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Barrier Island Migration Over A Consolidating Substrate, Julie Dean Rosati
Barrier Island Migration Over A Consolidating Substrate, Julie Dean Rosati
LSU Doctoral Dissertations
Barrier islands that overlie a compressible substrate load and consolidate the underlying subsurface. Through time, the elevation and aerial extent of these islands are reduced, making them more susceptible to inundation and overwash. Sand washed over the island and onto back-barrier marsh or into the bay or estuary begins the consolidation process on a previously non-loaded substrate, with time-dependent consolidation a function of the magnitude of the load, duration of load, and characteristics of the substrate. The result is an increase in the overwash, migration, breaching, and segmentation of these islands. This research determined the degree to which consolidation affects …
Platforms And Protocols For The Multidimensional Microchip Electrophoretic Analysis Of Complex Proteomes, John K. Osiri
Platforms And Protocols For The Multidimensional Microchip Electrophoretic Analysis Of Complex Proteomes, John K. Osiri
LSU Doctoral Dissertations
The need for rapid, portable and high-throughput systems in proteomics is now prevalent because of demands for generating new protein-based disease biomarkers. However, 2-D protein profile patterns are lending themselves as potential diagnostic tools for biomarker discovery. It is difficult to identify protein biomarkers which are low abundant in the presence of highly abundant proteins, especially in complex biological samples like serum. Protein profiles from 2-D separation of the protein content of cells or body fluids, which are unique to certain physiological or pathological states, are currently available on internet databases. In this work, we demonstrate the ability to separate …
Amyloid Aggregation-Mitigating Peptides As Potential Alzheimer's Drugs, Cyrus Kipkurui Bett
Amyloid Aggregation-Mitigating Peptides As Potential Alzheimer's Drugs, Cyrus Kipkurui Bett
LSU Doctoral Dissertations
Neuronal cytotoxicity observed in Alzheimer¡¦s disease (AD) is linked to the aggregation of £]-amyloid peptide (A£]) into toxic forms. Increasing evidence points to oligomeric species as the neurotoxic species compared to fibrils; disruption or inhibition of A£]ƒnself-assembly into oligomeric or fibrillar forms remains a viable therapeutic strategy to reduce A£] neurotoxicity. Amyloid aggregation mitigating peptides (AAMPs) were designed based on the A£]ƒn¡§hydrophobic core¡¨ A£]17-20, with C£\,£\-disubstituted amino acidsƒnƒv£\£\AAs) added into this core as disrupting agents. The number, distribution, and side chain functionality of £\£\AAs incorporated into the mitigator sequence was found influences the resultant aggregate morphology as indicated by ex-situ …
Single-Molecule Detection Of Unique Genome Signatures: Applications In Molecular Diagnostics And Homeland Security, Jason M. Emory
Single-Molecule Detection Of Unique Genome Signatures: Applications In Molecular Diagnostics And Homeland Security, Jason M. Emory
LSU Doctoral Dissertations
Single-molecule detection (SMD) offers an attractive approach for identifying the presence of certain markers that can be used for in vitro molecular diagnostics in a near real-time format. The ability to eliminate sample processing steps afforded by the ultra-high sensitivity associated with SMD yields an increased sampling pipeline. When SMD and microfluidics are used in conjunction with nucleic acid-based assays such as the ligase detection reaction coupled with single-pair fluorescent resonance energy transfer (LDR-spFRET), complete molecular profiling and screening of certain cancers, pathogenic bacteria, and other biomarkers becomes possible at remarkable speeds and sensitivities with high specificity. The merging of …
Local Behavior Of Distributions And Applications, Jasson Vindas
Local Behavior Of Distributions And Applications, Jasson Vindas
LSU Doctoral Dissertations
This dissertation studies local and asymptotic properties of distributions (generalized functions) in connection to several problems in harmonic analysis, approximation theory, classical real and complex function theory, tauberian theory, summability of divergent series and integrals, and number theory. In Chapter 2 we give two new proofs of the Prime Number Theory based on ideas from asymptotic analysis on spaces of distributions. Several inverse problems in Fourier analysis and summability theory are studied in detail. Chapter 3 provides a complete characterization of point values of tempered distributions and functions in terms of a generalized pointwise Fourier inversion formula. The relation of …
