Digital Commons Network^™

Physicochemical Characterization Of Novel 1,1 0-Phenanthrolines, Dominic Millheim

Masters Theses

1,10-Phenanthroline is a well-known and often-used ligand with a variety of interesting properties and applications to both organic and inorganic chemistry. Interest in novel 1,10-phenanthrolines substituted at the 5- and 6- position has grown recently due to their interesting fluorometric and spectroscopic properties. They have been evaluated recently for applications including chemical sensors, chemical indicators, pharmacological targets and bioactive reagents.

1,10-Phenanthroline, an epoxidated synthetic intermediate, and a novel 5,6- disubstituted aminoalcohol derivative were studied to determine the degree of influence that iterative physical and chemical transformations have on the donor properties of the N-C-C-N pocket. Multiple analytical techniques including potentiometry …

Fern Community Reassembly In Secondary Forests Of Puerto Rico: Predictors, Complexity, And Niche Model Assessment, Thomas J. Schmidt

Masters Theses

Approximately 94% of Puerto Rico’s forests were converted into agricultural systems by 1950. Since then, extensive abandonment of agricultural land has resulted in a considerable amount of forest regeneration throughout the main island. Ferns are a major non-woody component of oceanic, tropical island forests comprising up to seventy percent of the flora. Consequently, the composition and community structure of ferns may be indicative of the relative richness of these secondary forests. I used Maximum Entropy (Maxent), a widely-used mathematical tool for distinguishing suitable versus unsuitable fern niche space, along with ENMTools, a tool that assists Maxent with proper model selection, …

Automated Classification Of Eeg Signals Using Component Analysis And Support Vector Machines, Priya Balasubramanian

Masters Theses

Epileptic seizures are characterized by abnormal electrical activity occurring in the brain. EEG records the seizures demonstrating changes in signal morphology. These signal characteristics, however, differ between patients as well as between different seizures in the same patient. Epilepsy is managed with anti-epileptic medications but in some extreme cases surgery might be necessary. Non-invasive surface electrode EEG measurement gives an estimate of the seizure onset but more invasive intra-cranial electrocorticogram (ECoG) are required at times for precise localization of the epileptogenic zone.

The epileptogenic zone can be described as the cortical area targeted for resection to render the patient symptom …

The Nutrient Intake Of Homeless Women Of Grand Rapids, Michigan, Emily D. Popma-Metsaars

Masters Theses

Background Homeless individuals comprise about 1% of the American population with 1/3 of this particular population being women. And despite the potential for hunger, the homeless population has a similar prevalence of overweight/obese as other Americans. The Heartside neighborhood of Grand Rapids is a very low-income area of the city, inhabited by the poor and homeless. The Food Access in Michigan Project is studying the relationship between food insecurity and food environments in Michigan.

Objectives The purpose of this study was to determine the characteristics of the diet of homeless women in Heartside. This study examined the level of food …

A Game Of Skill: Video Game Enthusiasm And Confidence With Computers, Rebecca L. Sevin

Masters Theses

This study explores the relationship between recreational involvement with video games and an interest in computer science as well as confidence with computers. Multiple works have acknowledged that the content in video games and the video game culture is presently very hostile towards women. Simultaneously, the number of women pursuing computer science has been decreasing since the 1980s. Past studies have suggested that playing video games can increase confidence with computers and may lead to an interest in computer science. Using data collected from 1,124 college students, this study addresses this issue by using a variety of measures to gauge …

Effects Of Summer School On Academic Achievement: Reducing Summer Learning Loss In Middle School, Angela Joy Aumaugher

Masters Theses

Summer learning loss has been implicated in the achievement gap between economically advantaged and disadvantaged students. The purpose of this study is to examine the effects of a summer school program on the degree of summer learning loss and academic achievement of middle school students. Participants included a census of middle school students who attended the summer school program at a small public charter school in the Midwest between the fall of 2010 and the spring of 2014. Achievement and learning loss were determined based on fall and spring testing using the Northwest Evaluation Association’s Measures for Academic Progress test, …

