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Development Of Triangular And Tetrahedral Finite Elements For Solutions To Thermoelastic Instabilities Using Hotspotter, Cortney Samuel Leneave

Electronic Theses and Dissertations

The objective of the work presented in this thesis is to develop first-order triangular and tetrahedral elements for solutions to Thermoelastic Instabilities (TEI) regarding sliding friction systems in Hotspotter.

Hotspotter software uses a finite element method and an eigenvalue method and is an important tool because currently no other commercial software exists which solves the TEI problem for critical velocities and wave numbers of a system. Hotspotter currently uses quadrilateral and hexahedral elements for two and three dimensional analysis, respectively. Typically, tri and tet elements are used in industry when doing static and dynamic stress analysis. Therefore, the Hotspotter user …

Exponential Random Graphs And A Generalization Of Parking Functions, Ryan Demuse

Electronic Theses and Dissertations

Random graphs are a powerful tool in the analysis of modern networks. Exponential random graph models provide a framework that allows one to encode desirable subgraph features directly into the probability measure. Using the theory of graph limits pioneered by Borgs et. al. as a foundation, we build upon the work of Chatterjee & Diaconis and Radin & Yin. We add complexity to the previously studied models by considering exponential random graph models with edge-weights coming from a generic distribution satisfying mild assumptions. In particular, we show that a large family of two-parameter, edge-weighted exponential random graphs display a phase …

Dislocation Mechanics Of Total Hip Arthroplasty: A Combined Experimental And Computational Analysis, Michael Scinto

Electronic Theses and Dissertations

While total hip arthroplasty is considered a successful procedure, dislocation remains a serious complication as recurrent dislocations may require additional surgeries. Knowledge on dislocation events as they occur in vivo are limited, therefore researchers rely on experimental and computational methods. A custom MATLAB script and an experimental procedure utilizing a six-degree of freedom actuator were developed to further understand how various surgical considerations affect dislocation mechanics in total hip arthroplasty. Computationally, it was determined that impingement free range of motion is limited during internal rotation in flexion and during external rotation in extension. Experimentally, our results suggest that the posterior …

Effectiveness Of An Interdependent Group Contingency With Randomization Using The Ipad, Chelsea Gyke

Electronic Theses and Dissertations

Classroom management, although considered one of the essentials of the optimal learning experience, is often a challenge for teachers. Certain classroom management strategies, such as group contingency interventions and token economies, are evidence-based strategies to aid teachers in gaining successful management of the classroom. The utilization of Class Dojo, a popular classroom management website, as a mechanism to implement an interdependent group contingency (IGC) intervention with randomized components may increase both the effectiveness of the intervention and the social validity of the intervention when compared to a manual implementation.

Participants included students in an elementary school self-contained special education classroom …

Accurate Quantitation Of Hexavalent Chromium For Reference Standard Certification And Quality Control Testing Using Speciated Isotope Dilution Mass Spectrometry, James E. Henderson

Electronic Theses and Dissertations

The ability to perform accurate, repeatable, and defensible elemental and molecular speciated analysis is immensely significant for measurements that support human health, environmental science, and industry. This is especially true since trivalent chromium [Cr(III)] is necessary for proper nutrition, while hexavalent chromium [Cr(VI)] is extremely toxic, genotoxic, and carcinogenic. The main challenges associated with speciated analysis are related to reactive species that are continuously transformed or converted to other species during sample processing. Accurate determination of Cr(III) and Cr(VI) species require a method that is capable of monitoring and correcting for interconversion, bias, and instrumental error. Traditional quantitative methods, such …

The Ethical Challenge For Hipaa’S Privacy Rule In The Genomics Era Of Data Analytics., Reem Shinawi

Electronic Theses and Dissertations

The thesis of this dissertation focuses on the Ethical Challenge for HIPAA’s Privacy Rule in the Genomics Era of Data Analytics. Data Analytics in Genomic Medicine challenges the individuals’ right to privacy. Hence, a balance is needed between the previous centrality of individual privacy and the need for population information to make breakthroughs in Genomic Medicine using Data Analytics. Such a problem demands regulatory solutions. And such solutions require the collaboration of professionals. Genomic Medicine is a field that deals with sensitive genetic information in both medicine, and research, it is essential to view it through HIPAA as it is …

