Digital Commons Network^™

Influence Of Ph And Acidic Side Chain Charges On The Behavior Of Designed Model Peptides In Lipid Bilayer Membranes, Venkatesan Rajagopalan

Graduate Theses and Dissertations

The molecular properties of transmembrane proteins and their interactions with lipids regulate biological function. Of particular interest are interfacial aromatic residues and charged residues in the core helix whose functions range from stabilizing the native structure to regulating ion channels. This dissertation addresses the pH dependence and influence of potentially negatively charged tyrosine, glutamic acid or aspartic acid side chains. We have employed GWALP23 (acetyl-GGALW5LALALALALALALW19LAGA-amide) as favorable host peptide framework. We have substituted W5 with Tyr (Y5GWALP23) and Leu residues with Glu (L12E, L14E or L16E) or Asp (L14D or L16D), and have incorporated specific 2H-labeled alanine residues within the …

Analysis Of Break-Points In Financial Time Series, Jean Remy Habimana

Graduate Theses and Dissertations

A time series is a set of random values collected at equal time intervals; this randomness makes these types of series not easy to predict because the structure of the series may change at any time. As discussed in previous research, the structure of time series may change at any time due to the change in mean and/or variance of the series. Consequently, based on this structure, it is wise not to assume that these series are stationary. This paper, discusses, a method of analyzing time series by considering the entire series non-stationary, assuming there is random change in unconditional …

Successful Secondary Agricultural Programs Outside The Classroom: A View Of Champions, Andrew Bolton

Graduate Theses and Dissertations

The purpose of this study was to study select secondary agricultural education programs and determine common traits among these programs which lead them to be successful in a number of different areas including: Career Development Events (CDE) winners, Leadership Development Events (LDE) winners, agricultural science fair winners, chapters of elected state FFA officers, proficiency award winners, national chapter awards, and state fair market show results. This study utilized a modified Delphi approach consisting of three rounds to reach consensus on the importance of traits related to successful SAE and FFA programs. Many traits were identified but the most important traits …

Coarse-Grained Simulations Of The Self-Assembly Of Dna-Linked Gold Nanoparticle Building Blocks, Charles Wrightsman Armistead

Graduate Theses and Dissertations

The self-assembly of nanoparticles (NPs) of varying shape, size, and composition for the purpose of constructing useful nanoassemblies with tailored properties remains challenging. Although progress has been made to design anisotropic building blocks that exhibit the required control for the precise placement of various NPs within a defined arrangement, there still exists obstacles in the technology to maximize the programmability in the self-assembly of NP building blocks. Currently, the self-assembly of nanostructures involves much experimental trial and error. Computational modeling is a possible approach that could be utilized to facilitate the purposeful design of the self-assembly of NP building blocks …

Safety Performance Prediction Of Large-Truck Drivers In The Transportation Industry, Emily Moneka Francis Xavier

Graduate Theses and Dissertations

The trucking industry and truck drivers play a key role in the United States commercial transportation sector. Accidents involving large trucks is one such big event that can cause huge problems to the driver, company, customer and other road users causing property damage and loss of life. The objective of this research is to concentrate on an individual transportation company and use their historical data to build models based on statistical and machine learning methods to predict accidents. The focus is to build models that has high accuracy and correctly predicts an accident. Logistic regression and penalized logistic regression models …

Examining Denitrification In Agricultural Ditch Sediments Vegetated With Rice Cutgrass (Leersia Oryzoides): Modeling Seasonal Variation Across Increasing Levels Of Nitrate Loading And Model Application To Pre-Existing Datasets, Shannon Lee Speir

Graduate Theses and Dissertations

Nitrogen (N) derived from fertilizer application in agricultural systems may contribute to significant environmental impacts, including eutrophication of fresh and coastal waters. Rice cutgrass (Leersia oryzoides) can significantly enhance denitrification potential in agricultural ditch sediments, but relationships with known drivers are not well understood. To address this, I examined effects of nitrate (NO3-) availability on dinitrogen gas (N2) and NO3- fluxes seasonally in Chapter 2. Denitrification rates were measured as N2 flux from intact vegetated sediment cores using Membrane Inlet Mass Spectrometry (MIMS). Michaelis-Menten models were developed from observations to mathematically describe N2 fluxes across the spring, summer, and fall …