Factors That Influence College Students Who Choose Engineering As Their Major To Presist In That Major To Their Fifth Semester, Kelli Elaine Wildman
Factors That Influence College Students Who Choose Engineering As Their Major To Presist In That Major To Their Fifth Semester, Kelli Elaine Wildman
LSU Doctoral Dissertations
Individuals, institutions, and society are affected by whether or not students persist in college; therefore, persistence and retention on college campuses is an important topic for higher education systems. However, little research has been done on program retention. Since engineering as a profession is expected to increase, it is imperative to have students persist in the major. The primary purpose of this study is to determine the influence of selected demographic and academic characteristics in the decision of first time in college (FTIC) traditional-age undergraduates who declare engineering as their major at admission to persist in the curriculum from second …
Merged Electrospray Ionization Mass Spectrometry, Jianan Dong
Merged Electrospray Ionization Mass Spectrometry, Jianan Dong
LSU Doctoral Dissertations
Ambient ionization allows the analysis of materials in their native environment without sample preparation by creating ions outside the mass spectrometer. The goal of this research was to develop new ambient ionization techniques for application to solids, liquids and particles under ambient conditions. Samples to be analyzed were directly merged with an electrospray of droplets, and then ionized and detected by a mass spectrometer. An ion trap mass spectrometer was modified with a nanoelectrospray source and configured for three experiments: merged electrospray ionization of dry particles, merged electrospray ionization of combustion products, and infrared laser desorption/ablation using electrospray for post-ionization. …
Phytochemical Analyses Of Bioactive Compounds In The Roots Of Cassia Alata Linn And The Anti-Angiogenic Evaluation Of Rhein As A Therapeutic Agent Against Breast Cancer Cells, Vivian Esther Fernand
Phytochemical Analyses Of Bioactive Compounds In The Roots Of Cassia Alata Linn And The Anti-Angiogenic Evaluation Of Rhein As A Therapeutic Agent Against Breast Cancer Cells, Vivian Esther Fernand
LSU Doctoral Dissertations
The research presented in this dissertation includes the novel phytochemical analysis of root extracts of Cassia alata L. and the anti-angiogenic evaluation of rhein in the treatment of breast cancer. To conduct these studies a combination of analytical techniques were employed, namely, chromatographic, spectroscopic, and bioanalytical. The first part of this research is focused on the phytochemical analysis of C. alata root extracts. A high performance liquid chromatography method was developed and validated for the determination of six phenolic compounds in the root extracts. The investigated compounds were identified by their ultraviolet spectra. Additionally, the presence of these phenolics was …
A Modular Approach To Lung Nodule Detection From Computed Tomography Images Using Artificial Neural Networks And Content Based Image Representation, Omer Muhammet Soysal
A Modular Approach To Lung Nodule Detection From Computed Tomography Images Using Artificial Neural Networks And Content Based Image Representation, Omer Muhammet Soysal
LSU Doctoral Dissertations
Lung cancer is one of the most lethal cancer types. Research in computer aided detection (CAD) and diagnosis for lung cancer aims at providing effective tools to assist physicians in cancer diagnosis and treatment to save lives. In this dissertation, we focus on developing a CAD framework for automated lung cancer nodule detection from 3D lung computed tomography (CT) images. Nodule detection is a challenging task that no machine intelligence can surpass human capability to date. In contrast, human recognition power is limited by vision capacity and may suffer from work overload and fatigue, whereas automated nodule detection systems can …
Beta-Diketone And -Ketoenamine-Based Organic Building Blocks For Porous Metal Organic-Materials, Yoseph Solomon Marcos
Beta-Diketone And -Ketoenamine-Based Organic Building Blocks For Porous Metal Organic-Materials, Yoseph Solomon Marcos
LSU Doctoral Dissertations
This dissertation focuses on synthesis of multifunctional â-diketone and â-ketoenamine ligands and their reaction with metal ions, mainly Cu2+. Several new bi-, tri-, and tetrafunctional organosilicon â-diketone building blocks with â-diketone groups at approx. 109° (tetrahedral) were successfully synthesized. New thiophene based bifunctional ligands where the â-diketones are at about 145° are also reported here. We also prepared a range of new aryl-â-ketoenamines from their analogous â-diketones in very high yield using a simple microwave-assisted procedure. Reactions of organosilicon tris(â-diketone)s LH3 with Cu2+ were explored quite intensively. These ligands form metal-organic-polyhedra (MOPs) that are soluble in organic solvents, and insoluble …
