Digital Commons Network^™

Continuous Reservoir Model Updating By Ensemble Kalman Filter On Grid Computing Architectures, Xin Li

LSU Doctoral Dissertations

A reservoir engineering Grid computing toolkit, ResGrid and its extensions, were developed and applied to designed reservoir simulation studies and continuous reservoir model updating. The toolkit provides reservoir engineers with high performance computing capacity to complete their projects without requiring them to delve into Grid resource heterogeneity, security certification, or network protocols.

Continuous and real-time reservoir model updating is an important component of closed-loop model-based reservoir management. The method must rapidly and continuously update reservoir models by assimilating production data, so that the performance predictions and the associated uncertainty are up-to-date for optimization. The ensemble Kalman filter (EnKF), a Bayesian …

A Novel Automated Approach Of Multi-Modality Retinal Image Registration And Fusion, Hua Cao

LSU Doctoral Dissertations

Biomedical image registration and fusion are usually scene dependent, and require intensive computational effort. A novel automated approach of feature-based control point detection and area-based registration and fusion of retinal images has been successfully designed and developed. The new algorithm, which is reliable and time-efficient, has an automatic adaptation from frame to frame with few tunable threshold parameters. The reference and the to-be-registered images are from two different modalities, i.e. angiogram grayscale images and fundus color images. The relative study of retinal images enhances the information on the fundus image by superimposing information contained in the angiogram image. Through the …

Exploration Of New Ternary Gallides And Investigation Of Their Structure-Property Relationships, Jung Young Cho

LSU Doctoral Dissertations

This dissertation focuses on the investigation of new ternary intermetallic gallides, which may exhibit exotic physical properties such as heavy-fermion behavior, large magnetoresistance, and even superconductivity. In particular, the Ln-Cu-Ga (Ln = lanthanides) system has been systematically investigated by changing a reaction ratio and/or using a different temperature profile to optimize desired phases. Single crystals of Ln2MGa12 (Ln = La, Ce; M = Ni, Cu) have been synthesized using Ga flux and compared to their Pd analogues. Interestingly, Ce2MGa12 (M = Ni, Cu) show enhanced Sommerfeld coefficient of ¡Ö 191 mJmol-1K-2 and ¡Ö 69 mJmol-1K-2 for Ni and Cu compounds, …

Towards An Extended Microscopic Theory For Upper-Fp-Shell Nuclei, Kalin Drumev

LSU Doctoral Dissertations

An extended SU(3) shell model that for the first time explicitly includes particles from the unique-parity levels in nuclei is introduced. Its relevance is established through calculations performed with realistic interactions for a group of upper fp-shell isotopes where valence nucleons beyond the N=28=Z core occupy levels of the normal-parity upper $fp$-shell ($f_{5/2},p_{3/2},p_{1/2}$) and the unique-parity $g_{9/2}$ intruder configuration. Specifically, the outcome suggests that the pseudo-SU(3) symmetry is quite good throughout the region and that only part of the configurations are relevant for the structure of the low-lying states. The levels of the upper $fp$-shell are handled within the framework …

Syntheses Of Trimethylamine- And Phosphonate- Substituted Carboranylporphyrins For Application In Boron Neutron Cancer Therapy, Michael William Easson

LSU Doctoral Dissertations

Chapter 1 contains an introduction to porphyrins and carboranylporphyrins, including their physical properties, history, methods of synthesis, medicinal applications, and an overview of recently published compounds. Chapter 2 contains the total synthesis of a series of trimethylamine- and phosphonate-substituted carboranylporphyrins for application in boron neutron capture therapy (BNCT), including characterization by proton nuclear magnetic resonance spectroscopy, matrix-assisted time-of-flight mass spectroscopy, high resolution mass spectroscopy, UV-Vis spectrophotometry, X-ray crystallography, and melting point apparatus. Chapter 3 contains synthetic methods which were investigated as alternate routes to porphyrin synthesis and functionalization. Chapter 4 presents the in vitro biological evaluation of trimethylamine- and phosphonate-substituted …

Factors That Influence Traditional-Age College Students To Re-Enroll In Their Third Year At A Research Extensive University In The Southern Region Of The United States, Joseph M. Lutta

