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Association Of Perfluorinated Chemicals With Endocrino-Carcinogenetic, Obesogenic And Metabolic Health And With Markers Of Chronic Inflammation And Oxidative Stress, Ogbebor Enaholo Omoike May 2020

Association Of Perfluorinated Chemicals With Endocrino-Carcinogenetic, Obesogenic And Metabolic Health And With Markers Of Chronic Inflammation And Oxidative Stress, Ogbebor Enaholo Omoike

Electronic Theses and Dissertations

First, this study examined the association of perfluorinated chemicals with 1) cardio-metabolic health outcomes and 2) the association of phthalates with cardiometabolic health outcomes, and 3) cardio-metabolic health outcomes while assessing the possibility of additive interactions between perfluorinated chemicals (PFCs) and phthalates. Second, association with markers of chronic inflammation and oxidative stress were explored. Finally, this study examined the association of these chemicals with estrogenic cancers- Breast cancer, prostate cancer, uterine cancer and ovarian cancer.

Using data from the National Health and Nutrition Examination Survey (NHANES), logistic regression models were used to investigate the relationship between PFCs and the cardio-metabolic …


Immobilization Of Phosphotungstic Acid On Silica Surface For Catalytic Alkylation Of Aromatic Compounds, Anastasia Kuvayskaya May 2020

Immobilization Of Phosphotungstic Acid On Silica Surface For Catalytic Alkylation Of Aromatic Compounds, Anastasia Kuvayskaya

Electronic Theses and Dissertations

Superacidic mesoporous materials containing covalently embedded PTA were synthesized by sol-gel method. Tetraethyl orthosilicate (TEOS) and phosphotungstic acid (PTA) were used as precursors in the synthesis, ionic and nonionic surfactants were used as pore-forming agents, the reaction proceeded in acidic media. TEM images revealed mesoporous structure with embedded PTA clusters. FT-IR spectra of obtained materials contained characteristic bands of PTA at 957 cm-1. Synthesized catalysts had high BET surface area and high concentration of acidic sites. Alkylation of 1,3,5-trimethylbenzene by 1-decene demonstrated high catalytic activity. The catalyst obtained with Pluronic P123 as a template was the most effective and resulted …


Exploring The Relationships Between Collegiate Sport Coaches’ Creative Productivity And Factors Of Creative Potential, Sean Flanders May 2020

Exploring The Relationships Between Collegiate Sport Coaches’ Creative Productivity And Factors Of Creative Potential, Sean Flanders

Electronic Theses and Dissertations

Sport coaches are perceived as problem solvers who engage in creativity to handle the spontaneity of competitive activity and generate winning results. However, while creativity in athletes has been researched, little has been investigated regarding coaches. Therefore, the purpose of this study was to examine different aspects of creativity – person, process, press, and product – among collegiate team sport coaches in the United States. Specifically, how personality traits, ideational fluency, remote association ability, years of coaching experience, and work climate related to creative product impact and frequency. A modified creativity personality test was found to be positively …


Devil In The Strawstack, Devil In The Details: A Comparative Study Of Old-Time Fiddle Tune Transcriptions, Kalia Yeagle May 2020

Devil In The Strawstack, Devil In The Details: A Comparative Study Of Old-Time Fiddle Tune Transcriptions, Kalia Yeagle

Electronic Theses and Dissertations

This thesis asks what transcriptions of old-time fiddle tunes might tell us about their underlying purposes and the nature of transcription. How could differing approaches to transcription reflect the intentions of the author, and what are those intentions? What does this suggest about how aural information is prioritized? Through a comparative analysis of three transcriptions of the same recording—Tommy Jarrell’s “Devil in the Strawstack”—this thesis examines how musical information is prioritized and how transcribers have adapted their methods to better reflect the nuances of old-time music. The three transcriptions come from Clare Milliner and Walt Koken (The Milliner-Koken Collection …


Silly Trip Wires, Jonathan Byrd May 2020

Silly Trip Wires, Jonathan Byrd

Electronic Theses and Dissertations

The artist discusses the work in Silly Trip Wires, 2020 his Master of Fine Arts exhibition. The exhibition includes an installation, Silly Trips Wires, and documentation of a smaller site-specific version of the work.

