Digital Commons Network^™

Impacts Of Synoptic-Scale Dynamics On Cloud Properties And Radiation In High Southern Latitudes, Tyler R. Barone

Master's Theses

Predicting future climate change relies on accurate representations of the earth’s surface radiation budget. Complex interactions between large-scale dynamical conditions (e.g., low-pressure systems) and microscale processes (e.g., cloud properties) are key contributors to energy budget biases within global climate models. Proper estimation of cloud microscale processes and their responses to synoptic-scale dynamics will greatly improve the accuracy of the simulated energy balance within global climate models. High-latitudinal clouds have significant influences on the Earth’s radiative balance. We examined observations from two field campaigns at Macquarie Island in the Southern Ocean and McMurdo Station in Antarctica. Two global climate models are …

Characterization And Evaluation Of Catalytic Activity Of Small Molecule Copper Complexes For Metallopolymer Design, Brenda Lu

Master's Theses

Catalysis is one of the driving forces in designing greener chemical processes for essential real-world applications. Enzymes, Nature’s catalysts, are known for their high selectivity, use of readily available metals and reagents, and ability to work under physiological conditions; three important qualities that synthetic chemists would like to mimic in their small molecule metal catalysts. Though most small molecule metal catalysts fall short of enzyme-like activity, we hypothesize that using a polymer scaffold as a secondary coordination sphere mimic around the metal complex will affect the microenvironment (steric and electronic) and enable enzyme-like activity. Previously, we synthesized ligand precursors and …

Melt Inclusion Record Of Submarine Caldera Formation On Axial Seamount, Juan De Fuca Ridge, Destiny Kapule

Master's Theses

This study contributes to understanding magmatic processes and the plumbing system of submarine volcanoes before, during, and after caldera formation with the use of melt inclusions (MIs). Major, trace and volatile geochemistry from both olivine and plagioclase-hosted MIs taken from volcaniclastic deposits around Axial Seamount reveal information about the storage conditions, ascent rates and eruption styles of magmas. Magma crystallizes in the subsurface, capturing MIs, and ascends where some host glasses may interact with seawater during eruption. Oversaturation in volatiles and low vesicularity show quick ascent rates. By analyzing chemical data within a pre-existing stratigraphic context this study can assess …

Optimizing Soluble Recombinant Expression Of The Aedes Aegypti Early Trypsin Protease, Neomi Millan

Master's Theses

The female Aedes aegypti mosquito is a primary vector for the transmission of blood–borne viral pathogens such as Chikungunya, Zika, Yellow Fever, and Dengue. The female mosquito will become infected with these pathogens through the uptake of a blood meal from an infected host. The midgut digestive enzymes are required to digest the blood meal to obtain necessary nutrients needed for the completion of the gonotrophic cycle. Blood meal digestion is biphasic and digestive enzymes are expressed at different time points after uptake of a blood meal. The focus of this study is on an early phase protease known as …

Interdependence Of Salt Concentration And Filler Particles On Crystallinity And Mechanical Behavior Of Peo-Litfsi Electrolytes For Lithium-Ion Batteries, Valeria Perez

Master's Theses

Developing composite polymer electrolytes is crucial for enhancing the safety, energy density, and performance of lithium-ion batteries. While it is widely accepted that introducing filler particles in PEO-based electrolytes can reduce crystallinity and enhance ionic conductivity, this conventional understanding applies primarily to electrolytes with high lithium salt concentrations. The hypothesis of this investigation is that the crystallinity change induced by LLZTO ceramic particles in PEO-LiTFSI electrolytes is contingent on the EO:Li molar ratio. This hypothesis is interrogated by measuring changes in crystallinity, spherulite morphology, and stiffness of composite polymer electrolytes with two different EO:Li molar ratios using differential scanning calorimetry, …

Quantifying Bromocarbon Emissions From Seaweed Aquaculture In California, Jessica C. Metter

Master's Theses

Feeding ruminant livestock seaweed rich in bromoform (CHBr3) is an emerging strategy to reduce methane emissions from the livestock sector to meet climate targets. Consequently, there is a strong interest in farming bromoform rich seaweeds (e.g., Asparagopsis taxiformis) on a large scale which may impact the atmospheric inventory of bromine and in return induce catalytic ozone destruction. However, to date, only three studies have measured bromoform emission rates from Asparagopsis seaweeds which vary by order of magnitude. To fill this gap, the most comprehensive data set of bromocarbon emissions from A. taxiformis, a leading candidate for enteric methane reduction in …

