Digital Commons Network^™

Conceptions Of Rurality: Examining Beliefs And Their Impact On Teacher Efficacy In A Small Appalachian School, Lori Wickham

Electronic Theses and Dissertations

The current literature documents the historical peripheralization of rural communities and the deficit narratives often imposed upon their schools, students and families. Research further suggests this history of peripheralization is often internalized by those identifying with these communities and that this internalization of deficit orientations may be impacting perceptions of possibility in educational practice. This mixed-methods study investigates more thoroughly if and how these core-periphery dynamics manifest in a small Appalachian school by examining possible connections between educators’ beliefs regarding rurality and their sense of teacher and collective efficacy. The research was guided by the following question:

How do rural …

[3+2]-Cycloadditions Of Tertiary Amine N-Oxides And Dipolarophiles Providing An Efficient Route To Heterocyclics And 1,2-Diamines, And Nickel Catalayzed Transformations, Sarah Hejnosz

Electronic Theses and Dissertations

Nitrogen containing compounds are ubiquitous in nature as well as pharmaceuticals. These structures exhibit rich bioactive and chemical properties boasting an array of practical applications. As a result, the synthetic methods of forming nitrogen containing compounds are highly sought after. More efficient syntheses of these structures could result in less expensive industrial processes, particularly in the pharmaceutical industry. Roussi and coworkers established a highly efficient synthetic route forming nitrogen containing heterocycles in a single step from commercially available reagents, however this chemistry has not be used since its discovery in the 1980. Herein, this work greatly expanded Roussi’s method and …

Investigating The Impact On Private Water Supply Of Hydraulic Fracturing Communication With An Abandoned Conventional Gas Well In New Freeport, Pa, Kiley Miller

Electronic Theses and Dissertations

In June of 2022 a “frac out” occurred in New Freeport, PA when an unconventional gas well under development by hydraulic fracturing, communicated with an abandoned gas well to the surface. An initial “zone of impact” encompassed much of the town’s main thoroughfare. Water samples were obtained from 17 private water wells, 5 springs and 1 pond (31 total samples) and analyzed for cations, anions, and light hydrocarbons. Methane was found in 18 of the samples, both located within and outside of the “zone of impact”. Mass ratio analyses indicated contamination from both unconventional and conventional wells. Interferometric Synthetic Aperture …

Improving School Culture: Teachers’ Perceptions Of School Culture In A Title I School And Their Beliefs About Improvement, Gina Kim

Electronic Theses and Dissertations

The purpose of this qualitative study was to promote a positive school culture in a Title I school by listening to veteran teachers’ voices about the policies and practices being implemented daily. The primary research question guiding this case study was: What are the perceptions of teachers, who have been in their position for 15+ years, about school culture in a Title I school? The secondary research question guiding this study was: What changes in policies and practices in a Title I school do veteran teachers suggest might improve school culture? Participants were purposefully sampled and included four classroom teachers …

Effectiveness Of 2016 Watershed Protection Plan On Bacteria And Nutrient Concentration Loads In The Attoyac Bayou Watershed, Jack Henson

Electronic Theses and Dissertations

In 2004, bacteria and nutrient sampling on the Attoyac Bayou Watershed discovered elevated concentrations of E. coli on five of the main channels key tributary streams. The Attoyac Bayou was then listed on the Texas 303d list of impaired waterbodies and further research was conducted to identify the main sources of contamination in the waterbody. In 2016, the Attoyac Bayou Watershed Plan (WPP) was developed to implement best management practices (BMPs) that would decrease bacteria and nutrient concentrations in the watershed. Educational outreach programs, on-site-sewage facility repair, and livestock management were some of the strategies suggested by the protection plan …

Bioinformatic Analysis Of The Interaction Of Evc And Evc2 Proteins, Md Atikul Islam Mamun

Electronic Theses and Dissertations

Protein to protein interactions are significant to various biological processes, functioning, and the regulation of cells and organisms. Proteins perform essential cellular tasks and often work together in complexes, enabling specific functions like enzymatic activity, signal transduction, DNA replication, and cell division. These interactions are important in signaling pathways, allowing proteins to interact sequentially, leading to specific cellular responses. Some proteins rely on chaperones to fold correctly, and protein to protein interactions enhance stability, preventing degradation.