LSU Doctoral Dissertations

Student retention is of policy significance to higher education systems. In the United States, student retention is a major problem in higher education affecting students, universities, and society. Most of the research on student retention has focused on first-year students. Little is known about the retention of college students after their first year. The primary purpose of this study was to determine the influence of selected demographic and academic characteristics on the decision of traditional-age, undergraduate students to re-enroll at a research-extensive university. The population was defined as all traditional-age undergraduate students who entered the selected university during the fall …

Lattice Boltzmann Modeling For Mass Transport Equations In Porous Media, Borja Servan Camas

LSU Doctoral Dissertations

The aim of this dissertation is to extend the lattice Boltzmann method (LBM) to cope with parameter heterogeneity and anisotropy in mass transport equations in porous media, as well as investigating the stability and accuracy. Although the LBM is a well known and effective numerical method to solve fluid flows, LBM has not been extensively applied to mass transport equations in porous medium flow yet, and only a few works can be found on improving LBM to cope with mass transport equations other than the diffusion and advection-diffusion equations. One of the reasons why LBM has not been extensively used …

Retro Models Of The Cisplatin-Dna Cross-Link With Carrier Ligands Having Sp2 N-Donor Triazine Rings, Vidhi Maheshwari

LSU Doctoral Dissertations

Rapid rotation of guanine base derivatives about Pt–N7 bonds results in fluxional behavior of models of the key DNA intrastrand G–G cross-link leading to anticancer activity of Pt(II) drugs (G = deoxyguanosine). This behavior impedes the characterization of LPtG2 models (L = one bidentate or two cis-unidentate carrier ligands; G = guanine derivative). The objective of this study is to understand the types of conformers formed as L is systematically varied. This work, relevant to Pt(II) anticancer drugs, has evolved from published studies with sp3 N-ligands (e.g., 2,2'-bipiperidine), to C2 symmetrical or unsymmetrical sp2 N-ligands having pyridine and/or triazine rings. …

The Rhetorical Myth Of The Athlete As A Moral Hero: The Implications Of Steroids In Sport And The Threatened Myth, Karen L. Hartman

LSU Doctoral Dissertations

This research analyzes changes in the rhetoric of a sustaining myth in order to better assess what happens when a myth is threatened. By examining American sport and its current struggle to withstand the widespread use of steroids, the author investigates how public discourse about the scandal turns athletes from mythical heroes to cheaters. The author begins by explicating the rhetorical construction of the athlete as a moral hero in America and how this myth is perpetuated today. The author then examines how steroids threaten the myth of the moral athlete and uses Major League Baseball as a case study …

Disciplinary Differences In Preferred Research Methods: A Comparison Of Groups In The Biglan Classification Scheme, Mark A. Alise

LSU Doctoral Dissertations

The Biglan system of classifying disciplines in groups based on similarities and differences in their subject matter has been validated in numerous empirical studies. The present study sought to expand that validation by comparing two Biglan groups that include disciplines representing the social and behavioral sciences. As a unique point of comparison, preferred research methods were contrasted between Psychology and Sociology forming one group of pure disciplines and Education and Nursing forming another group of applied disciplines. A code sheet was developed to categorize the various components of published research, distinguishing at the most basic level quantitative, qualitative, and mixed …

Analysis Of Equation And Diagram Construction In Applied Calculus Problem Solving, Ahmed Ibrahim Usman

LSU Doctoral Dissertations

The purpose of this study was to assess algebra and geometric prerequisites skills as incorporated into the Applied Calculus Optimization Problem (ACOP) solution. The difficulties that students encounter in applying algebraic and geometric prerequisites at the early stages of the ACOP solution were identified. The study analyzes errors related to variables and equations (i.e. algebraic symbol/transformation skills), drawing of geometric diagrams (visualization skills) and those associated with application of basic differentiation concepts into ACOP solution process. The study’s goals were addressed as seven specific research questions further subdivided into three main parts: the first four research questions investigated prerequisite algebraic …

Evidence For Symplectic Symmetry In Ab Initio No-Core Shell Model Results, Tomas Dytrych

LSU Doctoral Dissertations

Advances in the construction of realistic internucleon interactions together with the advent of massively parallel computers have resulted in a successful utilization of the ab initio approaches to the investigation of properties of light nuclei. The no-core shell model is a prominent ab initio method that yields a good description of the low-lying states in few-nucleon systems as well as in more complex p-shell nuclei. Nevertheless, its applicability is limited by the rapid growth of the many-body basis with larger model spaces and increasing number of nucleons. To extend the scope of the ab initio no-core shell model to heavier …

