Digital Commons Network^™

Adaptive Balancing Compensation In Distribution Grid Of Ultra High-Power Manufacturing Plants, Motab Almousa

LSU Doctoral Dissertations

This dissertation presents a method of adaptive compensation, capable of handling power factor and the supply quality improvement under non-sinusoidal conditions. The focus in this dissertation is put on developing compensation for ultra-high power metallurgical plants, meaning on compensation in three-phase, four-wire ultra-high power dynamic, distribution systems. A separate attention in the dissertation is put on the adaptive compensation of ultrahigh power arc furnaces. The dissertation also presents an original method of adaptive compensation of DC current generated by such arc furnaces.

The proposed compensator is developed in the frame of the Currents’ Physical Components (CPC) – based power theory. …

Gis Automated Delineation And Analysis Of Cancer Service Areas In The United States, Changzhen Wang

LSU Doctoral Dissertations

Delineating a meaningful and reliable geographic unit pertaining to cancer care is essential in examining geographic variations in cancer care for better analysis, management, and planning. Public health researchers have devoted great efforts to defining various service areas, which; however, lack scientific rigor or are unrepresentative of the highly specialized cancer care markets, and their methods have become obsolete in the era of big data and high geo-computation. This study develops the “Spatially Constrained Leiden (ScLeiden)” method, a network community detection algorithm in Geographic Information Systems (GIS), and applies it to delineate a series of coherent cancer service …

Development Of 1,2-Cis-Selective Glycosylation Protocols And Multistep Synthesis Of Glycans From Acinetobacter Baumannii., Dancan Kamau Njeri

LSU Doctoral Dissertations

Access to various oligosaccharides has been made possible by glycosylation reactions. This is mainly through chemical synthesis and enzymatic approaches. Herein, I talk about glycosylation through chemical synthesis. In general, glycosylation reactions lead to a mixture of 1,2-cis and 1,2-trans stereoisomers. Stereoselective access to 1,2-trans isomer is highly developed; it efficiently relies on neighboring group participation. However, efficient access to 1,2-cis selective glycosylation is still a work in progress. In Chapter 1, I highlight notable efforts developed so far that address the 1,2-cis selectivity challenge in glycosylation.

In Chapter 2, I demonstrate how I improved …

Determining The 3d Structure And Dynamics Of Mouse Notch1 Epidermal Growth Factor-Like Repeat 26 Using Nuclear Magnetic Resonance Spectroscopy, Kendra D. Jenkins

LSU Doctoral Dissertations

NOTCH is a transmembrane protein that transmits signals between cells in direct contact and alters gene expression. The signaling pathway is important because it is involved in cell fate determination. The NOTCH1 extracellular domain has 36 epidermal growth factor-like (EGF) repeats that are responsible for ligand binding. Mutations in the EGF-like repeats cause various neurological and developmental disorders. NOTCH1 signaling initiates when DSL ligands bind to EGF11-12, the minimum Ligand Binding Domain (LBD). The Abruptex region of the NOTCH1 protein (EGF24-29) is a highly glycosylated, flexible region with calcium binding sites that regulates NOTCH1 signaling and binding by interacting with …

Consequences Of Gulf Of Mexico Estuarine Tropical Cyclone Disturbance Regimes For Fish Assemblage Dynamics Conditionally Depend On Life-History Traits And Niche Characteristics, Stephen Edward Potts

LSU Doctoral Dissertations

Tropical cyclones (TC) are intense, localized disturbances that can potentially cause extensive damage to ecosystems. This dissertation is motivated by a need for interdisciplinary study of TC-ecosystem dynamics with applications to ecology, geography, and analytical methodology. I explore concept linkages between TC dynamics and ecosystems to characterize TC-ecosystem relationships as ecological disturbance regimes. This dissertation tests hypotheses and relationships of TC effects on estuarine fish assemblages in the north-western Gulf of Mexico. I explore concepts in TC-ecosystem relationships to link biotic dynamics with physical disturbance.