Cirrus Microphysical Properties And The Controlling Factors Using A Machine Learning Approach, Derek D. Ngo

Master's Theses

Cirrus clouds are located at high altitudes and are composed of ice crystals. The unique location of cirrus clouds and their large variability in-cloud microphysical properties allow them to have either warming or cooling effects on Earth’s surface and affect the Earth’s energy budget on a global scale. The examination of cirrus radiative effects is further complicated by multiple factors affecting their formation and evolution, including the effects of thermodynamic, dynamic, aerosol, and chemical tracer variables. In this work, we developed a composite aircraft-based in-situ observation dataset based on seven National Science Foundation (NSF) and five NASA flight campaigns that …

Micro-Scale Laser-Induced Fluorescence Thermometry For Multiphase Flow In Porous Media, Samuel J. Simmons

Master's Theses

In this thesis the use of Laser-Induced Fluorescence (LIF) thermometry was evaluated as a temperature measurement for multiphase flow in porous media. This optical temperature measurement technique utilizes the temperature-dependent emissive properties of fluorescent dyes to measure temperature. This research evaluates the accuracy, spatial resolution, and temporal resolution of LIF thermometry compared to existing temperature measurements. In this research water-soluble and oil-soluble fluorescent dyes are evaluated in terms of their temperature sensitivity. The ability of these dyes to measure temperature is compared to an Ansys FEA simulation of a fixed temperature gradient. For multiphase flow, the fluorescent dyes were both …

The Statue That Started It All: The Aphrodite Of Knidos, Amereece Sterba

Master's Theses

In this thesis, I argue that The Aphrodite of Knidos statue has had a significant impact on the perception of the female nude in art throughout history because of this statue's iconic nature; it lent itself to be easily copied by artists, which has allowed artists to alter the Knidian image for cultural purposes. This thesis explores why this statue became the canon in Antiquity and continued to be replicated in subsequent eras. The first chapter examines how Praxiteles created the formula that would become the canon. By looking at Knidian and other ancient statues that take inspiration from the …

Cloud Phase Distribution At A Global-Scale And The Governing Factors Using Satellite And In-Situ Airborne Observations, Dao Wang

Master's Theses

Cloud thermodynamic phase distributions play a crucial role in accurately representing cloud radiative effects and feedback in a changing climate. The partitioning of cloud thermodynamic phases (ice, liquid, and mixed phase) significantly influences Earth's surface temperature and its ability to mitigate the impact of global warming. Satellite-based cloud phase data are frequently used for the evaluation of global climate models, yet validation of them against in-situ observations is still lacking. This study examines global cloud phase distributions and their determinant factors by validating three satellite-based cloud phase products against an extensive in-situ airborne dataset. CALIPSO exhibits the most similar ice …

Parent Satisfaction Of Daily Organized Physical Education For Children With Autism Spectrum Disorder, Cody Mills

Master's Theses

Daily structured physical education programming should be protected to support the achievement of goals set within an individual education plan (IEP) for students with autism spectrum disorder (ASD). To ensure this is a priority, parent satisfaction is necessary to prioritize a healthy partnership between home and school. The objective of this research study is to identify the level of parent/guardian satisfaction in school-based and community-based daily organized physical education provided for children with autism. The research will determine if parents/guardians are wholly satisfied with the programming provided by their child’s school, or if greater satisfaction is attained when parents outsource …

Cultural Behaviors And Their Influence On The Proximal Femur: Comparisons Of Postural Behavior, Occupation, And Subsistence-Settlement Between A Pre-Contact And Historic Sample, Joanna Klein

Master's Theses

Little is known archaeologically about the Late Woodland Schroeder Mounds mortuary group from west-central Illinois. As such, bioarchaeological data is at the forefront of archaeological problem-solving for not only the site, but the geographical area as well. Skeletal data such as proximal femur angles and activity markers contribute to the understanding of subsistence-settlement trends and postural behavior of the mortuary complex. Femoral neck version is associated with postural behaviors such as squatting and kneeling. The neck-shaft angle is linked to mobility and settlement patterns. Bicondylar angle was explored to see if behaviors had any affect. Allen’s fossa and Poirier’s facet …

