Digital Commons Network^™

Novel Atomic Layer Deposition Processes Of Silver For Battery Applications, Darlington Ehijie Imhanzuaria

Graduate Theses and Dissertations

This thesis presents a novel approach to enhance the performance and stability of anode-free lithium-ion batteries (AFLBs) by employing atomic layer deposition (ALD) to coat copper (Cu) current collectors with a silver-aluminum oxide (AgAlO_x) layer. Leveraging the unique capabilities of ALD for precise and conformal deposition, the AgAlO_x coating was achieved using triethyl phosphine-(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)-silver(I) (Ag(fod)(PEt₃)), trimethylaluminum (TMA), and de-ionized water (H₂O) as precursors. This innovative coating method significantly enhanced the cycling stability and Coulombic efficiency (CE) of both Li||Cu and Cu||NMC811 cells, as evidenced by improved electrochemical performance metrics. The AgAlO_x layer …

Sample Archival System For Quantum Device Manufacturing: Design, Construction, And Integration, Corbin Russ

Graduate Theses and Dissertations

In the manufacturing of quantum devices using 2-dimentional (2D) materials, current processes rely on manual operations of production. MonArk Quantum Foundry is developing a facility to semi-automatically, and ultimately automatically, produce 2D materials. One crucial step in the experimentation process is archiving these materials and completed chips for future access. The sample archival system robot was produced to fulfill this need. The system is a 4 Degree-of-freedom (DOF) cartesian storage system that stores custom aluminum chip trays of sixty samples, having a total storage capacity of 14,400 samples. The sample archive system meets key goals from: it integrates with the …

An Analytical Evaluation Of Economic Geography Within Maine And Its Resource Industries: 1600 To Present, Maureen Mantooth

Graduate Theses and Dissertations

Resource peripheries represent a fringe area within economic geography, originating from the core-periphery theory developed by Friedmann and Miller. This concept has evolved to address global and regional contexts, referring to marginalized regions that rely heavily on the extraction and export of natural resources. By studying these regions, we gain a deeper understanding of critical components in global economic systems. This dissertation focuses on Maine as a case study of a resource periphery, using the framework proposed by Hayter et al. (2003) within the broader regional contexts of New England and the United States. Key factors explored include resource exploitation, …

Laughing Tiger, Michael Shum

Graduate Theses and Dissertations

Laughing Tiger is the title of my thesis exhibition/paper, as well as the middle name I was gifted with. The relationship I have with this name has changed throughout my life. At one point, this name was more a reminder of being different, but now it is a personal symbol I take pride in. My name is Michael Laughing Tiger Shum, and I make inventive autobiographical paintings about the relationships we invest in, whether it’s with others, objects, rituals, environments, and so on. I have broken down my painting practice into three main themes, which are actions, experiences, and thoughts. …

Mandatory Bliss, Jocelyn Reid

Graduate Theses and Dissertations

Mandatory Bliss is an exhibition of sculptural objects that discuss value, feminism, material hierarchy, and societal expectation. Using mundane structures and objects, this installation aims to frustrate and dissect the significance of the tangible items that we interact with every day.

Mindful Symbiotic Ecosystems. Designing For Women In Remote Workspaces, Andrea Guevara Araujo

Graduate Theses and Dissertations

Women represent 61% of designers in the workforce but hold only 29% of leadership roles. This disparity highlights a critical need for an ecosystem that removes barriers and cultivates mentorship, community, and leadership among women (Bolt, 2020). Even though women have proven their ability to succeed in male-dominated corporate cultures, the real question is not about capability but sustainability. Driven by overwork, competition, and burnout, the workplace does not just push women out; it leads to long-term instability for the entire organization (Krivkovich et al., 2024). In the workplace, a culture of masculinity reinforces harmful, outdated mindsets and glorifies aggressive, …

Public Comment: Using Critique-Like Mediating Artifacts To Democratize Discourse At City Council Meetings, Piper Schuerman

Graduate Theses and Dissertations

Are local governments designed for equitable citizen participation? While civic engagement aims to empower citizens and support representative governance, barriers to participation can hinder those outcomes. City council meetings, key venues for public input, pose specific challenges such as long durations, dense content, and intimidating formalities. These issues disproportionately affect Generation Z (born between 1997 and 2012), who frequently report feeling underinformed or having limited time to engage. This thesis explores how city council meetings might use multimodal mediating artifacts, inspired by design critique practices, to make public discourse more accessible for Gen Z adults.

