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Chromium Oxides And Lithiated Chromium Oxides. Promising Cathode Materials For Secondary Lithium Batteries, Pankaj Arora, Dong Zhang, Branko N. Popov, Ralph E. White Jan 1998

Chromium Oxides And Lithiated Chromium Oxides. Promising Cathode Materials For Secondary Lithium Batteries, Pankaj Arora, Dong Zhang, Branko N. Popov, Ralph E. White

Faculty Publications

Chromium oxides and lithiated chromium oxides were synthesized by thermal decomposition of chromium trioxide (CrO3) at high temperatures and oxygen pressures. Synthesis temperature and pressure markedly affect the performance of these cathode materials. Higher pressures lead to a higher O/Cr ratio and fewer impurities in the final product. These materials are stable intercalation hosts for lithium, and exhibit a higher capacity than any of the prominent positive electrodes used in secondary lithium batteries. m-CrOx has a capacity of 255 mAh/g, while m-LiCrOx has a capacity of 210 mAh/g, during the first discharge. The average …

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First-Principles Determination Of Elastic Properties Of Casio3 Perovskite At Lower Mantle Pressures, Bijaya B. Karki, Jason Crain Jan 1998

First-Principles Determination Of Elastic Properties Of Casio3 Perovskite At Lower Mantle Pressures, Bijaya B. Karki, Jason Crain

Faculty Publications

We investigate the equation of state and elasticity of cubic CaSiO perovskite up to 140 GPa using the plane wave pseudopotential method within the local density approximation. The calculated equation of state parameters of the cubic phase are in excellent agreement with those from recent quasi-hydrostatic compression data and from all-electron linearized augmented plane wave calculations. We determine the elastic constant tensor of the mineral from the calculated stress-strain relations. The bulk modulus of CaSiO perovskite is similar to that of MgSiO perovskite, however, its shear modulus is much higher at pressures corresponding to the lower mantle. This suggests that …

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Compilation Techniques For Out-Of-Core Parallel Computations, M. Kandemir, A. Choudhary, J. Ramanujam, R. Bordawekar Jan 1998

Compilation Techniques For Out-Of-Core Parallel Computations, M. Kandemir, A. Choudhary, J. Ramanujam, R. Bordawekar

Faculty Publications

The difficulty of handling out-of-core data limits the performance of supercomputers as well as the potential of the parallel machines. Since writing an efficient out-of-core version of a program is a difficult task and virtual memory systems do not perform well on scientific computations, we believe that there is a clear need for compiler directed explicit I/O approach for out-of-core computations. In this paper, we first present an out-of-core compilation strategy based on a disk storage abstraction. Then, we offer a compiler algorithm to optimize locality of disk accesses in out-of-core codes by choosing a good combination of file layouts …

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Chaos, Complexity, And Coevolution: The Web Of Law, Management Theory, And Law Related Services At The Millennium, Thomas Geu Jan 1998

Chaos, Complexity, And Coevolution: The Web Of Law, Management Theory, And Law Related Services At The Millennium, Thomas Geu

Faculty Publications

No abstract provided.

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Cognitive Agents, Michael N. Huhns, Munindar P. Singh Jan 1998

Cognitive Agents, Michael N. Huhns, Munindar P. Singh

Faculty Publications

Several researchers have proposed using cognitive concepts as a semantic basis for agent communications (M.N. Huhns and M.P. Singh, 1997). One of the leading candidates for such a semantics is based on Arcol, the communication language used within Artimis. Interestingly, this application (not only of Arcol, but also in general) appears extremely misguided. The intentional concepts are well suited to designing agents, but are not suited to giving a basis to a public, standardizable view of communication. A challenge for using the cognitive concepts is that although they are natural in several respects and can guide implementations, full blown implementations …

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Personal Assistants, Michael N. Huhns, Munindar P. Singh Jan 1998

Personal Assistants, Michael N. Huhns, Munindar P. Singh

Faculty Publications

Already there are simple personal agents to help with some of our shopping. There are agents to track stocks in our portfolios, advise us on how to use particular software products, and arrange meetings within corporate workgroups. However, none of these agents takes more than one aspect of our activities into account, nor do they adapt easily to our preferences. Personal assistants, on the other hand, are agents that can represent individuals on the Web. They help users in their day-to-day activities, especially those involving information retrieval, negotiation, or coordination. A personal assistant might schedule a meeting and then, based …

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Workflow Agents, Michael N. Huhns, Munindar P. Singh Jan 1998