Ecclesiological Sovereignty: Toward An Understanding Of The Sovereignty Of The Pope In The Context Of Luther's Responses, Erik Lee Grayvold

Master's Theses

This thesis seeks to address the contention between the perceived sovereign power of the Papacy and the Protestant Reformers. It will first provide a historical survey of how the Pope came to understand himself through the history of the Church. It will then analyze responses from the Reformers regarding this topic, focusing mainly on confessional documents and responses to these documents from the Roman Catholic Church. It will conclude with a survey of Luther’s specific responses to the situation and how his response to Papal authority and sovereignty impacted this theological development. This survey will also acknowledge situations in which …

Parental Autonomy Support And Children’S Stem Engagement During An At-Home Tinkering Activity, Bianca Martins Aldrich

Master's Theses

Parents play an important role guiding children’s learning of science, technology, engineering, and mathematics (STEM) in informal educational contexts. In this project, we considered the ways in which parents use autonomy supportive or controlling language to encourage or discourage children's independence in problem solving, as well as their feedback to children’s ideas and behaviors. We looked at the association between autonomy support and children’s behavioral, STEM, story, and emotional engagement during an at-home tinkering and storytelling activity. Parents and their 4- to 10- year old children were observed at home via Zoom. We coded parents’ and children’s behaviors using a …

Accident Prediction On E-Bikes Using Computer Vision, Rohith Puvvala Subramanyam

Master's Theses

Micro Mobility refers to small, confined pace range, and lightweight modes oftransportation, which include e-Bikes and e-Scooters. Micro Mobility riders are prone to harm and deadly injuries on city streets. Statistics show that on average 27 out of 82 (33%) humans, in the United States get injured every day in e-motorcycle injuries, which is rapidly increasing as compared to previous years. The current accident prediction strategies have been rather technically complicated to be incorporated onto micromobility vehicles which are lighter in weight and smaller in size. Current strategies bring key challenges to light. First, as micro-mobility vehicles are small and …

Structure, Construction, And Emplacement Of The Northern Margin Of The Late Cretaceous Sonora Pass Intrusive Suite: North-Central Sierra Nevada Batholith, California, Victoria A. Arnold

Master's Theses

Of the four voluminous, normally zoned Late Cretaceous intrusive suites of the Sierra Nevada batholith, the >1,000 km², ~96-88 Ma Sonora Pass intrusive suite is the oldest, northernmost, and least studied. It contains the marginal, equigranular Kinney Lakes hornblende-biotite granodiorite and the inner, porphyritic Topaz Lake biotite granodiorite. From this research, the Lake Alpine granodiorite is now considered the outermost part of the Sonora Pass intrusive suite. The suite intruded Early Cretaceous plutons and metasedimentary rocks. The Kinney Lakes and Lake Alpine granodiorites were constructed by multiple phases, as were the plutonic host rocks. The granodiorites are marked by schlieren …

Spatiotemporal Dynamics And Biogeochemical Responses In A Tidally Restricted Moro Cojo Slough, Ryan Chiu

Master's Theses

Four years of observational data for Moro Cojo Slough (MCS), a Mediterranean climate estuary in central California, linked anthropogenic nutrient loading and hydrological modifications to a shift in net ecosystem metabolism (NEM) that differs from the characteristic net heterotrophic behavior of most estuarine systems. A lack of precipitation and limited flushing during the dry seasons, as evidenced from hypersaline waters, contribute to high ecosystem respiration rates that drove NEM to nearly balanced or net autotrophic. During the wet seasons, increased runoff and nutrient loading due to precipitation elevated primary production rates within MCS, characterizing the system as net autotrophic. Box …

Quantum Mechanics And Dynamical Models For Finite Unlabeled Simple Graphs, Nathan M. Lewis

Master's Theses

This thesis constructs quantum mechanical theories of finite simple graphs for both labeled and unlabeled graphs.These theories may provide a description for discrete spacetime in a quantum gravity theory. Finite simple graphs and their properties are introduced. The first and second quantization of the standard quantum mechanics of particle systems are reviewed. A quantum mechanical theory of graphs similar to first quantization of standard quantum mechanics is developed via a correspondence of graph edges to particles in particle systems. An algorithm for constructing quantum states of graphs which is independent of graph vertex labeling is developed. It builds antisymmetric graphstates …