Grounded in activity theory and …

Using Scaffolding, Gamification, And Self Awareness To Create Responsive Ux/Ui In Cad Software To Nurture Metacognition In Novice Users, Obed Ibrahim Gonzalez

Graduate Theses and Dissertations

Computer-aided Design (CAD) software represents a significant shift from manual and analog design processes to digital workflows, offering substantial utility, accuracy, and productivity benefits. However, CAD software often presents a steep learning curve, particularly for novice users who are new to the software or possess only basic knowledge. Traditional CAD curricula have predominantly focused on technical problem-solving—teaching tools and systems—while often neglecting strategic knowledge that encompasses reflection, planning, and refining, which are essential components of metacognition. Metacognition is crucial for transforming novices into experts who use fewer and more complex commands, employ sophisticated planning, and achieve their goals more efficiently. …

Development And Investigation Of A Novel Near-Wall Methodology For Large-Eddy Simulation Based On Dynamic Hybrid Rans-Les, Michael Tullis

Graduate Theses and Dissertations

The use of computational fluid dynamics (CFD) to test engineering designs with reduced cost and time compared to physical testing has become increasingly common in a range of industries and research fields. While numerical methods exist that can accurately solve the equations that govern the flow of fluids, these methods are computationally expensive for practical engineering problems due to the large amount of computational power needed to resolve the fluid flow over the entire range of length and time scales. Several different approaches have been introduced to address this computational cost issue, namely Reynolds-averaged Navier-Stokes (RANS) modeling and scale resolving …

A Living House Never Stands Still, Holly Rose Kranker

Graduate Theses and Dissertations

A Living House Never Stands Still is an exhibition that explores the interplay between place, memory, and the suspension of time through diverse mediums and materials. I engage with seemingly mundane objects, interpreting them through a non-linear, dream-like, and irrational framework to unearth latent connections across time–past, present, and future. Central to these explorations is the concept of home—not merely as a physical location, but as an evolving entity. Home is a sacred space for me.

My recent studio reflections are focused on the lifecycle of objects, the emotional responses they evoke, and how these cycles emulate the human body …

Mechanical Properties And Microstructural Characteristics Of Hydrated Bcsa Cement At Extreme Temperatures, Behzad Farivar

Graduate Theses and Dissertations

Belitic Calcium Sulfoaluminate (BCSA) cement is an alternative binder known for its rapid setting and high early strength, making it ideal for applications such as fast-track construction and repair. This study presents a comprehensive investigation into the behavior of BCSA cement under a wide range of curing temperatures, with emphasis on early-age strength development, admixture effects, and the use of the maturity method for strength prediction.

The research evaluates BCSA cement performance in both hot and cold environments, ranging from approximately -28.9 °C (-20°F) to 49 °C (120°F). In warm climates, citric acid was used as a set retarder to …

Latent Variable Dyadic Regression Models For Predicting Over/Under Bets In Sports Betting, Alexcia Trejo

Graduate Theses and Dissertations

This thesis explores the use of latent factor models to uncover hidden structures in pair wise outcomes derived from Over/Under betting markets in sports betting. Specifically, we implement and evaluate the Eigen model, a latent space model that represents dyadic data using node-specific vectors whose inner product govern edge probabilities. By modeling relationships between teams as adjacency matrices of binary outcomes, we investigate the extent to which the Eigen model captures both homophily, the tendency of similar teams to yield consistent betting results, and stochastic equivalence, where different teams exhibit indistinguishable patterns of Over/Under outcomes. A Bayesian formulation of the …

Experimental Study Of Novel Bcsa Scc Repair Materials And Implications On Corrosion In Bcsa Concrete Structures, Elizabeth S.M. Poblete

Graduate Theses and Dissertations

Some current building codes for structural concrete allow the use of alternative cement concrete if their structural, durability, and fire performance can be shown to be comparable to portland cement (PC) concrete. One such alternative cement, belitic calcium sulfoaluminate (BCSA) cement, is a promising standalone replacement for portland cement given its lower global warming potential (GWP), fast setting time, and high early age compressive strength. These properties also make it an ideal repair material. But repair materials often need to be highly flowable and easy to consolidate and their performance when used to repair PC concrete structures must be understood. …