The Impact Of Unions On Information Asymmetry, Caroline Burke

Graduate Theses and Dissertations

Prior literature documents a positive association between union power, calculated using industry-level union data, and information asymmetry. Prior literature also finds a mitigating effect from employee ownership on the negative association between union power and voluntary disclosure. Using a sample of company observations for fiscal years 2008 through 2010, I examine the effect of company-specific measures of employee unionization on market-based measures of information asymmetry (proxied for by insider trading activity, analyst following, and analyst dispersion). I also examine whether employee ownership impacts the effect of company-specific measures of employee unionization on my market-based measures of information asymmetry. I find …

Survey Of Nasal Mites (Acari: Rhinonyssidae, Ereynetidae, Turbinoptidae) In Birds From Three States In The United States, Alexis Danel Hilario Perez

Graduate Theses and Dissertations

Avian nasal mites are obligate endoparasites that spend their entire life in the respiratory system of birds. In North America, bird nasal mites are represented by different unrelated families in three different orders of mites: Rhinonyssidae (Mesostigmata), Ereynetidae (Prostigmata), and the Cytoditidae and Turbinoptidae (Astigmata). The most-diverse and most-abundant family of nasal mites is the Rhinonyssidae, in which mite species may have different levels of host specificity from host orders to families or even species level. Nasal mites in North America have been surveyed in different locations, such as studies ranging from the Gulf Coast of the US to Canada. …

Big Data And Organizational Impacts: A Study Of Big Data Ventures, Taha Havakhor

Graduate Theses and Dissertations

New information technology (IT) ventures are at the forefront of developing IT innovations. In spite of their importance in the advancement of IT and the unique risks of survival that distinguishes them from established firms, the organizational literature on IT has mostly overlooked new IT ventures. Specifically, Big Data industry is a context where new IT ventures actively change the landscape of IT innovations. However, less is known about the factors influencing the economic success of Big Data ventures (BDVs), as well as the established firms that invest in them. To shed light on these factors, three essays are designed …

Artificial Quantum Many-Body States In Complex Oxide Heterostructures At Two-Dimensional Limit, Xiaoran Liu

Graduate Theses and Dissertations

As the representative family of complex oxides, transition metal oxides, where the lattice,

charge, orbital and spin degrees of freedom are tightly coupled, have been at the forefront

of condensed matter physics for decades. With the advancement of state-of-the-art heteroepitaxial deposition techniques, it has been recognized that combining these oxides on the atomic scale, the interfacial region offers great opportunities to discover emergent phenomena and tune materials' functionality. However, there still lacks general guiding principles for experimentalists, following which one can design and fabricate artificial systems on demand. The main theme of this dissertation is to devise and propose some …

Automatic Assessment Of Environmental Hazards For Fall Prevention Using Smart-Cameras, Jeffrey Kutchka

Graduate Theses and Dissertations

As technology advances in the field of Computer Vision, new applications will emerge. One device that has emerged is the smart-camera, a camera attached to an embedded system that can perform routines a regular camera could not, such as object or event detection. In this thesis we describe a smart-camera system we designed, implemented, and evaluated for fall prevention monitoring of at-risk people while in bed, whether it be for a hospital patient, nursing home resident, or at home elderly resident. The camera will give a nurse or caregiver environmental awareness of the at-risk person and notify them when that …

Initiating Race: Fraternal Organizations, Racial Identity, And Public Discourse In American Culture, 1865-1917, John D. Treat

Graduate Theses and Dissertations

Drawing on ritual books, organizational records, newspaper accounts, and the data available from cemetery headstones and census records, this work argues that adult fraternal organizations were key to the formation of civic discourse in the United States from the years following the Civil War to World War I. It particularly analyzes the role of working-class white and African-American organizations in framing racial identity, arguing that white organizations gave up older, comprehensive ideas of citizenship for understandings of Americanism rooted in racism and nativism. Counterbalancing this development, now-forgotten African-American fraternal organizations were among the earliest advocates of Afrocentrism. These organizations, form …