The Artist discusses the process of transition from military to civilian, and the potential effects that mental trauma from combat deployments can have on this process. This is tied to an analysis of how communicating the experience of veterans to civilians, through artwork, functions to bring about understanding.


Dunidedcudigunadie, Lawrence Reid May 2020

Dunidedcudigunadie, Lawrence Reid

Electronic Theses and Dissertations

The artist discusses his Master of Fine Arts exhibit, titled DUNIDEDCUDIGUNADIE. The exhibit is to be held at the Tipton Gallery in downtown Johnson City, TN, from April 2nd to April 10th, 2020. A live reception will be held the evening of April 3rd, featuring a performance with the work, titled Look at You!

The following thesis explores the artist’s formative years – investigating how childhood experiences combine with artistic and theoretical influences to inform his art-making process.


Govoreeting With Lewdies: A Critical Discourse Analysis Of A Clockwork Orange And Its Translations Across Media And Language, Willie Wallace May 2020

Govoreeting With Lewdies: A Critical Discourse Analysis Of A Clockwork Orange And Its Translations Across Media And Language, Willie Wallace

Electronic Theses and Dissertations

Much linguistic research has been done on the fictional argot of A Clockwork Orange, known as Nadsat, but few efforts have been made to expand beyond the classification and analysis of Nadsat. Using Critical Discourse Analysis, this paper looks at the overarching discourse of A Clockwork Orange and aims to answer three questions: What exigencies and discourses inform the creation of these works? What techniques and power structures are employed in the construction of these works? How do these works shape or attempt to shape the discourse? To answer these questions, I look at three instances of the discourse: …


A Novel Mode Of Action Of C-Reactive Protein In Protecting Against Streptococcus Pneumoniae Infection And Synergy With Antibiotics, Donald Ngwa May 2020

A Novel Mode Of Action Of C-Reactive Protein In Protecting Against Streptococcus Pneumoniae Infection And Synergy With Antibiotics, Donald Ngwa

Electronic Theses and Dissertations

C-reactive protein (CRP) is a part of the innate immune system, is synthesized in the liver, its blood level increases in inflammatory states, and it binds to Streptococcus pneumoniae. The conformation of CRP is altered under conditions mimicking an inflammatory milieu and this non-native CRP also binds to immobilized/aggregated/pathogenic proteins. Experiments in mice have revealed that one of the functions of CRP is to protect against pneumococcal infection. For protection, CRP must be injected into mice within two hours of administering pneumococci, thus, CRP is protective against early-stage infection but not against late-stage infection. It is unknown how CRP protects …


Managing Cosplay Performance: The Forms And Expectations Of Convention Roleplay, Isaac V. Price May 2020

Managing Cosplay Performance: The Forms And Expectations Of Convention Roleplay, Isaac V. Price

Electronic Theses and Dissertations

Costume play (i.e. cosplay) is a performance of fandom rife with rituals and communication practices. Cosplay roleplaying performances are cultural practices that reveal how cosplayers interact with one another and among non-cosplaying members of their fandoms. This study examines the expectations that cosplayers hold for roleplay, the forms of roleplay, and the ways in which roleplay can become an instigator of harassment. Through the lens of Face-Negotiation Theory, the author discusses how roleplay functions to maintain or threaten the public images of cosplayers and their audiences, and what strategies cosplayers implement to avoid the loss of face.


Protection Against Atherosclerosis By A Non-Native Pentameric Crp That Shares Its Ligand Recognition Functions With An Evolutionarily Distant Crp, Asmita Pathak May 2020

Protection Against Atherosclerosis By A Non-Native Pentameric Crp That Shares Its Ligand Recognition Functions With An Evolutionarily Distant Crp, Asmita Pathak