Leveraging Natural Variation In Yeast To Understand Susceptibility Differences In Parkinson’S Disease, Julio Andres Molina Pineda

Graduate Theses and Dissertations

Parkinson’s Disease (PD) is a neurodegenerative disorder that causes countless suffering around the world. Both forms, familial and sporadic, have been associated with the misfolding and cytotoxicity of α-synuclein, an otherwise non-pathogenic protein suspected to have various roles in the normal maintenance of the central nervous system. Model organisms have emerged as great vessels to uncover the cellular and molecular mechanisms that shape α-syn biology, and great strides have been made to understand it. Yet, it is still unclear why some individuals are affected by α-syn toxicity, while others not so much. Since it’s extremely complicated to study and probe …

Constraining Neutron Star Kicks Through Gravitational Wave Detection, James Phillips

Graduate Theses and Dissertations

Neutron stars have, on average, much higher proper motions than those of hot and bright O and B type main sequence stars. Thus, it is widely suspected that asymmetries in core-collapse supernovae provide a substantial kick to these compact objects at birth. Gen- eral Relativity predicts that such supernova asymmetries will generate bursts of gravitational radiation, though no such burst has been yet detected. Here we argue that the polarization amplitudes of those gravitational waves can be used to calculate the kicks imparted on that nascent neutron star. We begin by reviewing the evidence for natal kicks, then we describe …

Synthesis And X-Ray Characterization Of Nickel Phosphide Nanostructures For Water Oxidation, David Thompson

Graduate Theses and Dissertations

The pursuit of earth-abundant 3d transition metal catalysts for alkaline water electrolysis remains an active area of research. While NiFe layered double hydroxides (LDH) are currently the most active catalysts for the oxygen evolution reaction (OER), doping Ni-based catalysts with phosphorus to form Ni metal phosphides has emerged as a promising alternative. However, the complex crystalline and amorphous phases of NiP_x have hindered their characterization, and the OER mechanism and origin of activity remain unclear. This dissertation aims to elucidate the synthesis, OER performance, and in situ reconstruction of amorphous NiP_x-based nanomaterials, with a focus on in …

Parole Predictions: Estimating The Likelihood A Humanitarian Parole Group Will Receive A Status Adjustment, Amethyst Osborne

Graduate Theses and Dissertations

Humanitarian parole is an immigration policy that allows paroled individuals to enter or remain in the United States temporarily. The standard pathway for parolees to gain legal permanent residency (LPR) is limited by a number of requirements and restrictions, i.e., sponsorship from a family member or employer is usually required. However, in some instances, laws have been passed that grant an automatic adjustment to LPR status for select groups of parolees. This study is intended to investigate the circumstances that lead some groups to receive a status adjustment while other groups are denied a dedicated pathway to legal permanent residency. …

Sibling Groups And Family Adaptability And Cohesion Among Emerging Adult Women, Julianne M. Post

Graduate Theses and Dissertations

This study examined how sibling group size is related to family adaptability, cohesion, and individual resiliency outcomes during emerging adulthood. Using Bowen's Family Systems Theory and Olson's Circumplex Model, the research investigates sibling subsystems as sites where systemic imbalances are first experienced within families. Data from 124 college students revealed that larger sibling groups were associated with marginally higher disengagement and chaos resulting in decreased perceived social support, suggesting resiliency implications for youth growing up within larger families. While sibling size didn't directly predict mental health, family dynamics significantly mediated the relationship between sibling composition and resiliency outcomes. Demographic factors …

Effects Of Cholesterol Concentration On Liposome And Proteoliposome Behavior, Ehsaneh Khodadadi

Graduate Theses and Dissertations

Cholesterol is crucial in modulating the behavior and characteristics of biological membranes, liposomes, and proteoliposomes, for instance in drug delivery applications. Cholesterol regulates membrane stability by influencing lipid density, phase separation, and protein-membrane interactions. In planar bilayers, cholesterol enhances membrane thickness, reduces permeability, and promotes lipid ordering, adding rigidity and fluidity. Cholesterol also modulates membrane curvature in curved bilayers and vesicles, stabilizing low-curvature regions. In this work, all-atom molecular dynamics (MD) simulations were employed to examine how varying cholesterol concentrations influence the structure and dynamics of membranes, focusing on planar and curved geometries. Bilayers with cholesterol molar ratios of 0%, …