Workflow Agents, Michael N. Huhns, Munindar P. Singh

Faculty Publications

Software agents as user agents, resource agents, and brokers may be able to enhance usefulness of workflow applications. Workflow technology is important to network computing because workflows exist naturally wherever distributed resources are interrelated. The problem with current workflow technology is that it is often too rigid. The lack of freedom accorded to human participants causes workflow management systems to appear unfriendly. As a result, they are often ignored or circumvented. This rigidity also causes productivity losses by making it harder to accommodate the flexible, ad hoc reasoning of human intelligence. Another challenge is that system requirements are rarely static. …

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Anthropoid Agents, Michael N. Huhns, Munindar P. Singh Jan 1998

Anthropoid Agents, Michael N. Huhns, Munindar P. Singh

Faculty Publications

In the study of agents on the Internet, we often ascribe to them human qualities, such as beliefs and intentions. These qualities are best understood as metaphors that give developers a way to talk about and design the capabilities and applications of agents. Despite all the progress in computing, users have been slow to accept the technology. They have often accepted what was thrown at them, but only under economic duress. Bringing the technology closer to their emotional needs might ease this resistance. So how can we put a human face on computing? Maybe by putting an animated face on …

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Dominion, Dressing, Keeping, David Thomas Sumner Jan 1998

Dominion, Dressing, Keeping, David Thomas Sumner

Faculty Publications

In this essay, David Sumner uses his experiences rafting on the Colorado River to juxtapose the Biblical notions of "dressing and keeping" with ethical environmentalism.

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Sr‐ And Ni‐Doped Lacoo3 And Lafeo3 Perovskites: New Cathode Materials For Solid‐Oxide Fuel Cells, Kevin Huang, Hee Y. Lee, John B. Goodenough Jan 1998

Sr‐ And Ni‐Doped Lacoo3 And Lafeo3 Perovskites: New Cathode Materials For Solid‐Oxide Fuel Cells, Kevin Huang, Hee Y. Lee, John B. Goodenough

Faculty Publications

An improved cathode material for a solid‐oxide fuel cell would be a mixed electronic and oxide‐ion conductor with a good catalytic activity for oxygen reduction at an operating temperature T op ≥ 700°C and a thermal expansion matched to that of the electrolyte and interconnect. We report on the properties of Sr‐ and Ni‐doped LaCoO3 and LaFeO3 perovskites that meet these criteria. Single‐phase regions were determined by X‐ray diffraction, and thermogravimetric analysis measurements were used to obtain the temperatures above which oxygen loss, and hence oxide‐ion conductivity, occurs. The conductivity and Seebeck measurements indicate the coexistence of both …

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Greenwood Cemetery Cedar Falls, Iowa [Website], Thomas G. Connors Jan 1998

Greenwood Cemetery Cedar Falls, Iowa [Website], Thomas G. Connors

Faculty Publications

This site was created by history and social studies education students at the University of Northern Iowa in Cedar Falls, Iowa, under the direction of Thomas Connors ([email protected]), Assistant Professor of History, Karla Krueger, Curriculum & Technology Project Specialist, TyAnn Morehead, Educational Technology Specialist, Information Technology Services-Training, and John Schmitz and Justin Harringa, Technical Support Specialists. We gratefully acknowledge their support and assistance.

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Electrochemical Investigations Of Cobalt-Doped Limn2O4 As Cathode Material For Lithium-Ion Batteries, P. Arora, Branko Popov, Ralph E. White Jan 1998

Electrochemical Investigations Of Cobalt-Doped Limn2O4 As Cathode Material For Lithium-Ion Batteries, P. Arora, Branko Popov, Ralph E. White

Faculty Publications

A wide range (y = 0.05–0.33) of Co-doped LiCoyMn2–yO4 spinels were synthesized and electrochemically characterized. These Co-doped spinels showed improved specific capacity and capacity retention over pure spinels. Electrochemical impedance spectroscopy and the linear polarization resistance technique were used to determine the transport and electrochemical kinetic parameters of Co-doped spinels. The presence of Co in the spinel inhibits the passivation process occurring on the surface of the cathode. Also, Co increases the exchange current density and facilitates the charge-transfer reaction of the active material. The lower self-discharge observed for Co-doped spinels was attributed …

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Characterization Of Hydrogen Permeation Through Zinc-Nickel Alloys Under Corroding Conditions: Mathematical Model And Experimental Study, M. Ramasubramanian, Branko N. Popov, Ralph E. White Jan 1998