In Chapter 2, I compared spatial performance of generalized linear models (GLMs) and generalized additive …

Bioremediation Of Petroleum-Based Contaminants By Alkane-Degrading Bacterium Alcanivorax Borkumensis, Amber Julaine Pete

LSU Doctoral Dissertations

The world’s dependence on petroleum hydrocarbons has led to significant environmental implications. For example, oil spills cause lasting environmental damage, and the increase of plastics in the marine environment has been growing, specifically, microplastics that can be difficult to detect due to their small size. Petroleum hydrocarbons occur naturally in nearly all marine environments, which has allowed hundreds of microorganisms to evolve to utilize these hydrocarbons as their primary energy source. These microbes are classified as hydrocarbonoclastic and are utilized to remove spilled oil biodegradation. Over the last ten years, progress has been made in the biodegradation of oil spills …

On A Relation Between Ado And Links-Gould Invariants, Nurdin Takenov

LSU Doctoral Dissertations

In this thesis we consider two knot invariants: Akutsu-Deguchi-Ohtsuki(ADO) invariant and Links-Gould invariant. They both are based on Reshetikhin-Turaev construction and as such share a lot of similarities. Moreover, they are both related to the Alexander polynomial and may be considered generalizations of it. By experimentation we found that for many knots, the third order ADO invariant is a specialization of the Links-Gould invariant. The main result of the thesis is a proof of this relation for a large class of knots, specifically closures of braids with five strands.

Commutative C*-Algebras Generated By Toeplitz Operators On The Fock Space, Vishwa Nirmika Dewage

LSU Doctoral Dissertations

The Fock space $\mathcal{F}(\mathbb{C}^n)$ is the space of holomorphic functions on $\mathbb{C}^n$ that are square-integrable with respect to the Gaussian measure on $\mathbb{C}^n$. This space plays an essential role in several subfields of analysis and representation theory. In particular, it has for a long time been a model to study Toeplitz operators. Grudsky and Vasilevski showed in 2002 that radial Toeplitz operators on $\mathcal{F}(\mathbb{C})$ generate a commutative $C^*$-algebra $\mathcal{T}^G$, while Esmeral and Maximenko showed that $C^*$-algebra $\mathcal{T}^G$ is isometrically isomorphic to the $C^*$-algebra $C_{b,u}(\mathbb{N}_0,\rho_1)$. In this thesis, we extend the result to $k$-quasi-radial symbols acting on the Fock space $\mathcal{F}(\mathbb{C}^n)$. …

Experimental Investigation Of The Physical Properties Of Irmsnn (M = 1, 3 And N = 2, 4, 7), Smita Speer

LSU Doctoral Dissertations

Exploration of transition metal stannides, formed from a combination of transition metals (T) and Sn, has resulted in the discovery a variety of materials with interesting physical properties, which is in part due to the complexity of interactions that can occur between the T-d orbitals and Sn-p orbitals. There have been observations of (extremely) large magnetoresistance [1-4], topological flat and nearly flat bands [5-7], superconducting behavior in 2D and 3D systems [5, 8-11], ultrahigh carrier mobility [12-13], and more attributed to d-p orbital mixing in such systems. This dissertation will address the effects of T-Sn interactions …

Understanding Children's Museums' Approaches To Diversity: A Critical And Socio-Cultural Investigation, Amber Nicole Smith

LSU Doctoral Dissertations

Children begin to develop self-awareness and awareness of others at an early age (Marion, 2011). Before they reach kindergarten, children begin to make distinctions about race by noticing similarities and differences between themselves and others (Winkler, 2009). Exposing young children to diversity can help each child embrace their identity, accept and celebrate differences, and be accepting of themselves and others (Cole & Verwayne, 2018).

The purpose of this study is to explore how children’s museums support diversity through their programs and planning. The research of this study focuses on four children’s museums located in the United States. There are many …

Characterization Of Electrophoretic Deposited Zinc Oxide Nanopartices For The Fabrication Of Next-Generation Nanoscale Electronic Applications, Fawwaz Abduh A. Hazzazi

LSU Doctoral Dissertations

Several reports state that it is crucial to analyze nanoscale semiconductor materials and devices with potential benefits to meet the need for next-generation nanoelectronics, bio, and nanosensors. The progress in the electronics field is as significant now, with modern technology constantly evolving and a greater focus on more efficient robust optoelectronic applications. This dissertation focuses on the study and examination of the practicality of Electrophoretic Deposition (EPD) of zinc oxide (ZnO) nanoparticles (NPs) for use in semiconductor applications.