Exploring 2slgbtqia+ Parenting In Northwest Arkansas, Bailey Mason

Graduate Theses and Dissertations

Since the U.S. Census Bureau first published data on “same-sex” households in 2011, research has repeatedly indicated the majority of 2SLGBTQIA+ parents (here on referred to as “queer parents”) reside outside of major cities in heavily populated regions of the country. However, due to widespread metronormative narratives about the queer experience, the experiences of queer parents in less-populated regions are rarely studied. This qualitative study explores the lived experiences of queer parents in Northwest Arkansas, a region of the politically and religiously conservative Southern U.S. with areas both urban and rural. Applying grounded theory and drawing from queer theory to …

Crispy Not Risky: Effects Of Environmental Conditions On Low-Moisture Food Persistent Bacterial Pathogens, Manita Adhikari

Graduate Theses and Dissertations

Low-moisture foods (LMFs) were not historically seen as safety risks due to their ability to inhibit pathogen growth, but evidence shows pathogens can survive in LMFs long-term, causing outbreaks and recalls. Previous studies have lacked the ability to replicate real-world contamination scenarios in LMF processing environments. This research aimed to develop inoculation methods to form LMF persistent bacterial populations (LMF PBPs) and assess pathogen responses to environmental factors, culturing methods (broth vs. lawn), and matrix type and ratio. Inoculation methods tested were “direct” (combining bacterial culture and powder on a stainless-steel coupon) and “slurry” (premixing culture and powder). Matrices included …

Using Deep Learning And Two-Photon Excitation Fluorescence Microscopy To Predict Breast Cancer Recurrence And Response To Chemotherapy, Nicholas Powell

Graduate Theses and Dissertations

Accurate prediction of breast cancer recurrence plays a critical role in guiding treatment decisions, particularly regarding the use of systemic therapy for patients. While genomic assays such as the Oncotype DX Recurrence Score offer valuable prognostic information, they are limited in accessibility and application. The work presented in this thesis explores an imaging-based approach for the prediction of breast cancer recurrence that combines multiphoton microscopy (MPM) with deep learning to classify individual breast cancer biopsy samples by risk of recurrence. Genomic differences in tumors with different recurrence potentials may translate to distinct optical and structural information that can be captured …

Exploring Hybrid Cohort-Based Doctoral Program Features That Support Nontraditional Doctoral Students’ Persistence: A Preregistered Case Study., Glenda Winborn

Graduate Theses and Dissertations

With the rise of hybrid learning models, non-traditional learners have greater access to doctoral education. However, attrition rates from doctoral programs remain high, ranging from 40% to 50% across all doctoral programs and exceeding these levels in online non-traditional programs. Numerous causes of attrition or persistence in doctoral studies have been researched and can affect the student, the academic institution, and the broader academic society. This qualitative case study will explore adult and lifelong learning doctoral students' perceptions of the programmatic and instructional support resources that have helped improve persistence in their program. Two of the important programmatic features of …

Community Perceptions Of A Crisis Response Collaboration: A Community Survey Of Attitudes Towards Police And The Crisis Intervention Response Team., Meghan Anspach

Graduate Theses and Dissertations

This thesis examined community perceptions of the Fayetteville Police Department (FPD) and its Crisis Intervention Response Team (CIRT), focusing on how racial minorities and individuals from lower socioeconomic status (SES) backgrounds view these professionals and their roles in crisis situations. The research also aimed to determine whether perceptions of the collaborative effort through CIRT influenced views of the FPD. Previous research has explored perceptions of police, social workers, and co-response teams individually, but a gap remains in understanding how community members feel about the collaboration between police and social workers and whether these perceptions influence their views of the police. …

Trends In Prenatal Care Utilization, 2014-2022: The Role Of Race And Ethnicity, Sidney Bigham

