Digital Commons Network^™

A Modified Electrochemical Process For The Decomposition Of Hydrogen Sulfide In An Aqueous Alkaline Solution, Z. Mao, A. Anani, Ralph E. White, S. Srinivasan, A. J. Appleby

Faculty Publications

An electrochemical process for the decomposition of hydrogen sulfide into its constituents in an aqueous alkaline solution is presented. It essentially consists of presaturation of an alkaline scrubber solution with H₂S. Thereafter, partial neutralization of the presaturated solution provides not only the necessary mass balance for electrolysis, but also creates the optimum conditions under which passivation of the anode, as well as side chemical and electrochemical reactions, are minimized. Finally, the electrolysis stage of the process leads to precipitation of crystalline sulfur at the anode and evolution of hydrogen at the cathode. Regeneration of the alkaline solution via …

Mathematical Modeling Of A Nickel-Cadmium Battery: Effects Of Intercalation And Oxygen Reactions, Deyuan Fan, Ralph E. White

Faculty Publications

Extensions are presented for a previously published (1) mathematical model of a nickel-cadmium (Ni-Cd) cell. These extensions consist of intercalation thermodynamics for the nickel electrode and oxygen generation and reduction reactions during charge and overcharge. The simulated results indicate that intercalation may be important in the nickel electrode and that including the oxygen reactions provides a means of predicting the efficiency of the cell on charge and discharge.

In Situ Degradation Of Polyhalogenated Aromatic Hydrocarbons By Electrochemically Generated Superoxide Ions, E. E. Kalu, Ralph E. White

Faculty Publications

The reduction of dioxygen in aprotic media yields superoxide ions which react with polyhalogenated aromatic hydrocarbons by nucleophilic substitution. The degradation of hexachlorobenzene to bicarbonates and chlorides using in situ generated superoxide ions was carried out at room temperature in a flow cell system equipped with a gas fed, porous electrode. The effects of current, electrolyte flow, and aprotic media on the extent of degradation of hexachlorobenzene are presented.

A Mathematical Model Of A Hydrogen/Oxygen Alkaline Fuel Cell, Michael C. Kimble, Ralph E. White

Faculty Publications

A mathematical model of a hydrogen/oxygen alkaline fuel cell is presented that can be used to predict polarization behavior under various potential loads. The model describes the phenomena occurring in the solid, liquid, and gaseous phases of the anode, separator, and cathode regions, assuming a macrohomogeneous, three-phase porous electrode structure. The model calculates the spatial variation of the partial pressures of oxygen, hydrogen, and water vapor, dissolved oxygen and hydrogen concentrations, electrolyte concentration, and the solid- and solution-phase potential drops. By developing a complete model of the alkaline fuel cell, the interaction of the various transport and kinetic resistances can …

Effect Of Ohmic, Mass-Transfer, And Kinetic Resistances On Linear-Sweep Voltammetry In A Cylindrical-Pore Electrode, John W. Weidner, Peter S. Fedkiw

Faculty Publications

Extracting quantitative kinetic information from linear-sweep voltammograms (LSV) on porous electrodes is more difficult than on planar electrodes since the electrode surface is not uniformly accessible to the bulk supply of reactant or the counterelectrode. We present here a means to account for the effect of ohmic, mass-transfer, and kinetic resistances on LSV by modeling a pore in a porous matrix as a cylindrical-pore electrode, and solving the mass and charge conservation equations in the context of this geometry for the simply redox reaction O + ne^– <=> R where both O and R are soluble species. Both analytical …

Power Law Exponents For A Spreading Front And Growing Interface In An Irreversible Wetting, Evan Willett, Ras B. Pandey

Faculty Publications

Using computer simulations, the power-law behavior of the interface growth of a spreading fluid is studied in a two-dimensional lattice model. The interface width exponent ν and the dynamical exponent k for the evolution of the front are consistent with their dynamical scaling relation. The magnitude of these exponents seems to depend upon the nature of the substrate and the concentration of the carriers of the wetting fluid.

In Situ Infrared Evidence For The Electrochemical Incorporation Of Hydrogen Into Si And Ge, K. C. Mandal, F. Ozanam, J.-N. Chazalviel

Faculty Publications

No abstract provided.