Fleeing To Fault Zones: Incorporating Syrian Refugees Into Earthquake Risk Analysis Along The East Anatolian And Dead Sea Rift Fault Zones, Bradley Wilson

Graduate Theses and Dissertations

The influx of millions of Syrian refugees into Turkey has rapidly changed the population distribution along the Dead Sea Rift and East Anatolian Fault zones. In contrast to other countries in the Middle East where refugees are accommodated in camp environments, the majority of displaced individuals in Turkey are integrated into local cities, towns, and villages—placing stress on urban settings and increasing potential exposure to strong earthquake shaking. Yet, displaced populations are not traditionally captured in data sources used in earthquake risk analysis or loss estimations. Accordingly, this study presents a district-level analysis assessing the spatial overlap of earthquake hazards …

A Bifunctional Nanocomposites Based Electrochemical Biosensor For In-Field Detection Of Pathogenic Bacteria In Food, Meng Xu

Graduate Theses and Dissertations

This research focused on the application of electrochemical biosensors for the rapid detection of pathogenic bacteria, Escherichia coli O157:H7 and Salmonella Typhimurium, in foods. The possible presence of pathogenic bacteria in foods has always been a great threat to the wellbeing of people and the revenue of food companies. Therefore, the demand for rapid and sensitive methods to detect foodborne pathogens is growing. In this research, an impedimetric immunosensor was first developed for the rapid detection of E. coli O157:H7 and S. Typhimurium in foods. It was based on the techniques of immunomagnetic separation, enzyme labelling, and electrochemical impedance spectroscopy …

Quantitative Trait Loci Mapping, Genome-Wide Association Analysis, And Gene Expression Of Salt Tolerance In Soybean, Ailan Zeng

Graduate Theses and Dissertations

Salt stress is a common abiotic stress causing yield reduction in soybean. There are differential responses, namely tolerance (excluder) and intolerance (includer), among soybean germplasm. However, the genetic and physiological mechanism for salt tolerance is not clear. Identification of novel QTL for salt tolerance and genes that are differentially expressed under salt stress would help elucidate the salt tolerance mechanism and facilitate the development of salt tolerant cultivars through marker assisted selection (MAS). The objectives of this study were to identify new QTL or genes responsible for salt tolerance using three approaches: QTL mapping, association analysis, and RNA sequencing (RNA-seq). …

An Investigation Into Hybrid Models Of Mindreading: A Dual Type Theory Account, Alexandra Jewell

Graduate Theses and Dissertations

Mindreading, or attributing mental states to others, involves instances of simulation and theory; but there is controversy over which one of these methods is the primary, or default, mechanism. I propose that mindreading is a theory-based process, such that we utilize theory over simulation when both are available and reliable. To argue my position, I suggest that theory has been inaccurately portrayed in past discussion and that we possess two types: a connectionist network (tt1) and a traditional, conceptual folk-psychology (tt2). By dividing theory in this way, we can explain common phenomena of mindreading that other theory-based accounts do not …

Reasonableness And Clarity Of Tenure Expectations: Gender And Race Differences In Faculty Perceptions, Rodica Lisnic

Graduate Theses and Dissertations

This dissertation studies how higher education policies and practices can affect faculty retention and proposes changes that higher education institutions need to make to retain their faculty. Faculty assessment of reasonableness of tenure expectations is explored in the first manuscript and faculty perceptions of clarity of tenure expectations are explored in the second and third manuscripts. Job satisfaction data from a sample of 2438 tenure-track assistant professors at research universities is used.

The first manuscript investigates the reasonableness of tenure expectations as it relates to work-life balance. The focus is on whether women’s and men’s appraisal of departmental and institutional …

Relationship Among Genetic And Physiological Biomarkers, And Horse Characteristics, Casey Orr

Graduate Theses and Dissertations

The objective of this study was to evaluate relationships among genetic and physiological biomarkers and phenotypic characteristics in horses. Three breeds (Quarter Horse, Thoroughbreds, Miniatures), and five genes of interest (leptin, ghrelin, cytochrome P450, glucocorticoid receptor, and lactate dehydrogenase) were the basis of the investigation. Genomic DNA was extracted from buffy coat samples of Quarter Horses (n = 21), Thoroughbreds (n = 26), and Miniatures (n = 34). Data were analyzed using MIXED MODEL procedures of SAS, with the main effects of breed and SNP genotype. Horse was the experimental unit, and dependent variables were classified as physical, cell differentials, …

