Digital Commons Network^™

A Study Of Big Field Multivariate Cryptography., Ryann Cartor

Electronic Theses and Dissertations

As the world grapples with the possibility of widespread quantum computing, the cryptosystems of the day need to be up to date. Multivariate Public Key Cryptography is a leading option for security in a post quantum society. One goal of this work is to classify the security of multivariate schemes, especially C*variants. We begin by introducing Multivariate Public Key Cryptography and will then discuss different multivariate schemes and the main types of attacks that have been proven effective against multivariate schemes. Once we have developed an appropriate background, we analyze security of different schemes against particular attacks. Specifically, we …

Algebraic Properties Of Neural Codes., Katie C. Christensen

Electronic Theses and Dissertations

The neural rings and ideals as algebraic tools for analyzing the intrinsic structure of neural codes were introduced by C. Curto, V. Itskov, A. Veliz-Cuba, and N. Youngs in 2013. Since then they have been investigated in several papers, including the 2017 paper by S. G\"unt\"urk\"un, J. Jeffries, and J. Sun, in which the notion of polarization of neural ideals was introduced. We extend their ideas by introducing the polarization of motifs and neural codes, and show that these notions have very nice properties which allow the studying of the intrinsic structure of neural codes of length $n$ via the …

Characterizing Majority Rule On Various Discrete Models Of Consensus., Trevor Leach

Electronic Theses and Dissertations

In any social structure, there is often a need to reach decisions, not only within a group but between groups as well, sometimes even urgently so. Each of the individuals constituting these groups has their own preference for the decision to be made. We will discuss the problem of aggregating individual preferences into a collective preference and under what conditions we are required to select a collective majority. In this dissertation we will look at three models of consensus and show the conditions vary based on the model.

Evaluating Fluid Fluxes From Deep-Sea Seepage Habitats, Leigha E. Peterson

Electronic Theses and Dissertations

The permanently dark deep-sea, located at oceanic water depths greater than 200 m, represents the largest potential habitat space on Earth. The physicochemical conditions of the planet’s largest biome are tightly coupled to the exchange of matter and energy from terrestrial and sea-floor end-members. In fact, global ocean and climate systems are significantly impacted by deep-sea processes. Seafloor vents and seeps appear to act as geologic exchange conduits, returning recycled materials to the hydrosphere to sustain another generation of life. Despite submarine seepage having control on global elemental cycling, it is estimated that less than 1% of the deep-sea has …

Is Touchmath An Effective Intervention For Students With Autism?, April M. Huckaby

Electronic Theses and Dissertations

The TouchMath program was created in 1976 to help students struggling with basic mathematical computations (Bullock, 2005). Although the research has found TouchMath to be an effective intervention for students in the general and special education populations, only four studies have found the program to be effective for students with Autism Spectrum Disorder (Berry, 2009; Cihak & Foust, 2008; Fletcher, Boon, & Cihak, 2010; Yıkmış, 2016). The purpose of the study was to determine how the intervention can affect accuracy and fluency for students with ASD. The study focused on single-digit plus single-digit addition problems with three participants diagnosed with …

Simulation Of A Continuum Tumor Model Using Distributed Computing., Dylan A Goodin

Electronic Theses and Dissertations

Mathematical modeling aims to provide a theoretical framework for understanding tissue dynamics and for establishing treatment response for diseased tissues, such as tumors. Previously published continuum models have successfully represented idealized two-dimensional and three-dimensional tissue for short periods of time. A recently published continuum model of cancer increases model complexity and describes three-dimensional tissue that, due to the required complexity of the geometric multigrid solver, can only be feasibly applied to millimeter-scale simulations. Furthermore, the computational cost for such models has hindered their application in the laboratory and in the clinic. With computational demands greatly outpacing current openMP-based approaches on …

Molecular Characterization Of The Putative Nucleotide- Binding And Hydrolyzing Activities Of The Ellis Van Creveld (Evc) Protein, Giang Nguyen

