Digital Commons Network^™

Effect Of Hydration Status On Thermoregulatory Responses In Non-Obese And Obese Males, Matthew Tucker

Graduate Theses and Dissertations

During heat stress the human body thermoregulates via cutaneous vasodilation and sweating. Hypohydration can impair thermoregulatory responses that stem from the central nervous system (CNS), but it is unknown if impairments also occur post-synaptically in the microcirculation. Moreover, obese individuals may have impaired thermoregulation, possibly due to microvascular dysfunction. Purpose: The purpose of these studies was two-fold: 1) to determine if obese (OB) individuals exhibit impairments in thermoregulatory responses during exercise heat-stress (centrally-mediated) and intradermal infusion of vasoactive substances (peripherally-mediated) versus non-obese (N-OB), and 2) to determine if hypohydration subsequently affects these thermoregulatory responses differently between groups. Methods: Twenty-one healthy, …

In Vitro Fermentation Patterns Of Rice Bran Components By Human Gut Microbiota, Tung Minh Pham

Graduate Theses and Dissertations

The prevalence of colorectal cancer (CRC) has been increasing in recent years worldwide. In the United States, it is ranked the second leading cause of cancer death. Risks of CRC increase with age and are associated with several lifestyle factors such as diet, drinking and smoking habits, and levels of physical activity. There is an abundance of scientific literature demonstrating the protective roles of several dietary components including fibers and polyphenolic compounds. These compounds have been shown to be able to positively modulate gastrointestinal ecology by increasing the production of short-chain fatty acids (SCFA) and promoting the population of beneficial …

Investigation Of The Interaction Of Dimeric Ruthenium Complexes With Cytochrome B5, Christopher Dain Rupar

Graduate Theses and Dissertations

Photoreactive complexes to study the kinetics of electron transfer of proteins have been in use for a long time. It has always been speculated that complexes bind near the heme or the electron transfer reaction would not occur. But it is unkown exactly how the complex interacts with the protein. The structural, thermodynamic, and kinetic properties of rat liver microsomal cytochrome b5 were investigated when bound to ruthenium dimer complexes. Heteronuclear Single Quantum Coherence studies support a dynamic binding model of a dimer Ru complex bound near the protein’s heme involving residues H39, E44, G42, V61, G62, and H63. The …

High Throughput Phenotypic Evaluation Of Drought-Related Traits In Soybean, Hua Bai

Graduate Theses and Dissertations

Drought limits crop growth and yield in soybean. Rapid and effective methods of screening large numbers of soybean lines for drought tolerance are urgently needed. Two experiments were conducted to evaluate the effects of drought in soybean during reproductive stages. In the first experiment five genotypes from maturity groups 2 through 5 were tested under well-irrigated and drought conditions. Beginning at R5, leaf samples were taken for nitrogen concentration analysis. Pictures were taken across the top of each plot to determine the intensity of greenness using the Dark Green Color Index (DGCI). Aerial photographs were also taken to determine aerial …

It's Not The Load That Breaks You Down, It's The Way You Carry It: An Examination Of The Relationship Between Negative Identity And Consumer Behavior, Cassandra Denise Davis

Graduate Theses and Dissertations

Research examining Social identity and consumer behavior often centers on groups with positive Social identities, exploring the influence of similar identities (i.e., shared values, shared gender, shared political affiliations, shared ethnicity…etc.) or desired identities (e.g., sports celebrities, actors, and actresses). For example, research has shown that people display an increased attention to identity-based stimuli following the activation of a Socially distinct identity (Forehand, Deshpandé, and Reed 2002) and that heightening the self‐importance of a consumer Social identity leads to a preference for identity-related brands (Reed 2004). An important but often overlooked aspect of the influence of Social identity on consumption, …

Characterization Of Broiler Lines Divergently Selected For Breast Muscle Color, Sara Katherine Orlowski

Graduate Theses and Dissertations

An increase in the consumption of poultry has generated an increase in demand for higher yielding broilers. This has led to an increase in atypical meat and issues with appearance. Color is a direct result of a pH decline as meat goes through rigor mortis with meat generally becoming lighter. If the pH declines too rapidly or too slowly, meat quality can suffer. Physical properties of meat can be altered by pH. A fast pH decline results in pale meat with decreased tenderness. A slow pH decline can result in darker meat with a reduced shelf-life. With a known relationship …

The Large-Scale Synthesis And Asymmetric Hydrosilylations Of Cuiphet, A C2-Symmetric N-Heterocyclic Carbene, Elizabeth Suzanne Spahn