The feasibility of several synthesized electrolytes, with and without surfactants and APTES surface functionalization, is discussed. The primary objective of this study …

Surpassing The Standard Quantum Limit Using An Optical Spring, Torrey Cullen

LSU Doctoral Dissertations

In 1916, Albert Einstein predicted the existence of gravitational waves based on his new theory of general relativity. He predicted an accelerating mass with a non-zero quadrupole moment would emit energy in the form of gravitational waves. Often referred to as ripples in space-time, gravitational waves are extremely small by the time reach Earth, potentially having traveled hundreds of megaparsecs. It is common for these ripples in space-time to stretch and squeeze matter 1000 times smaller than the width of a proton.
Laser interferometer observatories were first built in the 1990s in the US and Europe, and as sensitivity improvements …

Breeding Ecology Of Mottled Ducks In Southwestern Louisiana, Elizabeth Sophia Bonczek

LSU Doctoral Dissertations

Mottled ducks are a resident species found in the southern United States that rely on coastal marsh and associated habitat to fulfill the needs of the entirety of their annual cycle. Population monitoring has revealed declines in western Gulf Coast (WGC) mottled ducks since 2008. Mottled duck populations are influenced by survival and recruitment, and changes in these factors may contribute to population declines. The overarching goal of this project was to identify the mechanisms potentially limiting WGC mottled ducks.

I captured adult female mottled ducks during molt on Rockefeller Wildlife Refuge and adjacent lands in southwestern Louisiana from 2017–2019. …

Optimizing The Performance Of Parallel And Concurrent Applications Based On Asynchronous Many-Task Runtimes, Weile Wei

LSU Doctoral Dissertations

Nowadays, High-performance Computing (HPC) scientific applications often face per- formance challenges when running on heterogeneous supercomputers, so do scalability, portability, and efficiency issues. For years, supercomputer architectures have been rapidly changing and becoming more complex, and this challenge will become even more com- plicated as we enter the exascale era, where computers will exceed one quintillion cal- culations per second. Software adaption and optimization are needed to address these challenges. Asynchronous many-task (AMT) systems show promise against the exascale challenge as they combine advantages of multi-core architectures with light-weight threads, asynchronous executions, smart scheduling, and portability across diverse architectures.

In …

Bloch Spectra For High Contrast Elastic Media, Jayasinghage Ruchira Nirmali Perera

LSU Doctoral Dissertations

The primary goal of this dissertation is to develop analytic representation formulas and power series to describe the band structure inside periodic elastic crystals made from high contrast inclusions. We use source free modes associated with structural spectra to represent the solution operator of the Lame' system inside phononic crystals. Then we obtain convergent power series for the Bloch wave spectrum using the representation formulas. An explicit bound on the convergence radius is given through the structural spectra of the inclusion array and the Dirichlet spectra of the inclusions. Sufficient conditions for the separation of spectral branches of the dispersion …

From Equal-Mass To Extreme-Mass-Ratio Binary Inspirals: Simulation Tools For Next Generation Gravitational Wave Detectors, Samuel Douglas Cupp

LSU Doctoral Dissertations

Current numerical codes can successfully evolve similar-mass binary black holes systems, and these numerical waveforms contributed to the success of the LIGO Collaboration's detection of gravitational waves. LIGO requires high resolution numerical waveforms for detection and parameter estimation of the source. Great effort was expended over several decades to produce the numerical methods used today. However, future detectors will require further improvements to numerical techniques to take full advantage of their detection capabilities. For example, the Laser Interferometer Space Antenna (LISA) will require higher resolution simulations of similar-mass-ratio systems than LIGO. LISA will also be able to detect extreme-mass-ratio inspiral …

Dynamics Of Polymer Melts And Polymer Nanocomposites Studied By Broadband Dielectric Spectroscopy, Mengchun Wu

LSU Doctoral Dissertations

Materials based on polymers and polymeric nanocomposites have properties advantageous for many applications. In many cases, the physical behavior is connected to molecular motion. Polymers are macromolecules in which both fast local motions and slower chain relaxations may contribute to the material properties. Answering fundamental questions on the molecular dynamics is challenging, because of the existence of many different processes and the strong temperature dependence of the processes. An investigation covering a broad window over many orders of magnitude in the time scale is needed. Hence, dielectric spectroscopy is an appropriate tool to enhance fundamental understanding. This dissertation pays special …

Producing Bacterial Cellulose From Coffee (Coffea Arabica) Kombucha Fermentation And Assessment Of Its Efficacy To Remove Pathogenic Bacteria From Contaminated Water And A Pollutant Dye From Aqueous Solution, Federico Bueno

