Digital Commons Network^™

Direct Attachment Of 4-Hydroxybenzoic Acid Polymers And Capture Agents To Flat Sheet And Microdialysis Membranes For Improved Mass Transport, Sarah Jane Phillips

Graduate Theses and Dissertations

Microdialysis (MD) sampling is a diffusion-based separation method which has the ability to sample any analyte that can diffuse across the semi-permeable membrane. However one challenge for MD is that for soluble proteins greater than 10 kDa, the relative recovery (RR) using a 100 kDa MD probe is between 1-5%.1 There are two major barriers that lead to these low recovery values - nonspecific adsorption (NSA) and poor solute mass transport. To overcome these two barriers, the modification of PES-based MD membranes has been initiated by laccase. Previous researchers have used laccase to modify PES flat sheet and hollow fiber …

Membrane Chromatography For Bioseparations: Ligand Design And Optimization, Zizhao Liu

Graduate Theses and Dissertations

Membrane chromatography, or membrane adsorber, represents an attractive alternative to conventional packed bed chromatography used in downstream processing. Membrane chromatography has many advantages, including high productivity, low buffer consumption and ease to scale up. This doctoral dissertation focuses on developing novel polymeric ligands for protein separations using membrane chromatography. Atom transfer radical polymerization (ATRP), known as a controlled radical polymerization technique, has been used to control the architecture of grafted polymeric ligands. The center theme of this dissertation is to develop new polymeric ligands and investigate how the polymer’s property (e.g. flexibility, hydrophobicity) and architecture (e.g. chain density, chain length) …

Selection Of Drought-Tolerant Soybean Lines Using A Field Screening Method And Identification Of Qtls For Slow Wilting And Nitrogen Fixation Associated With Drought-Tolerance, Mirta Beatriz Dalzotto

Graduate Theses and Dissertations

Drought causes significant yield reductions in soybean. The development of drought-tolerant cultivars is an effective alternative to overcome this abiotic stress. Slow wilting, prolonged nitrogen fixation, and minimal yield reduction under water stress play an important role in evaluating breeding materials. Despite advances in knowledge about plant responses to drought conditions, there is little information on effective methodologies for phenotype screening in the field, and some QTLs have been identified for drought tolerance. Field screenings under drought and irrigated conditions are necessary to detect drought tolerant lines. In addition, QTLs and molecular makers associated with drought tolerance traits will greatly …

Artificial Quantum Many-Body States In Complex Oxide Heterostructures At Two-Dimensional Limit, Xiaoran Liu

Graduate Theses and Dissertations

As the representative family of complex oxides, transition metal oxides, where the lattice,

charge, orbital and spin degrees of freedom are tightly coupled, have been at the forefront

of condensed matter physics for decades. With the advancement of state-of-the-art heteroepitaxial deposition techniques, it has been recognized that combining these oxides on the atomic scale, the interfacial region offers great opportunities to discover emergent phenomena and tune materials' functionality. However, there still lacks general guiding principles for experimentalists, following which one can design and fabricate artificial systems on demand. The main theme of this dissertation is to devise and propose some …

Automatic Assessment Of Environmental Hazards For Fall Prevention Using Smart-Cameras, Jeffrey Kutchka

Graduate Theses and Dissertations

As technology advances in the field of Computer Vision, new applications will emerge. One device that has emerged is the smart-camera, a camera attached to an embedded system that can perform routines a regular camera could not, such as object or event detection. In this thesis we describe a smart-camera system we designed, implemented, and evaluated for fall prevention monitoring of at-risk people while in bed, whether it be for a hospital patient, nursing home resident, or at home elderly resident. The camera will give a nurse or caregiver environmental awareness of the at-risk person and notify them when that …

Initiating Race: Fraternal Organizations, Racial Identity, And Public Discourse In American Culture, 1865-1917, John D. Treat

Graduate Theses and Dissertations

Drawing on ritual books, organizational records, newspaper accounts, and the data available from cemetery headstones and census records, this work argues that adult fraternal organizations were key to the formation of civic discourse in the United States from the years following the Civil War to World War I. It particularly analyzes the role of working-class white and African-American organizations in framing racial identity, arguing that white organizations gave up older, comprehensive ideas of citizenship for understandings of Americanism rooted in racism and nativism. Counterbalancing this development, now-forgotten African-American fraternal organizations were among the earliest advocates of Afrocentrism. These organizations, form …