Soil And Plant Property Differences Among High-Yield Soybean Areas In Arkansas, Taylor Cass Adams

Graduate Theses and Dissertations

Continued achievement of soybean [Glycine max (L.) Merr.] yields greater than 6719 kg ha-1 (100 bu ac-1) will depend on decreasing the yield gap, which is contingent on gathering more information regarding the soil physical, chemical, and microbiological environment and the main plant factors contributing to high-yield soybean. Therefore, understanding the main factor differences between high- and average-yield areas may provide insight for making management decisions to increase yields. The objectives of this study were i) to evaluate the effects of region and soil depth on soil property differences between high- and average-soybean-yielding areas, ii) to determine which soil properties …

Leveling The Playing Field: Teacher Perception Of Integrated Stem, Engineering, And Engineering Practices, Bridgette Fincher

Graduate Theses and Dissertations

The purpose of this study was to describe the perceptions and approaches of 14 third-through-fifth grade Arkansan elementary teachers towards integrative engineering and engineering practices during 80 hours of integrated STEM professional development training in the summer and fall of 2014. This training was known as Project Flight. The purpose of the professional development was to learn integrated STEM content related to aviation and to write grade level curriculum units using Wiggins and McTighe’s Understanding by Design curriculum framework. The current study builds upon on the original research.

Using a mixed method exploratory, embedded QUAL[quan] case study design and a …

Preparedness To Counsel Transgender College Students: Perceptions Of College Mental Health Clinicians, Valerie G. Couture

Graduate Theses and Dissertations

The purpose of this study was to assess the perceived preparedness levels of college mental health clinicians to counsel transgender college students. Multicultural counseling competency is required of professional counselors and transgender individuals are considered to be part of the multicultural population. A survey was completed by college mental health counselors (N = 84) from across the United States. The results showed a moderate amount of preparedness overall with no significant differences based on years of counseling experience nor graduation from a CACREP accredited program. Results did show the participants believed they do have a professional duty to be knowledgeable …

Fitting Eyewitness Identification And Confidence To A Diffusion Model Of Processing, Brittany Nicole Race

Graduate Theses and Dissertations

It is necessary to better serve justice to understand the mechanisms behind eyewitness identification and reports of confidence. The material contained within attempt to fit eyewitness identification to a diffusion model of processing, RTCON (Ratcliff & Starns, 2009). Participants saw eight mock crime videos and were then tasked with using eight showups or eight lineups to identify the suspects within the video. Half of the presentations were target present and half were target absent. Additionally, participants were either presented with biased or unbiased instructions. Strangely, unbiased lineups led to higher hit rates which is contrary to most findings in the …

The Association Between Known Risk Factors For Type 2 Diabetes, And The Body Mass Index Of Diabetic Adults, Faten Ahmed Almubarak

Graduate Theses and Dissertations

Diabetes mellitus (DM) has been a major research topic in scientific health studies. Diabetes is a chronic condition in which blood glucose levels are chronically elevated to more than 7.0 mmol/l in fasting plasma glucose test. The most common form of diabetes is Type 2 (TD2M). The International Diabetes Federation (2015) estimated the number of DM cases worldwide to be 415 million people in 2015. This number is predicted to increase by the year 2040, to 642 million people. The purpose of this study was to use the National Health Interview Survey (NHIS) data to identify the risk factors for …

A Content Analysis Of Advertising On Children’S Television Networks, Demarius Davis

Graduate Theses and Dissertations

This content analysis study on licensed characters in advertising collected data in summer 2015 from three children’s cable networks: Cartoon Network, Disney Channel and Nickelodeon. Using Social cognitive theory and based on past research (Barcus, 1975; Atkin, 1976; Calcott & Lee, 1994; Stitt & Kunkel, 2008; LoDolce et al., 2013; Castonguay et al., 2013), the study examined whether the use of licensed characters and emotional appeals varied in advertising for healthy or unhealthy foods, mass media genre and the character’s gender. The study found licensed characters are more likely to be used to promote unhealthy foods, originate from movies and …