Characterization Of Hydrogen Permeation Through Zinc-Nickel Alloys Under Corroding Conditions: Mathematical Model And Experimental Study, M. Ramasubramanian, Branko N. Popov, Ralph E. White

Faculty Publications

A mathematical model was developed for the characterization of hydrogen permeation into metals and alloys under corroding conditions. The model requires a knowledge of the corrosion rate of the given metal or alloy in solutions of various H+ concentrations. It provides quantitative values of rate constants of the hydrogen discharge, recombination, and adsorption reactions. This model can serve as a diagnostic criterion for determining the effectiveness of various metals and alloys as hydrogen permeation inhibitors and can be used for evaluation of hydrogen entry inhibition efficiency. Experiments were carried out to study the effectiveness of thin layers of electrodeposited …

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Characterization Of Sol-Gel-Derived Cobalt Oxide Xerogels As Electrochemical Capacitors, Chuan Lin, James A. Ritter, Branko N. Popov Jan 1998

Characterization Of Sol-Gel-Derived Cobalt Oxide Xerogels As Electrochemical Capacitors, Chuan Lin, James A. Ritter, Branko N. Popov

Faculty Publications

Very fine cobalt oxide xerogel powders were prepared using a unique solution chemistry associated with the sol-gel process. The effect of thermal treatment on the surface area, pore volume, crystallinity, particle structure, and corresponding electrochemical properties of the resulting xerogels was investigated and found to have significant effects on all of these properties. The xerogel remained amorphous as Co(OH)2 up to 160°C, and exhibited maxima in both the surface area and pore volume at this temperature. With an increase in the temperature above 200°C, both the surface area and pore volume decreased sharply, because the amorphous Co(OH)2 decomposed …

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Studies On Electroless Cobalt Coatings For Microencapsulation Of Hydrogen Storage Alloys, Bala S. Haran, Branko N. Popov, Ralph E. White Jan 1998

Studies On Electroless Cobalt Coatings For Microencapsulation Of Hydrogen Storage Alloys, Bala S. Haran, Branko N. Popov, Ralph E. White

Faculty Publications

LaNi4.27Sn0.24 alloy was microencapsulated with cobalt by electroless deposition from an alkaline hypophosphite bath. Discharge curves of the encapsulated alloy indicate an additional contribution to the capacity arising from the cobalt on the surface. Studies on cobalt thin films reveal the presence of adsorbed hydrogen in cobalt. The amount of hydrogen adsorbed was observed to increase with time of cathodic polarization and to reach a maximum. Polarization techniques have been used to characterize the cobalt-plated alloy as a function of state of charge. The equilibrium potential of the microencapsulated electrode at low hydrogen concentration is determined by …

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Theoretical Analysis Of Metal Hydride Electrodes: Studies On Equilibrium Potential And Exchange Current Density, Bala S. Haran, Branko N. Popov, Ralph E. White Jan 1998

Theoretical Analysis Of Metal Hydride Electrodes: Studies On Equilibrium Potential And Exchange Current Density, Bala S. Haran, Branko N. Popov, Ralph E. White

Faculty Publications

A theoretical model for the metal hydride electrode has been developed assuming that hydrogen diffusion in the alloy and charge-transfer at the surface control the discharge process. Theoretical equations for the dependence of equilibrium potential and exchange current density on the surface hydrogen concentration have been derived. These parameters have been used to correlate experimental data with the theoretical electrode discharge model. Analysis of both the experimental and theoretical discharge curves reveals a potential plateau determined by the magnitude of the interactions between the hydrogen in the alloy and the unhydrided metal. Neglecting these hydrogen-metal site interactions results in simulations …

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A Nonisothermal Nickel‐Hydrogen Cell Model, Pauline De Vidts, Javier Delgado, B. Wu, D. M. See, K. Kosanovich, Ralph E. White Jan 1998

A Nonisothermal Nickel‐Hydrogen Cell Model, Pauline De Vidts, Javier Delgado, B. Wu, D. M. See, K. Kosanovich, Ralph E. White

Faculty Publications

No abstract provided.

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Capacity Fade Mechanisms And Side Reactions In Lithium‐Ion Batteries, Pankaj Arora, Ralph E. White, Marc Doyle Jan 1998

Capacity Fade Mechanisms And Side Reactions In Lithium‐Ion Batteries, Pankaj Arora, Ralph E. White, Marc Doyle

Faculty Publications

No abstract provided.