Sedimentation On A Mixed Siliciclastic/Carbonate Continental Margin Over Decadal To Millennial Timescales: Gulf Of Papua, Zahid Muhammad
Sedimentation On A Mixed Siliciclastic/Carbonate Continental Margin Over Decadal To Millennial Timescales: Gulf Of Papua, Zahid Muhammad
LSU Doctoral Dissertations
Sediments from the Gulf of Papua were examined to estimate particle flux and sediment mass accumulation rates on multiple timescales. Patterns of sediment mass accumulation and inventory-derived 210Pb fluxes display regional variations, decreasing seaward, and along isobaths seaward from the northeastern shelf edge. The amount of terrigenous sediment load being discharged annually from the shelf and accumulating in Pandora Trough is approximately 7-14×106 tonnes. The existence of possible turbidity-current transport and deposition have been documented in deeper parts of the Gulf of Papua. High excess 210Pb fluxes estimated from seabed inventories at the shelf edge and upper slope are consistent …
An Introduction To The Life And The Songs Of Composer Chris Deblasio, With Special Emphasis On His Cycle All The Way Through Evening, Brian Bonin
LSU Doctoral Dissertations
For composer Chris DeBlasio, the omnipresence of HIV/AIDS during the final years of his life helped to channel his creative energies into a unique compositional voice. At a time when certain elements of the New York music scene rewarded atonality and musical experimentation, DeBlasio pursued a lyrically tonal, theatrically-informed style in the company of composers such as Jake Heggie and Ricky Ian Gordon. Unfortunately, his death in 1993 at age thirty-four limited the growing awareness of his compositions in the greater artistic community and robbed him of the success eventually experienced by his fellow tonal compatriots. Today, he is best …
Testing Of Gdcl3 Doping In Water Cherenkov Antineutrino Detectors, William Fitzgerald Coleman
Testing Of Gdcl3 Doping In Water Cherenkov Antineutrino Detectors, William Fitzgerald Coleman
LSU Doctoral Dissertations
Improved neutron and neutrino detection using water Cherenkov detectors loaded with gadolinium has been proposed for potential application in both large and small volume detectors. In this thesis, work performed to determine the effect on transparency resulting from use of GdCl3 in stainless steel constructed water Cherenkov detectors is presented. In addition, results of an experiment performed using a small volume water Cherenkov de- tector are reported. This was the first use of gadolinium loaded water to detect reactor antineutrinos.
Unavoidable Minors In Graphs And Matroids, Carolyn Barlow Chun
Unavoidable Minors In Graphs And Matroids, Carolyn Barlow Chun
LSU Doctoral Dissertations
It is well known that every sufficiently large connected graph G has either a vertex of high degree or a long path. If we require G to be more highly connected, then we ensure the presence of more highly structured minors. In particular, for all positive integers k, every 2-connected graph G has a series minor isomorphic to a k-edge cycle or K_{2,k}. In 1993, Oxley, Oporowski, and Thomas extended this result to 3- and internally 4-connected graphs identifying all unavoidable series minors of these classes. Loosely speaking, a series minor allows for arbitrary edge deletions but only allows edges …
Algorithms Related To Subgroups Of The Modular Group, Constantin Cristian Caranica
Algorithms Related To Subgroups Of The Modular Group, Constantin Cristian Caranica
LSU Doctoral Dissertations
Classifying subgroups of the modular group PSL_2{Z} is a fundamental problem with applications to modular forms, in addition to its group-theoretic interest. While a lot of research has been done on the congruence subgroups of PSL_2{Z}, very little is known about noncongruence subgroups. The purpose of this thesis is to find and characterize small-index noncongruence subgroups of the modular group PSL_2{Z}. We use the concept of Farey symbol to describe the subgroups of PSL_2{Z}. The first part contains results concerning the geometry of subgroups of PSL_2{Z}. The second part describes a graph-theoretical approach to finding all subgroups of a given …
Factors That Influence Course Completion Of Individuals Enrolled In Craft-Training Courses Offered By A Large Organization Of Member Construction Companies, Alvin James Justelien, Iii