Researchers at Stanford University School of Medicine discovered that EvC syndrome is related to a malfunction in the Hedgehog (Hh) signaling pathway. They found …

Assessment Of Facultative Sulfur Reducing Bacteria In Acidic And Circumneutral Passive Remediation Systems Using A Novel Culturing Technique, Natalie Lamagna

Electronic Theses and Dissertations

Pollution resulting from abandoned mine drainage (AMD) is widespread across the nation and impacts thousands of miles of watersheds in Pennsylvania alone. AMD contaminants pose hazards to ecosystems and to human health by lowering the pH and by suspending toxic heavy metals in water. Sulfur reducing bacteria (SRB) are known to remove metals and sulfur species from mine drainage through the formation of metal sulfide precipitates and have been documented to raise the alkalinity of water. Therefore, it is necessary to understand the environmental conditions in which these microorganisms survive. Environmental samples were collected from a circumneutral and an acidic …

The Effects Of Transcranial Direct Current Stimulation (Tdcs) On Facial Expression Approach/Avoidance In College Students And Faculty With Broad Autism Phenotype, Nicole R. Baker

Electronic Theses and Dissertations

Transcranial Direct Current Stimulation (tDCS) has been proposed as an alternative noninvasive therapy for individuals with autism. This study trained brain activity in college students and / or faculty with Broad Autism Phenotype (BAP) while eye tracking data was collected. The purpose of this study was to determine if tDCS training to the frontal lobes could increase approach toward social interactions in adults classified as BAP as demonstrated by eye-tracking measures in response to faces and gaze fixation. The study included 21 total participants recruited from the Science, Technology, Engineering, and Math (STEM) courses / professions at a Regional East …

Modifying The Composition Of A High Temperature Superconductor, Drue Lubanski

Electronic Theses and Dissertations

The purpose of this research was to recreate a known superconductor, YBa₂Cu₃O_x, and modify it in an attempt to raise its transition temperature. A superconductor is any material that excludes magnetic flux from its interior when at a temperature below its transition temperature. A “high temperature” superconductor refers to material that shows superconductivity at or above the temperature of liquid nitrogen temperatures (77.15K).

Here we were successful in reproducing the original YBa₂Cu₃O_x and measuring its critical temperature; However, our efforts at raising the transition temperature have, as of yet, …

Dinitroxides In Rapid Scan Electron Paramagnetic Resonance Imaging, Lukas B. Woodcock

Electronic Theses and Dissertations

Local tissue physiology is an important parameter in understanding disease behavior. Rapid Scan (RS) electron paramagnetic resonance (EPR) offers a unique, non-invasive tool for investigation of these so-called microenvironments through EPR Imaging (EPRI). Research into advancement of EPRI falls into many categories. Not least among those are advances in instrumentation and methodology. Presented here are updates to a benchtop EPRI instrument operating at 1 GHz targeted at pre-clinical EPRI applications. Newly developed methods for reducing RS-EPR background through inversion of the magnetic field are also demonstrated. EPR applications are limited in native biological systems due to the miniscule concentration of …

Unilinear Residuated Lattices, Xiao Zhuang

Electronic Theses and Dissertations

We characterize all residuated lattices that have height equal to 3 and show that the variety they generate has continuum-many subvarieties. More generally, we study unilinear residuated lattices: their lattice is a union of disjoint incomparable chains, with bounds added. We give the characterization of all unilinear residuated lattices. By presenting the constructions and axiomatizations for different classes of unilinear residuated lattices, we conclude that the study of unilinear residuated lattices can be reduced to the study of the ⊤-unital ones. Using the classification of unilinear residuated lattices, the idempotent unilinear residuated lattices are studied and amalgamation property and strong …

The Words. Or Holes. Or Both: Writing As An Integrative Methodology For Trauma, Daniel A. Castle

Electronic Theses and Dissertations

This project seeks to identify methods authors have used to integrate their traumatic experiences. My work will analyze the genre of War Literature and specific authors like J.R.R. Tolkien and Kurt Vonnegut to explore the way writers describe the trauma of combat. Using insights from neuroscience and psychology, I will expand the field of Cognitive Literary Studies from a focus on the reader to a focus on the writer by linking neurological functions with narrative tools.