LSU Doctoral Dissertations

Bacterial cellulose (BC), composed of cellulosic nanofibrils, is synthesized by a symbiotic culture of bacteria and yeast during the fermentation of coffee kombucha (CK). BC may be used as a purification agent and adsorbent. The overall goal of this project was to synthesize BC from CK fermentation and assess its efficacy in removing pathogenic bacteria from contaminated water and a pollutant dye from aqueous solution. The objectives of this study were to: (1) compare BCs that were produced from different carbohydrate substrates in the fermentation of CK, (2) characterize dried BCs produced using various drying methods, (3) evaluate BC as …

Characterization Of Gas Hydrate Formation And Its Impact On Slope Stability In Offshore Environments, Sulav Dhakal

LSU Doctoral Dissertations

Natural gas hydrates (NGH) are predominantly methane hydrates formed at high pressure and low temperature conditions typically in submarine sediments and permafrost. This dissertation is focused on the submarine methane hydrates formed by upward migration of free and dissolved gas. The methane gas stored within natural hydrates has more energy potential than all the combined oil and gas resources around the world. Numerical simulation of fluid flow, heat transport, and geomechanical stresses is used to characterize and evaluate the saturation, distribution, reservoir quality, and geohazards associated with hydrate-bearing sediments. Coupled thermo-hydro-mechanical (THM) simulation of hydrate formation, dissociation, and slope stability …

Lifecycle Reactive Transport Modeling For Assessing Integrity In Offshore Energy Systems, Temitope Ayokunle Ajayi

LSU Doctoral Dissertations

Subsurface leaks and spills are a matter of significant concern to the oil and gas industry because of their impact on health, safety and environment. It is thus important to study and assess the integrity of our energy systems and the physico-chemical processes that affect them.

To avoid leakage of fluids from wellbores, barrier materials are used for sealing formation fluids and creating a single flow path through the well. These barrier materials are constantly subjected to subsurface fluid fluxes and temperature, pressure and chemical conditions over the extended periods the wells remain underground. This makes it imperative to assess …

The Impact Of Second-Year Membership Experiences On Retention Among Panhellenic Sororities, Elizabeth Richardson Newell

LSU Doctoral Dissertations

ABSTRACT

Sorority membership retention is a newly emerging research topic with little to no existing information on what motivates members to remain. There are countless studies concerning college student retention in general, but there have yet to be studies that focus specifically on sorority women and their membership experiences. One major research question drove this study: What factors and/or experiences influence a second year National Panhellenic Conference (NPC) sorority member’s decision to actively participate in their sorority?

Using a theoretical framework developed from the social integration retention model proposed by Braxton, Hirschy, and McClendon in 2011, this study explored what …

Evaluating And Incorporating Site Variability In Different Geotechnical Engineering Applications, Md Habibur Rahman

LSU Doctoral Dissertations

Site investigation and characterization of subsurface soil conditions are crucial for geotechnical engineering design and analysis. Geotechnical properties vary inherently from one point to another within the same site. This study focused on evaluating the site variability from cone penetration tests (CPT) and soil boring data, and its implementation into the Load and Resistance Factor Design (LRFD) formulation. The total Coefficient of Variation (COV_R,total) for each site was estimated from COV_R,spatial (Spatial Coefficient of Variation) and COV_R,method (Method Coefficient of Variation) which were then used to calibrate the resistance factors (ϕ_spatial, ϕ_total) …

Sodium Mediates Developmentally Plastic Responses In Plants And Herbivores, Luis Santiago-Rosario

LSU Doctoral Dissertations

Sodium plays a crucial role in organismal performance, trophic-level interactions, and eco-evolutionary dynamics. For plants, sodium impacts osmoregulation, growth, and water uptake. For animals, sodium is essential influencing osmoregulatory processes, muscle and neural development, and blood regulation. My dissertation aims to disentangle why sodium mismatch affects resource-consumer interactions and its influence on morphological and behavioral plasticity. First, I identified how sodium impacts plant performance and sodium accumulation strategies. I initially focused my research on understanding how increasing substrate sodium affects plant growth and tissue sodium accumulation strategies in controlled settings using a systematic review approach. I found that saltier plants …

Ligers Interferometric Survey Of M Dwarf Diameters, Tyler Gregory Ellis

LSU Doctoral Dissertations

In this dissertation, I present the largest single collection of M dwarf stellar radii in over a decade and contextualize these measurements with the systematic model discrepancies. The measurements of stellar angular diameters are also important in the quantification of the properties of exoplanets. In order to estimate the property of the exoplanet, it is first necessary to quantify the properties of the planet's host star. Using the survey results complemented with previous direct observations of the angular diameters of low mass stars, I develop updated updated surface brightness relationships. These relationships allow predictions of angular diameters using easy to …