Factors That Influence Course Completion Of Individuals Enrolled In Craft-Training Courses Offered By A Large Organization Of Member Construction Companies, Alvin James Justelien, Iii
LSU Doctoral Dissertations
The construction industry is one of the largest providers of jobs in the United States. Between 2009 and 2013, approximately 20% of the 7.7 million Americans employed in construction related jobs (Bureau of Labor Statistics (BLS), 2009) would be eligible to retire. The industrial construction industry must attract, train, and retain a significant number of people to the construction industry. The primary purpose of this study was to determine the influence of selected personal demographic characteristics and academic behaviors of individuals participating in craft training courses offered by a large organization of member construction companies who successfully completed or left …
Storm Surge Dynamics Over Wide Continental Shelves: Numerical Experiments Using The Finite-Volume Coastal Ocean Model, Joao Lima Rego
Storm Surge Dynamics Over Wide Continental Shelves: Numerical Experiments Using The Finite-Volume Coastal Ocean Model, Joao Lima Rego
LSU Doctoral Dissertations
Storm surge is an abnormal rise of the sea surface caused by atmospheric forcing, including the wind stress and atmospheric pressure associated with extra-tropical and tropical cyclones. Hurricanes and typhoons have a great impact on coastal regions, and can cause severe loss of lives and great damages. A systematic investigation of storm surge impact to the coasts of Louisiana and Texas, where the continental shelf reaches up to 200 km in width, is conducted here using the hydrodynamics Finite-Volume Coastal Ocean Model, FVCOM (Chen et al., 2003). The model is applied to the northern Gulf of Mexico to simulate the …
Scanning Probe Microscopy Investigations Of (1) Arrays Of Cysteine-Coated Cds Nanoparticles And (2) Structures Formed During The Early Stages Of The Corrosion Of Copper Surfaces, Brian Robert Lewandowski
Scanning Probe Microscopy Investigations Of (1) Arrays Of Cysteine-Coated Cds Nanoparticles And (2) Structures Formed During The Early Stages Of The Corrosion Of Copper Surfaces, Brian Robert Lewandowski
LSU Doctoral Dissertations
Scanning probe microscopy (SPM) characterizations are becoming more prevalent for surface investigations due to their capabilities for obtaining structural information and physical measurements. New capabilities of SPM for studying and controlling nanoscale processes are emerging as valuable assets in research. A fundamental understanding of the interactions of surface reactions provides essential information for developing workable applications for nanotechnology. Two applications of SPM are discussed in this dissertation. The first investigation uses atomic force microscopy (AFM) for the characterization of nanostructures produced with a newly developed lithographic technique called “two-particle” lithography. This new technique is based on particle lithography for the …
Leadership Survival And The Process Of Economic Integration, Schuyler Richard Porche
Leadership Survival And The Process Of Economic Integration, Schuyler Richard Porche
LSU Doctoral Dissertations
The central contribution of this dissertation to political science is explaining the role of leadership survival theory in shaping the political process of initiation, broadening, deepening, and failure of economic integration agreements by nation states. The empirical research involves the creation of a dataset recording changes in economic integration for the period 1950-1999 and utilizing advanced quantitative methods to study the process. Most existing research focuses on the initiation of trade agreements. I demonstrate that the process of economic integration agreements among polities is shaped by iterated political interaction at both the domestic and international levels. The critical test in …
Fabrication Of Nanostructured Surfaces With Well-Defined Chemistry Using Particle Lithography, Jie-Ren Li
Fabrication Of Nanostructured Surfaces With Well-Defined Chemistry Using Particle Lithography, Jie-Ren Li
LSU Doctoral Dissertations
Natural self-assembly processes provide nanofabrication capabilities for designing surfaces with nanoscale control of surface chemistry and relative orientation of the nanomaterials on the surfaces. Particle lithography was used to produce periodic arrays of protein nanostructures. Monodisperse mesoparticles can be applied to rapidly prepare millions of uniform protein nanostructures on flat surfaces using the conventional benchtop chemistry steps of mixing, centrifuging, evaporation and drying. Nanopatterns of bovine serum albumin and staphylococcal protein A were produced with particle lithography. The immobilized proteins remain attached to the surface and form nanopatterns over micron areas corresponding to the thickness of a single layer of …