Electronic Theses and Dissertations

Ellis–van Creveld (EvC) syndrome is a rare autosomal recessive disorder that is characterized by short-limb dwarfism, extra fingers or toes, malformed teeth and nails, and congenital heart defects. Mutations in two genes, EVC and EVC2, which are located on chromosome 4, have been shown to be responsible for EvC syndrome. The protein products of these genes, EVC and EVC2 physically interact and together, they are tethered to the base of the primary cilium of cells. This multi-protein assembly positively regulates the Sonic and Indian hedgehog signaling pathways by promoting downstream processes after activation of the smoothened receptor (Smo), by the …

Generation Of Full-Length Wild-Type Gata4 Protein And Characterization Of Its Binding To Unc-45 Domains, Morgan Anderson

Electronic Theses and Dissertations

Striated muscle UNC-45 (SM UNC-45) protein acts as a chaperone for cardiac and skeletal muscle myosins; regulating their folding, assembly into thick filaments, interaction with other sarcomeric proteins, and degradation. GATA4 is an important transcription factor that regulates the expression of several cardiac muscle proteins, including myosin. A previous study demonstrated for the first time that SM UNC-45 (also known as UNC-45B) physically interacted with GATA4. The major revelation from this study is that SM UNC-45 has the potential to exert both short-term (protein level) and long-term (gene level) controls over myosin and therefore muscle structure and function. The aim …

Electrical Brain Activity And The Examinee's Level Of Effort During Performance Validity Tasks, Roselia Juan

Electronic Theses and Dissertations

Many people who intend to obtain benefits from an assessment may resort to performing poorly on assessments. Previous literature has found that cognitive deficits and long-term symptomatic complaints are reported by individuals with mild Traumatic Brain Injuries. Limited studies have investigated how brain activity measured via Quantitative Electroencephalography (QEEG) relates to mental effort during cognitive tasks. The purpose of this study was to investigate electrical brain activity, as measured by Peak (PK) frequency, on frontal brain areas (i.e. locations F3-F4) in individuals giving poor mental effort. Measures of effort, in this study, include the Test of Memory Malingering, Rey 15-Item …

Ripple Effects: The Transformation Of Sfasu Women's Social Clubs To National Sororities, Lea Brannon Clark

Electronic Theses and Dissertations

Shortly after Stephen F. Austin Teachers College (SFA) opened in 1923, students began organizing social clubs. By the late 1920s, women formed the Amities and Pine Burrs to develop friendships and a sense of belonging. The Fideles and Sigma Gammas arrived on campus in the late 1940s as more women began attending SFA. Dr. Ralph W. Steen’s appointment as president brought significant changes to SFA and inadvertently to the social groups.

Responsible for adding more classrooms and dormitories, expanding course work and faculty, the new president also influenced the campus population by attempting to bring in students from metropolitan areas. …

Unconventional Oil And Gas Extraction In Ohio: Regulations, Production And Water Quality, Brittany Garman

Electronic Theses and Dissertations

The Utica shale play is the main target for unconventional oil and gas extraction in Ohio. Over 2,000 wells have been drilled since the first in 2011. This rapid expansion has led to concerns over the availability of information and potential environmental impacts. An assessment of readily available data was done through an examination of the ODNR website for oil and gas regulations, permits, spud and completion reports, water usage and waste data, and complaints, as well as brine and de-icer application. Water quality testing of an exceptional warm water tributary in the Captina Creek watershed in Belmont County, Ohio …

The Influence Of Question Sequencing Using Formative Assessment In Introductory Statistics, Bryan Nelson

Electronic Theses and Dissertations

Formative assessment has long been used to gauge students’ understanding of course material prior to taking an exam. With the advent of more advanced technology, only recently have instructors been able to combine formative assessment with a student response system to allow students to respond to questions in real time during class. Previous studies show mixed findings on the relationship between the use of student response systems and student learning. For example, some studies show that those students who used a student response system performed better on exams or in the course when compared to those who did not, while …

Water Quality Assessment Of Deer Lakes County Park Before, During And After Unconventional Shale Gas Drilling, Daniel Robinson

Electronic Theses and Dissertations

Allegheny County, Pennsylvania, signed a lease to allow unconventional natural gas extraction from Marcellus Shale beneath Deer Lakes County Park in 2014. The park has three man-made lakes and four waterways that eventually flow into the Allegheny River. Drilling commenced in early 2016, and there are now five producing wells. The park has an extensive abandoned coal mine network and several abandoned oil and gas wells. Thus, an independent water quality study was undertaken beginning in July 2015. Samples from seven different sites in the park were used to establish a water quality baseline prior to the drilling. Monthly sampling …