Role Of The Inner Shell Architecture On The Various Blinking States And Decay Dynamics Of Core-Shell And Core-Multishell Quantum Dots, Pooja Bajwa

Graduate Theses and Dissertations

Colloidal semiconductor nanocrystals (quantum dots, QDs) have received much attention in recent years due to their uniquely size-tunable properties leading to a number of promising applications. Some of their most popular applications include their use as fluorescent probes in biology, as electro-optical components and in photovoltaic devices. CdSe-based QDs are particularly important because of their ease of synthesis, high photoluminescence quantum yields (PL QYs) across the whole visible spectrum and their photostabilty. Shelling of core QDs is usually carried out to improve their optical properties, minimize outer environmental effects on their properties, and avoid toxic element exposure to the environment. …

Two Essays On Analytical Capabilities: Antecedents And Consequences, Rishikesh Jena

Graduate Theses and Dissertations

Although organizations are rapidly embracing business analytics (BA) to enhance organizational performance, only a small proportion have managed to build analytical capabilities. While BA continues to draw attention from academics and practitioners, theoretical understanding of antecedents and consequences of analytical capabilities remain limited and lack a systematic view. In order to address the research gap, the two essays investigate: (a) the impact of organization’s core information processing mechanisms and its impact on analytical capabilities, (b) the sequential approach to integration of IT-enabled business processes and its impact on analytical capabilities, and (c) network position and its impact on analytical capabilities. …

Query Theory Applications: Choice Experiments Under Oath, Attendance To Attributes, And Genetically Modified Food Labeling Policy, Nathan Paul Kemper

Graduate Theses and Dissertations

In recent years, there has been an intensifying campaign by some stakeholders regarding concern over genetically modified (GM) foods in the U.S. As a result, the issue of labeling has entered into the federal agenda. This research uses Query Theory to provide a deeper understanding of the demand for GM foods and the preferences for GM policy. Query theory is first applied to the formation of hypothetical bias in the estimation of consumers’ willingness-to-pay. To address this, the honesty oath is used as an ex-ante technique to reduce hypothetical bias.

Paper one using Query Theory in a discrete-choice experiment (DCE) …

Just In Time Assembly (Jita) - A Run Time Interpretation Approach For Achieving Productivity Of Creating Custom Accelerators In Fpgas, Sen Ma

Graduate Theses and Dissertations

The reconfigurable computing community has yet to be successful in allowing programmers to access FPGAs through traditional software development flows. Existing barriers that prevent programmers from using FPGAs include: 1) knowledge of hardware programming models, 2) the need to work within the vendor specific CAD tools and hardware synthesis. This thesis presents a series of published papers that explore different aspects of a new approach being developed to remove the barriers and enable programmers to compile accelerators on next generation reconfigurable manycore architectures. The approach is entitled Just In Time Assembly (JITA) of hardware accelerators. The approach has been defined …

Development Of A Pluto Chamber For Surface Simulations, Zachary Michael Mcmahon

Graduate Theses and Dissertations

In light of the exciting new discoveries being made by the New Horizons team, more data on Pluto is available than ever before. However, with the increase in recovered data, there is now a need for laboratory data to interpret it. Laboratory simulation of these conditions and subsequent testing of materials and samples therein is now possible and necessary to understand what has been observed. To do these simulations, a vessel that can achieve low temperatures and high vacuum is required. The scope of this work presented here was to design, build, and test a chamber that could perform these …

Removal Of Carboxylic Acids And Water From Pyrolysis Oil, George Alexander Marshall

Graduate Theses and Dissertations

Over 70% of the world’s energy consumption is provided by fossil fuels and with those reserves depleting at a fast rate, alternative energy sources or methods are needed to support the world’s energy needs. This research was done in an attempt to make it more economically feasible to produce fuel products, such as bio-diesel, from the upgrading of bio-oil obtained from the pyrolysis of biomass waste material such as sawdust. The high water and oxygenated compound content of bio-oil make it undesirable for fuel use; however, two methods involving surface modified commercial membranes were utilized in hopes of overcoming these …