Louis Aragon And Pierre Drieu La Rochelle: Servility And Subversion, Oana Carmina Cimpean

LSU Doctoral Dissertations

This dissertation addresses the use of literature in support of political ideologies, starting from the cases of Louis Aragon and Pierre Drieu La Rochelle. Aragon and Drieu wrote extensively about man’s alienation in the modern world and, more importantly, about the possibility of overcoming that alienation. Both argued for the creation of a new man who could erect a new world on the ruins of the old. Though Aragon was a communist and Drieu a fascist, they shared an apocalyptic view of the world and believed themselves to be living in the last stage of history, the prelude to a …

The Synthesis Of Water Soluble N-Acyl Chitosan Derivatives For Characterization As Antibacterial Agents, Lakia Monique Champagne

LSU Doctoral Dissertations

Currently, natural polysaccharides are being utilized increasingly in the markets because they exhibit biodegradability, biocompatibility, versatility, and are found abundant in nature. The diversity of natural polysaccharides provides the chemist with a broad spectrum of raw materials that can be used in many biological applications. Chitosan is a natural polysaccharide that possesses excellent biological properties. It has been recognized for its antibacterial activity, in that it is destructive towards the bacterium Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus). The antibacterial property of chitosan can be enhanced by changing the hydrophobic/hydrophilic nature of the polysaccharide backbone. This research entails …

Surgery Description Of Colored Knots, Steven Daniel Wallace

LSU Doctoral Dissertations

By a knot, or link, we mean a circle, or a collection of circles, embedded in the three-sphere S3. The study of knots is a very rich subject and plays a key role in the area of low-dimensional topology. In fact, a theorem of W.B.R. Lickorish and A.D. Wallace states that any three-dimensional manifold may be described by Dehn surgery along a link which is the process of removing the link from S3 and then gluing it back in a way that possibly changes the resulting manifold. In this dissertation, we will be interested in the pair (K, ρ) consisting …

Thermomechanical Interaction Analysis Of Bodies Subjected To Oscillatory Heat Source, Jun Wen

LSU Doctoral Dissertations

Surface heating by application of a moving heat source is a common problem in most manufacturing processes as well as in many tribological applications. The existing literature on studies of moving heat source problems primarily concentrates on unidirectional moving heat sources. Yet, a more complete analysis requires understanding of thermal behavior of bodies in relative sliding contacts subjected to oscillatory heat sources and thermomechanical interaction. In this dissertation, two analytical models are developed for rapid evaluation of the transient temperature in solids undergoing oscillatory heat source. In the first model, an analytical technique is presented to treat oscillatory heat source …

Investigation Of Superconductivity And Physical Properties Of Intermetallic Compounds: Mon, Mo₃Sb₇, Mgcni₃ And Transition Metal Diborides, Amar Bahadur Karki

LSU Doctoral Dissertations

In this dissertation work, I report on the interesting results of our detailed investigations of the synthesis, structural, electrical and magnetic characterization of three different classes of intermetallic systems. Mo₃Sb₇ wires, thin films and microfibers exhibit the highest T_c ~ 8 K, which is substantially higher than the 2.2 K reported for the single crystal and powder of Mo₃Sb₇. The suppression of the spin fluctuations in Mo₃Sb₇ is evident by the absence of a parabolic dependence of magnetic susceptibility at 1 T. MoN wires, thin films and coated microfibers …

Optimal Robust Fault Detection, Nike Liu

LSU Doctoral Dissertations

This dissertation gives complete, analytic, and optimal solutions to several robust fault detection problems for both continuous and discrete linear systems that have been considered in the research community in the last twenty years. It is shown that several well-recognized robust fault detection problems, such as H_minus\H_2, H_2\ H_infinity and H_infinity\H_infinity problems, have a very simple optimal solution in an observer form by solving a standard algebraic Riccati equation. The optimal solutions to some other robust fault detection problems, such as H_minus\H_2 and H_2\H_2 problems are also given. In addition, it is shown that some well-studied and seeming sensible optimization …