Intrinsic Motivation By The Principles Of Non-Linear Dynamical Systems, Phu C. Nguyen

Master's Theses

The design of appropriate control rules for the stabilization of dynamical systems can require quite substantial domain knowledge. Modern AI methodologies, such as Reinforcement Learning, are often used to mitigate the need for such knowledge. However, these can be slow and often rely on at least some hand-designed reward structure, and thus human input, to be more effective. Here, we propose an alternative route to construct rewards requiring only minimal domain knowledge, essentially relying on the structure of the dynamical system itself. For this, we use truncated Lyapunov exponents as rewards to calculate the stabilizing controller from samples. Concretely, the …

Bosons In Anti De Sitter Spacetime, Thi Khanh Linh Pham

Master's Theses

I am extremely grateful to Dr. Kassahun Betre for his support and guidance throughout my thesis journey. His wisdom, knowledge, and encouragement have been invaluable to me. His willingness to take me on making this project and the collaborative friendship is the highlight of my master’s program. Many thanks to Dr. Curtis Asplund and Dr. Ehsan Khatami for participating on my committee and with regard to their valuable feedback on my thesis draft, ensuring the completion of this work. Finally, I am grateful to my family for their unwavering love and all the support and absolute patience over the years …

Controllability-Constrained Deep Neural Network Models For Enhanced Control Of Dynamical Systems, Suruchi Sharma

Master's Theses

Control of a dynamical system without the knowledge of dynamics is an important and challenging task. Modern machine learning approaches, such as deep neural networks (DNNs), allow for the estimation of a dynamics model from control inputs and corresponding state observation outputs. Such data-driven models are often utilized for the derivation of model-based controllers. However, in general, there are no guarantees that a model represented by DNNs will be controllable according to the formal control-theoretical meaning of controllability, which is crucial for the design of effective controllers. This often precludes the use of DNN-estimated models in applications, where formal controllability …

Daily Synoptic-Scale Influences On Weather-Dependent Renewable Energy Supply And Demand In Hypothetical Fully Electrified North American Interconnections, Howard Tang

Master's Theses

Energy grids around the world are becoming increasingly penetrated by renewable energy sources, resulting in progressively variable energy generation. This study aims to provide a fundamental basis for observing atmospheric conditions in relation to weather-dependent renewable energy supply, where daily synoptic-scale influences are considered in hypothetical fully electrified North American interconnections. Three renewable energy types – 100% wind energy, 100% solar energy, and a 50-50 split of wind and solar energy – are scaled to meet weather-driven energy demand on average in three interconnections, namely the Western Interconnection, the Eastern Interconnection, and a hypothetical combined interconnection composed of the Western, …

Reconstructing Auditory Evoked Cortical Response With Fewer Trials, Zoey Y. Zhang

Master's Theses

Auditory evoked fields (AEF) paradigm is a common research tool to study human auditory responses by using Magnetoencephalography (MEG), a neuroimaging tool. AEF paradigm requires repetition over many trials to achieve adequate signal-to-noise ratio (SNR), but Autistic children and some other populations cannot tolerate prolonged exam time due to various reasons. To address these challenges, this project uses a novel machine learning algorithm, Champagne with baseline noise learning, to reconstruct AEF data with fewer trials (80%, 60%, 40%, 20%) but produce the same results as using all AEF trials (100%). The results show that this novel machine learning algorithm can …

Queen Academy, Hantian Zhnag

Master's Theses

As an upmarket novel exploring immigration and racial dynamics, Queen Academy lies at the intersection of Kathryn Ma’s The Chinese Groove, Timothy Wang’s Slant, and Toni Morrison’s The Bluest Eye in style and subject. The protagonist Kang comes to the US from China to study statistics, but finds himself becoming a “potato queen”—an Asian gay man interested in dating white men only—and locked in self-loathing. It will take a heartbreak and treading the line of illegality to see himself again. Overall, by engaging with themes of immigration, belonging, and racialized desire, the novel takes the stance that the …