The Effects Of Constructed Wetlands On Metal Solubilization And Bioavailability In Passive Mine Remediation, Elizabeth Cochran

Electronic Theses and Dissertations

The legacy of coal mining in Appalachia has left many watersheds impacted by abandoned mine drainage. The drainage degrades streams, groundwater and habitats with acidity and toxic heavy metals. The Lowber Passive Remediation System has been in operation since 2004 to remediate high amounts of dissolved Fe, SO₄, Al, and Mn. The site consists of six settling ponds and an extensive wetlands at the finish. This study investigated the resolubilization of Fe and Mn in the wetlands and the role of bacteria in resolubilization. During three seasons, field measurements of water quality and lab analysis of Fe, Mn, …

Synthesis, Characterization And Crystal Growth Of I2-Ii-Iv-Vi4 And I4-Ii-Iv2-Vi7 Diamond-Like Semiconductors With Potential In Ir-Nlo Applications, Jennifer Glenn

Electronic Theses and Dissertations

In this dissertation, several new and existing diamond-like semiconductors (DLSs) were synthesized and investigated for their potential in infrared nonlinear optical (IR-NLO) applications. In Chapter 2 growth of large single crystals of Li₂MnGeS₄ was carried out using iodine vapor transport and a newly created graphite-tube containment system. This crystallization method produced sizable single crystals on the scale of 2x1x1 mm³, that were used to determine the material’s magnetic properties. Magnetization data indicate that the compound is antiferromagnetic with a Néel temperature of 10 K and an effective magnetic moment of 5.6 /f.u.. The specific heat …

Enhancing Access And Success Of Underserved Students In Dual Enrollment Programs, Theodore Mbaegbu

Electronic Theses and Dissertations

This study examines dual enrollment activities and their impact with a focus on equitable recruitment, persistence, and targeted success mechanisms for Black students and students from low-income families. The lived experiences of four former students from diverse racial and socio-economic backgrounds, and the perspectives of ten dual enrollment practitioners garnered from a purposeful sampling of two Southwestern Pennsylvania universities inform the study. A qualitative approach examines interviews, focus group, and survey data through thematic investigative interpretation to yield common and unique experiences and perspectives relevant to recruitment processes, funding, support systems, and observed outcomes. The findings indicate how adequate preparation, …

Nontraditional Hydrogen Bonding In Asymmetric Lewis Acid Catalysis, Brandon Vernier

Electronic Theses and Dissertations

In the field of asymmetric induction, there is a shift from the synthesis of reaction

specific chiral auxiliaries towards a broader mechanistic approach. Our approach is to

develop a theory of asymmetric catalyst design from first principles. The Diels-Alder

reaction of 2-methacrolein and 1,3-cyclopentadiene in the presence of 15 mole % lmenthoxy

aluminum dichloride, reported by Koga, achieved the (S)-exo-Diels-Alder

cycloadduct with 72% ee (0% ee Endo for acrolein). The dramatic change from 72% to 0%

ee is a significant fact that has been overlooked in practical organic synthesis.

In the first phase of this work, the conformational landscape of …

Unconventional Gas Extraction In Southwestern Pennsylvania: Complaints, Production, And Water Quality, Dannielle Pratt

Electronic Theses and Dissertations

The dramatic rise in unconventional oil and gas extraction in Pennsylvania has presented a challenge to the Pennsylvania Department of Environmental Protection in managing regulatory required data, and the uniformity of public access via their online databases. This study analyzed over a decade of all the oil and gas complaints and unconventional gas production in Washington County. Of the 1,811 wells drilled between 2004 and 2018, 1,683 are producing, 74 are plugged, 52 regulatory inactive, and 2 abandoned. The PADEP received 10,389 complaints from 2004 to 2018. Only 2,420 of 4,489 water quality complaints were resolved within the legally required …

The Impact Of 1:1 Technology Initiatives On Lesson Planning, Michael Amick

Electronic Theses and Dissertations

Districts across the country are quickly moving toward a 1:1 student to laptop ratio. Where computer labs or carts were once the norm, many districts are now purchasing all students a laptop to start the year. This movement is occurring at a rapid pace, despite a growing body of research that shows that increased technology does not automatically lead to achievement gains. The teacher plays a vital role in student outcomes, with or without technology. In particular, the manner in which teachers plan lessons is significant to classroom outcomes. This is evident in that the Charlotte Danielson Framework for Teaching …

The Ethics Of Occultic Communication: An Invocation Of Joshua Gunn And Sissela Bok, James Thomas Begley Jr.

