Digital Commons Network^™

Peptoid-Based Microsphere Coatings For Biomaterial Applications, Jesse Leland Roberts

Graduate Theses and Dissertations

Peptoids are peptidomimetic oligomers that predominantly harness similarities to peptides for biomimetic functionality. The incorporation of chiral, aromatic side chains in the peptoid sequence allows for the formation of distinct secondary structures and self-assembly into supramolecular assemblies, including microspheres. Peptoid microspheres can be coated onto substrates for potential use in biosensor technologies, tissue engineering platforms, and drug-delivery systems. They have the potential for use in biomedical applications due to their resistance to proteolytic degradation and low immunogenicity. This dissertation focuses on the physical characteristics and robustness of the peptoid microsphere coatings in various physiological conditions, along with their ability to …

Surface Modified Polypropylene Membranes For Treating Hydraulic Fracturing Produced Waters By Membrane Distillation, Tharaka Hawpe Gamage

Graduate Theses and Dissertations

Membrane distillation is an emerging technology for treating hydraulic fracturing flowback and produced waters. Suppression of membrane fouling by inorganic and polar and non-polar organic compounds is a challenge. Here polyhydroxyethyl methacrylate, polyacrylic acid, polvinylallyl imidazolium bromide and polyvinylhexyl imidazolium bromide chains have been grafted from the membrane surface. Fouling is initially due to adsorption of organic compounds followed by scale formation. When challenged with produced water, membranes modified with polvinylallyl imidazolium bromide chains provided the greatest resistance to fouling. For EC pretreated produced water and synthetic produced water that contained mainly inorganic species, the flux decline was much less.

The United States And Portuguese Angola: Space, Race, And The Cold War In Africa, Alex J. Marino

Graduate Theses and Dissertations

This dissertation is an international history of the role of the United States in the process of decolonization in Angola, a former colony of Portugal. I argue that the United States embraced Portugal, Angola, and neighboring Democratic Republic of Congo as irreplaceable Cold War allies. Decolonization in Africa challenged America’s relationship with all three countries, as competing forces within the American public called for Washington to adopt an anti-colonial, anti- racist ideology, while others demanded their government to support white supremacy at home and abroad. Decolonization in Angola, a protracted liberation struggle that started in 1961 and lasted until 1974, …

Si-Based Germanium Tin Photodetectors For Infrared Imaging And High-Speed Detection, Huong Tran

Graduate Theses and Dissertations

Infrared (IR) radiation spans the wavelengths of the windows: (1) near-IR region ranging from 0.8 to 1.0 μm, (2) shortwave IR (SWIR) ranging from 1.0 to 3.0 μm, (3) mid-wave IR (MWIR) region covering from 3.0 to 5.0 μm, (4) longwave IR (LWIR) spanning from 8.0 to 12.0 μm, and (5) very longwave IR extending beyond 12.0 μm. The MWIR and LWIR regions are important for night vision in the military, and since the atmosphere does not absorb at these wavelengths, they are also used for free-space communications and astronomy. Automotive and defect detection in the food industry and electronic …

Investigative Study Of Microalgal And Electrochemical Wastewater Treatment Systems And Modeling Of The Wafer-Enhanced Electrodeionization Using Supervised Learning, Humeyra Betul Ulusoy Erol

Graduate Theses and Dissertations

Wastewater has a serious impact on environment and public health due to its high concentration of nutrients and toxic contaminants. Without proper treatment, excess nutrients discharged in wastewater can cause a damage to the ecosystem such as undesirable pH shifts, cyanotoxin production, and low dissolved oxygen concentrations.

Main objectives of this dissertation work were to investigate i) the biofuel potential of P. cruentum when grown in swine wastewater, ii) the influence of four most commonly used ion exchange resins on the system efficiency and selectivity for the removal of sodium, calcium, and magnesium ions, and iii) the modeling of wafer-enhanced …

Racialized Reality: Crime News And Racial Stereotype Framing, Warrington Sebree

Graduate Theses and Dissertations

Research shows that crime news is a primary mechanism for shaping public consciousness surrounding legal order, social morality, and threats present in their citizens communities. This research explores how news media influences negative attitudes towards criminal justice reform and Black identity. Utilizing Framing Theory, this study focuses on whether negative stereotypes in crime news triggers racial prejudice and bias towards African Americans. Participants of this study will consist of current students at the University of Arkansas, Fayetteville. The findings suggest that knowing the race of a potential criminal assailant influences respondents’ attitudes towards presumptions of guilt, future criminality, and criminal …

