Digital Commons Network^™

The Release, Transport, And Utilization Of Phosphorus From Bed-Sediments: A Study Of A Eutrophic Littoral Cove On Beaver Lake In Northwest Arkansas, James A. Mccarty

Graduate Theses and Dissertations

Eutrophication of surface waters not only impacts the environment but also water treatment processes, the most significant of which is from the effects of algae. During peak algal growth in many southern U.S. reservoirs, inflows that bring nutrients are at an annual minimum, and phosphorus released from bed-sediments is trapped in the hypolimnion. Littoral areas, described as the most productive zone of the lake, may be a possible source of phosphorus that fuels algal growth in the reservoir. I studied an isolated shallow cove in the War Eagle Creek arm of Beaver Lake in Northwest Arkansas to measure, quantify, and …

A Structure Theorem For Bad 3-Orbifolds, Rachel Julie Lehman

Graduate Theses and Dissertations

We explicitly construct 10 families of bad 3-orbifolds, X , having the following property: given any bad 3-orbifold, O, it admits an embedded suborbifold X ∈ X such that after removing this member from O, and capping the resulting boundary, and then iterating this process finitely many times, you obtain a good 3-orbifold. Reversing this process gives us a procedure to obtain any possible bad 3-orbifold starting with a good 3-orbifold. Each member of X has 1 or 2 spherical boundary components and has underlying topological space S2 × I or (S2 × S1)\B3.

A Novel Three-Level Isolated Ac-Dc Pfc Power Converter Topology With Reduced Number Of Switches, Obaid Aldosari

Graduate Theses and Dissertations

The three-level isolated AC-DC power factor corrected (PFC) converter provides safe and more efficient power conversion. In comparison with two-level, three-level PFC converter has the advantages of low total harmonic distortion, low device voltage rating, low di/dt, better output performance, high power factor, and low switching losses at higher switching frequencies. The high frequency transformer (HFT) grants galvanic isolation, steps up or down secondary voltage, and limits damage in case of a fault current.

The existing three-level converter based on solid-state transformer (SST) topologies convert ac power from the electrical grid to a dc load while maintaining at least the …

Integrated Hyperspectral And Geochemical Analysis Of The Upper Mississippian Meramec Stack Play And Outcrop Equivalents, Anadarko Basin And Ozark Uplift, Oklahoma, David Gates

Graduate Theses and Dissertations

The principle goal of this project was to investigate compositional, textural, and sedimentological variability in the Oklahoma STACK Play’s Meramec Formation and time equivalent outcrops of the Pryor Creek Formation in northeastern Oklahoma and to assess the potential of a partial-SWIR (Short Wave Infrared, 900-1700 nm) hyperspectral imaging sensor for drill core and sUAS-based (small Unmanned Aircraft Systems) outcrop characterization.

The STACK Play is a colloquial term that refers to stacked unconventional petroleum reservoirs that are primarily located in Canadian, Kingfisher, Blaine, and Dewey Counties, central Oklahoma. Discovery of, and commercial production from, the play was initiated in 2011 by …

Spatial Analysis Of Soil Creep Rates On Mount Sequoyah, Fayetteville Arkansas, Amy Suzanne Morris

Graduate Theses and Dissertations

Mount Sequoyah in Fayetteville, Arkansas, is a part of the Boston Mountains, which are considered a deeply dissected plateau. The area is prone to mass wasting, which is the general downslope movement of sediments, soils, and rock through different processes that cause instabilities along a hillslope, and in its soil and loose rubble mantle. For this study, we looked at soil creep, which is the small-scale movement of soil downhill because of gravity, wetting and drying cycles, and heating and cooling cycles.