Functionalized Materials From Atom Transfer Radical Processes, Sean Fischer

Electronic Theses and Dissertations

This work is focused on the synthesis, characterization, and application of functionalized materials prepared from atom transfer radical processes. Atom transfer radical processes encompass both atom transfer radical addition (ATRA) and polymerization (ATRP) reactions, both of which are catalyzed by ppm amounts of copper complexes. The synthetic efforts of ATRA include increasing adduct selectivity through optimization of reaction conditions to generate small molecules in high to moderate yields. ATRA provides retention of the halogen moiety, which is an attractive functional group that can be further modified with other transformations. Specifically, the copper-catalyzed azide-alkyne [3+2] cycloaddition (CuAAC) allows for the realization …

Atom Transfer Radical Processes: From Catalyst Design To Polymer Synthesis, Characterization, And Application, Michael Novak

Electronic Theses and Dissertations

Due to the toxicity of heavy metals and their prevalence in the environment there exists a need to develop highly active transition metal catalysts ultimately reducing the amount needed for chemical transformations. Additionally, there is interest in the scientific community for creating new materials that can remove these pollutants from industrial wastewater prior to its release into the environment. The work presented here focuses on the reduction and removal of heavy metals from industrial hazardous waste by designing novel highly active catalysts and developing polymeric adsorbents.

Highly active catalyst complexes consisting of novel hybrid ligands, 2-(dimethylamino)ethyl-bis-[2-(pyridylmethyl)amine] (M1-T2), and bis[2-(dimethylamino)ethyl]-2-(pyridylmethyl)amine (M2-T1), …

Fluoride Removal With Augmented Bentonite In Drinking Water And Community Perceptions In Arusha, Tanzania, Kara Okular

Electronic Theses and Dissertations

High fluoride concentrations in drinking water affect millions of people around the world. The World Health Organization recommended a fluoride concentration in drinking water of ≤ 1.5 mg/L; fluoride above this concentration can cause long-term dental and skeletal fluorosis. Fluoride imparts no taste to water; therefore, people do not realize that they are ingesting high fluoridated water. Researchers sought to develop a material to remove fluoride from drinking water through sorption. Aluminum was used to form a double ionic layer on the bentonite clay surface. Once mixed in contaminated water, a coagulant, ferric sulfate, was used to separate the bentonite …

Control Of Corrosion On Ss316l Using Surface Initiated Polymers, Alexander Rupprecht

Electronic Theses and Dissertations

Pitting corrosion is arguably one of the most destructive and dangerous forms of corrosion, resulting in damage to structures, the environment, and public health. In addition, damage caused to structures such as bridges, pipelines, and boats, corrosion also has a profound effect on the biomedical community. Implanted metallic devices (i.e., vascular stents and artificial joints) are prone to pitting corrosion caused by aggressive ions present in extracellular fluid. To provide a corrosion-resistant surface on SS316L, films of poly(styrene), poly(methyl acrylate), and poly(methyl methacrylate) were formed using surface-initiated atom transfer radical polymerization (SI-ATRP). The resulting hydrophobic polymer films had a fractional …

Species Distribution Modeling For Arid Adapted Habitat Specialists In Zion National Park, Sam Driver, Chris M. Schalk, Daniel Unger, David Kulhavy

Electronic Theses and Dissertations

The Arizona toad (Anaxyrus microscaphus) and Jones’ waxy dogbane (Cycladenia humilis var. jonesii) are habitat specialists with historical ranges in the desert southwest and specifically, Zion National Park (ZION). The machine learning method, MaxEnt, constructed species distribution models (SDMs) in ZION for the two study species at 30 m and 900 m spatial resolutions using climate, topographic, and remotely sensed data. Additionally, 900 m forecasting models were constructed to observe the shifts in suitable habitat for the years 2050 and 2070, based off two representative concentration pathway scenarios. Results indicate promising predictive power for both high …