Graduate Theses and Dissertations

CuIPhEt is a C2-symmetric N-heterocyclic carbene catalyst used in the asymmetric hydrosilylation of a variety of prochiral ketones with good yields and selectivities. The large-scale, five-step synthesis of this carbene has been devised. The second step of the synthetic plan includes a double asymmetric hydrogenation of a 1,1-diaryl alkene—a traditionally difficult transformation. The procedure for the use of CuIPhEt in asymmetric hydrosilylations has been optimized and used on both the originally published substrate scope and new compounds. This protocol for the hydrosilylation has been applied in a 10 g reduction to create an intermediate for use toward the total synthesis …

Effects Of Amino Acid Supplementation Of Reduced Crude Protein (Rcp) Diets On The Performance And Carcass Quality Of Growing-Finishing Swine, Ashley Nicole Young

Graduate Theses and Dissertations

Barrows and gilts (215/gender) were used to test the effects of synthetic AA supplementation of reduced CP diets on the growth performance and quality characteristics of the LM and the fatty acid composition of the LM and s.c. jowl fat from growing-finishing swine. Pigs were blocked by BW within gender, and allocated randomly to pens (6 pigs/pen) which were then assigned randomly within each block and gender to either corn-SBM diets 1) that were devoid of synthetic lysine (Ctrl); 2) with reduced CP diets where lysine was added to all diets (RCP1); 3) with reduced CP where lysine, threonine, and …

The Impact Of Climate Change In Bangladesh On The Rice Market And Farm Households, Mst Ashrafun Nahar

Graduate Theses and Dissertations

Bangladesh is trying to achieve self-sufficiency in domestic rice production but climate change effects on agricultural production makes it challenging to attain the goal. The country is highly vulnerable to the effects of climate change since it is the major cause to rise in sea level, more warm summer, and happening food and cyclone in the country.

This study develops an Aggregate Farm Household Model to analyze the impact of potential land loss and yield reduction from climate change on production, consumption, prices, welfare, and the ability of government to achieve self-sufficiency in rice production. The model is calibrated to …

Mechanism Of Rapid Electron Transfer Reactions Involving Cytochrome Bc1, Cytochrome C And Cytochrome Oxidase, Jeremy Erik Durchman

Graduate Theses and Dissertations

Electron transfer between mitochondrial proteins complexes represents the primary means by which living things acquire the requisite energy for survival. The coupling of electron transfer to proton translocation creates an electrochemical gradient that drives the synthesis of highly energetic compounds such as ATP. The purpose of these studies is to measure rates of electron transfer and elucidate the important governing factors in the redox events involving cytochrome bc1, cytochrome c and cytochrome oxidase. Using rapid initiation of redox events triggered by laser flash excitation of ruthenium compounds, and strategically monitoring unique spectral properties of these proteins in the visible region …

Verbing History: A Textualist Approach To Gendered Politics In U.S. History Curriculum, Ginney Patricia Norton

Graduate Theses and Dissertations

Using three curricular interventions from World War II, I employ an alternative rhetorical history to understand how Social studies curriculum has become a space for the simultaneous deliberation of both national identity and gender politics. In working through the propaganda of Rosie the Riveter, the stories of the women of Oak Ridge, Tennessee, and the experiences of gay men and women in the military during the war, I suggest that Social studies curriculum normalizes and reifies gendered, racial, and queer citizenship in relationship to white, masculine, and heteronormative citizenship. It also utilizes epideictic rhetoric to rhetorically and historically construct problematic …

Evaluation Of Agricultural Policy In The Dairy Sector In Kosovo And Efficiency Analysis At The Farm Level, Egzon Bajrami

Graduate Theses and Dissertations

This thesis consists of two studies on the dairy sector in Kosovo. The first study evaluates the effect of the Subsidy per Head Scheme (SPHS) on increasing production, land use, gross income and number of dairy cows on dairy farms in Kosovo. Results from the Propensity Score Matching (PSM) approach using four alternative matching algorithms revealed that SPHS has not had any impact on increasing land use, gross income or the number of dairy cows per farm. Furthermore, SPHS had a negative impact on decreasing land use and number of cows for the participating dairy farmers in the program. In …

Associations Of Single Nucleotide Polymorphisms In The Bovine Prolactin, Melatonin Receptor 1a, And Dopamine Receptor D2 Genes With Hair Coat Shedding Scores And Productivity Traits In Beef Cattle, Laura R. Meyer