Electrochemical Oxidation Of Individual Silver Nanoparticles: Exploring The Effect Of Particle Shape, Capping Ligand, Electrolyte, And Potential On The Signal, Jazlynn Sikes

Graduate Theses and Dissertations

Nanomaterials have revolutionized science and technology. Their unique properties can be exploited, and nanoparticles are being used as catalysts, antimicrobials, drug delivery vehicles, sensors, and more. However, the fundamental properties of nanomaterials and their interactions with their surrounding environments are still poorly understood. In this work, a single-particle approach was used to observe the effects of capping ligand, surrounding solution, and particle shape on the oxidative process to gain deeper understanding of silver nanoparticle properties. When allowed the opportunity, the particles will adsorb to the electrode surface then oxidize in rapid succession upon electrode activation, regardless of capping ligand as …

Digital Marketing And The Culture Industry: The Ethics Of Big Data, Jonathan Michael Bowman

Graduate Theses and Dissertations

Instead of the steady march of the one percent growth in ecommerce as compared to total retail revenues in the last decade (to comprise about nine percent of the industry at the close of 2019), we have witnessed leaps now to over twenty percent in just the last year. Scott Galloway marks the pandemic as an accelerant not just of digital marketing posting a year of growth for each month of quarantine but as an accelerant of each major GAFA (Google, Amazon, Facebook, and Apple) firm from market dominance to total dominance (Galloway 2020). Viewing these trends from the standpoint …

Oxone® Mediated Tempo-Oxidized Cellulose Nanomaterials: Material Characterization, Ultrafiltration Membrane Separations, And Thin Film Composite Gas Transport Analysis, John Phillips Moore

Graduate Theses and Dissertations

Cellulose nanomaterials (CNMs) are derived from plant matter and are comprised of nanoscopic cellulose crystals and fibers. They have a diverse set of applications, from cosmetics to oil recovery. This study focuses on the properties of Oxone® mediated TEMPO-oxidized cellulose nanomaterials (OTO-CNMs) and their use in controlling the transport properties of polymeric substrates. Synthesis and characterization of cellulosic nanoparticles have resulted in the creation of OTO-CNMs with properties that increase hydrophilicity. With added hydrophilicity, OTO-CNMs possess lower fouling propensity, making them ideal membrane additive for transport limited separations such as hemodialysis.

To utilize the material and unique properties thereof, this …

Crop Response To Low-Dose Dicamba, Mason Castner

Graduate Theses and Dissertations

The introduction of dicamba-resistant (DR) soybean [Glycine max (L.) Merr.] and cotton (Gossypium hirsutum L.) followed by a label allowing over-the-top applications of dicamba in the 2017 provided growers an additional option for broadleaf weed control. Because non-DR soybean is sensitive to low concentrations of dicamba, postemergence dicamba applications present growers choosing to plant non-DR soybean with concerns of damage from off-target movement through physical drift and volatilization of the herbicide as well as tank-contamination from prior dicamba application. Consequences of low-dose dicamba exposure on sensitive vegetative and reproductive soybean have been well researched, but little is known regarding the …

Quantum Dynamical Phenomena In Non-Hermitian And Magnomechanical Systems, Saeid Vashahri Ghamsari

Graduate Theses and Dissertations

In this dissertation, we have investigated quantum dynamics via three case studies. First, we studied a system of two coupled waveguides respectively carrying optical damping and optical gain in addition to squeezing elements in one or both waveguides. Such a system is expected to generate highly entangled light fields in the two waveguides. We, however, show that the degree of the created entanglement is significantly affected by the quantum noises associated with the amplification and dissipation. Because of the noise effect, one can only have nonzero entanglement for a limited time interval. Second, we generalized the first project by considering …

Achieving Differential Privacy And Fairness In Machine Learning, Depeng Xu

Graduate Theses and Dissertations

Machine learning algorithms are used to make decisions in various applications, such as recruiting, lending and policing. These algorithms rely on large amounts of sensitive individual information to work properly. Hence, there are sociological concerns about machine learning algorithms on matters like privacy and fairness. Currently, many studies only focus on protecting individual privacy or ensuring fairness of algorithms separately without taking consideration of their connection. However, there are new challenges arising in privacy preserving and fairness-aware machine learning. On one hand, there is fairness within the private model, i.e., how to meet both privacy and fairness requirements simultaneously in …