By measuring the tilt of utility poles, we determined multiple causes of soil creep. The variables that are …

Low Latency Anomaly Detection With Imperfect Models, Samrat Nath

Graduate Theses and Dissertations

The problem of anomaly detection deals with detecting abrupt changes/anomalies in the distribution of sequentially observed data in a stochastic system. This problem applies to many applications, such as signal processing, intrusion detection, quality control, medical diagnosis, etc. A low latency anomaly detection algorithm, which is based on the framework of quickest change detection (QCD), aims at minimizing the detection delay of anomalies in the sequentially observed data while ensuring satisfactory detection accuracy. Moreover, in many practical applications, complete knowledge of the post-change distribution model might not be available due to the unexpected nature of the change. Hence, the objective …

Dynamic Fraud Detection Via Sequential Modeling, Panpan Zheng

Graduate Theses and Dissertations

The impacts of information revolution are omnipresent from life to work. The web services have signicantly changed our living styles in daily life, such as Facebook for communication and Wikipedia for knowledge acquirement. Besides, varieties of information systems, such as data management system and management information system, make us work more eciently. However, it is usually a double-edged sword. With the popularity of web services, relevant security issues are arising, such as fake news on Facebook and vandalism on Wikipedia, which denitely impose severe security threats to OSNs and their legitimate participants. Likewise, oce automation incurs another challenging security issue, …

Incorporating Geophysical Data In Slope Stability Modeling For Two Slopes In Arkansas, Vanessa Lebow

Graduate Theses and Dissertations

Slope failures in the United States alone cause millions of dollars in damage to infrastructure, threaten national monuments, create environmental hazards, and take an average of 25-50 lives a year. With the inevitable construction that occurs on slopes, it is imperative that the slopes be properly designed which requires a thorough understanding of slope grade, subsurface soil conditions, soil strength parameters, water table locations, and depth to bedrock across the entire site. The preferred method of data collection would be to use borings and other in-situ methods; however, sometimes due to cost constraints or site accessibility only a very limited …

Cytotoxicity And Mutagenicity Of Disinfection Byproduct Mixtures Formulated Using Free Chlorine And Monochloramine, Yonas Ghebremedhin

Graduate Theses and Dissertations

Bioassays have been used extensively to assess various toxicity endpoints of drinking water disinfection byproducts (DBPs), but an emphasis on single compounds prevails. In this research, DBP mixtures were assessed using a cytotoxicity test with Chinese Hamster Ovary (CHO) cells and an Ames fluctuation test with Salmonella typhimurium TA-98 and TA-100 with and without S9 rat liver homogenate. Seven whole mixture DBP concentrates were formulated using reconstituted natural organic matter (NOM) extracts from the Upper Mississippi River using scaled disinfectant dosing protocols with free chlorine and monochloramine in the presence and absence of added bromide. DBPs were identified by gas …

Extracting Social Network From Literary Prose, Tarana Tasmin Bipasha

Graduate Theses and Dissertations

This thesis develops an approach to extract social networks from literary prose, namely, Jane Austen’s published novels from eighteenth- and nineteenth- century. Dialogue interaction plays a key role while we derive the networks, thus our technique relies upon our ability to determine when two characters are in conversation. Our process involves encoding plain literary text into the Text Encoding Initiative’s (TEI) XML format, character name identification, conversation and co-occurrence detection, and social network construction. Previous work in social network construction for literature have focused on drama, specifically manually TEI-encoded Shakespearean plays in which character interactions are much easier to track …

The Cognition Of Controversy: Examining Policy Elites’ Narrative Cognition And Communication Around Hydraulic Fracturing Practices In The U.S., Rachael M. Moyer

Graduate Theses and Dissertations

The use of hydraulic fracturing (HF) technologies to extract oil and gas in the United States has sparked contentious policy debates, producing inconsistent and inefficient policies that have done little to address the impacts of HF in any comprehensive way. Debates are accompanied by competing policy narratives that position HF as either an environmental threat or an economic opportunity, but little is known about how policy narratives around HF are used by individuals. This dissertation systematically examines how individuals cognitively internalize elements of competing HF policy narratives. Organized into three empirical chapters, this dissertation analyzes narrative cognition (Jones, Shanahan, and …

Characterizing Hydrothermal System Groundwater Dynamics Using Conservative And Non-Conservative Tracers: Insights And Implications Drawn From Study At The Taupo Volcanic Zone (New Zealand) And Valles Caldera (Usa), Joshua Michael Blackstock