Electronic Theses and Dissertations

Occultic rhetoric, according to Joshua Gunn, is a genre of discourse concerned with the study and practice of secret communications. The strategic sharing of secret messages involves a host of methods and conventions designed for the selective disclosure of hidden knowledge, thus controlling the boundaries of (and accessibility to power between) insider and outsider groups. Occultic rhetoric has its uses in everyday encounters, but the abuse of such manipulative strategies, especially by those in the academy and other positions of power and trust, calls for an ethical response. This dissertation submits occultic rhetoric to moral investigation by incorporating the works …

Modeling And Prediction Of Amorphous Solid Dispersion Formation Using A Molecular Descriptor, Kevin Deboyace

Electronic Theses and Dissertations

Poor aqueous solubility of an active pharmaceutical ingredient (API) is a significant hurdle during drug development. Delivering a drug in its amorphous solid-state is a potential method to overcome this issue, since the amorphous form has increased apparent aqueous solubility. However, the amorphous state is only metastable, and is thermodynamically driven to recrystallize. As a result, pure amorphous drugs are seldom used in marketed products. Intimately mixing a drug in its amorphous form with a polymer, known as an amorphous solid dispersion (ASD), has the potential to significantly extend the physical stability of the amorphous form, while maintaining the benefit …

Reclaiming Rhetorical Intersectionality: From Silence To Parrhesia And Attuned Listening, Tahirah Walker

Electronic Theses and Dissertations

Intersectionality is a term applied by Kimberlé Williams Crenshaw in the late 1980s to a social experience. A person experiences intersectionality when different aspects of her identity converge in a way that causes uniquely amplified marginalization or oppression. The classic three identities that produce intersectionality experiences in the United States are race, gender, and class, making poor women of color the central figures of intersectionality study. Crenshaw explained that these forces take three main forms: structural, political and representational (“Mapping the Margins” 1243).

Intersectionality has always been rhetorical. Structural, political and representational intersectionality are supported in language. The power of …

Microplastics In The Digestive System Of The Atlantic Sharpnose Shark (Rhizoprionodon Terraenovae) In Winyah Bay, Sc, Elise Virginia Pullen

Electronic Theses and Dissertations

The digestive tracts and livers of adult male Atlantic sharpnose sharks (N=16), Rhizoprionodon terraenovae, from Winyah Bay, South Carolina were examined for ingested microplastics. R. terraenovae is a small, locally abundant, coastal mesopredatory elasmobranch belonging to the family Carcharhinidae. Microfibers comprised the largest categories of plastics (94% of the total), and were found in 100% of sharks examined. The number of micro- and other plastics ranged from 34 to 75 per individual and totaled 927. The majority of plastics (40%) were blue in coloration, and 55% were <1 mm in length. Microplastics were observed on both the interior and exterior of the organs examined, and three microfibers were embedded within the stomach lining, an observation not previously reported in marine vertebrates and one which represents a potential pathway for the translocation of ingested microplastics.

Engineering Noble-Metal Nanostructures For Biosensing Applications, Haihang Ye

Electronic Theses and Dissertations

The ability to engineer noble-metal nanostructures (NMNSs) in a controllable manner and to understand the structure-dependent properties greatly boost our knowledge in rational design of biosensing technologies. In particular, as a type of highly efficient peroxidase mimics, NMNSs hold promising potential to break through the bottleneck of conventional enzyme-based in vitro diagnostics. During the time of my Ph.D. study, I have successfully: 1) directed a two-step method involving seed-mediated growth and chemical etching for the synthesis of Ru nanoframes (RuNFs) with face-centered cubic crystal phase and enhanced catalytic activities; 2) demonstrated, for the first time, the inherent peroxidase-like activity of …