Michigan's Clay Bluffs: The Description And Comparison Of An Erosion-Dependent Natural Community, Nathaniel G. Fuller

Masters Theses

The clay bluffs of Michigan are a natural community found along the shores of the Great Lakes. Groundwater is found to be critical to sustaining the alkaline wetlands on the face of the bluff as well as the source of most erosion events. The clay bluffs are unusual in their vegetation, disturbance regime and geographical context. This thesis focuses primarily on describing seeping clay bluffs and exploring the comparison to other natural communities. The purpose of this is twofold, to better understand the ways in which natural communities are described as distinct from one another, and to assess the distinctness …

Exploration Of The Validity Of The Two-Dimensional Sagittal Plane Standing Long Jump Model, Lauren Hickox

Masters Theses

Most previous standing long jump studies have been based on the assumption of two-dimensional sagittal plane motion. The purpose of this study was to investigate the validity of this assumption. Standing long jump trials were collected using six adult male subjects. Each subject stood with a foot on each of two force plates and performed eight standing long jumps for maximal distance. Inverse dynamics analyses were performed for the two-dimensional (2D) and three-dimensional (3D) models and the joint moments, powers, and work values were compared. The differences between these models with respect to the validity of the common planar jumping …

The Nucleic Acid Binding Properties Of The Pwi Motif, Hamideh Keshavarz-Mohammadian

Masters Theses

The PWI motif is a highly conserved domain that contains a Proline-Tryptophan-Isoleucine (PWI) tripeptide sequence, for which it is named. Proteins that contain a PWI motif are known to be involved in the constitutive and alternative splicing and the 3'-end processing of messenger RNA transcripts. The hypothesized role of the PWI motif is to nonspecifically interact with nucleic acids. The PWI motif is capable of binding both doublestranded and single stranded forms of DNA and RNA. The structure of the highly conserved core of the PWI motif reveals that it adopts a four-helix bundle fold. The structured core domain, however, …

Electron Transfer In Pnicogen Bond, Liangyu Guan

Masters Theses

Abstract is available for download as a separate file.

Replacement Of Solvent Based Ink By Water Based Inks For Gravure Presses With Low Efficiency Ink Driers, Viraj Suresh Dalvi

Masters Theses

Rotogravure printing of decorative laminates, wall coverings, or vinyl floorings process often uses solvent based inks. The main constraining factor with solvent based ink is presence of volatile organic compounds (VOC’s). Due to the environmental norms on Volatile Organic Compounds (VOCs), and restrictions on using solvent based inks, the ink industry came up with water based ink as more environmentally friendly alternative. Organizations which print decorative laminates, wall coverings, or vinyl floorings with solvent based inks have gravure printing infrastructure, which is often equipped with low efficiency driers capable of drying solvent based inks. In order to comply with environmental …

Effects Of Road Salt On Asylum Lake Geochemistry, Davina A. Wyman

Masters Theses

Several studies indicate that seasonal applications of road deicers can lead to saline runoff entering surface water and groundwater, which can in turn change the chemistry, density, and physical mixing patterns of urban lakes. An investigation at Asylum Lake, an urban lake located near three major roadways, was conducted to determine the degree of road salt contamination in the lake, to determine if salt loading disrupts seasonal mixing patterns, and to determine the extent of redox stratification present due to eutrophic conditions. Samples were collected monthly from the deepest point in Asylum Lake over a 19-month period and analyzed for …

Trajectory Optimization For A Misson To The Trojan Asteroids, Shivaji Senapati Gadsing

Masters Theses

The problem of finding a minimum-fuel trajectory for a mission to the Jovian Trojan asteroids is considered. The problem is formulated as a modified traveling salesman problem. Two different types of algorithms such as an exhaustive search algorithm and a serial rendezvous search algorithm are developed. The General Mission Analysis Tool (GMAT) is employed for finding optimum trajectories with minimal fuel consumption. The selection of a minimum-fuel mission trajectory, and the associated target asteroids, will be a key factor in determining feasibility and scientific value of a Trojan tour and rendezvous mission.