Acetylacetone Oxidation At Room Temperature: A Multiplexed Photoionization Mass Spectrometric Investigation, Study Of The Russell Intermediates In Gas Phase Reactions, And The Investigation Of Oxidation Reaction Products Of Ethanol At Room Temperature, Sara Gallarati

Master's Theses

This thesis presents the combustion study of acetyl acetone using synchrotron radiation coupled with multiplexed photoionization mass spectrometry at 298 K. The experiments were performed at the Chemical Dynamics Beamline 9.0.2 at the Advanced Light Source of the Lawrence Berkeley National Laboratory. The reaction of acetyl acetone with chlorine (Cl) radicals was analyzed based on their photoionization spectra and reaction kinetic profiles.

Additionally, a study of the Russell intermediate has been performed. Previous to experimentation at the Advanced Light Source, computational analysis has been investigated to evaluate compounds that could possibly lead to the formation of a stable species. The …

Near-Infrared Dye-Glycogen Conjugates For Photodynamic And Photothermal Therapy, Farbod Shirinichi

Master's Theses

Near-Infrared (NIR) dyes are small organic molecules emerging as promising imaging agents and therapeutics for anticancer application. However, their small size inevitably resulted in several drawbacks, including low in vivo stability, inherent toxicity, and lack of targeting ability, which compromise their potential for clinical use. This project aims to address those issues by developing a novel “macromolecular” NIR dye. By covalently engineering the glycogen surface with indocyanine green (an FDA-approved NIR dye), we will create a series of glycogen-NIR dye conjugates with a size of 100-200 nm. In addition, this NIR dye is not stable in water for a long …

Post Pandemic Cyberbiosecurity Threats From Terrorist Groups, Haley D. Dodge

Master's Theses

The research in this thesis explored the research question: Are United States (US) health systems accessible to cyber-bio terrorist attacks post-pandemic, within the context of the emerging discipline of cyberbiosecurity? Key findings of the analysis demonstrated how US health systems are more accessible to cyber-bio terrorist attacks specifically from cyber hacking groups based on the increasing sophistication of their cyber capabilities and the lack of cyber protection for biological systems. The concept of cyberbiosecurity was first introduced in 2018 by researchers exploring the converging threat landscape of the cyber and biology domains. As biology is growing more dependent upon vulnerable …

Identifying And Minimizing Underspecification In Breast Cancer Subtyping, Jonathan Cheuk-Kiu Tang

Master's Theses

In the realm of biomedical technology, both accuracy and consistency are crucial to the development and deployment of these tools. While accuracy is easy to measure, consistency metrics are not so simple to measure, especially in the scope of biomedicine where prediction consistency can be difficult to achieve. Typically, biomedical datasets contain a significantly larger amount of features compared to the amount of samples, which goes against ordinary data mining practices. As a result, predictive models may fail to find valid pathways for prediction during training on such datasets. This concept is known as underspecification.

Underspecification has been more accepted …

The Rise Of Terrorism In Africa And What It Means For U.S. Policymakers, Bridget Mary Hughes

Master's Theses

This thesis utilizes three case studies to measure the rise of terrorism in Africa. This qualitative data leads the reader to one ultimate question: what does the rise in terrorism in Africa mean for the United States (U.S.) and U.S. policymakers, National Security academia, students in National Security, if anything at all? The answer is: if civilian and military compounds are being targeted by these violent extremists, as these three case studies demonstrate, it is my recommendation that U.S. policymakers cease sending troops to the African theater and, instead, allocate funding to the citizens and nonprofits of the countries whom …

Wildfire Spread Prediction Using Attention Mechanisms In U-Net, Kamen Haresh Shah, Kamen Haresh Shah

Master's Theses

An investigation into using attention mechanisms for better feature extraction in wildfire spread prediction models. This research examines the U-net architecture to achieve image segmentation, a process that partitions images by classifying pixels into one of two classes. The deep learning models explored in this research integrate modern deep learning architectures, and techniques used to optimize them. The models are trained on 12 distinct observational variables derived from the Google Earth Engine catalog. Evaluation is conducted with accuracy, Dice coefficient score, ROC-AUC, and F1-score. This research concludes that when augmenting U-net with attention mechanisms, the attention component improves feature suppression …