Leaning Robust Sequence Features Via Dynamic Temporal Pattern Discovery, Hao Hu

Electronic Theses and Dissertations

As a major type of data, time series possess invaluable latent knowledge for describing the real world and human society. In order to improve the ability of intelligent systems for understanding the world and people, it is critical to design sophisticated machine learning algorithms for extracting robust time series features from such latent knowledge. Motivated by the successful applications of deep learning in computer vision, more and more machine learning researchers put their attentions on the topic of applying deep learning techniques to time series data. However, directly employing current deep models in most time series domains could be problematic. …

Methodological Improvements In The Mrna Profiling Assays For Incorporation Into Dna Casework Workflows, Paris Volk

Electronic Theses and Dissertations

Currently, DNA profiling is the gold standard to identify an individual. However, determining body fluid origin is important in criminal investigations, offering additional information surrounding the circumstances of a crime. However, crime labs can only definitively identify blood and semen and presumptively saliva using techniques that consume time and sample and do not simultaneously identify all forensically relevant body fluids. This causes many crime labs to want to bypass body fluid identification altogether. Therefore, advances into more definitive molecular-based body fluid methods are necessary. One such technique is mRNA profiling because it provides a highly sensitive and specific approach to …

Analysis Of Hydrodynamic And Bathymetric Gradients In Canaveral National Seashore Following Living Shoreline And Oyster Restorations, David Spiering

Electronic Theses and Dissertations

Coastal vulnerability has been gaining recognition as a critical issue, especially with the increasing predictions of sea level rise. Susceptibility to extreme events, eutrophication, and shoreline modification has left many coastal regions in a degraded state. Shoreline protection has traditionally taken the form of seawalls and offshore breakwaters which can be detrimental to both the local ecosystems and adjoining shorelines. The objective of this thesis is to analyze the hydrodynamic and bathymetric variation that occurs within Mosquito Lagoon, Florida following living shoreline and oyster reef restorations. The shoreline sites were sampled using a Before-After-Control-Impact (BACI) design and data were analyzed …

Use Of Anodic Stripping Voltammetry To Study The Size-Selective Electrophoretic Deposition And Aggregation-Dependent Oxidation Of Metal Nanoparticles., Stacy L. Allen

Electronic Theses and Dissertations

This dissertation describes how anodic stripping voltammetry (ASV) was used to study size-controlled electrophoretic deposition (EPD) and the aggregation-dependent oxidation properties of citrate-stabilized Au nanoparticles (NPs). EPD of citrate-coated Au NPs occurs in the presence of hydroquinone (HQ) onto indium-tin-oxide-coated glass electrodes (glass/ITO) at potentials positive of the HQ oxidation potential. HQ oxidation produces protons at the electrode surface, which serve to neutralize the citrate molecules that electrostatically stabilize the Au NPs. Neutralization leads to the loss of stabilization and deposition onto the electrode. EPD in the presence of ferrocyanide, a non-proton-producing molecule, at oxidation potentials resulted in no deposition …

Creating A College-Going Culture : Accountability Models And Measuring Institutional Rigor In Secondary Schools., Roland O'Daniel

Electronic Theses and Dissertations

This dissertation is an examination of approaches Kentucky high schools have taken in an effort to prepare their graduates to be college and career ready. This dissertation consists of three separate articles. The first explores Kentucky college readiness reform efforts at the secondary school level since the passing of the No Child Left Behind Act of 2002. The need for an educated population is critical to a strong economy and citizenship. Creating that educated population has been a focus for centuries but in the recent history the United States has taken a different approach. Since 2002, No Child Left Behind …

Clustering Of Multiple Instance Data., Andrew D. Karem

Electronic Theses and Dissertations

An emergent area of research in machine learning that aims to develop tools to analyze data where objects have multiple representations is Multiple Instance Learning (MIL). In MIL, each object is represented by a bag that includes a collection of feature vectors called instances. A bag is positive if it contains at least one positive instance, and negative if no instances are positive. One of the main objectives in MIL is to identify a region in the instance feature space with high correlation to instances from positive bags and low correlation to instances from negative bags -- this region is …