Fleeing To Fault Zones: Incorporating Syrian Refugees Into Earthquake Risk Analysis Along The East Anatolian And Dead Sea Rift Fault Zones, Bradley Wilson

Graduate Theses and Dissertations

The influx of millions of Syrian refugees into Turkey has rapidly changed the population distribution along the Dead Sea Rift and East Anatolian Fault zones. In contrast to other countries in the Middle East where refugees are accommodated in camp environments, the majority of displaced individuals in Turkey are integrated into local cities, towns, and villages—placing stress on urban settings and increasing potential exposure to strong earthquake shaking. Yet, displaced populations are not traditionally captured in data sources used in earthquake risk analysis or loss estimations. Accordingly, this study presents a district-level analysis assessing the spatial overlap of earthquake hazards …

Reasonableness And Clarity Of Tenure Expectations: Gender And Race Differences In Faculty Perceptions, Rodica Lisnic

Graduate Theses and Dissertations

This dissertation studies how higher education policies and practices can affect faculty retention and proposes changes that higher education institutions need to make to retain their faculty. Faculty assessment of reasonableness of tenure expectations is explored in the first manuscript and faculty perceptions of clarity of tenure expectations are explored in the second and third manuscripts. Job satisfaction data from a sample of 2438 tenure-track assistant professors at research universities is used.

The first manuscript investigates the reasonableness of tenure expectations as it relates to work-life balance. The focus is on whether women’s and men’s appraisal of departmental and institutional …

Role Of The Inner Shell Architecture On The Various Blinking States And Decay Dynamics Of Core-Shell And Core-Multishell Quantum Dots, Pooja Bajwa

Graduate Theses and Dissertations

Colloidal semiconductor nanocrystals (quantum dots, QDs) have received much attention in recent years due to their uniquely size-tunable properties leading to a number of promising applications. Some of their most popular applications include their use as fluorescent probes in biology, as electro-optical components and in photovoltaic devices. CdSe-based QDs are particularly important because of their ease of synthesis, high photoluminescence quantum yields (PL QYs) across the whole visible spectrum and their photostabilty. Shelling of core QDs is usually carried out to improve their optical properties, minimize outer environmental effects on their properties, and avoid toxic element exposure to the environment. …

The Effects Of Using Cinnamon Leaf And Bark Essential Oils On Listeria Monocytogenes (L.M.), Salmonella Typhimurium (S.T.), In Model System, Strawberry Shake And Fresh Celery, And Sensory & Shelf Life Studies, Wafaa Brnawi

Graduate Theses and Dissertations

Essential oils derived from the bark and leaves of the cinnamon plant have long been used as natural preservatives and flavoring agents in different types of foods. In this study, we evaluated the antimicrobial effects of cinnamon essential oils (CEOs), obtained from cinnamon leaf or bark, against two foodborne pathogens i.e., Salmonella Typhimurium (S.T.) and Listeria monocytogenes (L.m.). Two different concentrations of microbial loading were used i.e.,109 and 104, cultured in nutrient media broth, strawberry shakes, and on celery sticks. Both CEOs of leaf and bark at 0.5% and 1% were found to completely inhibit S.T. and L.m., immediately after …

Two Essays On Analytical Capabilities: Antecedents And Consequences, Rishikesh Jena

Graduate Theses and Dissertations

Although organizations are rapidly embracing business analytics (BA) to enhance organizational performance, only a small proportion have managed to build analytical capabilities. While BA continues to draw attention from academics and practitioners, theoretical understanding of antecedents and consequences of analytical capabilities remain limited and lack a systematic view. In order to address the research gap, the two essays investigate: (a) the impact of organization’s core information processing mechanisms and its impact on analytical capabilities, (b) the sequential approach to integration of IT-enabled business processes and its impact on analytical capabilities, and (c) network position and its impact on analytical capabilities. …

Scaffold And Tissue Based Therapies To Improve Skeletal Muscle Regeneration After Volumetric Muscle Loss, Benjamin Kasukonis

Graduate Theses and Dissertations

Volumetric muscle loss (VML) is an injury to skeletal muscle characterized by a loss of more than 20% of a muscles volume. The combination of the bulk loss of tissue, transection and separation of myofibers proximal and distal to the injury, loss of innervation and blood supply, and the depletion of muscle progenitor cells results in permanent fibrosis and functional deficits due to loss of contractile tissue. Scaffolds, cells, and engineered constructs have been explored as potential therapeutic interventions to induce myogenesis at the site of a VML injury in animal models, in addition to limited clinical trials. This dissertation …