Weak Localisation Theory For Lightly Doped Semiconductor Quantum Wires, G. Y. Hu, R. F. O'Connell

Faculty Publications

A weak localisation theory for a semiconductor quantum wire, which has a width of the order of the Fermi wavelength is presented. In the model the electronic motion is essentially one-dimensional and the localisation length L1 is much larger than the mean free path l, so that, in contrast to conventional theories a non-localised quantum wire with a total length Lproperties, the authors study the temperature dependence and the subbands effect of the weak localisation. They find that when (the phase coherent length) Lphi>L, the conductance of the quantum wire depends on L instead of Lphi, implying a temperature …

Dielectric Response Of A Quasi-One-Dimensional Electron System, G. Y. Hu, R. F. O'Connell

Faculty Publications

The dielectric response of a quasi-one-dimensional electron system is studied by including fluctuation effects (in the polarizability) and by using a recently derived analytic form for the electron-electron interactions. General forms for the polarizability matrices both for the intra- and inter-subband cases are presented. The generalized polarizability is analytic over the whole region of the wavevectors and rigorously retains the number neutrality. Various differences between the intra- and inter-subband cases for the polarizability and the dielectric matrix function are studied. The theory is used to study impurity screening and plasmon excitations in the presence of multi-subbands. The authors show that …

Genevan Scholars In Intellectual Europe: From The 17th Century To The Middle Of The 19th Century - French, Theodore S. Feldman

Faculty Publications

No abstract provided.

Below The Magic Mountain: A Social History Of Tuberculosis In 20th Century Britain, L. Margaret Barnett

Faculty Publications

©Albion

Publisher's Version

Purification And Characterization Of A Dna Polymerase From The Cyanobacterium Anacystis Nidulans R2, Hsiu-Jin Lin, Gordon C. Cannon, Sabine Heinhorst

Faculty Publications

A DNA polymerase has been highly purified from Anacystis nidulans R2. Electrophoretic analysis in sodium dodecyl sulfate-polyacrylamide gels revealed that the final fraction contains three bands of M_r 107,000, 93,000, and 51,000, respectively. Analysis of purified DNA polymerase activity in situ indicates that of the three polypeptides the M_r 107,000 species has the catalytic activities. The native molecular weight of the enzyme was estimated by glycerol gradient sedimentation to be 100,000. The enzyme has an absolute requirement for a divalent cation. Mg²⁺ can be replaced with Mn²⁺, but the DNA polymerase is less active. Potassium …

Exercise Tolerance And Alcohol Intake: Blood Pressure Relation, G. Harley Hartung, Harold W. Kohl Iii, Steven N. Blair, Steven J. Lawrence, Ronald B. Harrist

Faculty Publications

The relations of systolic and diastolic blood pressures to alcohol intake and exercise tolerance levels in 15,612 men and 3,855 women were investigated. Alcohol intake was assessed by questionnaire and stratified into seven levels for men and six for women according to the ounces of ethanol consumed per week. Exercise tolerance was determined by maximal treadmill exercise testing and was categorized into six age-specific by sex-specific levels. Both systolic and diastolic blood pressure were significantly related to both alcohol intake and exercise tolerance levels in both men and women. These relations, which were positive for alcohol and negative for exercise …

The Effect Of Externally Applied Oscillating Electric Fields On The L=1 And L=2 Diocotron Modes In Non-Neutral Plasmas, Ross L. Spencer

Faculty Publications

A high-frequency oscillating electric field can change the properties of diocotron modes in non-neutral plasmas. The effect depends crucially on the azimuthal mode number, m, of the applied field. For m=0, plus or minus 1 there is no effect, and for applied standing waves there is also no effect. But if the applied field has the form of a traveling wave with the norm of m greater than or equal to 2, the frequency of stable diocotron modes can be modified and for the norm of m greater than or equal to 3, the l=2 instability of hollow density profiles …

A Judicial Postscript On The Church-State Debates Of 1989: How Porous The Wall, How Civil The State?, William W. Van Alstyne

Faculty Publications

This work is a continuation of the debate regarding the Establishment Clause. The focus lies with Justice O’Connor’s concurrence in County of Allegheny v. ACLU and how this opinion harkens back to a concept shared by Jefferson and Madison, that the establishment clause is designed to prevent government favoritism.