Electronic Theses and Dissertations

C-reactive protein (CRP) is an acute phase protein of the innate immune system that has been evolutionarily conserved. Human CRP is known to exist in two different pentameric conformations; native CRP and non-native CRP that possess differential ligand recognition functions. The structure of CRP evolved from arthropods to humans, in terms of subunit composition, disulfide bonds, and glycosylation pattern. Along with change in structure, the gene expression pattern of CRP also evolved from a constitutive protein in lower invertebrates to an acute phase protein in humans. The objective of this study was to determine the function of a non-native pentameric …


Trends In Advertising: How The Rise In Artificial Intelligence May Influence The Field Of Content Strategy, Joel Eaton May 2020

Trends In Advertising: How The Rise In Artificial Intelligence May Influence The Field Of Content Strategy, Joel Eaton

Electronic Theses and Dissertations

Whereas prior research on artificial intelligence has dealt with automation in fields like medicine, engineering, and computer science, this research study seeks to answer the question, “To what extent can AI be creative in the context of content strategy?” To answer this, this study employs content analysis using 16 online news and blog articles from primarily marketing organizations to identify and explain key variables surrounding the relationship between the computer and the creative professional. This study has found that the core belief that AI will play the future role of creative assistant in the context of content strategy is shared …


Metaphors And Emotions In Advertising: A Rhetorical Analysis Of Audi’S Online Video Commercials, Richard Opoku Amoako May 2020

Metaphors And Emotions In Advertising: A Rhetorical Analysis Of Audi’S Online Video Commercials, Richard Opoku Amoako

Electronic Theses and Dissertations

Advertising often employs metaphor because of its rhetorical utility. By drawing on analogous imagery and language, metaphor has the potential to elicit emotional responses. As the digital age is increasingly saturated with commercial messaging, advertising experts leverage the persuasive power of metaphor and emotion to produce creative, compelling, and memorable commercials. German automobile company Audi employs metaphorical language and imagery in their video advertisements to arouse consumer emotions. In this study, I conduct rhetorical analyses of Audi’s online video commercials in order to: identify instances in their ads that employ metaphorical language and imagery; investigate how those metaphors function rhetorically; …


Blend It Like Beckett: Samuel Beckett And Experimental Contemporary Creative Writing, Sam Nicole Campbell May 2020

Blend It Like Beckett: Samuel Beckett And Experimental Contemporary Creative Writing, Sam Nicole Campbell

Electronic Theses and Dissertations

Samuel Beckett penned novels, short stories, poetry, stage plays, radio plays, and scripts—and he did each in a way that blended genre, challenged the norms of creative writing, and surprised audiences around the globe. His experimental approach to creative writing included the use of absurdism, genre-hybridization, and ergodicism, which led to Beckett fundamentally changing the approach to creative writing. His aesthetics have trickled down through the years and can be seen in contemporary works, including Aimee Bender’s short story collection The Girl in the Flammable Skirt and Mark Z. Danielewski’s novel House of Leaves[1]. By examining these works …


The Emotional Plague, Nicholas Raynolds May 2020

The Emotional Plague, Nicholas Raynolds

Electronic Theses and Dissertations

The artist discusses his Master of Fine Arts thesis exhibition “the emotional plague” held at the Reese Museum in Johnson City, Tennessee from March 2nd through March 27th, 2020 in which he examines a number of literary and invented narrative subjects influenced by science fiction, Surrealism and the current political climate in an attempt to reconcile the social and the personal through the creative act.

Largely improvisational in their conception, the paintings and drawings in this exhibition reflect ideas derived from writers, thinkers and artists including Wilhelm Reich, J.G. Ballard, W.S. Burroughs and Goya, all distilled through the uncertain territory …


Quality Of Life Of Adults Who Have Attempted Suicide, Karen Hoefer May 2020

Quality Of Life Of Adults Who Have Attempted Suicide, Karen Hoefer

Electronic Theses and Dissertations

This study focuses on the quality of life of suicide attempt survivors and the trajectories of their lives after their last attempt in the past two to ten years. Employing both a quantitative and qualitative approach but focusing largely on the qualitative data, I collected demographic data, gathered responses on an abbreviated Reasons for Living Inventory, and conducted open-ended phone interviews with 26 participants. The primary life course finding is that participants’ suicide attempts are often built on years of dealing with mental illness. The analysis also dispels many stereotypes associated with people who have attempted suicide. I explore patterns …