Proxy Records Of Paleohurricanes For The Western And Southern Caribbean, Terrence Allen Mccloskey
Proxy Records Of Paleohurricanes For The Western And Southern Caribbean, Terrence Allen Mccloskey
LSU Doctoral Dissertations
This dissertation evaluates the hypothesis that hurricane activity levels in the North Atlantic during the late Holocene have been driven by latitudinal movements of the North Atlantic circulation system. Multi-millennial sedimentary proxy records, based on the occurrence of overwash clastic layers, provide clear evidence of abruptly alternating periods of hurricane landfall frequency for Nicaragua and Belize. Three Belizean transects exhibit an Active period (hyperactivity) occurring from ~2000-6000 cal yr BP, although dating is inconsistent across the transects. An Active period covering the last 500 years is found at one location. The Nicaraguan record, derived from three transects covering >90 km …
Peptide Targeting Of Platinum Anti-Cancer Drug And Synthesis Of Water Soluble Monofunctional Pt(Ii) Complexes Useful For Biological Labeling, Margaret W. Ndinguri
Peptide Targeting Of Platinum Anti-Cancer Drug And Synthesis Of Water Soluble Monofunctional Pt(Ii) Complexes Useful For Biological Labeling, Margaret W. Ndinguri
LSU Doctoral Dissertations
Platinum has been used as an inorganic medicinal agent with various applications such as anti cancer agents. Several new targeted Pt(II) conjugates were synthesized having the NGR and LHRH targeting motif. The platinum conjugates bearing the NGR motif revealed selective delivery and destruction of cancer cells that had CD13 receptors compared to untargeted carboplatin drug. The development of targeted chemotherapeutic has opened a new approach for efficient delivery of antitumor toxins with minimal exposure to normal cells. Several peptide sequences are known to have the ability to target tumors, for instance NGR motif which home specifically in solid tumors and …
The Effects Of Performance Feedback Plus Graphing On The Treatment Integrity Of A Parent Implemented Reading Intervention Program, Lacey Leblanc
The Effects Of Performance Feedback Plus Graphing On The Treatment Integrity Of A Parent Implemented Reading Intervention Program, Lacey Leblanc
LSU Doctoral Dissertations
Repeated reading is an effective intervention that has been demonstrated to remediate reading problems in children. The parent tutoring literature has shown that this intervention is effective in the home environment as well as the school environment. One primary difference between home-based and school-based interventions is that a consultant is often available to work with teachers, whereas parents are not always offered this resource. However, research has demonstrated that behavioral consultation in the home environment, in which a parent serves the role of the consultee, is an effective method for addressing academic concerns. In order to make sound conclusions regarding …
On-Line Laser Desorption/Ionization Mass Spectrometry, Damien A. Narcisse
On-Line Laser Desorption/Ionization Mass Spectrometry, Damien A. Narcisse
LSU Doctoral Dissertations
Interfaces for on-line laser desorption/ionization mass spectrometry are presented in this dissertation. An on line laser desorption interface allows samples to be introduced directly into the mass spectrometer for high-throughput applications. For this research, a linear time of flight mass spectrometer was constructed with an ionization source designed to accept various laser desorption interfaces. A ball inlet interface was used for continuous analyte deposition at atmospheric pressure and vacuum ionization. A solvent-based cleaning system and a separate capillary for MALDI matrix delivery was utilized for continuous on line sampling with the ball inlet interface. Microfluidic devices were brought into contact …
State Feedback Control With Time Delay, Akshay Nareshraj Singh
State Feedback Control With Time Delay, Akshay Nareshraj Singh
LSU Doctoral Dissertations
In this thesis we start with an introduction to the theory of vibration control. We broadly classify the control methods into passive and active schemes. We introduce the problem of state feedback control and provide the classical solution in the form of Ackermann formula. We then identify the limitations of the classical approach and present the more elegant solution of partial pole assignment without spillover. We highlight the problem with model uncertainties and describe the method of pole assignment using data from measured receptances. This approach is extended for pole assignment for a linear vibrating system by using state feedback …