Petrology Of The Gradational Intrusive Contact Between The Packsaddle Schist And The Town Mountain Granite, Enchanted Rock State Natural Area, Llano Uplift, Central Texas, Travis Galle

Electronic Theses and Dissertations

The Mesoproterozoic intrusive contact between the ~1.1 Ga anorogenic Town Mountain Granite and the ~1.3 Ga Packsaddle Schist is a gradational contact exhumed within the Llano uplift. This contact is exposed along the southeastern margin of the Enchanted Rock batholith in central Texas. Field observations, hand sample and thin section petrography, and handheld X-ray fluorescence analysis of hand samples were used to characterize the gradational nature of this contact at multiple scales. The style of gradation between the Town Mountain Granite and Packsaddle Schist varies throughout the study area, containing both injection and permeation. The complex relationships observed at the …

Tree Canopy Effects On Roof-Harvested Rainwater In East Texas, Kimberly Gamez

Electronic Theses and Dissertations

Nine experimental metal roofs with rainwater harvesting systems were constructed and water quality parameters were measured in 2016-2017 in order to evaluate the effects of arboreal overhang on roof-harvested rainwater quality collected in East Texas. Three treatments were evaluated: Rainwater collected from roofs without any overhanging tree vegetation, rainwater collected from roofs under predominantly Southern yellow pine tree cover, and rainwater collected from roofs under predominantly hardwood tree cover. Rainwater was collected from these roofs for one year. The effects of canopy cover on water quality parameters, comparison to drinking water standards, first-flush efficiency, and seasonal effects were evaluated.

Significant …

Early Life History Of Tarpon (Megalops Atlanticus) In South Carolina Estuaries: Assessment Of Juvenile Recruitment And Validity Of Aging And Back-Calculation Methods, Garrett M. Elmo

Electronic Theses and Dissertations

No abstract provided.

Parametric Model Development For Heterogeneous Atmospheric Conditions, Daniel Paul Greenway

Electronic Theses and Dissertations

No abstract provided.

Inter-Annual To Inter-Decadal Spatiotemporal Effects Of Storm And Nourishment Events In North Myrtle Beach, South Carolina, Christina Mary Boyce

Electronic Theses and Dissertations

No abstract provided.

Development And Applications Of Condensed Phase Cavity Ring-Down Spectroscopy For Studies Of Electrochemical And Interfacial., Shadi Ahmad Alnaanah

Electronic Theses and Dissertations

This dissertation reports the development of ultra-sensitive platforms based on the laser cavity ring-down spectroscopic (CRDS) technique to enable optical and spectroelectrochemical investigations in the condensed phase of matter at challenging scenarios. Firstly, an electrically-active solid/liquid interface for the evanescent-wave cavity ring-down spectroscopy (EW-CRDS) was developed to specroelectrochemically investigate redox events. By coating the interface of total internal reflection of the EW-CRDS platform with a high quality optically transparent and electrically conductive indium tin oxide thin film (ITO), we demonstrated that sufficiently long ring-down times can be achieved to allow for spectroelectrochemical investigations of redox species at solid/liquid interfaces at …

A Phenomenological Study Of Kindergarten Teachers' Perceptions Of Their Students In The Age Of Kindergarten Readiness., Adam Nelson Stephens

Electronic Theses and Dissertations

Kindergarten has changed dramatically from a play-based, social experience a generation ago to the literacy- and numeracy-based curricula of today. With this shift in academic expectations, children now take a kindergarten readiness assessment at the beginning of the school year to determine their likelihood of success based on their pre-kindergarten preparation. While previous studies have examined teachers’ perceptions of current kindergarten practices, expectations, and students, few use teachers’ descriptions as the data (Abry et al., 2015; Hustedt et al., 2018). This phenomenological study reports how kindergarten teachers at three Central Kentucky elementary schools describe their attitudes about their own kindergarten …

Black Male Student Success In Historically Black Colleges And Universities (Hbcus), Cherise A. Johnson