Shareholder Access To The Proxy Revisited, Jayne W. Barnard

Faculty Publications

No abstract provided.

Analysis Of Bacterial Genome Organization And Replication Using Pulsed-Field Gel Electrophoresis, A. Dingwall, L. Shapiro, Bert Ely

Faculty Publications

The techniques described in this chapter provide a framework with which to begin an analysis of important features of bacterial genome organization and gene function. In this report we describe the preparation of chromosomal DNA, conditions for digestion with restriction endonucleases, and electrophoretic methods that result in the optimal resolution of large DNA restriction fragments. The sizes of the separated fragments can be summed to accurately determine genome size. The fragments can also be probed in hybridization experiments to produce low-resolution genomic restriction maps, and the precise locations of insertion or deletion mutations can be rapidly identified. In addition, PFGE …

Degree Of Adaptive Approximation, Ronald A. Devore, Ming Yu Xiang

Faculty Publications

We obtain various estimates for the error in adaptive approximation and also establish a relationship between adaptive approximation and free-knot spline approximation.

Impacts On California Agriculture Of A Ban On Rice Straw Burning, B. Gardner Delworth, Richard E. Howitt, Charles Goodman

Faculty Publications

The burning of agricultural residues, particularly rice straw, has long been an issue of public concern in California's Sacramento Valley. Especially during days of autumn temperature inversions, the smoke in the atmosphere from burning is regarded by some as a serious health hazard and by nearly all residents as a public nuisance. Strong pressures have resulted in stringent regulations over agricultural burning, but a growing number of voices advocate a strict prohibition on burning. The prospect of a burning ban is worrisome to rice growers since burning is not only the most cost-effective way of disposing of the straw, but …

Computer Simulation Study Of Conductivity In A 2-Dimensional Binary Fluid Mixture, Ras B. Pandey

Faculty Publications

A computer-simulation model is introduced to study the transport properties of a binary fluid mixture in which the constituents of one fluid (the tracer particles) carry charges in a linear charge-density gradient in the background charge of the second fluid. In the steady-state equilibrium, an effective conductivity σ_c(p,r) is estimated as a function of the carrier concentration p and the range of interactions r. The conductivity is observed to vary nonmonotonically with the concentration p, and it exhibits a maximum at a characteristic value p_c. The conductivity decreases when the …

Techniques For Cubic Algebraic Surfaces Ii, Thomas W. Sederberg

Faculty Publications

A survey of some techniques that may have potential for free-form modeling with algebraic surfaces is continued. Classical results as well as several recent innovations are included. Specific attention is paid to cubic algebraic surfaces, although many of the ideas presented have application to algebraic surfaces of any degree. Topics addressed include piecewise constructions, interpolation to points and space curves, and parameterization.

Theory Of Light Scattering By A Nonequilibrium Binary Mixture, J.C. Nieuwoudt, B.M. Law

Faculty Publications

A binary mixture subject to a large temperature gradient is studied. Solutions of the evolution equations for the time-dependent fluctuation correlations are obtained using mode-coupling theory subject to the assumption that the mixture is not close to a critical point. From these results predictions for the light-scattering spectrum at the Rayleigh and Brillouin lines are made. The temperature gradient is shown to cause a large enhancement of the scattering amplitude at the Rayleigh line, whereas the effect at the Brillouin line is found to be small.

Control Of Vortical Separation On A Circular Cone, Nikos J. Mourtos

Faculty Publications

For conical bodies, at moderate angles of attack, the flow separates from the lee side, forming two vortices. Although the vortex lift contrihution is highly desirable, as the angle of attack increases, the vortex system becomes asymmetric, and eventually the vortices breakdown. Thus, some control of the separation process is necessary if the vortex lift is to be exploited at higher angles of attack. The theoretical model which is used in this analysis has three parts. First, the 'single line-vortex' model is used within the framework of 'slender-body theory' to compute the outer inviscid field for specified separation lines. Second, …

Academic Freedom, Hate Speech, And The Idea Of A University, Rodney A. Smolla

Faculty Publications

No abstract provided.