Query Theory Applications: Choice Experiments Under Oath, Attendance To Attributes, And Genetically Modified Food Labeling Policy, Nathan Paul Kemper

Graduate Theses and Dissertations

In recent years, there has been an intensifying campaign by some stakeholders regarding concern over genetically modified (GM) foods in the U.S. As a result, the issue of labeling has entered into the federal agenda. This research uses Query Theory to provide a deeper understanding of the demand for GM foods and the preferences for GM policy. Query theory is first applied to the formation of hypothetical bias in the estimation of consumers’ willingness-to-pay. To address this, the honesty oath is used as an ex-ante technique to reduce hypothetical bias.

Paper one using Query Theory in a discrete-choice experiment (DCE) …

Just In Time Assembly (Jita) - A Run Time Interpretation Approach For Achieving Productivity Of Creating Custom Accelerators In Fpgas, Sen Ma

Graduate Theses and Dissertations

The reconfigurable computing community has yet to be successful in allowing programmers to access FPGAs through traditional software development flows. Existing barriers that prevent programmers from using FPGAs include: 1) knowledge of hardware programming models, 2) the need to work within the vendor specific CAD tools and hardware synthesis. This thesis presents a series of published papers that explore different aspects of a new approach being developed to remove the barriers and enable programmers to compile accelerators on next generation reconfigurable manycore architectures. The approach is entitled Just In Time Assembly (JITA) of hardware accelerators. The approach has been defined …

Immunotherapeutic Strategies To Reverse Tumor Associated Immunosuppression In Breast Cancer, Sruthi Ravindranathan

Graduate Theses and Dissertations

Heterogenous cancers such as breast carcinoma, would highly benefit from personalized vaccine approaches such as autologous tumor cell vaccines (ATCVs). By using cancer cells that are isolated from self, this approach has the potential to generate a polyclonal immune response against tumor antigens, that are specific to the individual. However, so far, ATCVs against breast cancers have not had any clinical success due to the poor immunogenicity of the malignant cells.

In this study, for the first time, we determined tumor derived G-CSF to play a major role in affecting immune response against breast cancer ATCVs. By using CRISPR/Cas9 genome …

Measuring Nonlinear Properties Of Graphene Thin Films Using Z-Scan Technique, Thekrayat Hassan Al Abdulaal

Graduate Theses and Dissertations

The nonlinear studies of two-dimensional (2D) nanomaterials, specifically graphene, are very significant since graphene is finding its usefulness in handling the enormous heat in nanoscale high-density power electronics. Graphene has emerged to be a promising nanomaterial as an excellent heat spreader due to its high thermal conductivity. However, the experimental nonlinear study of graphene materials and their application in developing future optoelectronic devices demands for more developed research.

The research objective is first to build a precise, and sensitive technique to investigate and understand the thermal nonlinear properties, including nonlinear refractive index (n2), nonlinear absorption coefficient (β), and thermo-optic coefficient …

Si-Based Germanium-Tin (Gesn) Emitters For Short-Wave Infrared Optoelectronics, Seyed Amir Ghetmiri

Graduate Theses and Dissertations

Conventional integrated electronics have reached a physical limit, and their efficiency has been influenced by the generated heat in the high-density electronic packages. Integrated photonic circuits based on the highly developed Si complementary-metal-oxide-semiconductor (CMOS) infrastructure was proposed as a viable solution; however, Si-based emitters are the most challenging component for the monolithic integrated photonic circuits. The indirect bandgap of silicon and germanium is a bottleneck for the further development of photonic and optoelectronic integrated circuits.