New Chemoselective Dehydration And Cyclization Strategies Enabled By Triphosgene, Moshood Oreofeoluwa Ganiu

LSU Doctoral Dissertations

Since Friedrich Wöhler’s synthesis of urea in 1828, the techniques of organic synthesis have developed and advanced greatly. This advancement has facilitated the discovery of new organic synthetic methods, and enabled access to a more expansive chemical space. The purpose of this dissertation is to present the development of new organic synthetic reactions that were uncovered through previous discoveries. Additionally, the main theme of this work relies on exploiting the versatility of triphosgene in organic synthesis. To this end, the developed chemistries rely on the ability of triphosgene to serve as an activating agent, and a chloride source.

Chapter 1 …

Efficient Low Dimensional Representation Of Vector Gaussian Distributions, Md Mahmudul Hasan

LSU Doctoral Dissertations

This dissertation seeks to find optimal graphical tree model for low dimensional representation of vector Gaussian distributions. For a special case we assumed that the population co-variance matrix $\Sigma_x$ has an additional latent graphical constraint, namely, a latent star topology. We have found the Constrained Minimum Determinant Factor Analysis (CMDFA) and Constrained Minimum Trace Factor Analysis (CMTFA) decompositions of this special $\Sigma_x$ in connection with the operational meanings of the respective solutions. Characterizing the CMDFA solution of special $\Sigma_x$, according to the second interpretation of Wyner's common information, is equivalent to solving the source coding problem of finding the minimum …

New Synthetic Reactions Enabled By Protected Oxyallyl And Amidoallyl Cations, Binod Nepal

LSU Doctoral Dissertations

This dissertation entails design and development of two new synthetic methodologies made possible through the generation of cationic species, namely oxyallyl and amidoallyl cations. Chapter 1 involves literature survey on generation and trapping of oxyallyl cations. Mostly known for cycloaddition reactions with these elusive species, the most recent approach of direct nucleophilic capture of oxyallyl cations are discussed. Apt design of substrates and reaction conditions by Kartika Group to access a-electrophilic carbon towards the synthesis of a variety of value-added compounds, i.e., 1,4- and 1,6-dicarbonyls, carbazoles, densely substituted pyrroles and furans are elaborated.

Chapter 2 focuses on our discovery of …

Computer Science At Community Colleges: Attitudes And Trends, Trenton W. Dawson

LSU Doctoral Dissertations

This study aimed to understand the identity and attitude of students enrolled in computer science (CS) or programming-related course at community colleges nationwide. This study quantitatively evaluation data for estimating the relationships between students’ identity and attitudes toward computer science with prior programming experience and other demographic factors. I distributed the survey to community college faculty of computer science programs nationwide. Questions for this study were adapted from the Computing Attitude Survey developed by Weibe, Williams, Yang, & Miller (2003). Using two robust quantitative statistical methodologies, I investigated the correlations and predictability of previous programming experience, gender, race, and age …

Tuning Properties Of Topological Insulators: An Ab-Initio Approach, Karunya Shailesh Shirali

LSU Doctoral Dissertations

This thesis develops a first-principles based approach to explore the tuning of topological properties of the tetradymite topological insulators. We begin by setting up a framework to systematically obtain the bulk and surface properties of topological insulators, treating the structural and electronic properties on an equal footing. We determine a consistent method for including the van der Waals interactions, which are responsible for the weak coupling between sets of atomic layers in this family of layered materials, which is important in obtaining accurate structural properties. We obtain close agreement with experimental values for both the bulk and surface states.

To …

A Deep Reinforcement Learning Approach With Prioritized Experience Replay And Importance Factor For Makespan Minimization In Manufacturing, Jose Napoleon Martinez

LSU Doctoral Dissertations

In this research, we investigated the application of deep reinforcement learning (DRL) to a common manufacturing scheduling optimization problem, max makespan minimization. In this application, tasks are scheduled to undergo processing in identical processing units (for instance, identical machines, machining centers, or cells). The optimization goal is to assign the jobs to be scheduled to units to minimize the maximum processing time (i.e., makespan) on any unit.

Machine learning methods have the potential to "learn" structures in the distribution of job times that could lead to improved optimization performance and time over traditional optimization methods, as well as to adapt …