Elasto-Plastic And Damage Modeling Of Reinforced Concrete, Ziad N. Taqieddin

LSU Doctoral Dissertations

Modeling the mechanical behavior of Reinforced Concrete (RC) is still one of the most difficult challenges in the field of structural engineering. The Nonlinear Finite Element Analysis (NFEA) and modeling of the behavior of RC members are the primary goals of this study. The macroscopic components of RC, Concrete material and reinforcing steel, are represented herein by separate material models. These material models are combined together using a model that describes the global effect of interaction between reinforcing steel and concrete in order to simulate the behavior of the composite RC material. A thermodynamically consistent constitutive model for concrete that …

Investigation Of Antimonide Structure Types And The Structural Studies Of Molybdates, Dixie Plaisance Gautreaux

LSU Doctoral Dissertations

This dissertation highlights the investigation of ternary lanthanide antimonide structure types and their physical properties. In particular, these ternary phases allow for the systematic investigation of the structure in an effort to correlate structure and properties. The ternary antimonides are layered structures with two-dimensional square sheets or nets, which influence the properties of these materials. In an effort to determine how structural changes influence the physical properties, various single crystals of compounds relating to the orthorhombic CeNiSb3 structure have been grown and characterized. The layered CeNiSb3 structure consists of Sb sheets, NiSb6 distorted octahedra, and CeSb9 monocapped square anti-prisms. LnNi(Sn,Sb)3 …

Concentration Of Phosphorylated Proteins Using Modified Pmma Microanalytical Devices, Jowell Guerra Bolivar

LSU Doctoral Dissertations

This work describes the application of PMMA-based microanalytical devices for the affinity-type preconcentration of posttranslational modified proteins (PTMs). The choice of poly(methyl methacrylate), PMMA, is based on its biocompatibility, its functional methyl ester group for potential modification, and its extensive applications to create biological microelectromechanical systems (BioMEMS). Developing methodologies for preconcentration of PTMs is important for cancer diagnosis due to PTMs’ influence in the regulatory mechanism underlying the early stage of apoptosis or regulated cell death. Towards this goal, nitroavidin which can reversibly binds to biotin (and biotinylated proteins), was prepared using reported procedure and was characterized using several techniques …

Stochastic Demand Forecast And Inventory Management Of A Seasonal Product A Supply Chain System, Mohammad Anwar Ashek Rahman

LSU Doctoral Dissertations

Estimation of seasonal demand prior to an active demand season is essential in supply chain management. The business cycle of the seasonal demand is divided into two stages: stage-1, the slow-demand period, and stage-2, the peak-demand period. The focus here is to determine an appropriate demand forecast for the peak-demand period. In the first set of forecasting model, a standard gamma and an inverse gamma prior distribution are used to forecast demand. The parameters of the prior model are estimated and updated based on current observation using Bayesian technique. The forecasts are derived for both complete and incomplete datasets. The …

Chemical Analysis Of Polymer Blends Via Synchrotron X-Ray Tomography, Heath Alan Barnett

LSU Doctoral Dissertations

Material properties of industrial polymer blends are of great importance. X-ray tomography has been used to obtain spatial chemical information about various polymer blends. The spatial images are acquired with synchrotron X-ray tomography because of its rapidity, good spatial resolution, large field-of-view, and elemental sensitivity. The spatial absorption data acquired from X-ray tomography experiments is converted to spatial chemical information via a linear least squares fit of multi-spectral X-ray absorption data. A fiberglass-reinforced polymer blend with a new-generation flame retardant is studied with multi-energy synchrotron X-ray tomography to assess the blend homogeneity. Relative to other composite materials, this sample is …

Growth And Properties Of Metal-On-Metal Nanostructures: Ag On Cu(110) And Co On Ag(110), Indrajith Chandima Senevirathne

LSU Doctoral Dissertations

Heteroepitaxial nanostructures have a diverse array of applications and show novel phenomena that arise from the exotic physics exhibited in reduced dimensions. We have investigated two nano-structured systems in order to gain insights into the dynamics of their nucleation, growth and have observed striking differences, due in part to a competition between lattice strain, surface and interfacial free energies. When Ag is deposited on clean, single-crystal Cu(110), it initially wets the surface with a (111) monolayer, and spontaneously nucleates nanowires as the coverage is increased. The nanowires nucleate at defects and step edges and grow aligned along the [1–10] direction. …