The Varied Thermal Response Of Magnetic Iron-Oxide Nanoparticles During Induction Heating In Liquid And Solid-Liquid Phase Change Mediums, Joshua Tompkins

Graduate Theses and Dissertations

This study investigates the induction heating response of uncapped iron oxide nanoparticles sonically dispersed as a nanofluid and mechanically distributed in solid phase change materials. The nanoparticles examined have a mean diameter of 14.42 nm and are magnetically heated in an alternating magnetic field at an amplitude of 72.6 kA/m at frequencies of 217, 303, and 397 kHz. Nanoparticle characterization was undertaken through transition electron microscopy, x-ray diffraction, and dynamic light scattering when in suspension. Carrier fluids were characterized through viscosity, heat capacity, and density measurements which were used in the calorimetric calculation of the specific absorption rate (SAR) of …

Adhesion And Deformation Mechanisms Of Polydopamine And Polytetrafluoroethylene: A Multiscale Computational Study, Matthew Brownell

Graduate Theses and Dissertations

Polydopamine (PDA) has been shown to bond via covalent bonding, van der Waals forces, and hydrogen bonding and is known to adhere strongly to almost any material. The application of PDA between a substrate and a PTFE surface coating has resulted in low friction and a greatly reduced wear rate. Previous research probing the capabilities and limitations of PDA/PTFE films have studied the wear and mechanical properties of the film, but the overall adhesive and deformation mechanisms remain unclear.

In this research, we investigate the tribological properties of PDA and PTFE molecules and composites from the atomic to the microscale …

Cement Stabilized Crushed Stone Base Course Strength And Stiffness Analysis, Andrew Deschenes

Graduate Theses and Dissertations

Approximately 70 – 80% of state departments of transportations (DOTs) utilize the 1993 AASTHO Guide for Design of Pavement Structures (1993 AASHTO) [1] for structural design of pavements. A growing portion of DOT’s are beginning to implement the Mechanistic-Empirical Pavement Design Guide (MEPDG), referred to as AASHTOWare Pavement ME [2]. The 1993 AASHTO flexible guide applies empirically derived unitless strength values referred to as structural layer coefficients and structural numbers (SN) to pavement thickness and pavement types. The 1993 AASHTO rigid flexible guide utilizes the depth and strength of the concrete pavement, with the composite spring constant (kc), which is …

An Investigation Into The Effects Of Fly Ash On Freeze-Thaw Durability Prediction, Yancy Schrader

Graduate Theses and Dissertations

Air is purposefully entrained into concrete primarily to improve resistance to freeze-thaw deterioration while saturated with water. Air entraining admixtures (AEAs) are chemical admixtures designed to entrain air into the concrete to provide adequate resistance to the effects of freezing and thawing. One of the challenges associated with air entrainment in concrete is the interaction of an AEA with supplementary cementitious materials present in the concrete, particularly fly ash. Fly ash is a by-product of the coal fired electrical generation industry, and often contains residual unburned carbon and other components that can increase the AEA demand of a particular concrete …

Effect Of Citric Acid On Slump, Compressive Strength, And Setting Time Of Belitic Calcium Sulfoaluminate Concrete, Israel Aguilar Rosero

Graduate Theses and Dissertations

Belitic calcium sulfoaluminate (BCSA) cement has well established advantages related to fast setting time, fast strength gain, long-term strengths, shrinkage, and sustainability. Due to its fast setting and hardening, this type of cement has historically been used to repair concrete structures, highways, and runways. This work provides much needed guidance on establishing mix design criteria for BCSA cement. Guidance is also given on the effects of set retarders on strength, slump, and setting times. Citric acid and a phosphonic acid-based admixture were tested as retarders for different concrete mixtures. Three studies were performed. In the slump study five different water …

Seismic Loading Effects Within Orthogonally Connected Steel Lateral Force Resisting Systems, Alhussin Faraj Aliwan

Graduate Theses and Dissertations

Steel buildings located within seismically active regions require special design considerations to ensure public safety and prevent collapse during an extreme seismic event. Two commonly used steel systems are special moment frames (SMFs) and buckling-restrained braced frames (BRBFs). When two seismic systems share a common column in an orthogonal configuration (such as at a building corner), design specifications currently consider a 100+30 rule wherein the shared column is designed for 100% fuse demand in one direction, plus 30% fuse demand from the other direction. While this rule has been shown to be reasonable for elastic building response, a few studies …