Mechanisms Behind The Chaperone Activity Of Nucleic Acids, Theodore J. Litberg

Electronic Theses and Dissertations

Understanding the interplay between nucleic acids and protein aggregation is integral to the understanding of proteostasis, aging, and neurodegenerative disease progression. Nucleic acids are known to modulate the aggregation of PrP, tau, ⍺-synuclein, and other disease relevant proteins. Although the interactions between misfolded protein and nucleic acids can play a role in disease, this interaction may potentially be beneficial as well. Our group and others have shown nucleic acids can be powerful chaperones. Previous work has shown both RNA and DNA can prevent protein aggregation and RNA can pass off protein clients to the heat shock protein (Hsp) system. Here …

Consensus-Based Active And Reactive Power Control And Management Of Microgrids, Shruti Singh

Electronic Theses and Dissertations

Microgrids incorporating distributed generation and renewable energy sources offer potential solutions to the energy crisis while modernizing traditional grids. Despite cost-effectiveness in some technologies, financial support remains crucial for expensive ones like PV, fuel cells, and storage technologies. Microgrids bring economic benefits, efficiency, reduced emissions, and improved power quality. Their success hinges on cost reductions in renewables, storage, reliability, and energy management systems, enabling operation both with and without the utility grid.

Economic Dispatch optimizes system costs, considering all constraints. Various methods tackle this problem, including quadratic convex functions, Lagrangian relaxation, and quadratic programming. For microgrids with distributed generators, seamless …

Controllable Language Generation Using Deep Learning, Rohola Zandie

Electronic Theses and Dissertations

The advent of deep neural networks has sparked a revolution in Artificial Intelligence (AI), notably with the creation of Transformer models like GPT-X and ChatGPT. These models have surpassed previous methods in various Natural Language Processing (NLP) tasks. As the NLP field evolves, there is a need to further understand and question the capabilities of these models. Text generation, a crucial part of NLP, remains an area where our comprehension is limited while being critical in research.

This dissertation focuses on the challenging problem of controlling the general behaviors of language models such as sentiment, topical focus, and logical reasoning. …

Do-It-Together: Informal Transformative Sustainability Education, Derek Brannon

Electronic Theses and Dissertations

The Climate Crisis is an urgent and inescapable reality students are thrust into. Learners must be prepared adequately for their futures, not only for their sakes but also because collective and transformative change is required. Transformative sustainability education provides one pathway to this transformation and focuses on radically altering students’ perceptions about the world and their agency in effecting change on ecological issues. The field of transformative sustainability education is emergent and thus is still fragmented, leaving gaps in the literature. Little research has been conducted on how informal and nonformal university spaces can be used to create transformative experiences …

Terrain And Adversary-Aware Autonomous Robot Navigation, Aniekan Ufot Inyang

Electronic Theses and Dissertations

In autonomous robot navigation, the robot is able to understand the environment around it for intelligent navigation. From its world model of this environment, it generates a global plan for navigation from a position to a goal based on different factors. This research aims to implement autonomous robot navigation by learning terrain affordances: traversability (moving quickly) and concealment (staying hidden from an adversary) using the Preference-based Inverse Reward Learning (PbIRL) methodology. The PbIRL methodology reduces the barrier of generating initial demonstration data to learn the terrain affordances by using a human expert’s preferences to learn individual weights over the terrain …

International Doctoral Student Experiences In Educational Administration Programs In The United States: A Phenomenological Study, Ping Robert

Electronic Theses and Dissertations

Background: In recent years, more international students are enrolling in Educational Administration (EA) programs in the United States. While EA programs wish to recruit and retain international students, more research is needed on supporting international graduate students in graduate education programs and EA programs specifically. Purpose: The present phenomenological study aims to understand the experience of international doctoral students in U.S. EA programs. The present research was guided by the question: “What is the essence of international postgraduate student experiences in EA programs in the United States?” Methodology: The present study used hermeneutic phenomenology to describe and interpret data from …

Polar Body Membrane Breakdown Occurs Independent Of Macroautophagy In C. Elegans, Shruti Kolli