Visual Language Representation For Use Case Evolution And Traceability, Coretta Willis Douglas

LSU Doctoral Dissertations

The primary goal of this research is to assist non-technical stakeholders involved in requirements engineering with a comprehensible method for managing changing requirements within a specific domain. An important part of managing evolving requirements over time is to maintain a temporal ordering of the changes and to support traceability of the modifications. This research defines a semi-formal syntactical and semantic definition of such a method using a visual language, RE/TRAC (Requirements Evolution with Traceability), and a supporting formal semantic notation RE/TRAC-SEM. RE/TRAC-SEM is an ontological specification employing a combination of models, including verbal definitions, set theory and a string language …

Dactyls Reveal Evolutionary Patterns In Decapod Crustaceans, Jeffrey Guy Agnew

LSU Doctoral Dissertations

Because of their high preservation potential and uses in foraging and defense, decapod crustacean dactyls (movable fingers of claws) are potentially excellent test subjects for an ongoing debate concerning the relative importance of top-down (predators) and bottom-up (prey) controls on morphologic diversification and evolution. The utility of dactyls for inferring evolutionary patterns were evaluated using living and subfossil xanthoid crabs sampled from the southeast U.S. Atlantic and Gulf of Mexico coasts, and were used to: (1) distinguish the roles of selection and constraint on dactyl morphology through allometric and shape comparisons in the context of the crab’s phylogenetic relationships and …

Multimedia Mathematics Intervention For Math-Delayed Middle School Students, Lisa L. Stokes

LSU Doctoral Dissertations

The purpose of this study is to determine if the Sharpening Math Skills Lab technology-mediated mathematics instructional practices for math-delayed middle school students have positive effects on their mathematics achievement and spatial visualization ability and to gauge student engagement in learning, implementation of the principles of instructional design, and attitudes toward mathematics instruction. The results of a recent meta-analysis report a range of significantly positive to significantly negative effect sizes which establish a need for further evaluation of academic achievement utilizing technology-mediated mathematics programs at the middle school level (Slavin, Lake, & Groff, 2007). The literature (Moreno & Mayer, 2000) …

Teachers' Perspectives On The Unintended Consequences Of High Stakes Testing, David Christopher Charles

LSU Doctoral Dissertations

A mixed methods design was utilized that was divided into three phases to verify and explore high stakes testing’s effects on teachers’ perceptions regarding classroom practices, pressure, and commitment to the educational profession. Phase I utilized previous surveys and a peer review to create a knowledge base to generate a survey instrument that measured the three areas assumed to be affected by high stakes testing (commitment, pressure, and classroom practice). The survey instrument that was created was piloted. Throughout Phase II there was a series of three-step analysis: First, the means and standard deviations from the results of the surveys …

Dynamic Shear Bands In Metals Under High Strain Rates, Amin Hisham Almasri

LSU Doctoral Dissertations

Adiabatic shear bands have been observed for a long time to occur under different conditions in many applications. Analysis of these localizations highly depends on the selection of the constitutive model. Hence, two constitutive models that take temperature and strain rate effect into account are proposed. The first model is a physically based model that depends on basic physical quantities, such as dislocation densities, Burgers vector, and activation energy. The second model is a simple empirical power model with a softening term. The empirical constitutive law is seen to be more successful in capturing the mechanical behavior of steel alloy …

Synthesis And Surface Characterization Of Silica-Polypeptide Composite Particles, Erick Isael Soto-Cantu

LSU Doctoral Dissertations

The synthesis and sequential surface characterization of silica-polypeptide composite particles is described. Nearly monodisperse colloidal silica cores were obtained by the alkaline hydrolysis of tetraethyl orthosilicate (TEOS). The hydrodynamic radius can be easily controlled in the range of ƒî 20-140 nm by the water/TEOS ratio in the starting reaction mixture. The surface of the synthesized silica cores was further passivated/functionalized (P/F) by a mixture of (3-aminopropyl) trimethoxysilane (APS) and methyl-trimethoxysilane (MTMS). The amino groups were quantified using UV-Vis spectrometry after reaction with ninhydrin. The use of zeta potential measurements of the P/F silica particles at low pH is presented as …