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Determination Of Oxygen Chemical Diffusion Coefficients In Single Crystal Strontium Titanate By Capacitance Manometry, Douglas Bugh Schwarz

Masters Theses

"The use of the tensi-volumetric apparatus to study the non-stoichiometric behavior of strontium titanate was discussed. Oxidation kinetics of reduced single crystal strontium titanate were measured with an ultrasensitive capacitance manometer as the sample absorbed oxygen in response to a changing oxygen activity.

The oxidation kinetics were found to fit a solution to Fick's second law for rectangularly shaped samples....

The procedure selected for measurement of the oxidation kinetics, and the method of obtaining diffusion coefficients from the oxidation data was discussed along with potential sources of error of the system"--Abstract, page ii.

A Multiple-Plan Evaluation Model For Small Ungauged Watersheds, James R. Dexter

Masters Theses

A computer solution model is proposed for simulation of the effect of alternative measures for flood damage reduction. The goal of the model is to optimize the value of an objective function which will maximize the amount of net benefits returned by the project. The evaluation includes unit hydrograph synthesis, direct runoff construction, computation of average annual damages, and optimization of an objective function. A test application of the model is made on a small community affected by floods from a small ungauged stream"--Abstract, page iii.

A Comparative Analysis Of The Capabilities Of Three Stereo Radar Techniques When Operating In The Presence Of System Errors, George L. Bair

Masters Theses

"Three stereo radar techniques for producing stereo images from which topographic data and maps may be obtained are described and their performance in the presence of system errors is determined. The techniques are: an improved single flight technique which uses a combination of two antenna beam characteristics which permits terrain illumination from nearly the same aircraft position, a previously proposed single flight technique which uses two horizontal linear arrays generating vertical fan beams at different azimuth angles, and an existing two flight technique which uses a horizontal array generating a side-looking fan beam.

Error analyses are performed to determine the …

A Numerical Study Of Ordinary Differential Equations With Periodic Coefficients, Richard Bruce Schuessler

Masters Theses

"In this thesis a method for solving ordinary differential equations with periodic coefficients is derived. In addition, by utilization of Floquet theory, a theorem is given by which it is possible to determine the stability of the zero solution. Error bounds are given for the method and for the two dimensional case bounds are given for the error in the eigenvalues. Several numerical examples are given to illustrate the method"--Abstract, page ii.

A Kinetic Study Of The Cerium (Iv)-Oxalic Acid System In Acidic Sulfate Media., Robert Richard Kessler

Masters Theses

"The kinetics of the cerium (IV) oxidation of oxalic acid was studied by a stopped-flow spectrophotometric technique in acidic sulfate media. The media consisted of perchloric acid, sodium sulfate and sodium perchlorate which allowed for the determination and control of the various sulfate and hydroxo species of cerium (IV) at prescribed hydrogen ion concentrations. The rate of reaction decreases rapidly with increasing sulfate concentration which yields evidence against previous reports indicating Ce (SO₄)₂ and Ce (SO₄)^2-₃ as the reactive cerium (IV) species. The results indicate that Ce (SO₄)²⁺ is the …

A Discrete Approach To Surface Interpolation, Jerry Lee Albert Sandvos

Masters Theses

"An equidistant spacing of two dimensional data points is a requirement of most automated analysis routines. In this thesis, a method of generating such equispaced data from randomly spaced data is developed and implemented by a set of computer routines. The method represents the study area as a two dimensional spatial array, in which each array cell represents the data value of a subarea of the study area. A routine sorts and places the data in the array. Missing values in the array are interpolated from nearest neighbors. Filtering is used to smooth errors and a contouring routine is used …

A Computerized Simulation Of A Personal Rapid Transit System., James Richard Cromer

Masters Theses

"The movement of people from an origin to a destination has become a complex and sometimes severe problem, The present modes of transportation available, which include the rapid rail systems, bus transit service, and the personal automobile, have proven quite ineffective in dealing with the situation, A new concept in the transportation area is that of Personal Rapid Transit (PRT). This concept offers a promising solution to many of our people and goods movement difficulties. Before this new system can be implemented it is necessary that various design, construction, and operational criteria be evaluated to determine the optimal system to …

On Finding A Minimal Multiple Fault Test Set In Combinational Networks., Dang Quang Tam

Masters Theses

"A simple and systematic approach which generates exactly a minimal multiple fault test set T mm in irredundant combinational networks is presented. It is shown that the Equivalent Sum of Product of a given network contains all the information necessary to determine this minimal test set. The failures which may occur are limited to permanent stuck at O (or 1) faults"-- Abstract, p. ii

A Study Of Some Heuristic Models For Predicting The Reflection From Spherical Surfaces., Bruce Wayne Rau