Electronic Theses and Dissertations

Failure to digest cell corpses can lead to lupus-like autoimmune disorders in mammals. To better understand if LC3-associated phagocytosis (LAP) drives cell corpse breakdown in phagolysosomes, we studied the clearance of the C. elegans polar body during embryonic development. ATG16L1 has separable roles in regulating LC3 recruitment during macroautophagy and LAP. We demonstrated that the ATG16L1 C. elegans orthologs, ATG-16.1 and ATG-16.2, function redundantly to promote polar body membrane breakdown. We also discovered that truncating the LAP-specific WD40 domain of ATG-16.2 unexpectedly disrupts autophagy. Furthermore, we confirmed that polar body membrane breakdown occurs independent of macroautophagy. We also showed that …

The West Point Talent Based Branching Program As A Predictor Of Performance At The Army’S Field Artillery Basic Officer Leadership Course: Implications For Officer Retention, Ryan Oldroyd Scott

Electronic Theses and Dissertations

Junior officer attrition has increased over the last two decades. The early departure of army officers leaves a dearth of middle- and senior-level leadership, creating risk for future military readiness. West Point leaders theorized that new officers’ poor person–job fit within their specific career fields contributed to attrition. West Point implemented a talent-based system to place new officers into branches that should offer a stronger person–job fit, hoping it would reduce officer attrition. To begin the investigation on how this talent-based system affects attrition, this study examined graduates who joined the field artillery career field to ascertain if the various …

Insights Into The Structural And Electronic Properties Of 2d Polar Sic/Gec Heterostructures And Asxp1−X Alloys., Kazi Jannatul Tasnim

Electronic Theses and Dissertations

Due to the unique structural and electronic properties along with the practical applications in current and near future, investigations about the group-IV graphene-like two-dimensional (2D) sheets have been accelerated. Among them, 2D SiC and GeC sheets are polar materials with in-plane charge transfer from Si (Ge) to C atoms. An interesting question is how the electrostatic force, triggered by such in-plane charge transfer, plays a role in stabilizing the vertical heterostructures formed by 2D SiC and GeC sheets beyond vdW interaction. To answer this question, we have systematically investigated, in my PhD research projects, the effects of the electrostatic interaction …

Interactive Computer-Based Simulations As Exploratory Learning Activities., Derek Mcclellan

Electronic Theses and Dissertations

Typical college lectures follow a direct instruction framework, where instructors deliver a lecture, followed by an activity. Exploratory learning flips this routine by providing students with an activity prior to instruction. Research suggests that this inversion benefits students’ conceptual understanding and ability to transfer their knowledge. The majority of exploratory learning tasks in the literature are problem-solving activities. The current work investigates the use of computer-based simulations during exploratory learning, and whether manipulating the cognitive load of the activity impacts learning. In Experiment 1, undergraduate students (N=66) were randomly assigned to explore a simulation-based circuit construction activity prior …

A Machine Learning Approach To Constructing Ramsey Graphs Leads To The Trahtenbrot-Zykov Problem., Emily Hawboldt

Electronic Theses and Dissertations

Attempts at approaching the well-known and difficult problem of constructing Ramsey graphs via machine learning lead to another difficult problem posed by Zykov in 1963 (now commonly referred to as the Trahtenbrot-Zykov problem): For which graphs F does there exist some graph G such that the neighborhood of every vertex in G induces a subgraph isomorphic to F? Chapter 1 provides a brief introduction to graph theory. Chapter 2 introduces Ramsey theory for graphs. Chapter 3 details a reinforcement learning implementation for Ramsey graph construction. The implementation is based on board game software, specifically the AlphaZero program and its …

Stability Of Cauchy's Equation On Δ+., Holden Wells

Electronic Theses and Dissertations

The most famous functional equation f(x+y)=f(x)+f(y) known as Cauchy's equation due to its appearance in the seminal analysis text Cours d'Analyse (Cauchy 1821), was used to understand fundamental aspects of the real numbers and the importance of regularity assumptions in mathematical analysis. Since then, the equation has been abstracted and examined in many contexts. One such examination, introduced by Stanislaw Ulam and furthered by Donald Hyers, was that of stability. Hyers demonstrated that Cauchy's equation exhibited stability over Banach Spaces in the following sense: functions that approximately satisfy Cauchy's equation are approximated with the same level of error by functions …

