Digital Commons Network^™

Physicochemical Characterization Of Novel 1,1 0-Phenanthrolines, Dominic Millheim

Masters Theses

1,10-Phenanthroline is a well-known and often-used ligand with a variety of interesting properties and applications to both organic and inorganic chemistry. Interest in novel 1,10-phenanthrolines substituted at the 5- and 6- position has grown recently due to their interesting fluorometric and spectroscopic properties. They have been evaluated recently for applications including chemical sensors, chemical indicators, pharmacological targets and bioactive reagents.

1,10-Phenanthroline, an epoxidated synthetic intermediate, and a novel 5,6- disubstituted aminoalcohol derivative were studied to determine the degree of influence that iterative physical and chemical transformations have on the donor properties of the N-C-C-N pocket. Multiple analytical techniques including potentiometry …

Fern Community Reassembly In Secondary Forests Of Puerto Rico: Predictors, Complexity, And Niche Model Assessment, Thomas J. Schmidt

Masters Theses

Approximately 94% of Puerto Rico’s forests were converted into agricultural systems by 1950. Since then, extensive abandonment of agricultural land has resulted in a considerable amount of forest regeneration throughout the main island. Ferns are a major non-woody component of oceanic, tropical island forests comprising up to seventy percent of the flora. Consequently, the composition and community structure of ferns may be indicative of the relative richness of these secondary forests. I used Maximum Entropy (Maxent), a widely-used mathematical tool for distinguishing suitable versus unsuitable fern niche space, along with ENMTools, a tool that assists Maxent with proper model selection, …

Automated Classification Of Eeg Signals Using Component Analysis And Support Vector Machines, Priya Balasubramanian

Masters Theses

Epileptic seizures are characterized by abnormal electrical activity occurring in the brain. EEG records the seizures demonstrating changes in signal morphology. These signal characteristics, however, differ between patients as well as between different seizures in the same patient. Epilepsy is managed with anti-epileptic medications but in some extreme cases surgery might be necessary. Non-invasive surface electrode EEG measurement gives an estimate of the seizure onset but more invasive intra-cranial electrocorticogram (ECoG) are required at times for precise localization of the epileptogenic zone.

The epileptogenic zone can be described as the cortical area targeted for resection to render the patient symptom …

Genetic Health And Population Viability Of Reintroduced American Marten In Michigan, Tamara L. Hillman

Masters Theses

American marten (Martes americana) were extirpated from Michigan’s Lower Peninsula (LP) in 1911, and subsequently from the Upper Peninsula (UP) in 1939 due to habitat loss and unregulated trapping. The species was later reintroduced in the UP in the mid-1950s, and to the LP in the mid-1980s. Previous research has determined the small founding sizes used in the LP reintroductions have resulted in losses of genetic diversity, while research in the UP has produced discordant results concerning the effects of the reintroduction methods on genetic health and population structure. Since past research of marten in the LP, no …

The Nutrient Intake Of Homeless Women Of Grand Rapids, Michigan, Emily D. Popma-Metsaars

Masters Theses

Background Homeless individuals comprise about 1% of the American population with 1/3 of this particular population being women. And despite the potential for hunger, the homeless population has a similar prevalence of overweight/obese as other Americans. The Heartside neighborhood of Grand Rapids is a very low-income area of the city, inhabited by the poor and homeless. The Food Access in Michigan Project is studying the relationship between food insecurity and food environments in Michigan.