Graduate Theses and Dissertations

Calving rate is a qualitative trait regulated by several genes and is strongly affected by the environment. With the development of biotechnology and gene identification, scientists are able to determine which genes affect these productivity traits to improve accurate selection decisions. Prolactin (PRL) has been associated with reproductive traits, melatonin receptor 1a (MTNR1A) has been associated with meat quality traits, and the dopamine receptor D2 (DRD2) gene has been associated with hair coat score (HCS) in cattle. Our objective was to determine associations between mutations in the PRL, MTNR1A, and DRD2 genes and cow-calf profitability traits. Genomic DNA was extracted …

Black Male Emerging Adults: Investigating Inequalities In Adult Transitions, Social Learning, And Criminality, De Andre' Terrell Beadle

Graduate Theses and Dissertations

Emerging adulthood is a life stage that developed as a result of numerous macro-structural changes in recent decades (Arnett 2015), and which has implications for life course criminality and identity formation (Massoglia & Uggen 2010). Much research has been done in the area of the new life stage known as “emerging adulthood,” however little to no research has been done on how emerging adulthood relates to or changes classic findings in criminology, especially about the importance of disadvantages embedded in racial inequalities. This mixed method study analyzes data from the National Study of Youth and Religion (NSYR) to examine Social …

Validation Of N-Star Nitrogen Rate Recommendations And Evaluation Of N-Star Soil Sampling Procedures For Clay Soils In Arkansas, Jarom Thane Davidson

Graduate Theses and Dissertations

The two methods for determining N-fertilizer recommendations for rice (Oryza sativa L.) in Arkansas are the standard N recommendation (SR) based on soil texture, previous crop, and rice cultivar, and the Nitrogen-Soil Test for Rice (N-STaR) which quantifies the potentially mineralizable-N of the soil and provides a site-specific N recommendation. The N-STaR program has recently been developed, and the validation of N-STaR for clay soils is an important step in ensuring that N-STaR predicts correct N-fertilizer rates for rice under a delayed-flood production system. Small-plot trials located across Arkansas compared the N-STaR 95 and 100% relative grain yield (RGY) N …

Stream Microbial Communities As Potential Indicators Of River And Landscape Disturbance In North-Central Arkansas, Wilson Howard Johnson

Graduate Theses and Dissertations

In the past decade, 29 shale basins have been actively developed across 20 states for extraction of natural gas (NG) via horizontal drilling/hydraulic fracturing (=fracking). This includes ~5000 wells within the Fayetteville shale of north-central Arkansas. Development often impacts both river- and landscapes, and management requires catchment-level evaluations over time, with organismal presence/absence as indicators. For this study next-generation sequencing was used to identify/characterize microbial communities within biofilm of eight Arkansas River tributaries, so as to gauge potential catchment influences. Streams spanned a gradient of landscape features and hydrological flows, with four serving as ‘potentially impacted catchment zones’ (PICZ) and …

Two Studies: Stereoselective C-C Bond Formations Of N-Boc-Piperidines Using Selected Organolithiums And Visible-Light-Mediated Synthesis Of Fused Indolines Using Tethered Styrenes, Scott Alan Morris

Graduate Theses and Dissertations

Chemists worldwide have accepted the challenge of developing methods to access a variety of compounds as single enantiomers, including the use of enzymes, chiral auxiliaries, and resolutions. In particular, dynamic resolutions offer a unique way to access chiral compounds using a few controllable steps, including the variation of both time and temperature. Many groups have implemented this methodology to generate various polysubstituted pyrrolidines and piperidines, which are substructures ranking high on the list of nitrogen–containing pharmaceuticals.

The Gawley group revealed a catalytic dynamic resolution (CDR) of N–Boc–piperidine using a chiral ligand. Impressively, the chemistry was tolerant of a variety of …

Two-Electron Quenching Of Dinuclear Ruthenium(Ii) Polypyridyl Complexes, Yinling Zhang

Graduate Theses and Dissertations

A bridging ligand 5,5’-Bi- 1,10-phenanthroline, diphen, was prepared using dichlorobis(triphenylphosphine)Ni(II), Ni(PPh3)2Cl2 as catalyst with a yield of 40%. Yellow cubic crystals were able to obtain from the good purity product for single crystal analysis. The torsion angle between the planes of the subunit phenanthrolines is about 66 degrees.

