Digital Commons Network^™

Prediction, Recommendation And Group Analytics Models In The Domain Of Mashup Services And Cyber-Argumentation Platform, Md Mahfuzer Rahman

Graduate Theses and Dissertations

Mashup application development is becoming a widespread software development practice due to its appeal for a shorter application development period. Application developers usually use web APIs from different sources to create a new streamlined service and provide various features to end-users. This kind of practice saves time, ensures reliability, accuracy, and security in the developed applications. Mashup application developers integrate these available APIs into their applications. Still, they have to go through thousands of available web APIs and chose only a few appropriate ones for their application. Recommending relevant web APIs might help application developers in this situation. However, very …

Electrochemical Oxidation Of Individual Silver Nanoparticles: Exploring The Effect Of Particle Shape, Capping Ligand, Electrolyte, And Potential On The Signal, Jazlynn Sikes

Graduate Theses and Dissertations

Nanomaterials have revolutionized science and technology. Their unique properties can be exploited, and nanoparticles are being used as catalysts, antimicrobials, drug delivery vehicles, sensors, and more. However, the fundamental properties of nanomaterials and their interactions with their surrounding environments are still poorly understood. In this work, a single-particle approach was used to observe the effects of capping ligand, surrounding solution, and particle shape on the oxidative process to gain deeper understanding of silver nanoparticle properties. When allowed the opportunity, the particles will adsorb to the electrode surface then oxidize in rapid succession upon electrode activation, regardless of capping ligand as …

Characterization Of Problematic Red Clay Soils In Arkansas For The Purpose Of Onsite Wastewater System Placement, Bailey Darnell

Graduate Theses and Dissertations

Distinguishing between red-clay soils that are non-expansive and can reduce and red-clay soils developing in problematic red parent material, which are expansive, but also non-reducing, is key for proper on-site wastewater system placement. The Arkansas Department of Health allows for the placement of on-site wastewater systems in certain red-clay soils that have the potential to reduce, but only in the Ozark Highlands [Major Land Resource Area (MLRA) 116A], which is referred to as the red-soil exception. There is currently little scientific data to support the geographic restriction of the red-soil exception. The objectives of this study were to: i) confirm …

Developing A Microdialysis Sampling-Based Biofilm/Macrophage Co-Culture Model, Alda Diaz Perez

Graduate Theses and Dissertations

The host immune system and bacterial cells are known to interact during the human lifetime. Bacteria secrete a wide variety of signaling molecules, known as quorum sensing (QSC) molecules, that modulate the host immune system. While immune-biofilm interactions involve this chemical signaling network, the mechanisms through which this occurs are not well understood. This work aimed to develop a new method that can be used not only in vitro settings but also in vivo. The microdialysis sampling technique has widely been used in in vitro and in vivo settings in humans, mice, and rats for the collection of neuropeptides, cytokines, …

Achieving Differential Privacy And Fairness In Machine Learning, Depeng Xu

Graduate Theses and Dissertations

Machine learning algorithms are used to make decisions in various applications, such as recruiting, lending and policing. These algorithms rely on large amounts of sensitive individual information to work properly. Hence, there are sociological concerns about machine learning algorithms on matters like privacy and fairness. Currently, many studies only focus on protecting individual privacy or ensuring fairness of algorithms separately without taking consideration of their connection. However, there are new challenges arising in privacy preserving and fairness-aware machine learning. On one hand, there is fairness within the private model, i.e., how to meet both privacy and fairness requirements simultaneously in …

Network-Based Detection And Prevention System Against Dns-Based Attacks, Yasir Faraj Mohammed

Graduate Theses and Dissertations

Individuals and organizations rely on the Internet as an essential environment for personal or business transactions. However, individuals and organizations have been primary targets for attacks that steal sensitive data. Adversaries can use different approaches to hide their activities inside the compromised network and communicate covertly between the malicious servers and the victims. The domain name system (DNS) protocol is one of these approaches that adversaries use to transfer stolen data outside the organization's network using various forms of DNS tunneling attacks. The main reason for targeting the DNS protocol is because DNS is available in almost every network, ignored, …

The Impact Of Funds Of Knowledge Instruction In Career And Technical Education Among Junior High Students: A Mixed Methods Study, Sheri D. Deaton