Quantum Nonlinear Optics: Applications To Quantum Metrology, Imaging, And Information, Ryan Glasser
Quantum Nonlinear Optics: Applications To Quantum Metrology, Imaging, And Information, Ryan Glasser
LSU Doctoral Dissertations
The fields of quantum and nonlinear optics have given rise to a variety of nonclassical states of light that have been proven to surpass certain limitations set by classical physics. Namely, certain squeezed and entangled states have been shown to beat the shot-noise limit when making precision phase measurements in interferometry, as well as write lithographic patterns that are smaller than classically allowed by the Rayleigh diffraction limit. Additionally, single-photon sources and entangled photon pairs have given rise to provably secure quantum key distribution for cryptography. Producing these quantum states of light has proven a difficult task. Nonlinear crystals, when …
An Integrated Agent-Based Microsimulation Model For Hurricane Evacuation In New Orleans, Wei Liang
An Integrated Agent-Based Microsimulation Model For Hurricane Evacuation In New Orleans, Wei Liang
LSU Doctoral Dissertations
Mass evacuation of urban areas due to hurricanes is a critical problem that requires extensive basic and applied research. Knowing the accurate evacuation time needed for the entire region in advance such that the evacuation order can be issued on a timely basis is crucial for the officials. Microsimulation modeling, which focuses on the characteristics of individual motorists and travel behavior, has been used widely in traffic simulation as it can lead to the most accurate result. However, because detailed driver response modeling and path processing must be incorporated, vehicle-based microscopic models have always been used only to simulate small …
The Structure Of 4-Separations In 4-Connected Matroids, Jeremy M. Aikin
The Structure Of 4-Separations In 4-Connected Matroids, Jeremy M. Aikin
LSU Doctoral Dissertations
Oxley, Semple and Whittle described a tree decomposition for a 3-connected matroid M that displays, up to a natural equivalence, all non-trivial 3-separations of M. Crossing 3-separations gave rise to fundamental structures known as flowers. In this dissertation, we define generalized flower structure called a k-flower, with no assumptions on the connectivity of M. We completely classify k-flowers in terms of the local connectivity between pairs of petals. Specializing to the case of 4-connected matroids, we give a new notion of equivalence of 4-separations that we show will be needed to describe a tree decomposition for 4-connected matroids. Finally, we …
Atom-Based Computer Simulation Studies Of Gas-To-Liquid Nucleation In Atmospherically Relevant Systems: Clarifying Discrepancies And Elucidating Mechanisms, Ricky Bendanillo Nellas
Atom-Based Computer Simulation Studies Of Gas-To-Liquid Nucleation In Atmospherically Relevant Systems: Clarifying Discrepancies And Elucidating Mechanisms, Ricky Bendanillo Nellas
LSU Doctoral Dissertations
For over a century, nucleation for all systems was thought simplistically to be a process that advances through the formation of critical clusters with a well-defined composition. Our results show intriguing nucleation mechanisms that challenge the aforementioned notion. We employed the simple TraPPE-UA (transferable potential for phase equilibria – united atom) force field and the AVUS-HR approach (a combination of aggregation-volume-bias Monte Carlo, umbrella sampling, and histogram reweighting), to investigate the homogeneous vapor-to-liquid nucleation of various nucleating systems. We found out that these systems could nucleate through a variety of unique non-ideal mechanisms. Alongside existing experimental investigations, this dissertation presents …
The Effects Of Activation On Employers Of Reserve And National Guard Soldiers, Lee Lamar Hisey
The Effects Of Activation On Employers Of Reserve And National Guard Soldiers, Lee Lamar Hisey
LSU Doctoral Dissertations
The purpose of this study was to examine the effects of military deployment or activation of reserve and National Guard soldiers on civilian employers. Understanding how activation affects the operations of civilian employers will increase awareness of the effects of labor stability on organizations. The study utilizes survey methodology to measure changes in organizational output, customer satisfaction, and employee behavior. In addition, number of employees supervised, strategies employed to adapt to the effects of activation on operations, organizational types, and the amount of time required for the organization to return to pre-activation levels of performance were measured. The sample was …