Objectives The purpose of this study was to determine the characteristics of the diet of homeless women in Heartside. This study examined the level of food …

Effects Of Fatty Acid Structure On Endothelial Cell Expression Of Connexin43, Albert E. Sowers Iii

Masters Theses

The epidemic of obesity-related metabolic and cardiovascular diseases is linked to elevated fatty acids (FA). Epidemiological data argue that trans FA contribute to the development and progression of these disease processes. Previous work suggests the similarity in structure between saturated and trans FA may stimulate inflammation through trans FA interactions with toll-like receptor 4 (TLR4). To evaluate the impact of trans FA on cardiovascular health, the response of endothelial cells to trans FA was evaluated. Specifically, responses to the 18-carbon trans FA elaidic acid (EA) were compared to the same length cis FA oleic acid (OA). Endothelial cells were exposed …

Diffusion Of The Lnternet And Its Effect On Gender Attitudes: A Cross-National Approach, Robert Roznowski

Masters Theses

The rapid diffusion of the Internet worldwide generates discussion about the social implications of the Internet. To explore the effect of Internet diffusion worldwide, this study examines changes in reported gender attitudes since the introduction of the Internet. I propose that the diffusion of the Internet fosters egalitarian changes in gender attitudes. Using cross-national data from forty countries over a time span of nearly twenty years, I successfully implement an alternative analysis technique, the slope-slope model, to examine the relationship between rates of Internet diffusion and changes in gender attitudes in the economic, political, and education domains. Internet diffusion affects …

I Get By With A Little Help From My Friends: A Qualitative Study Of Nurse Close Work Friendship And Social Support, Jennifer Ptacek

Masters Theses

The nursing profession is laden with numerous job, emotional labor, and communication stressors, which come from both patients and healthcare organizations. These frequent and simultaneous pressures can result in nurse burnout and turnover (Tracy, 2009). Socially supportive workplace communication has been identified as a solution to reducing nurse stress, burnout, and turnover (Apker & Ray, 2003), but has not specifically considered social support in nurse work friendships. A mixed qualitative method study was conducted with five nurse best friend pairs, using job observations of participants’ work friendship communication and individual and joint interviews. Two major communication themes emerged from the …

"Race Becomes Biology": Co-Occurring Oral And Systemic Disease As Embodiment Of Structural Violence In An American Skeletal Sample, Rieti G. Gengo

Masters Theses

In recent years, a large number of biomedical studies have demonstrated that the bacteria that contribute to periodontal disease can migrate outside the oral cavity, causing a host of systemic infections. Yet, to date, only one bioarchaeological investigation has addressed this co-occurring disease process in a past population. The results of this thesis confirm the bioarchaeological visibility of the correlation between oral and systemic disease based on data derived from a sample of white and black adults from the Robert J. Terry Anatomical Skeletal Collection. Vertical recessions and porous remodeling of the alveolar crest were examined to identify periodontitis. Periosteal …

Virtual Analysis And Evaluation Of Roundabout Safety And Operational Features, Elisha Jackson Wankogere

Masters Theses

Roundabouts can be a solution to safety concerns present at other types of intersections. Recently in the United States, there has been an increase in conversion of problematic intersections to roundabouts to improve their safety. However, it is difficult to make these roundabouts, especially multi-lane roundabouts, safe to all ranges of users. Roundabout features such as advance warning and signage play an important role in determining driver performance as they navigate the roundabout.

This research is an effort to evaluate new and existing roundabout safety and operational features such as signs and pavement markings and how they influence performance of …

The Efficacy Of Music As A Non-Analgesic Method Of Reducing Pain Perception During Cold Pressor Trials, Amanda Lynn Ziemba

Masters Theses

The purpose of this project was to investigate the impact of differentiated onset of self-selected music on pain perception and pain tolerance during a cold pressor test. Subjects participated in four trials during which music was presented at different points of time in relation to their exposure to the cold pressor test. Results indicated that listening to music prior to and concurrently with the onset of the pain resulted in lower self-reported pain (F(3, 66) :3.25, p < .05). Behavioral results indicated that subjects were able to tolerate an average of 25s longer (F(2.04,44.81): I.56,p > .05.) when music was presented after the onset of painful stimuli. Both results have positive implications for the clinical use of music as …