Graduate Theses and Dissertations

Hydrothermal systems constitute an important component of heat and mass transport within Earth’s crust having direct and indirect impacts to society. Investigating contemporary hydrochemical differences and change are critical to evaluating and deconvolving factors that influence geothermal systems through time. In this dissertation, groundwater mixing approaches were used to study hydrochemical differences in two globally significant hydrothermal areas, which included fabrication of a low-cost dissolved CO2 monitoring for dissolved inorganic carbon (DIC). In the Taupo Volcanic Zone (New Zealand), empirical spatial relations were used to derive low-temperature groundwater end-members of Cl and Cl/Br for end-member mixing analysis (EMMA). Using EMMA, …

The Feedback-Related Negativity Is A Time-Dependent Brain Mechanism That Facilitates Aversive Learning: Implications For The Reinforcement Learning Frn Hypothesis, Eric Rawls

Graduate Theses and Dissertations

Organisms encode rewarding and aversive experiences through reinforcement learning, capitalizing on prediction errors (PEs), which adapt action strategies over time. Computational theories are explicit that PE signals should update action weights continuously over the course of a behavioral task, an important time-dependent variation that is eschewed in traditional neuroscience studies that average over large numbers of trials. I examined variation in reaction times and feedback-locked cortical activity over time as a function of PE to critically examine theories indicating that PE signals drive time-dependent learning. We recorded EEG while participants completed a novel reinforcement task that varied prediction error on …

Interfacial Contact With Noble Metal - Noble Metal And Noble Metal - 2d Semiconductor Nanostructures Enhance Optical Activity, Ricardo Raphael Lopez Romo

Graduate Theses and Dissertations

Noble metal nanoparticles and two-dimensional (2D) transition metal dichalcogenide (TMD) crystals offer unique optical and electronic properties that include strong exciton binding, spin-orbital coupling, and localized surface plasmon resonance. Controlling these properties at high spatiotemporal resolution can support emerging optoelectronic coupling and enhanced optical features. Excitation dynamics of these optical properties on physicochemically bonded mono- and few-layer TMD crystals with metal nanocrystals and two overlapping spherical metal nanocrystals were examined by concurrently (i) DDA simulations and (ii) far-field optical transmission UV-vis spectroscopic measurements. Initially, a novel and scalable method to unsettle van der Waals bonds in bulk TMDs to prepare …

Understanding And Controlling Lithium Microstructure During Electroplating For Energy Applications, Yang Tian

Graduate Theses and Dissertations

Lithium-ion batteries are reaching the specific theoretical capacity limit, while lithium metal batteries are regarded as the ideal energy storage system for the next generation “beyond lithium-ion” battery systems. The lithium metal anode is considered as the “Holy grail” of anodes due to its relatively low electrochemical potential (-3.04 V vs SHE) and high theoretical capacity (3860 mAh g-1). However, the application of lithium metal anodes is hindered because of significant reaction between metallic lithium and electrolytes, as well as uneven electro-plating, which leads to dendrite formation, causing safety problems.

The kinetic parameters of Li ions such as diffusion coefficient …

Surface Modification Of Pvdf Membranes For Treating Produced Waters By Direct Contact Membrane Distillation, Zahra Anari

Graduate Theses and Dissertations

Direct contact membrane distillation is a promising unit operation for treating hydraulic fracturing flow back and produced water. However, while a hydrophobic membrane is essential to prevent the passage of water from the feed to the permeate side, fouling by dissolved organic species can compromise membrane performance and result in wetting of the membrane pores. Here four monomers, hydroxyethylmethacrylate, acrylic acid, 1-vinyl-3-allylimidazolium bromide, and 1-vinyl-3-hexylimidazolium bromide have been grafted from the surface of a PVDF membrane. The modified and base membranes were tested in a direct contact membrane distillation system. All membranes were challenged with real produced water. In addition, …