Masters Theses

"Four heuristic models' available for predicting the behavior or radiation Non regularly reflected from spherical surfaces have been studied. The four models include: the classical Lambert, the s-factor as deduced by Look, the Lommel-Seeliger, and the Euler's approach. Because each of these analyses was deduced for flat plate geometry, it was first necessary to integrate these flat plate expressions over the surface of a sphere to develop appropriate expressions for the power rejected from the surface of a sphere based upon e ach of the above theories. As an integral part of this investigation, various basic quantities were listed (i. …

An Analysis Of The Bourbeuse River As A Source Of Concrete Aggregate., David John Lexa

Masters Theses

"This thesis represents a study made to evaluate the sand and gravel deposits of the Bourbeuse River as a source of concrete aggregate. The Meramec River has long been a major source of aggregate in Missouri; however, proposed dam construction will limit the quantity available for exploitation. The Bourbeuse River, a tributary of the Meramec, was chosen for evaluation as an alternate source.

The study was conducted in two parts: an estimation of available quantity; a determination of the quality of the material. Quantity of material was estimated through an analysis of drill logs, correlated with the results of basic …

Heavy And Alkali Metal Content Of Surface And Ground Waters In The Joplin Area, Missouri., Edwin Joseph Garrison

Masters Theses

"Over 50 water samples were collected in the fall and spring from springs, streams, lakes and selected water wells within a radius of six miles from the population center of Joplin, Missouri, which lies within the formerly active Tri-State mining district. The samples were analyzed for Ca, Mg, Na, K, Cu, Pb, Zn, Cd, Fe and Hg. Water well samples represent deep (Cambrian-Ordovician) and shallow (Mississippian) rock sources. Statistical evaluations of the data were conducted to help delineate the patterns and causes of metal variations.

The Ca, Mg, Na, K, Zn and Fe concentrations, listed in descending order of abundance, …

Reliability Analysis Of The University Of Missouri--Rolla Reactor, Jimmy Dale Schottel

Masters Theses

"The reliability of Nuclear Installations is becoming an important area of research. In this report an approach to reliability analysis was made. The actual failure data was utilized to predict theoretical failure distributions. These distributions were then used to determine future reliability of components, subsystems and system"--Abstract, p. ii

Charge Transfer Between H ˉIons And O₂ Molecules And D ˉIons And O₂ Molecules In The Ground State., Paul Edgar Chaplin

Masters Theses

"This thesis has been prepared in the style utilized by the Physical Review A. Pages 1-17 will be presented for publication in that journal. Appendices I, II, III, and IV have been added for purposes normal to thesis writing"-- Abstract, p. ii

Two-Dimensional Radiative Transfer In Semi-Infinite Isotropically Scattering Medium., Thomas Lee Linsenbardt

Masters Theses

"Two-dimensional radiative transfer in a semi-infinite medium has been investigated. The medium was considered to be homogeneous, absorbing, non-emitting, and isotopically scattering. Cosine, step, and finite strip variations of collimated and diffuse incident radiation were considered. Collimated incident radiation was restricted to lie in planes perpendicular to the direction of its spatial variation.

Expressions for source functions, fluxes, and intensities at the boundary and inside the medium were obtained by assuming cos foe varying incident radiation. This assumption allowed the two-dimensional problem to be reduced to a one-dimensional integral equation for the source function. This integral equation vias transformed into …

An Analysis Of The (N-1,N) Pad ̌Approximant To The Ideal Delay Operator In Terms Of Bessell Functions., Carl Richard Erdmann

Masters Theses

"A realizable, lowpass, non-minimum phase approximation to the ideal distortion less delay operator e^-st₀ is analyzed in terms of the Bessel functions. The characteristics of the first ten members of the approximation are explicitly considered in this paper. The approximation is demonstrated to be realizable for all orders. Amplitude and phase characteristics are described in relation to the ideal delay operator in compact form and in terms of existing ii tabulated functions. Both amplitude and delay bandwidths are characterized by simple and accurate approximations. The maximally flat properties of both amplitude and delay responses are demonstrated. The transient …

An Algorithm For Minimizing The Riding Time Of Students On School Buses., Dennis Ray Morgan

Masters Theses

"This thesis presents an algorithm which selects from a given set of stops a subset of stops corresponding to a given bus which minimize the riding time of students in going to and from school. The time required in picking up students at their stops and delivering them to school is analyzed. An example is given which illustrates the formulation of a problem and the results obtained from the solution. Finally, the program which was used in the solution of the problem is given along with its implementation"-- Abstract, p. ii

Barometric And Pump Test Determination Of The Characteristics Of A Carbonate Aquifer In The Vicinity Of Norman Creek, Phelps County, Missouri., Somchai Wongsawat

Masters Theses

"Carbonate rock aquifers underlie many parts of Missouri. As population and water use increase, these aquifers will increase in importance as sources of water supply. The purpose of this study is to investigate the applicability of barometric calculations and a variety of pump test evaluation equations to a shallow confined doloii mite aquifer. The aquifer is the upper Gasconade Formation of Lower Ordovician age in the vicinity of Norman Creek, south central Phelps County, Missouri.