Graduate Theses and Dissertations

The United States has made significant advancements in healthcare, yet maternal mortality rates continue to rise, with pronounced racial and ethnic disparities in prenatal care (PNC) utilization. The current study examines PNC trends from 2014 to 2022 using data from the CDC WONDER Natality database, focusing on disparities across racial and ethnic groups and the impact of the COVID-19 pandemic. Findings reveal a concerning decline in PNC utilization, with average visits decreasing from 11.24 in 2014 to 10.96 in 2022. Persistent racial disparities are evident, as Non-Hispanic Black and Hispanic women consistently receive fewer PNC visits compared to Non-Hispanic White …

Polyphenol-Protein Interactions In Pigmented Cereals – A Clean-Label Approach To Tailor Starch Viscosity, Annegret Jannasch

Graduate Theses and Dissertations

Viscosity plays an important role in the food industry as it affects the quality, processing stability, and shelf-life of food and impacts physiological responses such as satiation and satiety. Greater viscosity reduces food intake by increasing the perception of satiety, primarily by delaying gastric emptying and increasing tactile stimulation. Starch is commonly added to food products as a viscosifying ingredient, which often involves chemically modifying the starch via cross-linking, to enhance its resistance to high shear, temperature and acidity. However, chemically modified starches are not “clean-label” ingredients due to the use of toxic chemicals. Therefore, further exploration is needed to …

Quantifying The Effects Of Urbanization On Stream Nutrient Loads And Decomposition, Caroline Anscombe

Graduate Theses and Dissertations

Urban stream syndrome (USS) refers to the common symptoms of degradation in urban streams globally. Two symptoms of USS are increased nutrient and salt concentrations in streams, affecting ecosystem structure and function. Excess nutrients negatively impact freshwater ecosystems, placing downstream habitats at risk of eutrophication and harmful algal blooms. Excess salt runoff, derived from road salt application, is toxic to freshwater organisms and affects leaf litter decomposition, the base of aquatic food webs. Here, I aimed to quantify the effects of nutrient pollution and salinization on urban water quality and ecosystem function. Despite the widespread consequences of nutrient pollution, most …

Evaluation Of Fluridone In Rice, Maria Carolina De Carvalho Rocha Souza

Graduate Theses and Dissertations

The increasing pressure of Palmer amaranth [Amaranthus palmeri (S.) Watson] in rice (Oryza sativa L.) fields demands new chemical control options to manage this weed. The recent labeling of fluridone on this crop from the three-leaf rice stage offers an additional residual herbicide for battling Palmer amaranth; however, research is needed to evaluate its effectiveness and rice tolerance. Field experiments were conducted to evaluate Palmer amaranth control and rice tolerance to fluridone across different locations in Arkansas in 2022, 2023, and 2024. Preemergence (PRE) applications of fluridone at 168 g ai ha^⁻1; (1× label rate) and 336 …

Controls On Nutrient And Sediment Export In A Non-Perennial Agricultural Stream, Kathleen Cutting

Graduate Theses and Dissertations

Climate change is expected to increase flow variability and intermittency in streams, changing the magnitude and timing nutrient and sediment delivery. This may exacerbate water quality issues in agricultural landscapes, where nutrient and sediment inputs are often elevated. Elevated nutrients can drive eutrophication in downstream waterways, and excess sediment loss can decrease primary productivity. Non-perennial headwater streams are particularly vulnerable to the impacts of climate change and agriculture as they serve as key sites for nutrient cycling at the terrestrial-aquatic interface. Despite their importance, the interactive effects of agriculture and stream intermittency, as well as unpaved roads in rural watersheds …

Gene Expression And Transfection Of C15orf57 In Chicken Show Clear Correlation To The Function Of The Ap2 Complex, E. Ashton Magdich

Graduate Theses and Dissertations

Discovering the functions of functionally unknown genes has made a huge impact on biological understanding including poultry species. In this thesis, C15orf57 (or C5H15orf57, chicken chromosome 5 human ortholog H15 open reading frame 57), was studied to understand its genetic characteristics and function. Chapter one is literature reviews on annotation of genes, the gene information on C15orf57, the importance of characterizing unknown genes in the genome, and what is known now about C15orf57. The Chapter 2 is for the structural characterization of C15orf57, gene expression of C15orf57 in various organ tissues using the qPCR method and effect of overexpression of …