Fractional Order State Feedback Control For Improved Lateral Stability Of Semi-Autonomous Commercial Heavy Vehicles, Rasheed Mazen Abdulkader

Graduate Theses and Dissertations

With the growing development of autonomous and semi-autonomous large commercial heavy vehicles, the lateral stability control of articulated vehicles have caught the attention of researchers recently. Active vehicle front steering (AFS) can enhance the handling performance and stability of articulated vehicles for an emergency highway maneuver scenario. However, with large vehicles such tractor-trailers, the system becomes more complex to control and there is an increased occurrence of instabilities. This research investigates a new control scheme based on fractional calculus as a technique that ensures lateral stability of articulated large heavy vehicles during evasive highway maneuvering scenarios. The control method is …

Rotational Tuning Of Transmembrane Helix Properties Based On The Precise Placements Of Aromatic And Charged Residues, Matthew J. Mckay

Graduate Theses and Dissertations

Designed model transmembrane peptides and oriented 2H and 15N solid-state nuclear magnetic resonance (NMR) spectroscopy were used to analyze how simple sequence modifications can influence peptide structure, behavior and dynamics as well as for determining the pKa of glutamic acid at the membrane interface. The GW5,19ALP23 (acetyl-GGALW(LA)6LWLAGA-amide) peptide framework adopts a well-defined tilted orientation in lipid bilayers (DLPC, DMPC and DOPC) and undergoes low amounts of dynamic motion. The sequence was initially modified by moving the Trp residues outwards to positions 4 and 20. This new sequence GW4,20ALP23 (acetyl-GGAW(AL)7AWAGA-amide) displays high amounts of signal averaging of NMR observables caused by …

Observable Persistent Effects Of Habitat Management Efforts In The Ozark Highlands After 10 Years, Maxwell Carnes-Mason

Graduate Theses and Dissertations

I investigated the lasting impacts of a management plan designed to improve oak regeneration and benefit wildlife in the Ozark Highlands in Madison, Co., AR. To assess the efficacy of the management plan, I used variables relevant to the success and establishment of oak trees. Controlled burns and selective logging were used to thin the canopy, increase ground level productivity, and increase the abundance of small mammals. I used measurements of overstory and understory densities, light availability, and the density of mice in the genus Peromyscus across time to look at the lasting impacts of management. Different treatment plots were …

Probing Of Carbohydrate-Protein Interactions Using Galactonoamidine Inhibitors, Jessica B. Pickens

Graduate Theses and Dissertations

Glycoside hydrolases are ubiquitous and one of the most catalytically proficient enzymes known, and thus understanding their mechanisms are crucial. Most research has focused on the interaction of the glycon of substrates and their inhibitors within the active site of glycoside hydrolases. The inhibitors employed to probe these interactions generally had small aglycons (i.e. a hydrogen atom, amidines, small aliphatic groups, or benzyl groups). Here, the interactions of the aglycon with glycoside hydrolases are examined by probing the active sites with a library of 25 galactonoamidines. The studies described in this dissertation aim to increase the understanding of stabilization of …

Nematode Populations As Affected By Residue And Water Management In A Long-Term Wheat-Soybean Double Crop In Eastern Arkansas, Lucia Emperatriz Escalante Ortiz

Graduate Theses and Dissertations

Soybeans (Glycine max) are one of the major row crops in the United States, particularly in Arkansas. Soybean cyst nematode (SCN, Heterodera glycines) and southern root-knot nematode (RKN, Meloidogyne incognita) are two of the most damaging pests that cause major economic losses in soybeans. Little is known concerning the effects of common and alternative agronomic practices on nematodes in fields with nematode population densities below threshold levels. Therefore, the objective of this study was to evaluate the effects of the combination of tillage (conventional tillage and no-tillage), irrigation (irrigated and non-irrigated), wheat (Triticum aestivum) residue burning (burned and no burned), …

An Investigation Of Metal Sulfides As The Source Of The Low Emissivity Anomaly On The Highlands Of Venus, Sara Taeko Port