The transfer trajectory followed by a spacecraft between …

Gpu-Accelerated Influenza Simulations For Operational Modeling, Peter Holvenstot

Masters Theses

Simulations of influenza spread are useful for decision-making during public-health emergencies. Policy-makers use models to predict disease spread and estimate the effects of various intervention strategies. Effective modeling of targeted intervention strategies requires accurate modeling of individual-level behavior and transmission. However, this greatly increases the computational costs of these agent-based models. In addition, if the models are used as an outbreak progresses, some operational decisions must occur rapidly in order to contain the spread of the disease.

Graphics Processing Units (GPUs) are a type of specialized processor used to drive graphical displays. Many recent devices also allow users to write …

Integrating Art Education And Literacy Education: A Curriculum For The Secondary Level, Erin Moody-Zoet

Masters Theses

The purpose of this paper is to examine, through the design of a new curriculum, how the integration of reading and writing literacy into a visual arts curriculum can strengthen literacy skills as well as foster creative thinking at the middle school level. There is a growing demand for the integration of literacy in all core, and non-core curricula. By developing a curriculum that integrates literacy strategies in a visual arts program, as well as touches on the disconnect that I see between individuals and their own creative outlets, a curriculum is established that fosters and engages students in creative …

Investigating Teachers’ Self-Reported Efficacy In Instructing Culturally And Linguistically Diverse Learners In Alternative Settings, Liane Kay Lancaster

Masters Theses

Teachers in alternative schools have limited to no knowledge of issues influencing students who are culturally and linguistically different. Current educational research lacks an in-depth examination of teachers’ perceptions of their use of culturally relevant practices with this group.

Using an adaptation of Siwatu’s (2007) Culturally Responsive Teaching Self-Efficacy Scale and drawing upon the theories of constructivism and multiculturalism, this study documents the perceptions of teachers’ preparedness in an alternative high school in the Midwest. The investigator collected information that may assist teachers and teacher preparation institutions in delivering instruction that better suits students who are culturally and linguistically diverse. …

Starting A Charter School In Benton Harbor, Michigan, Donald W. Pearson

Masters Theses

This project investigates the process of starting a public school academy (i.e., charter school) in Benton Harbor, Michigan and completing the authorizing application. The dynamics of the project is documented in four phases. The first is the inquiry phase which is identifying, clarifying and documenting the problem. Phase two is designing a comprehension strategy in response to the problem. The third phase is implementing, creating and submitting a viable application for authorization to an educational institution and which is to be submitted to the Michigan State Department of Education for a charter school grant. The last phase of the project …

Predictive Modeling In The Search For Vertebrate Fossils: Geographic Object Based Image Analysis (Geobia) In The Eocene Of Wyoming, Bryan Bommersbach

Masters Theses

The development and testing of predictive models for identifying productive fossil localities represents a promising interdisciplinary endeavor among geographic information scientists, paleoanthropologists, and vertebrate paleontologists. This thesis analyzed high resolution (2m spatial resolution) commercial satellite imagery from the Worldview-2 satellite of five areas of the Great Divide Basin using a GEographic Object-Based Image Analysis (GEOBIA) technique, which segments the image into spectrally homogeneous, multi-pixel image objects. In addition to allowing statistical analysis of the spectral characteristics of the image objects, GEOBIA techniques also let analysts incorporate expert knowledge and contextual information to improve classification accuracy. The spectral characteristics of the …

Localization And System Identification Of A Quadcopter Uav, Kenneth Befus

Masters Theses

The research conducted explores the comparison of several trilateration algorithms as they apply to the localization of a quadcopter micro air vehicle (MAV). A localization system is developed employing a network of combined ultrasonic/radio frequency sensors used to wirelessly provide range (distance) measurements defining the location of the quadcopter in 3-dimensional space. A Monte Carlo simulation is conducted using the extrinsic parameters of the localization system to evaluate the adequacy of each trilateration method as it applies to this specific quadcopter application. The optimal position calculation method is determined.