A dinuclear ruthenium (II) polypyridyl complex, (phen)2Ru(diphen)Ru(phen)24+, was synthesized by using polymeric ruthenium carbonyl compound as the entry point, diphen as the bridging ligand and 1,10-phenanthroline, phen, as the terminal legand. Brown needlelike crystals were precipitated from acetonitrile that were not suitable for single crystal diffraction.

The photochemistry of the dimer was …

Effectiveness Of The Arkansas 4-H Atv Safety Training Course, Jesse Bocksnick

Graduate Theses and Dissertations

In response to popularity of ATVs in Arkansas and youth ATV accident rates, the Arkansas 4-H program established an ATV safety training program in 2008. The program has educated 1,500 youth in Arkansas about basic concepts of safe ATV operation in response to youth accident rates. The course covered proper equipment, laws, proper riding, and handling techniques. The program has not been evaluated. The study was to evaluate participants’ knowledge levels prior to participation in the program and after receiving instruction and hands-on ATV operation training, and to determine if Standard Course and S-Course participants’ knowledge scores were different. The …

Fragmentality, Elena Volkova

Graduate Theses and Dissertations

Contemporary art is dedicated to the conversation between the past and the present, the established and the experimental; it becomes more and more trans-border, as life itself. Nowadays, people live in the world, where their beliefs, ideas, politics, and religion are constantly colliding. The more people expand boundaries and develop connections, the more complex and tangled our society becomes as a system.

FRAGmentality presents a set of mixed media pieces incorporating painting, weaving, embroidery and three-dimensional elements dedicated to these contradictions in the modern society. It deals with structures within Social relations and human nature.

Being a representative of a …

Void Loop ( ) {, Jonathan Barrett Cromer

Graduate Theses and Dissertations

Void loop is an exhibition that addresses the dynamics of survival through an investigation of power, predation, migration, destruction, and renewal. As an installation of sculpture, video, and sound, the work on display explores associations between the human and natural worlds that inform who we are as individual, Social and biological beings. The repeated code surrounding the “void loop” title is a basic call and response serial communication between the microcontroller and the sensors. It commands the microcontroller to infinitely loop all code following the function, mimicking the repetitions of a pulsing heart. For the exhibition each piece is based …

Quantifying, Assessing, And Mitigating Methane Emissions From Super-Emitters In The Oil And Gas Supply Chain, David Richard Lyon

Graduate Theses and Dissertations

Methane emissions from the oil and gas (O&G) supply chain reduce potential climate benefits of natural gas as a replacement for other fossil fuels that emit more carbon dioxide per energy produced. O&G facilities have skewed emission rate distributions with a small fraction of sites contributing the majority of emissions. Knowledge of the identity and cause of these high emission facilities, referred to as super-emitters or fat-tail sources, is critical for reducing supply chain emissions. This dissertation addresses the quantification of super-emitter emissions, assessment of their prevalence and relationship to site characteristics, and mitigation with continuous leak detection systems. Chapter …

Algal Wastewater Treatment And Biofuel Production: An Assessment Of Measurement Methods, And Impact Of Nutrient Availability And Species Composition, John F. Chamberlin

Graduate Theses and Dissertations

In order to move towards a more sustainable future, human civilization will need to decrease its impacts on air and water quality and minimize consumption of fossil fuels. Using algae for wastewater treatment and biofuel production offers one approach to progress towards these goals simultaneously. Algae are capable of removing nutrients from wastewater and carbon dioxide from the air, and the biomass formed in that process can be used to generate a wide-range of products including fertilizer or fuels that could power combustion engines, power plants, or zero-emission fuel cell vehicles. Using wastewater for biofuel production has the potential to …

Nanofiltration Rejection Of Contaminants Of Emerging Concern From Municipal Water Resource Recovery Facility Secondary Effluents For Potable Reuse Applications, Steven Michael Jones

Graduate Theses and Dissertations

As reuse of municipal water resource recovery facility (WRRF) effluent becomes vital to augment diminishing fresh drinking water resources, concern exists that conventional barriers may prove deficient and the upcycling of contaminants of emerging concern (CECs) could prove harmful to human health and aquatic species if more effective and robust treatment barriers are not in place.