Portrait Of Modern Pluralism: A Practitioner's Perspective On Interest Group Politics And Theory., Mary Ellen Wiederwohl May 2020

Portrait Of Modern Pluralism: A Practitioner's Perspective On Interest Group Politics And Theory., Mary Ellen Wiederwohl

Electronic Theses and Dissertations

This thesis presents a practitioner’s view on interest groups and interest group theory based primarily on Mancur Olson’s conclusions that small, organized minority interests have an advantage over the large, disorganized majority interests in the policymaking process; it tests the “why” behind this theory through an examination of a variety of factors, including the influence of money, the power of communications tools deployed by these interests, and the lobbyists’ role. It includes an introduction plus four chapters, including literature review, research methods, participant observations and in-depth interviews, and conclusion. The research methods included primarily participant observation based on a two-decade …


Rope: An Original Piece For String Orchestra Played Concurrently With Alfred Hitchcock's Film, Douglas William-Solomon Espie May 2020

Rope: An Original Piece For String Orchestra Played Concurrently With Alfred Hitchcock's Film, Douglas William-Solomon Espie

Electronic Theses and Dissertations

This thesis presents an original piece of music designed to be performed concurrently with Alfred Hitchcock’s Rope (1948). The film provides a canvas upon which a musically dominant multimedia experience is built. An accompanying analysis explains the variety of compositional techniques used, explaining their significance and how each deviates from a traditional film score. The objective of this work is to challenge the existing relationship between music and film, and add to the growing body of repertoire of live works featuring synchronized video, modeling example methods of live multimedia performance. In this exploration, the goal was not to be anti-cinematic, …


Students’ Perceptions Of Campus Sexual Assault Resources: An Appalachian Perspective, Rychelle Moses May 2020

Students’ Perceptions Of Campus Sexual Assault Resources: An Appalachian Perspective, Rychelle Moses

Electronic Theses and Dissertations

Research relating to campus sexual assault has traditionally focused on its prevalence and factors that serve to influence risk of victimization. Less attention has been directed toward the presence and effectiveness of campus sexual assault resources. In addition, few studies have explored the role that culture and other geographical factors may play in this process. The current study seeks to address this limitation in two unique ways: (1) determining whether an Appalachian upbringing influences knowledge of and willingness to utilize campus sexual assault resources and (2) exploring its impact on adherence to common rape myths. Survey data are gathered from …


“A Lot Of Prayer, And Some Wine In-Between”: Applying The Relational Turbulence Model To The Stepparent-Biological Parent Marriage., Paul Taylor May 2020

“A Lot Of Prayer, And Some Wine In-Between”: Applying The Relational Turbulence Model To The Stepparent-Biological Parent Marriage., Paul Taylor

Electronic Theses and Dissertations

The present study utilizes the relational turbulence model (RTM) to illuminate stepparent experiences of relational uncertainty and partner interference within the context of the stepparent-biological parent marriage. In-depth, semi-structured interviews with 6 stepparents revealed four primary themes pertaining to how stepparents experienced relational uncertainty: (a) enactment of parenting, (b) competing expectations, (c) shifts in attitude and behavior by spouse, and (d) differences between marriage partners. Interference from partners was experienced by stepparents in relation to the enactment of parenting and the maintaining of the marriage as an intimate relationship.


Emotional Appeals In Nonprofit Advertising: A Rhetorical Analysis Of Print Ads By The Susan G. Komen Breast Cancer Foundation And The American Cancer Society, Dominique N. A. Harrison May 2020

Emotional Appeals In Nonprofit Advertising: A Rhetorical Analysis Of Print Ads By The Susan G. Komen Breast Cancer Foundation And The American Cancer Society, Dominique N. A. Harrison

Electronic Theses and Dissertations

Emotional appeals are frequently employed in strategic messaging by nonprofit organizations. In this study, I identify instances of emotional appeals in select print adverts of the Susan G. Komen Breast Cancer Foundation and the American Cancer Society, and use rhetorical analysis to explore how each organization’s tactics are strategic in their appeal to target audiences’ emotions. In doing so, I identify several reoccurring emotional themes—including hope, love, and unity—that engage their target audiences and persuade them to respond to diverse calls-to-action. In order to make these appeals to audience emotion, the adverts employ rhetorical devices such as personification, metaphor, repetition, …