Furthermore, flight testing is performed in which real range measurement data …

Electroplating Of Nanoengineered Polymer Substrate, Brandon Voelker

Masters Theses

The development of a polyethylene based polymer with metallic inclusions, a nanoengineered polymer, has recently opened up great potential for many new commercial and industrial applications. The major advantage of developing these nanoengineered polymers is to be able to tailor the resistance and other properties by varying the composition of the polymer. The industrial usage of this polymer benefits from the addition of an electrically conductive, metallic coating. This research develops methods of electroplating nickel and copper layers on to the polymer substrates using DC and pulsed techniques.

Electroplating is conducted in a 1000 mL beaker using a specialized plating …

Overtime Traffic Enforcement Evaluation: A Methodology For Selecting Agencies And Enforcement Periods, Dario Enrique Romero Santana

Masters Theses

Multiple studies have stated the advantages of police traffic enforcement on crash reduction (Zaidel, February 2002). It is very important to identify locations and time periods where police enforcement produces the greatest crash reductions. The objectives of this study were to: (1) determine the impact of overtime traffic enforcement on crash occurrence; (2) develop procedures to identify police agencies with potential to reduce targeted crashes; and (3) develop procedures to identify additional time periods in which enforcement activities should be conducted. In order to accomplish these objectives, many methodologies were explored. The study used crash and enforcement data collected by …

Owning Our Food System: Urban Community Gardening And Local Food Movements, Paige A. Edwards

Masters Theses

Food is a means of examining culture, including identity, autonomy and power. It creates relationships and memories between people via shared connections. Through food, I explore local food movements and urban community gardening.

We both ingest and produce garden-grown foods. This movement is often described as simple nostalgia. I suggest that it is a response against heavily processed foods within a system reliant on mass produced food. This desire for ownership pushes community gardens and other counter-hegemonic spaces forward in their goals of using social practice to challenge the established food industry and take control within their own lives.

An Enhanced Self-Healing Protection System In Smart Grid: Using Advanced And Intelligent Devices And Applying Hierarchical Routing In Sensor Network Technique, Mohamed Eid Aljahani

Masters Theses

This paper presents a self-healing protection systems were designed using PSCAD software to test and investigate the efficiency of this method. The system was applied on a typical distribution system with loads, buses, and power sources. The availability of advanced and intelligent devices, such as IEDs and PMUs was the trigger to design proficient and accurate self-healing protection systems which are associated with future smart grids. Deploying optimal sensors distributed within the grid could be a suitable method to monitor and control the distribution network. By using a hierarchical clustering communication technique, optimal sensors can work wirelessly and efficiently without …

An Integral Framework For Sustainable Building Design, Bushra Asfari

Masters Theses

Selection of materials for building design is a delicate process hinged of a number of factors which can be cost or environmental related, depending on the objectives of the design. This process becomes more difficult when designers are faced with several material options for each building component. This thesis presents the design and development of a framework that enables designers understand the trade-off between cost and environmental related factors when selecting materials for building design. The framework is based on the integration of Autodesk Revit, Microsoft access, and modeling modified Harmony search multi-objective optimization tool adapted to account for material …

Stratigraphic Framework And Landsystem Correlation For Deposits Of The Saginaw Lobe, Michigan, Usa, Ivan R. Guzman