Graduate Theses and Dissertations

Since its detection in the 1960s the source of the unusual radar emissivity signal seen on several highlands on Venus has long eluded researchers. Researchers have determined that a mineral with a high dielectric constant could explain the signal. Using a Venus simulation chamber, we experimentally investigated this enigma to build upon the candidate mineral list that has been compiled over the last several decades. We tested the stability of 8 different minerals and elements at two to three different temperature/pressure regimes in three different gas mixtures meant to simulate the conditions found on Venus for a period of no …

Studies Of Initial Growth Of Gan On Inn, Alaa Alnami

Graduate Theses and Dissertations

III-nitride materials have recently attracted much attention for applications in both the microelectronics and optoelectronics. For optoelectronic devices, III-nitride materials with tunable energy band gaps can be used as the active region of devices to enhance the absorption or emission. A such material is indium nitride (InN), which along with gallium nitride (GaN) and aluminum nitride (AlN) embody the very real promise of forming the basis of a broad spectrum, a high efficiency solar cell. One of the remaining complications in incorporating InN into a solar cell design is the effects of the high temperature growth of the GaN crystal …

Reactivity Of Photogenerated Amine Radical Cations, Qile Wang

Graduate Theses and Dissertations

Recently photoredox catalysis has emerged as a powerful tool in organic synthesis led by Professor McMillan, Stephenson, Yoon. Upon absorption of visible light, photocatalyst can be excited to its singlet state followed by intersystem crossing to form a long lived excited triplet state. While amine serves as electron donor, single electron transfer (SET) can happen between excited triplet photocatalyst and nitrogen atom on amine to give a reduced photocatalyst and amine radical cation.

Cyclopropylamines or cyclobutylamines can be oxidized by excited photocatalyst to generate amine radical cations and due to the ring strain, subsequent C-C bond cleavages can lead to …

Suitability Assessment For Integrated Urban Development In Makkah City Of Saudi Arabia, Mislat Alotaibi

Graduate Theses and Dissertations

Makkah – the third most populated city in Saudi Arabia with a population of 1,684,408 according to the 2010 demographic survey conducted by the Saudi General Authority for Statistics – is experiencing urban sprawl, which can be defined as an unplanned urban expansion that might degrade the environment and diminish the aesthetic view. This is a persisting problem in Makkah driven by multitude of processes involving the random expansion in its undeveloped land and the removal of its historic mountains surrounding Al-Masjid Al-Haram (the Holy Mosque) in an attempt to push the city limit of urban capacity within its administrative …

Improving Earthquake Disaster Models With Post-Event Data: Insights From The 2015 Gorkha, Nepal Earthquake, Bradley Steven Wilson

Graduate Theses and Dissertations

Immense amounts of data are collected following earthquake disasters. Yet, it remains unclear how researchers’ might take full advantage of diverse post-disaster datasets. Using data from the 2015 Gorkha Nepal earthquake, this dissertation explores three ways in which post- disaster survey and assessment datasets can be used to inform models of seismic risk, vulnerability, and recovery processes. The first article presents an empirical analysis of scale issues in disaster vulnerability indices using a novel dataset of 750,000 households. This study finds that using aggregated household data to create social vulnerability indices can produce results that are meaningfully different from equivalent …

The Shelf To Basin Transition And Tectonostratigraphy Of The Atoka Formation (Lower Pennsylvanian) In The Arkoma Basin, Northwest Arkansas, Travis Gibson White

Graduate Theses and Dissertations

The east-to-west oriented Arkoma Basin is a peripheral foreland basin or depositional trough that developed during the Carboniferous Period. This formation covers an aerial extent of approximately 33,800 square miles and spans from west-central Arkansas into southeastern Oklahoma (McGilvery, Manger, and Zachry, 2016; Perry, 1995). The Atoka Formation, deposited during the early Pennsylvanian, is the largest Paleozoic formation by aerial extent in the state of Arkansas and is located within and comprises the bulk of Arkoma Basin sediments (McFarland, 2004; Nance, 2018). This formation has been informally divided into three divisions, the lower, middle, and upper, based on their stratigraphic …