Neuroprotective Effect Of An Α-7 Nicotinic Acetylcholine Receptor Agonist And A Positive Allosteric Modulator In An In Vitro Model Of Glaucoma, Leah Lyons

Masters Theses

Glaucoma is one of several neurodegenerative diseases of the central nervous system for which a pharmacologic cure is yet to be discovered. In previous studies acetylcholine (ACh) has provided neuroprotection for retinal ganglion cells (RGC) in the mammalian retina under glaucomatous conditions (Wehrwein et al., 2004). More specifically, an α7 nicotinic ACh receptor (nAChR) agonist has demonstrated neuroprotection for RGCs in both in vitro and in vivo models of glaucoma (Iwamoto et al., 2014). In this study, this α7 nAChR agonist was combined with a positive allosteric modulator (PAM) in dissociated adult porcine retinas to evaluate its effect on isolated …

Professional Experiences Of Women Administrators In Student Services, Christy M. Mayo

Masters Theses

The number of women pursuing higher education now outnumbers that of men. However, the number of women in administration and faculty roles does not mirror that of the student population. Instead, women are often found in midlevel and low level positions, especially within student services and student affairs. This thesis is a qualitative study that employs the phenomenological method to explore and examine the professional experiences of seven midlevel administrators in student affairs and student services at GVSU. The constant comparative method of coding was used to analyze the data, identify themes, and articulate assertions. The themes that emerged from …

Material | Adventure, Diana Wagner

Masters Theses

With the generous support of the RISD Grad Studies|Grant I traveled to London, England to deepen my thesis research of material libraries. This opportunity allowed me to visit the resources that inspired my enthusiasm for materials and to challenge the questions I posed in my thesis research, How we, artists and designers, learn from materials in the context of the library? The sources explored within this book highlight a growing community of academic and research based material collections in London, along with some exceptional exhibitions of materials and process in the context of the museum and archive.

Southern Black Gospel Music: Qualitative Look At Quartet Sound During The Gospel `Boom' Period Of 1940-1960, Beatrice Pate

Masters Theses

The purpose of this work is to identify features of southern black gospel music, and to highlight what makes the music unique. One goal is to present information about black gospel music and distinguishing the different definitions of gospel through various ages of gospel music. A historical accounting for the gospel music is necessary, to distinguish how the different definitions of gospel are from other forms of gospel music during different ages of gospel. The distinctions are important for understanding gospel music and the `Southern' gospel music distinction. The quartet sound was the most popular form of music during the …

Integrating Art Education And Literacy Education: A Curriculum For The Secondary Level, Erin Moody-Zoet

Masters Theses

The purpose of this paper is to examine, through the design of a new curriculum, how the integration of reading and writing literacy into a visual arts curriculum can strengthen literacy skills as well as foster creative thinking at the middle school level. There is a growing demand for the integration of literacy in all core, and non-core curricula. By developing a curriculum that integrates literacy strategies in a visual arts program, as well as touches on the disconnect that I see between individuals and their own creative outlets, a curriculum is established that fosters and engages students in creative …

A Gross National Happiness Infused Curriculum: The Promise Of A More Meaningful Education In Bhutan, Sonam Zangmo

Masters Theses

Schooling in our modern society is aimed primarily to secure a career so that individuals will find their places in the political and economic systems. However, many believe that education should be reconceived so that student skills and attributes are understood more fully in relation to their impact on the local as well as the global community. The Gross National Happiness infused curriculum aspires to facilitate the holistic education that would address some of the humanistic values we need in this era. In this paper I study the concepts of Gross National Happiness and how the Gross National Happiness infused …

Resting Site Characteristics Of American Marten In The Northern Lower Peninsula Of Michigan, Robert L. Sanders

