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A Comparision Of Teachers' Ratings Of Published Versus Ai-Generated Descriptions Of Evidence Based Practices In Education., Lora T. Hall Dec 2025

A Comparision Of Teachers' Ratings Of Published Versus Ai-Generated Descriptions Of Evidence Based Practices In Education., Lora T. Hall

Electronic Theses and Dissertations

The persistent gap between educational research and classroom practice continues to limit teachers’ use of evidence-based practices (EBPs), despite strong empirical support and federal mandates encouraging their implementation. A key barrier to closing this research-to-practice gap is the limited accessibility, usability, and perceived relevance of traditional research dissemination formats. With the rapid rise of artificial intelligence (AI) tools capable of summarizing and restructuring complex information, this study examined whether AI-generated practitioner-oriented descriptions of an EBP would be rated differently from a published practitioner article on the same practice. Using an experimental cross-sectional survey design, 70 in-service teachers were randomly assigned …


Synthesis, Characterization, And Chemical Reactivity Of Calcium-Alginate Hydrogel Beads Containing Metal Nanoparticles And Nanoclusters., Rajiv Kumar Singh Dec 2025

Synthesis, Characterization, And Chemical Reactivity Of Calcium-Alginate Hydrogel Beads Containing Metal Nanoparticles And Nanoclusters., Rajiv Kumar Singh

Electronic Theses and Dissertations

This dissertation explores the synthesis, stability, and reactivity of various metal nanoparticles (NPs) and nanoclusters (NCs) of varied size and stabilizers contained within millimeter-sized calcium alginate (Ca-Alg) hydrogel polymer beads. Hydrogel beads synthesized by combining sodium alginate with Au or Ag NPs stabilized with trisodium citrate (Cit) and adding dropwise into a 4.0 M Ca2+ solution remained stable and contained within the beads. Those synthesized Au, Pd and AuPd NCs stabilized with glutathione (SG) became partially released from the hydrogel within a day. The synthesis of beads containing aggregated Cit Au NPs occurs by inducing aggregation with tetrakis(hydroxymethyl) phosphonium …


The Important Of Female Coaches: What Barriers They Face, Why They Stay, And What Can Be Done To Attract More., Hayley E. Yourous Dec 2025

The Important Of Female Coaches: What Barriers They Face, Why They Stay, And What Can Be Done To Attract More., Hayley E. Yourous

Electronic Theses and Dissertations

After the passage of Title IX, there has been an increase in the number of females participating in sports; however, the same cannot translate to women in coaching or leadership positions (Acosta & Carpenter, 2014; Hart et al., 1986; LaVoi & Baeth, 2018). The purpose of this hermeneutic phenomenological study was to explore the lived experiences of females who had served as head coaches in the high school setting with at least eight years of experience as a head coach. The NCAA (2022) reported in 2020 that female coaches accounted for 41.3% of female teams' head coaches, both intercollegiate and …


Alkali-Silica Reactivity And Ionic Transport In Mortar With Hydrophobic Inclusions., Isaac Offei Dec 2025

Alkali-Silica Reactivity And Ionic Transport In Mortar With Hydrophobic Inclusions., Isaac Offei

Electronic Theses and Dissertations

Alkali-silica reaction (ASR) causes extensive damage to concrete infrastructure worldwide, with traditional mitigation strategies increasingly constrained by supplementary cementitious material (SCM) supply limitations. This dissertation investigates an innovative approach to ASR prevention through strategic application of hydrophobic materials to modify moisture and ionic transport pathways in cement mortars. The research employed a comprehensive three-objective experimental program using highly reactive aggregates and three hydrophobic materials: hexamethyldisilazane (HMDS)-treated fumed silica, silane-based emulsion, and silane-based crème. The first objective demonstrated the feasibility of hydrophobic aggregate surface modification, achieving 46% and 38% reductions in ASR expansion for washed and non-washed hydrophobic aggregates, respectively. Microstructural …


Floodplain Lake Hydrodynamic And Morphodynamic Connections Through Hydraulic Modeling Along The Pee Dee River, Sc, Charles Cj Mina Dec 2025

Floodplain Lake Hydrodynamic And Morphodynamic Connections Through Hydraulic Modeling Along The Pee Dee River, Sc, Charles Cj Mina

Electronic Theses and Dissertations

Rivers have been essential in the success of humankind. This reliance has created a vested interest in studying the rivers' environmental history through using floodplain deposits, with the assumption that coarser sediments correlate to higher discharge floods. However, shifting hydrological connectivity and hydrodynamics can complicate this correlation in primary repositories of flood deposits, oxbow lakes, by altering the texture of sediments delivered to them. Studying these complications is essential for quantifying paleoflood magnitude using the sediment record, but has been difficult, as the currently used index of hydrological connectivity relies on water stage, which does not reflect the sediment flux …


The Food Truck: A Multi-Product Newsvendor With Expectile Risk, Sekyiwaah Nuamah Dec 2025

The Food Truck: A Multi-Product Newsvendor With Expectile Risk, Sekyiwaah Nuamah

Electronic Theses and Dissertations

The Newsvendor Problem is a fundamental model in Operation Research and Supply Chain Management used to determine the optimal order quantity under uncertain demand to minimize expected costs.
This research extends the classical Newsvendor problem to a multi--product setting, addressing the risk of asymmetric cost structures faced by a food truck. This thesis introduces expectile risk measures to quantify and manage uncertainty in demand, moving beyond traditional risk metrics. To evaluate the impact of expectile-based decision-making, we analyze three types of demand distributions--simple, symmetric, and skewed. For skewed distributions, we apply linear spline inverse interpolation to derive expectile values from …