Masters Theses

Since the time of the Last Glacial Maximum (LGM) the south-central portion of the Lower Michigan Peninsula has been subject to several glacial advances and retreats by the Saginaw lobe. As part of the U.S Geological Survey Great Lakes Geological Mapping Coalition projects, several rotosonic borings were drilled between 2006 and 2013 in Barry, Kalamazoo and Calhoun Counties. Gamma ray logs and textural analyses were completed for each core. Five of these borings were selected according to their diamicton (till) content and correlated using water well logs and surficial geology maps. Glacial deposits such as diamicton serve as evidence of …

Chemistry Graduate Teaching Assistants: A Comparison Of The Classroom Discourse Within Expository And Problem-Based Learning Laboratories, Kelley M. Current

Masters Theses

Graduate Teaching Assistants (GTAs) commonly function as instructors within undergraduate chemistry laboratories. This study sought to explore and describe GTA classroom discourse within two distinct instructional modes, using discourse analysis as the theoretical framework. Theclassroom discourse within a series of verification style labs was comparedto the classroom discourse produced within a set of Problem-Based Learning (PBL) labs. The results suggest three primary findings: (1) the apparent relationship between the instructional mode and form of GTA classroom discourse, (2) the patterns in classroom discourse observed within a given instructional mode repeat, irrespective of content, and (3) the classroom discourse observed within …

Improved Accuracy In Real-Time Rfid Localization Systems Using Kalman Filtering, Benjamin J. Sanda

Masters Theses

The use of Radio Frequency Identification (RFID) has become widespread in industry as a means to quickly and wirelessly identify and track packages and equipment. Now there is a commercial interest in using RFID to provide real-time localization. Efforts to use RFID technology for this purpose experience localization errors due to noise and multipath effects inherent to these environments. This paper presents the use of both linear Kalman filters and non-linear Unscented Kalman filters to reduce error effects inherent to real-time RFID localization systems and provide more accurate localization results in indoor environments. A commercial RFID localization system designed for …

Scientism, Satire, And Sacrificial Ceremony In Dostoevsky's "Notes From Underground" And C.S. Lewis's "That Hideous Strength", Jonathan Smalt

Masters Theses

Though the nineteenth-century Victorian belief that science alone could provide utopia for man weakened in the epistemological uncertainty of the postmodern era, this belief still continues today. In order to understand our current scientific milieu--and the dangers of propagating scientism--we must first trace the rise of scientism in the nineteenth-century. Though removed, Fyodor Dostoevsky, in Notes From Underground (1864), and C.S. Lewis, in That Hideous Strength (1965), are united in their critiques of scientism as a conceptual framework for human residency. For Dostoevsky, the Crystal Palace of London's Great Exhibition (1862) embodied the nineteenth-century goal to found utopia through the …

Forbidden Fe Ii Emission Line Fluxes From The Weigelt Knots Of Eta Carinae, S. Towers

Masters Theses

Eta Carinae is an unparalleled object crossing many divisions of astrophysics. It has multiple, complicated and dynamic processes leading to absorption and emission spectra across all wavelengths from radio to hard x-ray. The spectra differ spatially across Eta Carinae's extended envelope and are changing rapidly over time.

The Weigelt Knots of Eta Carinae's ejecta emit spectra of numerous forbidden iron species lines, rare on Earth, but prevalent in the unique conditions surrounding this star. The Weigelt Knots' unique conditions occur almost nowhere else, making Eta Carinae, useful not only for understanding massive stars similar to it, but for understanding the …

Comparing Methods For Full Body Inverse Dynamics Analysis Of A Standing Long Jump, Nathaniel Vlietstra

Masters Theses

The classic iterative Newton-Euler method for inverse dynamics applied to calculating net joint torques in biomechanics analysis has a number of drawbacks. Many sources of error including imprecision in video motion capture data measurements can lead to significant errors in calculated net joint torques. Adding ground reaction force data overconstrains the solution. This study examined the effectiveness of various inverse dynamics analysis methods on a full body analysis of the standing long jump motion. These methods included variations in which equations for segments from the linksegment model were removed to relieve over constraint. Also considered were analysis methods applying least …