Masters Theses

American marten are usually associated with forests that are characteristically late successional, closed canopy, and diverse in structure; attributes that meet habitat requirements and provide resting site structures. Resting site structures are required habitat components that are used daily and provide protection from predation and inclement weather. I identified resting site characteristics of American marten in the Manistee National Forest in Michigan’s Lower Peninsula from May 2011 to December 2013. Twenty five marten (15 male and 10 female) were monitored using radio telemetry to identify what types of resting sites structures were used. I identified 522 unique resting site structures; …

Historical Demography And Dispersal Patterns In The Eastern Pipistrelle Bat (Perimyotis Subflavus), Alynn M. Martin

Masters Theses

The recent emergence of threats to North American bat conservation has prompted increased population genetics research on high risk species. The eastern pipistrelle bat is affected by both white-nose syndrome and wind turbine mortality. However, little work has been done regarding the population structure and effective population size of this species. Using the HVI region of the mitochondria and eight microsatellite loci, I analyzed male and female structure across the sample range of P. subflavus and estimated the effective population size of their populations. Pairwise F_ST values indicate that there is one panmictic population based on microsatellite data, while …

Effects Of Health Expenditures On Population Age Distribution And Labor Force Participation Rates: Empirical And Comparative Analysis, Jassim M. H. Al-Jebory

Masters Theses

Baby boom and population aging are the main features of the world population that are leading to child and elderly people in the labor force. Categorizing the world into low and high-income countries, the baby boom and child labor can be found in low-income countries, while population aging and elderly people in the labor force can be found in high-income countries. The cause of these features is declining rates of population and labor force ages 15-64, which is the most productive and active proportion. Health expenditures is one of the main factors that is associated with undesired trends of population …

Effects Of Various Partial Body Cooling Techniques On Core Temperature During Recovery From Prolonged Cycling-Induced Heat Stress, Afton Danielle Seeley

Masters Theses

The purpose of this study was to investigate the effects of using an ice-vest and a palm cooling device on core and skin temperatures, heart rate, and perceived thermal comfort during a one hour recovery period following exercise in the heat. Ten recreationally active adults cycled for one hour at 50% V0₂ peak on a cycle ergometer while exposed to 36°C 45%relative humidity environmental conditions. Following exercise, each subjectwas exposed to an ice vest, a palm cooling device, or a non cooling control while seated in the environmental chamber for 60 more minutes. No significant differencewas found betweenany of …

The Nucleic Acid Binding Properties Of The Pwi Motif, Hamideh Keshavarz-Mohammadian

Masters Theses

The PWI motif is a highly conserved domain that contains a Proline-Tryptophan-Isoleucine (PWI) tripeptide sequence, for which it is named. Proteins that contain a PWI motif are known to be involved in the constitutive and alternative splicing and the 3'-end processing of messenger RNA transcripts. The hypothesized role of the PWI motif is to nonspecifically interact with nucleic acids. The PWI motif is capable of binding both doublestranded and single stranded forms of DNA and RNA. The structure of the highly conserved core of the PWI motif reveals that it adopts a four-helix bundle fold. The structured core domain, however, …

The Effects Of Different Warm-Up Methods On Anaerobic Power, Bradley Kendall

Masters Theses

The purpose of this study was to investigate the effects of various warm-up methods on Wingate Anaerobic Test (WAnT) performance. The goal of this study was to investigate how a general cycling warm-up, a dynamic stretching routine, a static stretching routine, and the combination of both static stretching followed by cycling and dynamic stretching followed by cycling affect WAnT performance. Ten recreationally active subjects (5 males, 5 females), completed five WAnT on a Monark Ergomedic 984E cycle separated by at least 48 hours. Subjects were randomly assigned to an order of conditions and performed a different condition prior to each …

Comparison Of Dual- And Tri-Axial Accelerometer Accuracy, Lindsay Powell Toth

Masters Theses

The purpose of this study was to investigate the accuracy of the Omron HJ-720ITC and the Fitbit Zip activity monitors with regard to step count, energy expenditure, and distance traveled measurements. The importance of this research rests in the success rates of pedometer-based physical activity interventions which have been shown to increase physical activity while also enabling weight loss and lowering blood pressure in the adult population. Activity monitors available for retail sale must be found accurate for proper participation in exercise interventions especially low-cost devices as used in this study.