The Ge1-xSnx alloy, a group IV material system compatible with Si CMOS technology, was suggested as a desirable material that theoretically exhibits a direct bandgap …

Effects Of Harvest Conditions And Thickness Fractionation On Physicochemical Properties, Cooking And Sensory Characteristics Of Long Grain Rice, Sara Esther Jarma Arroyo

Graduate Theses and Dissertations

Previous research has demonstrated the extensive impacts of various environmental and processing conditions on rice milling and processing characteristics. Nevertheless, little is known about the influences of these conditions on cooking and sensory qualities of rice. The present study aimed to determine the impact of cultivating location, harvest moisture content (HMC), and thickness fractionation on the physicochemical properties, and cooking and sensory characteristics of long-grain rice. Four long-grain rice cultivars (purelines: Cheniere and V3501, and hybrids: XP760 and XL753) were cultivated at Harrisburg, AR and Alvin, TX, and harvested at three HMC. Rough rice lots were conditioned and a portion …

Investigation Of The Optical Properties Of Pbse/Pbx Nanocrystals For Photodetector Applications, Haley Ann Morris

Graduate Theses and Dissertations

Lead selenide and lead selenide/lead sulfide core/shell nanocrystals were investigated for use in near infrared photodetectors. A colloidal synthesis method was used for both the core and core/shell configurations. The lead sulfide shell was examined in order to mitigate oxidation of the nanoparticle surface. Absorbance and photoluminescence spectra were measured at room temperature and 77 K, respectively. Transmission electron microscopy images were also obtained to confirm crystallography and size. Bulk lead selenide was simulated in WIEN2k utilizing the linear-augmented plane wave method of solving density functional theory to better understand the electronic structure of PbSe. The crystal structure, electron density, …

How Select Groups Of Preservice Science Teachers With Inquiry Orientations View Teaching And Learning Science Through Inquiry, Peggy Diana Ward

Graduate Theses and Dissertations

Although hailed as a powerful form of instruction, in most teaching and learning contexts, inquiry-based instruction is fraught with ambiguous and conflicting definitions and descriptions. Yet little has been written about the experiences preservice science teacher have regarding their learning to teach science through inquiry. This project sought to understand how select preservice secondary science teachers enrolled in three UTeach programs in Arkansas conceptualize inquiry instruction and how they rationalize its value in a teaching and learning context. The three teacher education programs investigated in this study are adoption sites aligned with the UTeach Program in Austin, TX that distinguishes …

Optimal Sensing And Transmission In Energy Harvesting Sensor Networks, Xianwen Wu

Graduate Theses and Dissertations

Sensor networks equipped with energy harvesting (EH) devices have attracted great attentions recently. Compared with conventional sensor networks powered by batteries, the energy harvesting abilities of the sensor nodes make sustainable and environment-friendly sensor networks possible. However, the random, scarce and non-uniform energy supply features also necessitate a completely different approach to energy management.

A typical EH wireless sensor node consists of an EH module that converts ambient energy to electrical energy, which is stored in a rechargeable battery, and will be used to power the sensing and transmission operations of the sensor. Therefore, both sensing and transmission are subject …

Sedimentary Petrology Of The Hartshorne Formation, Southeastern Arkoma Basin, Arkansas, Ruizhe Yin

Graduate Theses and Dissertations

The Pennsylvanian Hartshorne Sandstone crops out in an east trending belt across central Arkansas immediately north of the Ouachita orogenic belt and south of the Boston Mountains. The unit, composed of massive to cross bedded sandstone ranging to 150m in thickness, was deposited by a west-flowing river system that extended from central Arkansas to southeastern Oklahoma. The source of the sediment has been extensively discussed but not completely established. The object of this thesis is to constrain the source area and terrain based on thin section mineralogy and texture. Thin sections were prepared from outcrops in the Arkoma Basin and …

Design, Fabrication And Measurement Of A Plasmonic Enhanced Terahertz Photoconductive Antenna, Nathan Matthias Burford

Graduate Theses and Dissertations

Generation of broadband terahertz (THz) pulses from ultrafast photoconductive antennas (PCAs) is an attractive method for THz spectroscopy and imaging. This provides a wide frequency bandwidth (0.1-4 THz) as well as the straightforward recovery of both the magnitude and phase of the transmitted and/or reflected signals. The achieved output THz power is low, approximately a few microwatts. This is due to the poor conversion of the femtosecond laser used as the optical pump to useable current inside the antenna semiconducting material. The majority of THz power comes from the photocarriers generated within ~ 100 nm distance from the antenna electrodes. …

Growth Of Gesn And Gepb Alloy Films Using Thermal Evaporator, Hakimah Alahmed

Graduate Theses and Dissertations

Silicon is the most important semiconductor material used in microelectronic devices. As the number of transistors keep doubling every 24 months (Moore’s law), transistors continue scaling down in size, electrical interconnect is reaching its limits to keep up with the scaling down rate in integrated circuits. These limitations are related to interconnect density and power consumption. Hence, replacing electrical interconnect with optical interconnect on the chip or between chips has the ability to overcome these limitations. However, silicon has poor light emitting efficiency, and other substitutes such as III-V materials are not suitable due to high cost, lattice mismatch, and …

Characteristics Of Lifelong Musicians, Austin Lamon Farnam

Graduate Theses and Dissertations

The purpose of this study was to investigate causes for lifelong musicianship through examining the life experiences and influences of ten lifelong musicians. The participants in this study have played music starting in their childhood and into adulthood. Ages of participants range between 35 and 60 years of age. All participants have separate careers in conjunction with being active musicians.