Graduate Theses and Dissertations

The purpose of this mixed methods study was to investigate students’ perceptions of their own Funds of Knowledge (FOK) and the impact that these funds have as students prepare for careers. This purpose was achieved through an embedded mixed methods design with qualitative data collection and analysis embedded within the quantitative research design. Analysis of data collected in a Career and Technical Education (CTE) classroom from the pre and post assessment instrument reveal that while direct instruction regarding FOK did not result in a statistically significant difference between the control and treatment groups, post assessment scores for participants in the …

Quantifying The Leaching Of Nutrients And Metals In A Pasture Soil As Affected By Excreta Of Ruminants Fed Alternative Diets, Ian Kennedy

Graduate Theses and Dissertations

The leaching of nitrate through the soil profile and into adjacent water systems has been a leading cause of water pollution and results in the loss of a valuable nutrient from animal production systems. Forage-based animal production systems may be improved through manipulation of animal diets that incorporate tannins and total polyphenolic compounds with feed, increasing the amount of nitrogen (N) retained by an animal/decreasing rates of digestion and altering the N-containing compounds that are excreted and deposited onto soil. Incorporating the forage legumes sericea lespedeza (Lespedeza cuneate [Dumont de Courset] G. Don) and lablab (Lablab purpurues L.) into the …

Characteristic Reassignment For Hardware Trojan Detection, Noah Waller

Graduate Theses and Dissertations

With the current business model and increasing complexity of hardware designs, third-party Intellectual Properties (IPs) are prevalently incorporated into first-party designs. However, the use of third-party IPs increases security concerns related to hardware Trojans inserted by attackers. A core threat posed by Hardware Trojans is the difficulty in detecting such malicious insertions/alternations in order to prevent the damage. This thesis work provides major improvements on a soft IP analysis methodology and tool known as the Structural Checking tool, which analyzes Register-Transfer Level (RTL) soft IPs for determining their functionalities and screening for hardware Trojans. This is done by breaking down …

Effect Of Citric Acid On Slump, Compressive Strength, And Setting Time Of Belitic Calcium Sulfoaluminate Concrete, Israel Aguilar Rosero

Graduate Theses and Dissertations

Belitic calcium sulfoaluminate (BCSA) cement has well established advantages related to fast setting time, fast strength gain, long-term strengths, shrinkage, and sustainability. Due to its fast setting and hardening, this type of cement has historically been used to repair concrete structures, highways, and runways. This work provides much needed guidance on establishing mix design criteria for BCSA cement. Guidance is also given on the effects of set retarders on strength, slump, and setting times. Citric acid and a phosphonic acid-based admixture were tested as retarders for different concrete mixtures. Three studies were performed. In the slump study five different water …

Seismic Loading Effects Within Orthogonally Connected Steel Lateral Force Resisting Systems, Alhussin Faraj Aliwan

Graduate Theses and Dissertations

Steel buildings located within seismically active regions require special design considerations to ensure public safety and prevent collapse during an extreme seismic event. Two commonly used steel systems are special moment frames (SMFs) and buckling-restrained braced frames (BRBFs). When two seismic systems share a common column in an orthogonal configuration (such as at a building corner), design specifications currently consider a 100+30 rule wherein the shared column is designed for 100% fuse demand in one direction, plus 30% fuse demand from the other direction. While this rule has been shown to be reasonable for elastic building response, a few studies …

Mechanical And Frictional Behavior Of Textured And Non-Textured Surfaces, Raghuram R. Santhapuram

Graduate Theses and Dissertations

Tribology is the study of surfaces where two objects are sliding against another. Significant energy is lost due to friction between the sliding surfaces. Therefore, developing or designing surfaces to minimize friction is critical for the durability and reliability of the mechanical components. Several researchers have identified that surface texturing at the nanoscale (nanotexture) would reduce the friction between the contacting surfaces. The nanotextured surfaces have several applications in microelectromechanical systems and nanoelectromechanical systems. This dissertation employs molecular dynamics simulations to investigate the frictional and mechanical response of nanotextured aluminum (Al) and Al/amorphous silicon (a-Si) composite surfaces.