In order to test the accuracy of the Omron …

Failure Of Democratic Consolidation: The Three Year Interlude Of Military Rule (1958-1962) In Burma, Zaw Thein

Masters Theses

Many scholars believe that the period between 1948 when Burma won Independence and 1962 when the military took over the country from the elected civilian government as the parliamentary democracy era. During this era, there was a three-year interlude where the military leaders ruled the country as the Caretaker Government- a euphemism for the three-year military interlude. My argument is that this interlude happened due to the growing strength of the military as an institution and the decline of political parties in Burma. The strength of the military institution was due to the civil war that broke out just after …

Effects Of Road Salt On Asylum Lake Geochemistry, Davina A. Wyman

Masters Theses

Several studies indicate that seasonal applications of road deicers can lead to saline runoff entering surface water and groundwater, which can in turn change the chemistry, density, and physical mixing patterns of urban lakes. An investigation at Asylum Lake, an urban lake located near three major roadways, was conducted to determine the degree of road salt contamination in the lake, to determine if salt loading disrupts seasonal mixing patterns, and to determine the extent of redox stratification present due to eutrophic conditions. Samples were collected monthly from the deepest point in Asylum Lake over a 19-month period and analyzed for …

The British Women’S Land Army: Gender, Identity, And Landscapes, Hilary M.K. Anderson

Masters Theses

The land girls who comprised the Women’s Land Army in Great Britain during the Second World War challenged cultural assumptions regarding gender and femininity. Through their work in agriculture, social anxieties were provoked regarding proper notions of femininity and separate spheres, which left these women in conflicting positions as they carved a spot for themselves in a war torn society. In order to carry out their work in the Women’s Land Army, land girls operated at the convergence of private and public spheres in a conjoined space. Living and operating in this conjoined space enabled them to blur the ideological …

A Comparison Of Two Variations Of A Stimulus-Stimulus Pairing Procedure On Novel And Infrequent Vocalizations Of Children With Autism, Andrew J. Bulla

Masters Theses

Despite the growth in a behavioral technology for the treatment of autism, a small population of individuals with autism fails to develop functional language. One procedure used for inducing vocalizations in non-verbal children is a stimulus-stimulus pairing (SSP) procedure. In an SSP procedure a vocalization is paired with a reinforcer over a period of time to establish the vocalization as a learned reinforcer, and any utterance of the target vocalization is believed to be automatically reinforced thus increasing the frequency of the vocalization. Past research has yielded mixed results with the SSP procedure, and more research is warranted to identify …

Gpu-Accelerated Influenza Simulations For Operational Modeling, Peter Holvenstot

Masters Theses

Simulations of influenza spread are useful for decision-making during public-health emergencies. Policy-makers use models to predict disease spread and estimate the effects of various intervention strategies. Effective modeling of targeted intervention strategies requires accurate modeling of individual-level behavior and transmission. However, this greatly increases the computational costs of these agent-based models. In addition, if the models are used as an outbreak progresses, some operational decisions must occur rapidly in order to contain the spread of the disease.

Graphics Processing Units (GPUs) are a type of specialized processor used to drive graphical displays. Many recent devices also allow users to write …

Starting A Charter School In Benton Harbor, Michigan, Donald W. Pearson

Masters Theses

This project investigates the process of starting a public school academy (i.e., charter school) in Benton Harbor, Michigan and completing the authorizing application. The dynamics of the project is documented in four phases. The first is the inquiry phase which is identifying, clarifying and documenting the problem. Phase two is designing a comprehension strategy in response to the problem. The third phase is implementing, creating and submitting a viable application for authorization to an educational institution and which is to be submitted to the Michigan State Department of Education for a charter school grant. The last phase of the project …