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The Role Of Oxygen At The Second Discharge Plateau Of Nickel Hydroxide, Sathya Motupally, Mukul Jain, Venkat Srinivasan, John W. Weidner Jan 1998

The Role Of Oxygen At The Second Discharge Plateau Of Nickel Hydroxide, Sathya Motupally, Mukul Jain, Venkat Srinivasan, John W. Weidner

Faculty Publications

It was shown that the appearance of a secondary discharge plateau approximately 400 mV below the primary plateau can result from the reduction of oxygen. During the galvanostatic discharge of planar nickel-hydroxide films at room temperature and in 3 weight percent KOH solutions, the second discharge plateau was observed only in the presence of dissolved oxygen in the electrolyte. When the solution was deoxygenated, no residual capacity could be extracted from the films even at low discharge rates or from overcharged films. In addition, the duration of the second plateau is inversely proportional to the square of the discharge current, …

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Steady-State Modeling Of A Parallel-Plate Electrochemical Fluorination Reactor, Kamal Jha, Gerald L. Bauer, John W. Weidner Jan 1998

Steady-State Modeling Of A Parallel-Plate Electrochemical Fluorination Reactor, Kamal Jha, Gerald L. Bauer, John W. Weidner

Faculty Publications

A steady-state mathematical model of a parallel-plate reactor was developed for studying the electrochemical fluorination of organic compounds dissolved in anhydrous hydrogen fluoride. The model incorporates two-phase flow with differential material, energy, and pressure balances. Profiles of temperature, pressure, vapor volume fraction, and current density in the reactor are presented at two inlet temperatures to provide insight into the operation of the reactor. The effects of the inlet temperature, feed flow rate, and cell current on the cell pack voltage and current efficiency of the reactor are presented to determine problematic operating regions for the reactor. Optimum operating currents based …

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The Effect Of Particle Size On The Discharge Performance Of A Nickel-Metal Hydride Cell, Jussi M. Heikonen, Harry J. Ploehn, Ralph E. White Jan 1998

The Effect Of Particle Size On The Discharge Performance Of A Nickel-Metal Hydride Cell, Jussi M. Heikonen, Harry J. Ploehn, Ralph E. White

Faculty Publications

We investigate the effect of particle size on the discharge performance of a nickel-metal hydride cell with a mathematical model. Electrodes with uniform as well as with nonuniform particle sizes are studied. With uniform particle size, the dependence of the particle-to-particle resistance on the particle size is taken into account. The optimal particle size depends on the discharge rate. Moreover, we show that under certain conditions it is advantageous to use a nonuniform particle size. In general, the higher the discharge current density, the more the particle size affects the electrode performance.

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Measurement Of Thin Liquid Film Drainage Using A Novel High-Speed Impedance Analyzer, Kevin O. Hool, Robert C. Saunders, Harry J. Ploehn Jan 1998

Measurement Of Thin Liquid Film Drainage Using A Novel High-Speed Impedance Analyzer, Kevin O. Hool, Robert C. Saunders, Harry J. Ploehn

Faculty Publications

This work describes the design and implementation of a new instrument, called the thin film impedance analyzer, which measures the rate of drainage of thin oil films. The instrument forms an oil film by elevating a planar oil–water interface into a water drop hanging from a stainless steel capillary tube immersed in the oil. The instrument measures the magnitude of the impedance of the matter between the capillary tube and a screen electrode immersed in the lower water phase. Under appropriate conditions, the capacitance of the oil film dominates the impedance. The instrument records the increase in the magnitude of …

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Π-Systems As Lithium/Hydrogen Bond Acceptors: Some Theoretical Observations, Salai Cheettu Ammal, P. Venuvanalingam Jan 1998

Π-Systems As Lithium/Hydrogen Bond Acceptors: Some Theoretical Observations, Salai Cheettu Ammal, P. Venuvanalingam

Faculty Publications

Ab initio calculations at the Hartree–Fock and correlated levels and density functional theory calculations have been performed with 6-31++G(d,p) and 6-311++G(d,p)basis sets on LiF and HF complexes of benzene, ethylene, and acetylene. Complex binding energies have been corrected for basis set superposition error, and zero point energy corrections have been done on Hartree–Fock binding energies. Computed results indicate that the complexes exist in different conformations and among them those with π-lithium and π-hydrogen bonds are the most stable. π-lithium bonds are stronger than π-hydrogen bonds. The computed binding energies and geometry of HF complexes correlate well with the available experimental …