This study determines …

Numerical Simulations Of Directed Self-Assembly Methods In Di-Block Copolymer Films For Efficient Manufacturing Of Nanoscale Patterns With Long-Range Order, Joseph Hill

Graduate Theses and Dissertations

Directed self-assembly (DSA) of block copolymers (BCPs) has been shown as a viable method to achieve bulk fabrication of surface patterns with feature sizes smaller than those available through traditional photolithography. Under appropriate thermodynamic conditions, BCPs will self-assemble into ordered micro-domain morphologies, a desirable feature for many applications. One of the primary interests in this field of research is the application of thin-film BCPs to existing photolithography techniques. This “bottom-up” approach utilizes the self-assembled BCP nanostructures as a sacrificial templating layer in the lithographic process.

While self-assembly occurs spontaneously, extending orientational uniformity over centimeter-length scales remains a critical challenge. A …

Conditional Distance Correlation Test For Gene Expression Level, Dna Methylation Level And Copy Number, Shanshan Zhang

Graduate Theses and Dissertations

Over the past years, efforts have been devoted to the genome-wide analysis of genetic and epigenetic profiles to better understand the underlying biological mechanisms of complex diseases such as cancer. It is of great importance to unravel the complex dependence structure between biological factors, and many conditional dependence tests have been developed to meet this need. The traditional partial correlation method can only capture the linear partial correlation, but not the nonlinear correlation. To overcome this limitation, we propose to use the innovative conditional distance correlation (CDC), which measures the conditional dependence between random vectors and detect nonlinear relations. In …

Development And Characterization Of Metal Contacts For Graded Composition Ingan Solar Cells, Reem E. Alhelais

Graduate Theses and Dissertations

There is an increasing demand for high-power electronic components and optoelectronic devices with low-loss and high efficiency. III-nitride semiconductor materials have demonstrated great potential for high-power, high-frequency, and high-temperature applications because of their remarkable and wide-ranging electronic and physical properties. These material systems, including alloys of AlN, GaN, and InN, are currently being explored for their potential to develop efficient photovoltaic cells. They can potentially achieve higher efficiency because of their very high direct wide band edge, absorption coefficients, and resistance to defects. The compositionally graded Group III-nitride alloy allows access to a large range of energies by varying the …

Predicting The Hydration Free Energy Of Small Alkanes And Alcohols From Custom, Electronic Structure-Based Force Fields, T. Ryan Rogers

Graduate Theses and Dissertations

Mathematical theories reveal the fundamental physics involved in experimentalphenomena. Computer models of such theories are routinely used to corroborate or explain experiments and predict properties of chemical systems. Therefore, an important effort in computational chemistry is the development of more accurate and efficient chemical models. Current-generation models are only beginning to approach experimental-quality predictions of hydration free energies (HFEs).Using computations of quantum mechanical (QM) forces and classical simulations based on these forces, I investigate models to predict several properties of solutes and solutions. This dissertation is a collection of projects exemplifying methods used to gain insight into chemical systems.

Simulations …

Optical Properties Of Ultrathin In(Ga)As/Gaas And In(Ga)N/Gan Quantum Wells, Yurii Maidaniuk

Graduate Theses and Dissertations

Recently, structures based on ultrathin quantum wells (QWs) began to play a critical role in modern devices, such as lasers, solar cells, infrared photodetectors, and light-emitting diodes. However, due to the lack of understanding of the formation mechanism of ultrathin QWs during the capping process, scientists and engineers cannot fully explore the potential of such structures. This study aims to investigate how structural parameters of ultrathin QWs affect their emission properties by conducting a systematic analysis of the optical properties of In(Ga)As/GaAs and In(Ga)N/GaN ultrathin QWs. Specifically, the analysis involved photoluminescence measurements combined with effective bandgap simulation, x-ray diffraction, and …

Fractional Order Identification Method And Control: Development Of Control For Non-Minimum Phase Fractional Order System, Majid Abdullah Alhomim

Graduate Theses and Dissertations

The increasing use of renewable energy has resulted in the need for improved a dc-dc converters. This type of electronic-based equipment is needed to interface the dc voltages normally encountered with solar arrays and battery systems to voltage levels suitable for connecting three phase inverters to distribution level networks. As grid-connected solar power levels continue to increase, there is a corresponding need for improved modeling and control of power electronic converters. In particular, higher levels of boost ratios are needed to connect low voltage circuits (less than 1000 V) to medium voltage levels in the range of 13 kV to …

Culturally Responsive Science Education And Teaching: Current Literature, Preservice Elementary Science Teachers And Lesson Planning, Lundon Pinneo

Graduate Theses and Dissertations

First, a meta-analysis of Culturally Responsive (CR) science teaching characteristics and practices was conducted. Findings revealed that there are a limited number of CR teaching studies at the elementary science level. When studies conducted at the middle, secondary and postsecondary level were included, six themes which encompassed the characteristics and pedagogical practices of effective CR science teachers and teacher development emerged. These themes were academics, cultural competency, social inequities, CR learning environment, rejection of the deficit lens and pedagogical strategies.