Electronic Theses and Dissertations

When compared to their peer counterparts, Black male students have a lower college attrition rate. Universities and higher education institutions explore ways to increase the retention and graduation rates for Black male students persisting toward college graduation, and all Black male students need to be included in the dialogue. This qualitative instrumental collective case study explored first-generation Black male college students’ lived experiences that contributed to their persistence toward graduation from Historically Black Colleges and Universities (HBCUs) framed within Tinto’s retention theory (1993). Snowball sampling was used to identify eight first-generation Black male students that were in good academic standing …

Imparting 3d Representations To Artificial Intelligence For A Full Assessment Of Pressure Injuries., Sofia Zahia

Electronic Theses and Dissertations

During recent decades, researches have shown great interest to machine learning techniques in order to extract meaningful information from the large amount of data being collected each day. Especially in the medical field, images play a significant role in the detection of several health issues. Hence, medical image analysis remarkably participates in the diagnosis process and it is considered a suitable environment to interact with the technology of intelligent systems. Deep Learning (DL) has recently captured the interest of researchers as it has proven to be efficient in detecting underlying features in the data and outperformed the classical machine learning …

Teacher Perceptions Of Collegial Collaboration In An Academy Structure., Kristy Marie Field

Electronic Theses and Dissertations

Collaboration in is an often researched, many-named concept with a definition which has historically been unclear. What one calls collegiality another may call teacher teaming and yet another may refer to as professional networking. Scholars agree effective teacher collaboration can lead to higher student achievement, teacher efficacy, and teacher retention. However, as elusive as an agreed-upon definition may be an agreed-upon structure that fosters an effective version of this collaboration. When Ford began the Ford Next Generation Learning initiative, they embarked on the path to developing a school model that focused on school and community partnerships to support long-term, transformational …

Teacher Perceptions Of Blended Learning To Support 21st Century Learners, Nikki Hensley

Electronic Theses and Dissertations

The purpose of this qualitative study was to understand teacher perceptions of blended learning as an instructional methodology for addressing the needs of diverse learners. The researcher explored the perceptions of teachers who were participating in an ongoing professional development program within their school district. This program focused on improving teaching and learning through the implementation of a blended learning approach. The researcher examined the experiences of teachers as they learned to adapt pedagogical practices to address the learning needs of 21st century students through blended learning. The researcher sought to gain a better understanding of how teachers perceived that …

The Persistence Of Acid Mine Drainage At An East Texas Coal Mine, Sarah Zagurski

Electronic Theses and Dissertations

The objective of this study was to estimate the time it will take for acid forming materials (pyrite) to be weathered to a state of equilibrium and thus cease to produce acid in ground and surface waters within Oak Hill Mine. This was accomplished using an ex-situ kinetic leaching study incorporating a humidity cell in a controlled laboratory setting. Leaching was conducted on soil cores obtained from the vadose zone at Oak Hill Mine and the humidity cell was used to accelerate oxidation of the pyrite within the cores.

An in-situ field study was also conducted that monitored groundwater conditions …

Stratigraphy, Petrology, Diagenesis, Paleontology, And Depositional Environments Of The Harrisburg Member Of The Kaibab Formation In Northern Arizona And Southern Utah, Zachery T. Case

Electronic Theses and Dissertations

The Kaibab Formation has two members, the Fossil Mountain Member below and the Harrisburg Member above. They were deposited in shallow-marine shelf to restricted coastal settings. Stratigraphically above are the Rock Canyon Conglomerate and the Moenkopi Formation; consisting of the Timpoweap and Lower Red members; which are the only members present in the study area. The Rock Canyon Conglomerate was deposited in depressions and as a regolith. The Timpoweap and Lower Red members were deposited in shallow marine to tidal environments.