Data collection was attained through a three phase process of an observation, interview, and collection of artifacts. Data was coded using open, focused, and axial coding and further analyzed for the purpose of identifying emerging themes. From the analysis, the …

The Role Of Organic Matter In The Fate And Transport Of Antibiotic Resistance, Metals, And Nutrients In The Karst Of Northwest Arkansas, Victor Lee Roland Ii

Graduate Theses and Dissertations

Organic matter (OM) in the environment acts as a nutrient, but may also act as a transport vector for harmful chemical compounds and bacteria. Acetate is a labile form of OM produced during fermentation in anaerobic lagoons used to store animal fecal-waste from concentrated animal feeding operations (CAFOs). Dry and liquid fertilizers from CAFOs pose a threat to groundwater by introducing excessive amounts of nutrients (e.g. OM, nitrate and ammonia), metals, and antibiotic compounds. In the epikarst of Northern Arkansas in the Buffalo River watershed additional input of labile dissolved organic carbon (DOC) from liquid CAFO waste-fertilizers was hypothesized to …

Asbestos Cement Pipe Condition Assessment And Remaining Service Life Prediction, Abiy Melles Ghirmay

Graduate Theses and Dissertations

This research details a condition assessment of asbestos cement (AC) pipe within in the Bella Vista Village Property Owners Association water distribution system. Bella Vista Village contains appropriately 300 miles of AC pipe with nominal diameters from 6-14 inch. The goal of the research is to determine the current condition of AC pipe within the system and predict future performance of the pipes. AC pipe samples were obtained from 23 locations disturbed across the distribution system with nominal pipe diameters of 6-8 inch. Estimates of current level of degradation were obtained using phenolphthalein staining and hardness measurements of each sample. …

Agro-Climatic Change, Crop Production And Mitigation Strategies-Case Studies In Arkansas, Usa And Kenya, John Westley Magugu

Graduate Theses and Dissertations

Although climate change impacts vary geographically and temporally, studies at local levels are not readily available for stakeholders to better understand how their local communities would be affected and what remedial measures could be more effective in their local contexts. This dissertation has examined climate change and its impacts in two different local contexts: eastern Arkansas in the USA and Nyando in Kenya. The first part of this dissertation develops agro-meteorological indicators and examines the relationship between agro-meteorological indicators and crop yields in eastern Arkansas between 1960 and 2014. Results reveal that temperature based indicators were more strongly correlated to …

4d Printing Dielectric Elastomer Actuator Based Soft Robots, Jiyu Cai

Graduate Theses and Dissertations

4D printing is an emerging technology that prints 3D structural smart materials that can respond to external stimuli and change shape over time. 4D printing represents a major manufacturing paradigm shift from single-function static structures to dynamic structures with highly integrated functionalities. Direct printing of dynamic structures can provide great benefits (e.g., design freedom, low material cost) to a wide variety of applications, such as sensors and actuators, and robotics. Soft robotics is a new direction of robotics in which hard and rigid components are replaced by soft and flexible materials to mimic mechanisms that works in living creatures, which …

Factors Influencing Participation In Professional Development To Promote Online Course Excellence And The Impact On Faculty Confidence And Teaching, Elizabeth Ann Mascher

Graduate Theses and Dissertations

The purpose of this study was to examine factors influencing participation in professional development designed to safeguard online course excellence and the impact on confidence and teaching. This purpose was achieved through a convergent mixed-methods investigation of faculty viewpoints of online course delivery and professional development offerings at a Midwestern state university. To support continued academic success in an increasing online market, the university implemented Quality Matters professional development to promote excellence in online course design. Analysis of data collected from a survey, in-depth interviews, and a focus group revealed faculty perspectives regarding the effectiveness of online course delivery, benefits …