Next, the impact of curriculum and practices designed to reflect these six themes on preservice elementary science teachers was explored. …

A Mixed-Methods Analysis Of Biofuels, Teresa Cristina Garcia

Graduate Theses and Dissertations

Brazil has the largest sugarcane acreage in the world (FAOSTAT, 2020) and is the world leader in the production of sugarcane-based ethanol (Sousa Junior et al., 2017). Due to the technical experience in the production of biofuels and the availability of sugarcane straw and bagasse, the country has a great potential to commercially produce second-generation ethanol (E2G) (Nyko et. al., 2010). In 2017, Brazil enacted a new National Biofuels Policy, called RenovaBio, to expand the production and use of biofuels in the country. This dissertation combines three essays that explore biofuels law and policy with a special focus on Brazil. …

Development Of An Effect Size To Classify The Magnitude Of Dif In Dichotomous And Polytomous Items, James D. Weese

Graduate Theses and Dissertations

A standardized effect size for the SIBTEST/POLYSIBTEST procedure is proposed, allowing for Differential Item Functioning (DIF) to be classified with a single set of DIF heuristics regardless of whether data are dichotomous or polytomous. This proposed standardized effect size accounts for both variability in responses and whether participants are included in the SIBTEST/POLYSIBTEST calculations. First, a new set of unstandardized effect size heuristics are established for dichotomous data that are more aligned with Educational Testing Service (ETS) standards using two and three parameter logistic (2PL and 3PL) models. Second, a standardized effect size is proposed and compared to other DIF …

Fourier Transform Infrared Spectroscopy For The Measurement Of Gesn/(Si)Gesn, Solomon Opeyemi Ojo

Graduate Theses and Dissertations

Photoluminescence (PL) and Electroluminescence (EL) characterization techniques are important tools for studying the optical and electrical properties of (Si)GeSn. Light emission from these PL and EL measurements provides relevant information on material quality, bandgap energy, current density, and device efficiency. Prior to this work, the in-house PL set-up of this lab which involves the use of a commercially-obtained dispersive spectrometer was used for characterizing both GeSn thin film and fabricated devices, but these measurements were limited by issues bordering on low spectral resolution, spectral artifacts, and poor signal-to-noise ratio (SNR) thereby resulting in the possible loss of vital information and …

Association Mapping For Soybean (Glycine Max L. Merr.) Protein And Oil Content, Joseph Najjar

Graduate Theses and Dissertations

Soybean [Glycine Max (L.) Merrill] is an important economic crop because of its high content of seed protein and oil. Seed oil and protein content are quantitative inherited traits. The genetics of seed protein and oil levels have been extensively studied, with 367 QTL reported for protein and 475 QTL reported for oil to date. Validation of such QTLs, and identification of easily-automatable molecular markers around these QTL will aid the progression of breeding for such traits. The focus of this research was to discover novel and verify previously reported QTL related to protein and/or oil content via Genome-Wide Association …

Applications Of Cathodoluminescence In Plasmonic Nanostructures And Ultrathin Inas Quantum Layers, Qigeng Yan

Graduate Theses and Dissertations

Due to the advanced focusing ability, characterization methods based on the electron-beam excitation have been broadly applied to investigate nanomaterials. Structural or compositional information is commonly acquired using electron microscopes. Moreover, taking advantage of the super spatial resolution of the focused electron beam, optical properties of nanomaterials can be also obtained. Herein, general concepts and processes of the interaction between electrons and materials are studied. Two specific optical nanomaterials, including plasmonic nanostructures and semiconductor quantum layers, are investigated by the cathodoluminescence (CL) measurement.