Statistical Inference On Lung Cancer Screening Using The National Lung Screening Trial Data., Farhin Rahman

Electronic Theses and Dissertations

This dissertation consists of three research projects on cancer screening probability modeling. In these projects, the three key modeling parameters (sensitivity, sojourn time, transition density) for cancer screening were estimated, along with the long-term outcomes (including overdiagnosis as one outcome), the optimal screening time/age, the lead time distribution, and the probability of overdiagnosis at the future screening time were simulated to provide a statistical perspective on the effectiveness of cancer screening programs. In the first part of this dissertation, a statistical inference was conducted for male and female smokers using the National Lung Screening Trial (NLST) chest X-ray data. A …

Why Are Measures Of Depression Imperfectly Correlated? An Empirical Investigation., Eric Joseph Smith

Electronic Theses and Dissertations

Depression remains one of the most prevalent and impactful mental health disorders worldwide. A large number of measures of depressive symptoms are currently available, all designed to assess the same underlying construct. However, the measures tend not to correlate highly with one another. Measurement error cannot fully account for this observation, suggesting that clinical heterogeneity – that is, differences in symptom coverage across measures – might contribute to the lower-than-expected correlation between measures. We conducted two concurrent studies to examine this hypothesis. In Study 1, we developed a coding scheme to categorize items into one of 10 symptom categories. We …

Novel Breath Collection Techniques For Detection Of Covid-19., James Morris

Electronic Theses and Dissertations

Volatile Organic Compounds (VOC) generated endogenously in the human body can be used to detect diseases that induce oxidative stress and inflammation. Breath analysis has been used for the detection of diseases such as COPD, Depression, Lung Cancer and most recently COVID-19. Methods such as Exhaled Breath Condensate (EBC), Sorbent Tubes, Solid Phase Microextraction (SPME), and silicon microreactors have shown considerable capability in extracting and concentrating trace VOC’s present in human breath. Silicon microreactors functionalized with capture agents to derivatize carbonyl compounds are effective but the overall maximum flow rate of breath sample possible during analysis is low, making direct …

Statistical Methods For Assessing Treatment Effects On Ordinal Outcomes And Selecting Optimal Treatment On Survival Outcomes Using Observational Data., Huirong Hu

Electronic Theses and Dissertations

This dissertation consists of two projects investigating statistical methods in causal inference and personalized medication using observational data. In the first project, we propose a parametric marginal structural ordinal logistic regression model (MS-OLRM) to assess treatment effects on ordinal outcomes. Average treatment effect (ATE) is used to measure the difference of the mean outcomes if all patients would have been treated compared with the outcomes if they would not have been treated. Many statistical methods have been developed to estimate ATE when the outcome is continuous or binary. The methodology on assessing treatment effect for an ordinal outcome is less …

Intercalation And High-Pressure Investigations Of Black Arsenic Phosphorus: Unraveling Material Transformations., Dinushika Vithanage

Electronic Theses and Dissertations

Black arsenic phosphorus (b-As_yP_1-y) alloys have emerged as intriguing materials within the realm of two-dimensional (2D) materials, following the discovery of black phosphorus (BP). These alloys possess capability to overcome major limitations of BP and exhibit potential for tunability and enhancement of properties making them promising materials for a wide range of applications, including lithium-ion batteries. Inspired by the intriguing findings obtained for BP, this research focuses on understanding the structural modifications that can be achieved in b-As_yP_1-y alloys through the application of intercalation and high pressure. The initial phase of our investigation …

Non-Western Rendition Of Ambient Rhetoric Of Khajuraho Monuments., Shiva Hari Mainaly

Electronic Theses and Dissertations

This dissertation develops an ambient rhetoric: a living practice that is more disclosive than communicative, more entangled than intersectional, and more subtle than explicit and evidential. Rather than exploring the symbology, iconography, texture, and artistic integrity of Khajuraho monuments, I claim that Khajuraho monuments aim at convincing visitors with their persuadability and affectability inherent in their material bases, architectural panels, fractal design, allegorical cast, aura of attunement, and the environment in which the monument complex is nestled. Khajuraho groups of monuments in Central India, matchless in their monumentality, dynamic in their adjustment to the shifting socio-politico-cultural landscape in the world, …