The response of water level to atmospheric pressure showed that the carbonate aquifer in this study site has a rather high barometric efficiency (B_{av …}

Liquid Metal Heat Transfer In Longitudinal Flow Along A Cylinder And Flat Plate., Marvin Eugene Lohmann

Masters Theses

"In this investigation an analytical study is performed to determine the effect of axial heat conduction on laminar forced convection for longitudinal flow of liquid metals along a horizontal cylinder and a flat plate. ii

The flow and thermal boundary layers for the problems under consideration do not admit similarity solutions, the non-similarity arising from the transverse curvature; ε = (4/R) (vx/u _∞) ^½ of the cylindrical surface and from co the effect of the axial heat conduction expressible as Ω = 1/Pe_x , where Pe_x is the local Peclet number. The governing conservation equations along with …

Models For Molecular Vibration, Allan Bruce Capps

Masters Theses

“The purpose of the investigation is to determine if a classical model can be used to characterize molecular vibrational and librational (restricted rotation) frequencies. In general, the model treats a molecule as asymmetrical and rigid and simulates the intermolecular forces by springs along the bonds. Molecules constrained to a plane and molecules free to move in three dimensions are analyzed. The frequencies of water molecules are investigated, in particular. The model and analytic components are found to function well. Within the limits set for the model, the water molecule simulation is not successful as the motion becomes anharmonic for energy …

Post Irradiation Changes Of The Elastic Modulus Of Aluminum, Dale A. Powers

Masters Theses

"Aluminum samples of 99.99% and 99.999% purity were irradiated to neutron fluences of 3·8·10¹⁸ nvt and 1.4·10¹⁹ nvt (E greater than 0.1 Mev) at one-third of the melting temperature. The change in Young's modulus of elasticity after isothermal annealing in the temperature range of 110⁰C to 130⁰C was measured. After 2.5 hours of annealing, the modulus reached a steady state value which was decreased by 0.25% ± 0.17% from the unannealed value. Electron microscopy suggests the hardening mechanisms were dispersion hardening by silicon precipitates and void hardening"--Abstract, page ii.

Mercury Distribution In A Massive Sulfide Ore Deposit At Balmat, New York, David Ray Jessey

Masters Theses

"Ore samples consisting of diamond drill core and mine samples, collected from several Balmat ore bodies, were analyzed for their mercury content. The average contents in these ore bodies were found, in ppb, to be: Upper Gleason, 829; Middle and Lower Gleason, 504; Loomis, 546; Fowler, 195; No. 1 Zone, 37; Sylvia Lake, 59; No. 2 Mine, 5. If all of the mercury in these pyrite-sphalerite-galena ores occurs in the sphalerite, then the average sphalerite mercury contents, in ppb, are the following: Upper Gleason, 2490; Middle and Lower Gleason, 2516; Loomis, 2701; Fowler, 1376; No.1 Zone, 384; Sylvia Lake, 408; …

Investigation Of The Electric Field In The Vicinity Of A Water Drop Adhering To A Conductor, Jamnarn Hokierti

Masters Theses

"Electric field calculations in the vicinity of a conductor above ground are developed with constraints on the distance from the conductor for which the electric field equations can be applied for practical applications. The electric field in the vicinity of a small water drop adhering to the conductor has been calculated. Application of this electric field in the vicinity of the water drop has been used to compute the apparent surface charges and also the forces on the small water drop surface. Methods for the calculation of space charge due to ionization on the water drop has been suggested"--Abstract, page …

Comparison Of Scatter Storage Techniques Using An Analysis Of Variance Model, Robert Lee Kitsch

Masters Theses

"An analysis of variance model is developed to determine if a significant difference exists between various scatter storage techniques. The model is a two-factor hierarchical mixed design with each combination of transformation and search method considered as a treatment. The data used in the analysis is obtained from a computer program which provides statistics on the number of probes needed to load the (k+l)st item into a table for the different treatments. An ANOVA table was then computed for various load factors.

A significant difference among the treatments was detected for load factors above .4. Comparison of individual treatments using …

A Study On Two Iodine Containing Peptides Isolated From Porcine Thyroglobulin, Frederick E. Bishop Jr.