Surface plasmonic resonance can be generated when high-energy electrons strike the interface between the dielectric medium and …

Framework Grain Composition And Texture Of The Wedington Sandstone Member, Fayetteville Shale, As A Provenance And Sediment Dispersal Indicator For Clastic Depositional Systems Across The Northern Arkansas Structural Platform During The Late Mississippian, Tanner Wayne Corbin

Graduate Theses and Dissertations

The Wedington Sandstone Member of the Fayetteville Shale is a constructive delta complex in the Chesterian section of the Late Mississippian record in Northwest Arkansas. A comparative analysis of framework grain composition between the Wedington and two other stratigraphically proximal Carboniferous sandstones: the Batesville Sandstone (older) and the Basal Atoka-Spiro Sandstone (younger) has addressed three questions: 1) Is there similarity in sediment provenance for the three sandstones? 2) Do these three sandstone units have a similar sediment dispersal vector? 3) What are likely sediment source terrains for the Wedington Sandstone? Wedington samples overwhelmingly plot as quartzarenites with fewer samples plotting …

Seismic Expressions Of Paleokarst, Olanrewaju Ayodapo Aboaba

Graduate Theses and Dissertations

Paleokarst are characterized by epigene and/or hypogene processes in their formation and hold significant numbers of hydrocarbons and other natural resources. This dissertation examines worldwide seismic expression of paleokarst; and specifically, the characterization of paleokarst reservoirs developed across the Cherokee Platform, and in the Arkoma Basin, Oklahoma.

Worldwide subsurface paleokarst formations are of Precambrian to Miocene age and found at depths less than 200 m to as great as 8000 m. Karst can be are expressed on seismic records as sinkholes, paleocave collapse, and tower morphologies. Seismic modeling indicates that karst can be modeled and imaged to better understand its …

Ppmexplorer: Using Information Retrieval, Computer Vision And Transfer Learning Methods To Index And Explore Images Of Pompeii, Cindy Roullet

Graduate Theses and Dissertations

In this dissertation, we present and analyze the technology used in the making of PPMExplorer: Search, Find, and Explore Pompeii. PPMExplorer is a software tool made with data extracted from the Pompei: Pitture e Mosaic (PPM) volumes. PPM is a valuable set of volumes containing 20,000 historical annotated images of the archaeological site of Pompeii, Italy accompanied by extensive captions. We transformed the volumes from paper, to digital, to searchable. PPMExplorer enables archaeologist researchers to conduct and check hypotheses on historical findings. We present a theory that such a concept is possible by leveraging computer generated correlations between artifacts using …

Stability Of Group Four Monochalcogenides In Water And Air, William Shattuck

Graduate Theses and Dissertations

Previously published works have simulated the behavior of monolayer group IV monochalcogenides and predicted them to have very useful electronic properties. These simulations have also predicted that monolayers of group IV monochalcogenides will degrade quickly when exposed to water, even in extremely low concentrations. We hypothesize that thin samples of these materials will show signs of degradation if left in air and in water for an extended period of time.

Samples of each of the four monochalcogenides (GeS, GeSe, SnS and SnSe) were exfoliated onto clean oxidized silicon substrates. Chemical analysis showed the SnSe samples were contaminated, so they were …

Rice Chilling Aeration: Assessment Of Impacts On Grain Quality, Process Modeling And Validation, Soraya Shafiekhani

Graduate Theses and Dissertations

The goal of this study is to demonstrate the effectiveness of applying chilling temperatures during on-farm, in-bin drying and storage to maintain rice quality. Specific objectives include to demonstrate the effectiveness of chilling aeration to preserve rice quality characteristics, determine the drying kinetics of rice under low temperature environments, and develop models to predict heat and mass transfer in rice kernel during drying at low temperature environment. To date, there is limited research describing storability or drying behavior of rice in chilled environments. However, it is understood that chilling of high-moisture, > 21% wet basis rough rice could reduce the time …

Robust Control Of A Multi-Phase Interleaved Boost Converter For Photovoltaic Application Using Μ-Synthesis Approach, Badur Mueedh Alharbi

Graduate Theses and Dissertations

The high demand of energy efficiency has led to the development power converter topologies and control system designs within the field of power electronics. Recent advances of interleaved boost converters have showed improved features between the power conversion topologies in several aspects, including power quality, efficiency, sustainability and reliability.

Interleaved boost converter with multi-phase technique for PV system is an attractive area for distributed power generation. During load variation or power supply changes due to the weather changes the output voltage requires a robust control to maintain stable and perform robustness.

Connecting converters in series and parallel have the advantages …