Techniques For Cubic Algebraic Surfaces I, Thomas W. Sederberg

Faculty Publications

The tutorial presents some tools for free-form modeling with algebraic surfaces, that is, surfaces that can be defined using an implicit polynomial equation f(x, y, z )=0. Cubic algebraic surfaces (defined by an implicit equation of degree 3) are emphasized. While much of this material applies only to cubic surfaces, some applies to algebraic surfaces of any degree. This area of the tutorial introduces terminology, presents different methods for defining and modeling with cubic surfaces, and examines the power basis representation of algebraic surfaces. Methods of forcing an algebraic surface to interpolate a set of points or a space curve …

Universal Scaling Of Nonlocal And Local Resistance Fluctuations In Small Wires, H. Haucke, S. Washburn, A. D. Benoit, C. P. Umbach, Richard A. Webb

Faculty Publications

Resistance fluctuations in small metal samples result from coherent transport of the carriers. The wave functions of the carriers extend into regions which are not accessible classically. We have directly measured the length dependence of the nonlocal magnetoresistance fluctuations in Sb and Au wires by studying regions of our samples separated from the classical current path by a distance L which varied from 3L_cphi down to 0.2L_cphi (where L_cphi is the phase coherence length for the carriers in the metal). These fluctuations decay exponentially with L/L_cphi. Measurements along the classical current paths scale more slowly …

Eigenvalue Problems Of Ginzburg–Landau Operator In Bounded Domains, Kening Lu, Xing-Bin Pan

Faculty Publications

In this paper we study the eigenvalue problems for the Ginzburg–Landau operator with a large parameter in bounded domains in [openface R]2 under gauge invariant boundary conditions. The estimates for the eigenvalues are obtained and the asymptotic behavior of the associated eigenfunctions is discussed. These results play a key role in estimating the critical magnetic field in the mathematical theory of superconductivity.

Tomlinsonia Stichkania Sp. Nov., A Permineralized Grass From The Pliocene To (?)Pleistocene China Ranch Beds In Sperry Wash, California, William D. Tidwell, E. M. V. Nambudiri

Faculty Publications

Permineralized specimens of grasses assignable to Tomlinsonia as a new species Tomlinsonia stichkania occur in the China Ranch beds of Pliocene to possible Pleistocene age in Sperry Wash in the Alexander Hills of southeastern California. The round culm of these grasses is generally solid or occasionally hollow with collateral vascular bundles in the distinct outer and indistinct inner rings. Two-ranked leaf sheaths alternately encircle and overlap the culm. Ridges and furrows occur in the abaxial surfaces of the sheaths. The epidermis of the leaf sheaths is similar to that of the culm. The leaf lamina consists of a three-layered mesophyll. …

Consistency And Generalization In Incrementally Trained Connectionist Networks, Tony R. Martinez

Faculty Publications

This paper discusses aspects of consistency and generalization in connectionist networks which learn through incremental training by examples or rules. Differences between training set learning and incremental rule or example learning are presented. Generalization, the ability to output reasonable mappings when presented with novel input patterns, is discussed in light of the above learning methods. In particular, the contrast between humming distance generalization and generalizing by high order combinations of critical variables is overviewed. Examples of detailed rules for an incremental learning model are presented for both consistency and generalization constraints.

Interactive Morphometrics From Three-Dimensional Surface Images, William A. Barrett, Shawn C. Becker

Faculty Publications

Techniques have been developed for extracting three-dimensional (3D) measurements directly and interactively from 3D representations of surface anatomy. In order to obtain 3D measurements the anatomical surface is interrogated directly through the use of morphometric tools. Morphometric tools include points, 3D graphical "probes", and logical sectioning functions which interact with the surface through depth buffer compositing operations. Tools are interactively positioned on or through the surface to measure surface dimensions and partial volumes, or to define intersecting functions which allow surface anatomy to be visualized in the context of surrounding anatomy. Visualization is also enhanced because tools reveal much pertaining …