For Teaching Science In The Junior High School, Thomas S. Harro Aug 1966

A Technique For Teaching Science In The Junior High School, Thomas S. Harro

Masters Theses

Chapter I

The Problem and Its Background

The Problem

The current era is called the Space Age -- a time of phenomenal scientific progress. Accordingly, improvements in science programs at all levels of education are being urged and promoted on all sides. Federal grants are offered to motivate science teachers to improve their training; federal funds are available to aid school systems in the purchase of scientific equipment; and capable high-school and college students are urged to choose careers in the sciences.


An Investigation Of The Use Of The Semantic Differential For Assessing Reactions To Stuttering Behavior, Douglas J. Spurlock Aug 1966

An Investigation Of The Use Of The Semantic Differential For Assessing Reactions To Stuttering Behavior, Douglas J. Spurlock

Masters Theses

Introduction

The professional literature in the field of speech pathology contains a great many references to stuttering. A large part of this literature on stuttering has dealt with the problem of severity. The importance of the concept severity of stuttering can be viewed in its relation to the broad theoretical constructs in the field of stuttering. Severity is a way of quantifying the extent of abnormality or degree of interference with the normal speech process. To say that one stutter is more severe than another is to say that he appears to be more abnormal than the other. Severity of …


An Investigation Of The Surface Temperature Distribution In The Detroit Region, Allen R. Smith Aug 1966

An Investigation Of The Surface Temperature Distribution In The Detroit Region, Allen R. Smith

Masters Theses

Chapter I

Introduction

Climate and the City

Studies made of temperature in and around cities have shown the climate of the city to be anomalous in relation to its regional climate. The extent of this anomalous condition and the reasons for its occurrence vary from city to city and from season to season. So many variable factors are present in the generation or regeneration of heat within the city that no study has yet satisfactorily explained the total factors involved, or has indicated the percentage for which any one factor might be responsible. This being the case, the only objective …


Dimethyl Sulfoxide Oxidation Of Primary Alcohols, Carmen Vargas Zenarosa Aug 1966

Dimethyl Sulfoxide Oxidation Of Primary Alcohols, Carmen Vargas Zenarosa

Masters Theses

Historical

A method of selective oxidation of primary and secondary alcohols to the corresponding aldehydes and ketones has been developed recently, namely the use of dimethyl sulfoxide (DMSO) as the oxidizing agent, either alone or with dicyclohexylcarbodiimide (DCC)14, acid anhydrides1, or alkyl chloroformates10. The negatively polarized oxygen atom of the sulfoxide group in DMSO is ideally situated for a transfer to many electron-deficient substrates. The oxygen of the alcohol coordinates with the sulfur atom of DMSO through its oxygen atom; this is followed by β-elemination of dimethyl sulfide, thereby resulting in oxidation of the …


Synthesis Of A Substituted Tetrahydropyrimidopyrimidine, Jack Lee Parsons Aug 1966

Synthesis Of A Substituted Tetrahydropyrimidopyrimidine, Jack Lee Parsons

Masters Theses

Introduction

The purpose of this research was to develop a generalized synthesis of substituted tetrahydropyrimidopyrimidines. It was also of interest to prepare related compounds for the purpose of structure determination.

We were interested in tetrahydropyrimidopyrimidines as possible folic acid antagonists.


Studies On The Preparation Of Tetrasubstituted Hydrazones, William Kao Aug 1966

Studies On The Preparation Of Tetrasubstituted Hydrazones, William Kao

Masters Theses

Introduction

In a recent study of the ultraviolet spectra of substituted hydrazones, it was concluded that a sterio effect existed in tetrasubstituted hydrazones that significantly hindered complete rotation about the nitrogen-nitrogen bond. Weber16 noted that di- and tri-substituted hydrazones exhibited similar spectra with three strong absorption bands at approximately 235, 300, and 340 mu. In acid solutions, the spectra of these compounds showed a marked decrease in intensity of the long wavelength band. It has been postulated that this change was a consequence of the protonation of the non-bonding electron-pair on the amino nitrogen atom, and thus correlated the …


A Synoptic Air Mass Climatology Of The Eastern United States, Robert I. Wittick Jul 1966

A Synoptic Air Mass Climatology Of The Eastern United States, Robert I. Wittick

Masters Theses

Chapter I

Introduction

Orientation and Objective

The concept of the air mass was developed by a group of Norwegian meteorologists during World War I. An air mass, they said, was a body of air which was horizontally homogeneous with respect to temperature and humidity. These bodies of air were classified according to their place of origin since the basic character of an air mass is similar to that of its source region.

Since 1932 when the first air mass climatology was written by Dinies1, the meteorological and geographical journals have published many studies of air mass movements and …