Nine stratigraphic units were identified in the Harrisburg Member. Units one, two, three, five, six, seven, and nine are …

Characterization Of Adiposity And Inflammation Genetic Pleiotropy Underlying Cardiovascular Risk Factors In Hispanics., Mohammad Yaser (Anwar)

Electronic Theses and Dissertations

The observed overlap between genetic variants associated with both adiposity and inflammatory markers suggests that changes in both adiposity and inflammation could be partially mediated by common pathways. The pervasive but sparsely characterized “pleiotropic” genetic variants associated with both adiposity and inflammation have been hypothesized to provide insight into the shared biology. This study explored and characterized the genetic pleiotropy underpinning adiposity and inflammation using genetic and phenotypic observations from the Cameron County Hispanic Cohort (CCHC). A total of 3,313 samples and >9 million single nucleotide polymorphisms (SNPs) were examined in this study. Mixed model genome-wide association studies (GWAS) were …

Photoelectrical And Photoelectrochemical Characterization Of The Materials Used In Dye-Sensitized And Perovskite Solar Cells., Pom Lal Kharel

Electronic Theses and Dissertations

Solar energy is one of the most important alternative renewable energy sources to fulfill the increasing demand of energy in the world. Third-generation solar cells like dye-sensitized solar cells, perovskite solar cells, quantum dot solar cells, and organic solar cells are extensively studied to increase their photoconversion efficiency, and ultimately for their large-scale implementation. A dye-sensitized solar cell consists of a photoanode of a mesoporous film of titania sensitized with dye sandwiched with a counter electrode, which is usually a platinum-coated transparent conducting oxide, and a redox couple injected between the photoanode and counter electrode. Doping titania with rare-earth metal …

Statistical Approaches Of Gene Set Analysis With Quantitative Trait Loci For High-Throughput Genomic Studies., Samarendra Das

Electronic Theses and Dissertations

Recently, gene set analysis has become the first choice for gaining insights into the underlying complex biology of diseases through high-throughput genomic studies, such as Microarrays, bulk RNA-Sequencing, single cell RNA-Sequencing, etc. It also reduces the complexity of statistical analysis and enhances the explanatory power of the obtained results. Further, the statistical structure and steps common to these approaches have not yet been comprehensively discussed, which limits their utility. Hence, a comprehensive overview of the available gene set analysis approaches used for different high-throughput genomic studies is provided. The analysis of gene sets is usually carried out based on …

Design, Synthesis And Application Of Janus Gold Nanoprisms For Directed Self-Assembly., Md. Emtias Chowdhury

Electronic Theses and Dissertations

Colloidal Janus particles that possess more than one type of surface chemistry or functionalities have drawn significant interest due to their enormous potential in bottom-up synthetic strategies for complex superstructures. Moreover, the property of molecular recognition, tunability, and predictability of the DNA-mediated interactions enable a high degree of control over particle assembly to generate highly ordered nanostructures with emergent applications. In this dissertation, we present our works on the synthesis of Janus particles from anisotropic gold nanoprisms, and DNA- mediated assembly of nanoprisms and polymer beads in four major areas: 1) Facet selective asymmetric functionalization of gold nanoprisms for Janus …

Modified-Half-Normal Distribution And Different Methods To Estimate Average Treatment Effect., Jingchao Sun

Electronic Theses and Dissertations

This dissertation consists of three projects related to Modified-Half-Normal distribution and causal inference. In my first project, a new distribution called Modified-Half-Normal distribution was introduced. I explored a few of its distributional properties, the procedures for generating random samples based on Bayesian approaches, and the parameter estimation based on the method of moments. The second project deals with the problem of selection bias of average treatment effect (ATE) if we use the observational data. I combined the propensity score based inverse probability of treatment weighting (IPTW) method and the directed acyclic graph (DAG) to solve this problem. The third project …

Kindergarten Readiness And Grade 1 Mathematics Achievement., Faneshia Mcpherson Jones

Electronic Theses and Dissertations

From 2013-2019, all Kentucky school districts have administered a common screener to each student entering kindergarten. In this study, kindergarten readiness—determined by academic skills/cognitive development, language development, and physical development—was a significant predictor of grade 1 end-of-year mathematics achievement. The model predictions show that kindergarten students who met the readiness benchmark had higher grade 1 end-of-year mathematics scores compared to students who entered kindergarten below the readiness benchmark. The model predictions improved substantially with the inclusion of prior level of achievement as indicated by grade 1 beginning of the year mathematics achievement. However, students with stronger readiness skills demonstrated significantly …