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Ab Initio And Dft Investigations Of Lithium/Hydrogen Bonded Complexes Of Trimethylamine, Dimethyl Ether And Dimethyl Sulfide, Salai Cheettu Ammal, P. Venuvanalingam Jan 1998

Ab Initio And Dft Investigations Of Lithium/Hydrogen Bonded Complexes Of Trimethylamine, Dimethyl Ether And Dimethyl Sulfide, Salai Cheettu Ammal, P. Venuvanalingam

Faculty Publications

Ab initio and DFT computations have been carried out on LiF and HF complexes of a set of n-donors viz. trimethylamine, dimethyl ether and dimethyl sulfide with a 6-31++G(d,p) basis set. The effect of correlation has been included with MP2, MP4 and DFT calculations. NBO analyses of the wavefunctions have been performed to examine the intermolecular interaction at the orbital level. Calculations reveal that these donors form strong n→σ* complexes and computed binding energies of the (CH3)2O···HF complex agree very well with the experimental binding energies from IR spectroscopy. LiF forms stronger complexes than HF, …

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Agent Jurisprudence, Michael N. Huhns, Munindar P. Singh Jan 1998

Agent Jurisprudence, Michael N. Huhns, Munindar P. Singh

Faculty Publications

The agent metaphor comes packaged with a number of powerful abstractions. Some of these are psychological, such as beliefs, knowledge, and intentions-abstractions that were traditionally studied in AI. However, there are a number of other abstractions that the agent metaphor brings to the fore. Of these, one has been emphasizing the social abstractions. Close cousins of the social abstractions are the ethical and legal abstractions. These too are being recognized as increasingly important in developing agents that are not only sociable, but also well behaved.

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Justifying Racial Reform, Davison M. Douglas Jan 1998

Justifying Racial Reform, Davison M. Douglas

Faculty Publications

No abstract provided.

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The Bankruptcy Review Commission Recommendation On Classification Of Claims In Chapter 11, Scott F. Norberg Jan 1998

The Bankruptcy Review Commission Recommendation On Classification Of Claims In Chapter 11, Scott F. Norberg

Faculty Publications

No abstract provided.

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Retention Of Administrators In Nursing Homes: What Can Management Do?, Douglas A. Singh, Robert C. Schwab Jan 1998

Retention Of Administrators In Nursing Homes: What Can Management Do?, Douglas A. Singh, Robert C. Schwab

Faculty Publications

Annual turnover among nursing home administrators may be 40% or higher. To investigate the factors that could lead to greater administrator retention, responses to a survey (53% response rate) were analyzed using factor analysis and multiple regression models. Results show that higher retention is observed when administrators are allowed to function independently, are involved in decision making, are treated fairly, and are given reasonable goals to achieve. Organizations must hire administrators whose values match theirs. Multifacility chain organizations and for-profit facilities appear to have a greater need to embrace organizational principles that lead to greater job satisfaction.

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Is Sound Just Noise, Joshua D. Coval, Tyler Shumway Jan 1998

Is Sound Just Noise, Joshua D. Coval, Tyler Shumway

Faculty Publications

This paper analyzes the information content of the ambient noise level in the Chicago Board of Trade's 30-year Treasury Bond futures trading pit. Controlling for a variety of other variables, including lagged price changes, trading volumes, and news announcements, we find that the sound level conveys information which is highly economically and statistically significant. In particular, we find increases in the sound level precede periods of high price volatility and increased trading volumes. Increases in the sound level also presage the placement of block trades and relative increases in customer-driven trading. Our results add to our understanding of the market …

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Evaluation Of Ch4/Nox Reduced Mechanisms Used For Modeling Lean Premixed Turbulent Combustion Of Natural Gas, Hemant P. Mallampalli, Thomas H. Fletcher, J Y. Chen Jan 1998

Evaluation Of Ch4/Nox Reduced Mechanisms Used For Modeling Lean Premixed Turbulent Combustion Of Natural Gas, Hemant P. Mallampalli, Thomas H. Fletcher, J Y. Chen

Faculty Publications

This study has identified useful reduced kinetic schemes that can be used in comprehensive multi-dimensional gas-turbine combustor models. Reduced mechanisms lessen computational cost and possess the capability to accurately predict the overall flame structure, including gas temperatures and key intermediate species such as CH4, CO and NOx. In this study, four-new global mechanisms with 5, 6, 7, and 9 steps based on the full GRI 2.11 mechanism, were developed and evaluated for their potential to model natural-gas chemistry (including NOx chemistry) in gas turbine combustors. These new reduced mechanisms were optimized to model the high …

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