When Beauty Is More Than Skin Deep: A Content Analysis Of Popular Beauty Youtubers’ Video Strategies, Kristen Jones May 2020

When Beauty Is More Than Skin Deep: A Content Analysis Of Popular Beauty Youtubers’ Video Strategies, Kristen Jones

Electronic Theses and Dissertations

The beauty community on YouTube is a popular outlet for influencer generated video content. Beauty YouTubers provide their viewers with makeup-related videos from tutorials to the latest trends on the platform. As a result, the influencers have gained high subscriber counts that generate revenue through advertisements and brand partnerships. The influencers create relationships with their subscribers that lead to loyalty in the form of video views and merchandise purchasing. This study provides a content analysis of common characteristics within 10 popular beauty YouTubers’ videos examining the strategies used by the influencers. The top five videos from each beauty YouTuber were …


To Buy Or Not To Buy: Consumer Purchase Behavior Based On Lifestyle Brand Logo Colors, Chelsi Crockett May 2020

To Buy Or Not To Buy: Consumer Purchase Behavior Based On Lifestyle Brand Logo Colors, Chelsi Crockett

Electronic Theses and Dissertations

This research aims to examine the logos of lifestyle brands and explore whether certain logo colors elicit a purchase response in consumers. Color Theory and Impression Management Theory are examined alongside the idea of this study. Two-hundred-nine United States residents 18 years of age and older who are not color blind or color deficient participated in a voluntary online survey where they were presented with several differently colored lifestyle brand logos and then prompted to choose which color of lifestyle brand logo would prompt them to purchase a product from the brand in question. The variables of gender, age and, …


Managing Stress In A Constantly-Changing Workforce, Lorri Burch-Hubbard May 2020

Managing Stress In A Constantly-Changing Workforce, Lorri Burch-Hubbard

Electronic Theses and Dissertations

When staffing reductions occur in the workplace, staff left behind may face increased stress, may not be given the support they need to manage the feelings caused by the reduction. This study was conducted to evaluate the impact of stress caused by staffing reductions has on medical technologists (MT), medical technicians (MLT) and respiratory therapists (RT), and to identify any common methods of stress management used by those staff who remain in the organization.

Literature research showed the negative impact stress can have on individuals when it is not addressed, such as decreased work performance, health issues, and even the …


Synthesis And Characterization Of Carbon Monoxide Producers Bipyridine Flavonolate Palladium(Ii) And Platinum(Ii) Complexes: Potential Anti-Cancer Agents, Sarah Whitfield May 2020

Synthesis And Characterization Of Carbon Monoxide Producers Bipyridine Flavonolate Palladium(Ii) And Platinum(Ii) Complexes: Potential Anti-Cancer Agents, Sarah Whitfield

Electronic Theses and Dissertations

Novel designed metal ligand complexes as prodrugs are useful in the effort to find more effective and selective anti-cancer treatments. Carbon monoxide, CO, is known to induce mitochondrial collapse in cancer cells. Herein is described the synthesis of seven novel bipyridine flavonolate palladium(II) and platinum(II) complexes with the property of releasing carbon monoxide, and their characterization with FTIR, UV-Vis, fluorescence, NMR, and ESI mass spectra. Their ability to release carbon monoxide was investigated through oxygenation reaction under various conditions of temperature and light irradiation. The nitroxygenation reaction of the palladium complexes was also studied with nitrosyl hydride, HNO, generated in …


Chasing Destiny: A Novella, Kassandra Kim May 2020

Chasing Destiny: A Novella, Kassandra Kim

Electronic Theses and Dissertations

Chasing Destiny tells the story of Lyric Angel de la Cruz. She is the only daughter of five-time world heavyweight champion and three-time tag team champion Manuel de la Cruz and the oldest granddaughter of Julio de la Cruz, a legend in the wrestling world. For as long as Lyric can remember, her life has been surrounded by wrestling, and she wants to be involved with the business. But unlike her family that came before her. Lyric wants to create her own way in the business, however, when she tells Manuel her career path, he is furious that she would …