Using Bcsa Cement To Repair Waterway Transportation Structures, Anazaria Johanis Ortega Gonzalez

Graduate Theses and Dissertations

Many maritime structures (e.g., locks, dams, ports) in the US are either reaching or are past their design lives, and there are limited funds for the necessary maintenance activities which can lead to repairs that requires closures. These structures are not easy to detour and often require dewatering before repairs can be made, closures can cause delays and business-related losses which can have a large effect on the nation’s economy. Thus, it is advantageous to reduce the repair time for maritime structures. BCSA (belitic calcium sulfoaluminate) cement is a promising material to perform this type of repair due to its …

Leveraging Biomimicry And Additive Manufacturing To Improve Load Transfer In Brittle Materials, Ana Paula Bernardo

Graduate Theses and Dissertations

With the emergence of Additive Manufacturing (i.e., 3D printing) in construction, new strategically designed shapes can be created to improve load transfer through structural members and foundations. Cross-sections can be optimized to carry load using less material, or even using weaker constituent materials, like soils, which are cheap and abundant. The goal of this research is to investigate the benefits of using cellular patterns which leverage biomimicry in civil engineering applications, since nature has perfectly engineered materials and patterns which carry loads with the least amount of material possible. Most of the periodic cellular work to date has focused on …

Design, Fabrication, And Reliability Effects Of Additively Manufactured First Level Compliant Interconnects For Microelectronics Application, Tumininu David Olatunji

Graduate Theses and Dissertations

Semiconductor packaging and development is greatly dependent on the magnitude of interconnect and on-chip stress that ultimately limits the reliability of electronic components. Thermomechanical related strains occur because of the coefficient of thermal expansion mismatch from different conjoined materials being assembled to manufacture a device. To curb the effect of thermal expansion mismatch between conjoined parts, studies have been done in integrating compliant structures between dies, solder balls, and substrates. Initial studies have enabled the design and manufacturing of these structures using a photolithography approach which involves a high number of fabrication steps depending on the complexity of the structures …

Comparison Of Additively Manufactured And Wrought 17-4 Ph Stainless Steels In Ultra Low Cycle Fatigue, Timothy Strasser

Graduate Theses and Dissertations

Additive manufacturing (AM) processes allow for creation of complex geometries that are otherwise impractical to fabricate with traditional subtractive methods. AM technology has potential to improve the optimization of seismic lateral force resisting components which dissipate seismic energy through large plastic strains; however, the ultra low-cycle fatigue performance of AM metals are not yet well understood. Void formation during the AM fabrication process has potential to affect performance. This study compares the performance of heat-treated and non-heat-treated AM and wrought 17-4PH stainless steel in Ultra Low Cycle Fatigue. To understand ULCF performance differences between the AM and wrought specimens, post …

Mechanical And Frictional Behavior Of Textured And Non-Textured Surfaces, Raghuram R. Santhapuram

Graduate Theses and Dissertations

Tribology is the study of surfaces where two objects are sliding against another. Significant energy is lost due to friction between the sliding surfaces. Therefore, developing or designing surfaces to minimize friction is critical for the durability and reliability of the mechanical components. Several researchers have identified that surface texturing at the nanoscale (nanotexture) would reduce the friction between the contacting surfaces. The nanotextured surfaces have several applications in microelectromechanical systems and nanoelectromechanical systems. This dissertation employs molecular dynamics simulations to investigate the frictional and mechanical response of nanotextured aluminum (Al) and Al/amorphous silicon (a-Si) composite surfaces.

This study determines …

Numerical Simulations Of Directed Self-Assembly Methods In Di-Block Copolymer Films For Efficient Manufacturing Of Nanoscale Patterns With Long-Range Order, Joseph Hill

Graduate Theses and Dissertations

Directed self-assembly (DSA) of block copolymers (BCPs) has been shown as a viable method to achieve bulk fabrication of surface patterns with feature sizes smaller than those available through traditional photolithography. Under appropriate thermodynamic conditions, BCPs will self-assemble into ordered micro-domain morphologies, a desirable feature for many applications. One of the primary interests in this field of research is the application of thin-film BCPs to existing photolithography techniques. This “bottom-up” approach utilizes the self-assembled BCP nanostructures as a sacrificial templating layer in the lithographic process.