Quantitative Study Of The Antimicrobial Effects Of Silver On The Motility Of Escherichia Coli, Benjamin Russell

Graduate Theses and Dissertations

In recent decades, the number of antibiotic-resistant bacterial infections has grown to become a serious global threat. This rise can be attributed to the widespread misuse of antibiotics and the lack of newly developed drugs to fight resistant organisms. Novel bactericidal substances have, therefore, garnered significant research interest. Silver, due to its powerful antimicrobial effects, is one such substance. Silver is typically most effective in cationic form; however, advancements in nanotechnology have paved the way for the controlled fabrication of nano-silver. Silver nanoparticles have been shown to have increased antibacterial potency for a variety of reasons, including the release of …

The Van Hiele Analysis Of Curricular Materials: A Comparative Study, Vinay Kumar Kalyankar

Graduate Theses and Dissertations

The goal of this study is to investigate K-8 geometry curriculum standards and textbooks for their effectiveness in preparing students for high school geometry. The basis for the study is van Hiele theory pioneered by the Dutch educators and researchers of geometric understanding in adolescents, Dina van Hiele Geldof and Pierre van Hiele. Another driving force for this dissertation is research into mathematics textbooks and curriculum standards of school mathematics as seen in CCSSM and state specific standards documents, both of which influence the mathematics students have the opportunity to learn.

The K-8 geometry curriculum standards and textbook instructional segments …

Strategies To Improve Forage Utilization By Sheep Offered Forage Mixtures, Valens Niyigena

Graduate Theses and Dissertations

In the first experiment, alfalfa and novel endophyte-infected tall fescue (NE+) forages were harvested after a killing frost, then mixed to formulate 4 different treatments; alfalfa alone, 67% alfalfa +33% fescue, 33% alfalfa + 67% fescue, or 100% fescue. After 3 months of storage as silage, Dorper ewe lambs (n = 20; mean BW = 34.7 ± 6.65 kg) were fed silage for ad libitum consumption, using 5 animals per treatment. Increasing the proportion of NE+ tall fescue improved (P < 0.05) silage total acids and lactic acid concentrations and decreased silage ammonia concentration. Digestible dry matter and organic matter intake and nitrogen utilization parameters decreased with increasing inclusion of NE+ in diet. In the second experiment, 16 Dorper ewe lambs (41.8 ± 4.61 kg BW) were assigned to 4 different treatments; alfalfa silage alone (0 g/kg; CONT) or alfalfa silage mixed with chopped sericea lespedeza (SL) hay to provide 90 (LOW), 180 (MED), or 270 g/kg SL (HIGH) on a dry matter basis in a randomized complete block design experiment with 2 period to provide 4 observations per treatment for each experimental period. Increasing the proportion of sericea lespedeza in the diet decreased dry matter and organic matter digestibility but did not affect feed intake. Fecal nitrogen (g/kg N intake) increased linearly (P < 0.01) while urinary N (g/ day and g/ kg of N intake) tended to decreased linearly and quadratically (P ≤ 0.1) with increasing the proportion of SL in diet. In the third experiments, 16 gestating Dorper ewe lambs (49.1 ± 4.61 kg BW) were allocated to 4 treatments; alfalfa silage alone (0% g/kg; CONT) or alfalfa silage mixed with lablab purpureus(LP) hay to provide 90 (LOW), 180 (MED), or 270 g/kg LP (HIGH) on a dry matter (DM) basis, in a randomized complete block design experiment with a total 8 replication per treatment. Supplementation of LP in diet increased quadratically (P ≤ 0.04) forage dry matter, organic matter intake, digestible dry matter and digestible organic matter intake (P < 0.05). Nitrogen apparently absorbed and urinary N both decreased linearly (P < 0.01) with adding more LP hay in diet. Harvesting and mixing alfalfa and fescue after a killing frost improved silage fermentation characteristics and supplementation of tannins from SL and polyphenol from LP altered N excretion.

Key words: lablab, sericea lespedeza, alfalfa silage, nitrogen, sheep.