Masters Theses

"Two iodopeptides were isolated from thyroglobulin that had been digested with trypsin by paper electrophoresis and paper chromatography. The amino acid analysis demonstrated that the amino acid compositions were similar. The N-terminal amino acid of both iodopeptides was shown to be leucine. The amino acid sequence of one of the iodopeptides was determined by the Edman degradation method and digestion with the enzyme Carboxypeptidase A. The sequence was shown to be: NH₂-Leu-Asn-Ala-Ser-Glu-MIT-Gly-Thr-Ser-Gly-COOH. Other workers have shown that synthetic tyrosyl peptides with the sequence Glu-Tyr are iodinated by the thyroid peroxidase enzyme with a greater specificity than other tyrosyl peptides. This …

Study Of The Return-On-Investment Surface Of A Small Chemical Plant, Jose Antonio Casas Martinez-Ortiz

Masters Theses

"A study of the return-on-investment (ROI) surfaces for a single reactor chemical plant (Westbrook (8)) with a discontinuous investment function confirms its unimodality in the valid region. In both cases studied, the return-on-investment surfaces rise smoothly to the adiabatic boundary from a singular flow rate below which two of the component flow are not physically realizable. The optimum is located on the adiabatic boundary.

Comparison with these surfaces shows that using linear regression to obtain the parameters for an algebraic simulation of investment does not yield ROI values acceptably near the optimal. However, an heuristic approach, which assumes that minimizing …

Two-Dimensional Radiative Transfer In A Finite Scattering Mediu, James Warren Koewing

Masters Theses

"Exact formulations are presented for the source function, intensity and flux for a two-dimensional, isotropically scattering medium of finite thickness. Spatially varying collimated and diffuse radiation of the following types are incident on the medium: (1) cosine varying, (2) semi-infinite step, (3) step at the origin, and (4) finite strip. The solutions for the cosine varying collimated boundary condition are used to construct solutions for the other boundary conditions. The two-dimensional integral equations are reduced to one-dimensional equations by separating variables. Through a series of transformations, the one-dimensional equations are put into a form in which the source function, intensity …

Laser Holographic Interferometric Investigation Of Heat Transfer About An Isothermal Vertical Flat Plate, Richard Michael Quinlisk

Masters Theses

"A study of the laser holographic interferometer was conducted to compare heat transfer data obtained with the device to standard free convection boundary layer theory. The system studied was an isothermal vertical flat plate. The interferometer was used to obtain fringe patterns of the boundary layer at the plate surface.

Data from the holographic interferograms were recorded by making conventional two-dimensional photographs of the holographic images.

The optical data are shown to have a good correlation to Von-Karman theory. Values of the boundary layer thickness, temperature distribution, and heat transfer were compared. An attempt was made to probe the boundary …

Electrical Cable Design And Applications, Robert William Buente

Masters Theses

"The materials available for constructing various electrical cables are discussed, along with remarks/ pertaining to the attributes and limitations of each. The installation and maintenance considerations are discussed in detail. Electrical considerations involved with designing a cable system are outlined with references to their specific application. Special cable constructions, their applications, and their typical modes of installation are reviewed. The conclusion explains an overall cable system design approach along with miscellaneous information"--Abstract, page ii.

Diurnal Solar Heating And Cooling Of A Water Reservoir, Stephen Patrick Lepper

Masters Theses

"The transient diurnal heating of a water reservoir by solar radiation; and its cooling by surface convection, evaporation, and radiation emission was analytically modeled. The directional and spectral properties of the incident solar radiation, the air-water interface, and the selective attenuation of radiant energy by the water were properly included in the analysis. The diurnal vertical temperature distribution was predicted by numerically solving the energy equation using a finite difference technique. It was determined that the surface boundary conditions and the selective absorption of radiant energy by the water strongly influence the thermal stratification of stagnant water.

The diurnal compensating …

Calculation Of The Neutron Flux In The Side Regions Of The Prestressed Concrete Reactor Vessel Of A High Temperature Gas Cooled Reactor, Richard Robert Kent Jr.

Masters Theses

"Neutron flux in the side regions of the High Temperature Gas Cooled Reactor's (HTGR) Prestressed Concrete Reactor Vessel (PCRV) was determined using the Monte Carlo method. One quarter of the PCRV was modeled, with all major structures inside it, e.g. steam generator, auxiliary cooling loop, etc. imaged at their exact position and size. Initial neutron energies range from .001 eV to 3 MeV. Three neutron interactions were considered: absorbtion, elastic scattering, and inelastic scattering.

The flux was calculated for two different PCRV temperatures, 155° F and 647° F. The thermal flux showed a minor increase at the higher temperature. In …