While self-assembly occurs spontaneously, extending orientational uniformity over centimeter-length scales remains a critical challenge. A …

Application Of Percentage Within Limits Concepts On A Balanced Mix Design Of Asphalt Mixtures, Elvis Alexander Castillo Camarena

Graduate Theses and Dissertations

Many agencies have incorporated rutting, and more recently cracking, laboratory test requirements in the design process of asphalt mixtures. The objective of each additional specification is to produce a balance between the stability and durability of the final product. Although a performance-engineered mixture design (PEMD), denoted here as a balanced mix design (BMD), offers compelling benefits, there is concern regarding the compatibility of the BMD with current construction practices. The objective of this work is to correlate a BMD method with realistic binder content construction tolerances by applying the concepts of a percent-within-limits (PWL) approach to field QC/QA. First, Chapter …

Behavior Of Concrete Structures Reinforced With High Strength Steel, Rahman S. Kareem

Graduate Theses and Dissertations

The structural strength and corrosion resistance of concrete members are improved when A1035 steel is used as the main reinforcement. The enhancement of A1035 is achieved by the modification of the composition and microstructure of the steel. Therefore, the behavior of concrete structures reinforced with high-performance steel (A1035) is different from those reinforced with the regular steel (A615). Concrete bridge decks reinforced with different amounts of A1035 were studied in this research program. The structural behavior of twelve concrete bridge decks reinforced with A615 Grade 420 (60 ksi) and A1035 Grade 830 (120 ksi) steel was investigated at both service …

A Methodological Framework To Evaluate Community Perceptions Of Economic And Safety Impacts Attributed To Highway Bypass And Widening Projects, Karla Diaz-Corro

Graduate Theses and Dissertations

Transportation practitioners have proposed the construction of highway bypass and widening projects in rural communities to address traffic-related problems that include noise pollution and congestion, among others. In the past, the construction of bypass projects has led community residents to raise concerns about potential decreases in business activity for businesses located along the bypassed road. For transportation organizations, it is essential to understand the economic, social, and safety impacts of transportation projects in terms of public perceptions as public input is a required part of the project planning phase. Moreover, it is recommended that agencies perform retrospective analyses of project …

Moisture Monitoring Of A Clt Structure In A Southern Climate, Elizabeth Poblete

Graduate Theses and Dissertations

Understanding of moisture behavior in cross laminated timber (CLT) is critical to the widespread use of CLT in construction in the United States. Currently, very little data exists on the long-term impact of moisture on CLT. The objective of this research is to collect data regarding the long-term moisture variation in the CLT panel at the University of Arkansas Adohi Hall residence hall. The climate of Northwest Arkansas is different from previously monitored buildings, as they were in the Pacific Northwest. Comparatively, Northwest Arkansas has a warmer climate with higher average annual precipitation. Waterproofing efforts are usually employed to prevent …

Implications Of Lysine Acetylation On The Enzymes Of The Tca Cycle, Sumana Venkat

Graduate Theses and Dissertations

The tricarboxylic acid (TCA) cycle is a central route for the energy production via oxidative phosphorylation and is ubiquitous throughout nature. Apart from playing a major role in energy provision, it is also essential for a wide range of physiological functions in any organism. Although an increasing emphasis is laid on the interlinking role of the cycle, its regulation and control are less very less understood. As the field progresses, the consequences of TCA cycle anomalies are shown to be tied to various cancers and other disorders. The matter becomes more complex when considering the varying functions of the isozymes …

Development And Characterization Of Metal Contacts For Graded Composition Ingan Solar Cells, Reem E. Alhelais

Graduate Theses and Dissertations

There is an increasing demand for high-power electronic components and optoelectronic devices with low-loss and high efficiency. III-nitride semiconductor materials have demonstrated great potential for high-power, high-frequency, and high-temperature applications because of their remarkable and wide-ranging electronic and physical properties. These material systems, including alloys of AlN, GaN, and InN, are currently being explored for their potential to develop efficient photovoltaic cells. They can potentially achieve higher efficiency because of their very high direct wide band edge, absorption coefficients, and resistance to defects. The compositionally graded Group III-nitride alloy allows access to a large range of energies by varying the …