There are no federal Safe Drinking Water Act (SDWA) regulations in place specifically for direct potable reuse (DPR) of WRRF effluent. Out of necessity, some states are developing their own DPR reuse regulations. Currently, reverse osmosis (RO) is the default full advanced treatment (FAT) …

Genetic Determinism Of Xanthomonas Arboricola Pv. Pruni (Xap) Resistance, Fruit Quality, And Phenological Traits In Peach And Incorporation Of Marker-Assisted Selection (Mas) In The University Of Arkansas Peach And Nectarine Breeding Program, Terrence James Frett

Graduate Theses and Dissertations

For over two decades the incorporation of marker-assisted selection (MAS) has been discussed as an innovative approach to increase peach breeding efficiency. Although hundreds of quantitative trait loci (QTLs) have been identified, only a few have been converted into usable MAS tools. This highlights a disconnect between genomic discoveries and practical application in breeding programs, which has delayed use of MAS.

In this dissertation, three sequential steps were performed with the objective to bridge this gap and develop breeding-relevant DNA tests for MAS of fruit bacterial spot resistance (Xap1 and Xap6), fruit quality [blush (Rf), acidity (D), and acidity and …

Assessment Of An Industrial Type Radiant Heating System For Drying Rough Rice, Anne Adhiambo Okeyo

Graduate Theses and Dissertations

Rough rice is normally harvested at moisture contents (MCs) higher than that for safe storage. The objective for this study was to investigate the effectiveness of scaled-up infrared (IR) heating followed by tempering steps to dry freshly-harvested rough rice. An industrial type, pilot scale, IR drying equipment, designed to convey rough rice on a vibrating conveyor belt was used in this study. The heating zone of the equipment had catalytic IR emitters powered by natural gas. Freshly-harvested rough rice of long-grain pureline (cv. Cheniere), long-grain hybrid (cv. 6XP 756) and medium-grain (cv. CL 271) cultivars at initial moisture contents (IMCs) …

Emergence Phenology And Nematode Associates Of The Woodwasp, Sirex Nigricornis F. (Hymenoptera: Siricidae), In Arkansas And Mississippi Forests, Jessica Ann Hartshorn

Graduate Theses and Dissertations

Sirex nigricornis F. (Hymenoptera: Siricidae) is a native woodwasp in eastern North America that inhabits dead and dying pine trees during its univoltine development. Sirex noctilio is native to Eurasia and North Africa and was discovered in the northeastern United States in 2004 after a century of accidental introductions across the Southern Hemisphere. Since then, it has spread to seven states and southern Ontario. There is concern about its potential to negatively affect the multi-billion dollar pine timber industry of the southeastern United States. Effective monitoring tools are necessary to track the spread and establishment of S. noctilio. Deladenus siricidicola …

A Molecular Approach To Understanding The Effects Of Original-Xpc On The Modulation Of The Cecal Microbiota And The Survival Of Salmonella In The Poultry Host, Stephanie Roto

Graduate Theses and Dissertations

Salmonella is a foodborne pathogen commonly associated with poultry products; the economic burden to the U.S. is estimated to be approximately $693 million (without factoring in contaminated eggs). Recently, there has been pressure to withdraw sub-therapeutic levels of antibiotics (also known as antibiotic growth promoters; AGP) from poultry due to concern over antibiotic-resistant bacteria spreading to the human population. Therefore, various feed additives have been researched for their ability in providing protection against harmful pathogens and their potential growth promoting effects, both of which were attributes of poultry treated with AGP. This thesis consists of a comprehensive literature review that …

Measuring Teacher Effectiveness: A Comparison Across Va Models Utilizing Arkansas Data, Kelli Lane Blackford

Graduate Theses and Dissertations

A shift in accountability systems from No Child Left Behind to a reauthorization of the Elementary and Secondary Education Act redefined the mandate of classroom teachers from being highly qualified to highly effective. Whereas previously, a teacher was deemed highly qualified for having a bachelor’s degree, full state certification, and demonstrated knowledge of subject matter in the field they teach, a highly effective teacher had to demonstrate their abilities to move a student at an acceptable rate of student growth (one grade level in an academic year). To provide this evidence, student assessment data was now going to be a …

Heat Stress Effects On Cotton During Reproductive Development And Subsequent Acclimation Responses, Toby Ryan Fitzsimons

Graduate Theses and Dissertations

High temperature stress is among the most difficult to control abiotic factors affecting crop yields in the Southern United States due to its wide regional influence. Cotton (Gossypium hirsutum L.) though a tropical plant in origin, it is sensitive to the effects of high temperature. This is of particular concern when the warmest temperatures coincide with the most sensitive developmental stage of flowering. Thus, the capacity to improve cotton’s ability to tolerate heat stress has been a significant focus for many decades. Therefore, this research was composed of several different components all designed to investigate heat stress effects. Using a …