Efficient Conditional Inactivation Of Rdh10 Reveals Important Role Of Retinoic Acid During Lung Branching Morphogenesis., Nhut Quang Huy Tran May 2020

Efficient Conditional Inactivation Of Rdh10 Reveals Important Role Of Retinoic Acid During Lung Branching Morphogenesis., Nhut Quang Huy Tran

Electronic Theses and Dissertations

Birth defects are complicated pathological processes. Many birth defects can be traced back to disrupted regulation of molecular signaling pathways during embryogenesis. One of the most important gene regulatory factors during embryo development is retinoic acid (RA). However, studying the specific roles of RA in each organ during embryogenesis in vivo is challenging. The Sandell laboratory has a conditional mutant mouse model that can potentially be used for studying the role of RA during embryogenesis by inducing stage-specific RA deficiency. This model allows retinol dehydrogenase 10 (Rdh10), a gene required for RA production, to be inactivated at a …


Dixieland Crusaders: Mass Media, The Ku Klux Klan, And The Optics Of Populism, 1970-1979., Olivia E. Raymond May 2020

Dixieland Crusaders: Mass Media, The Ku Klux Klan, And The Optics Of Populism, 1970-1979., Olivia E. Raymond

Electronic Theses and Dissertations

The 1970s in the United States of America ushered in transformative policies that reshaped the nation. In her landmark essay, “The Long Civil Rights Movement and the Political Uses of the Past” (2005), Dr. Jacquelyn Dowd Hall reveals how Black activists inspired “a long movement of movements.” However, often forgotten in narratives of new activism from this era is the resurgence of white reactionary social movements. This thesis argues that mass media is central to mainstreaming radical far-right ideology to a national audience. It explores the political ramifications of sensationalist coverage of the Ku Klux Klan in mass media, specifically …


Rethinking Meredith Monk., Tracy Monaghan May 2020

Rethinking Meredith Monk., Tracy Monaghan

Electronic Theses and Dissertations

Meredith Monk’s decades of work embody an interdisciplinary art that exists at the intersection of sonic, visual, and kinesthetic artistic media. To date, scholars and critics of music and dance have only studied aspects of her work in isolation and have tended to omit the other critical aspects of Monk’s compositional language. For example, music scholars omit analysis of movement in their analyses, while dance scholars omit musical analyses. This has led to inappropriate categorization of her work, particularly into the vein of minimalism. My project represents the most in-depth study of all aspects of Monk’s music to date by …


A King's Royal Scars., Xavier Mikal Harris May 2020

A King's Royal Scars., Xavier Mikal Harris

Electronic Theses and Dissertations

This monograph is divided into five chapters covering my exploration of black male identity in America and the scars that come with it. Through a character study of the black male protagonist I portrayed in August Wilson’s King Hedley II, I will discuss the racial stigmas and circumstances that are tied to black male identity. Chapter one will consist of analyzing the prison system in America and how its unfair system targets black men. Chapter two will discuss the plight of poverty that largely affects black communities. Chapters three and four will discuss King Hedley’s dual identities created by …


Microrobots For Wafer Scale Microfactory: Design Fabrication Integration And Control., Ruoshi Zhang May 2020

Microrobots For Wafer Scale Microfactory: Design Fabrication Integration And Control., Ruoshi Zhang

Electronic Theses and Dissertations

Future assembly technologies will involve higher automation levels, in order to satisfy increased micro scale or nano scale precision requirements. Traditionally, assembly using a top-down robotic approach has been well-studied and applied to micro-electronics and MEMS industries, but less so in nanotechnology. With the bloom of nanotechnology ever since the 1990s, newly designed products with new materials, coatings and nanoparticles are gradually entering everyone’s life, while the industry has grown into a billion-dollar volume worldwide. Traditionally, nanotechnology products are assembled using bottom-up methods, such as self-assembly, rather than with top-down robotic assembly. This is due to considerations of volume handling …