Deep Learning With Kalman Filter, Rexford Julius Quaye Dec 2025

Deep Learning With Kalman Filter, Rexford Julius Quaye

Electronic Theses and Dissertations

This thesis presents an extension of the Kalman filter to handle nonlinear and non-Gaussian systems. The standard Kalman filter is optimal under Gaussian assumptions but struggles with more complex noise models. This work introduces a novel loss function based on the Mahalanobis distance, which incorporates the covariance structure of measurement errors, enabling the filter to adapt to non-Gaussian scenarios. The neural network framework is applied to predict the system’s process model, while retaining the classical Kalman measurement update. The proposed methodology is demonstrated through examples of car position and rocket altitude tracking. The results show that the new approach performs …


Exploring The Relationship Between Secondary Student Perceptions Of Teacher Involvement And Student Academic Success In Online Social Studies Courses, Thomas Matthew Herrington Dec 2025

Exploring The Relationship Between Secondary Student Perceptions Of Teacher Involvement And Student Academic Success In Online Social Studies Courses, Thomas Matthew Herrington

Electronic Theses and Dissertations

The rapid growth of online learning in secondary education has highlighted the need to better understand factors that contribute to student success. While considerable research has examined online learning at the postsecondary level and in state-tested subjects, little attention has been given to social studies courses. This qualitative study explored the relationship between secondary students’ perceptions of teacher involvement and their academic success in asynchronous online social studies courses. Participants included 22 students from two accredited high schools in Mississippi, one fully online and one traditional brick-and-mortar school, both of which offered asynchronous social studies courses approved by the state …


The Impact Of State-Mandated High-Stakes Standardized Testing On The Job Satisfaction Of Third-Grade Reading Teachers In Mississippi, Jenny Kate Ernst Dec 2025

The Impact Of State-Mandated High-Stakes Standardized Testing On The Job Satisfaction Of Third-Grade Reading Teachers In Mississippi, Jenny Kate Ernst

Electronic Theses and Dissertations

This qualitative study examined how state-mandated standardized testing influences the job satisfaction of current and former third-grade reading teachers in Mississippi. Guided by Self-Determination Theory, Herzberg’s Two-Factor Theory, and the Job Demands-Resources Model, the research explored how accountability pressures shape teachers’ motivation, emotional well-being, and instructional autonomy. Data were collected through an open-ended online survey of current and former Mississippi third-grade reading teachers. Analysis of responses revealed four central themes: emotional strain and burnout, loss of autonomy and creativity, impact on instructional practices, and student impact. Findings indicated that teachers perceive standardized testing as a major source of stress that …


Design And Prototyping Of An Acoustic Positioning System For Gps-Denied Environment, Harley Hogan Garrett Dec 2025

Design And Prototyping Of An Acoustic Positioning System For Gps-Denied Environment, Harley Hogan Garrett

Electronic Theses and Dissertations

Finding the placement of sensors is known as sensor localization, and is a necessary task to ensure that a network is capable of array processing operations, such as direction of arrival measurements. This thesis proposes a method to perform sensor localization for a wireless sensor network using acoustics. Each sensor is equipped with a microphone, speaker, and processor. Using these, the proposed system is able to find the distance between each sensor and later the geometry of the network. A series of optimizations help reduce error and improve the final accuracy of the system to within 6.5 cm. The proposed …


Stochastic Functional Data-Driven Models For Real-Time Battery Health Forecasting Under Dynamic Operating Conditions, Joshua Owusu Dec 2025

Stochastic Functional Data-Driven Models For Real-Time Battery Health Forecasting Under Dynamic Operating Conditions, Joshua Owusu

Electronic Theses and Dissertations

This thesis provides an effective statistical model to predict the real-time state of lithium-ion batteries for reliable Battery Management Systems (BMS). It highlights battery data (voltage, current, temperature) as smooth functional curves. The principal method demonstrates diminishing trends to health outcomes like State of Health (SoH) and Remaining Useful Life (RUL) by employing Functional Principal Component Analysis (FPCA) and Bayesian Functional Linear Models (FLMs). The primary objective is to figure out how uncertain forecasts are. Simulations demonstrate that the highest accuracy (lowest MSE) is achieved through low noise levels along with large sample sizes. The final system provides a highly …


Creating A Growth Mindset: A Mixed-Methods Program Review Research Study On The Effects Of Social–Emotional Learning On Retained Third-Grade Students, Casshaunda Davis Dec 2025

Creating A Growth Mindset: A Mixed-Methods Program Review Research Study On The Effects Of Social–Emotional Learning On Retained Third-Grade Students, Casshaunda Davis

Electronic Theses and Dissertations

In Mississippi’s public elementary schools, third-grade students are faced with promotion–retention decisions from the third-grade state assessment and, when retention is the outcome, students often experience negative emotional outcomes. In our school setting, the challenge is how better to help our retained, third-grade students to cope with retention and to grow a strong mindset of self-efficacy towards academic achievement after experiencing retention. This mixed-methods program review research study was conducted to institute a social–emotional learning intervention program in our existing MTSS behavioral program offered to Tier III (at-risk) students. I followed an intervention program to foster a growth mindset for …


Topic Modeling And Culturomic Analysis Of 30,000 Books Over 100 Years Using Gensim, Michael A. Freeman Dec 2025

Topic Modeling And Culturomic Analysis Of 30,000 Books Over 100 Years Using Gensim, Michael A. Freeman

Electronic Theses and Dissertations

This thesis explores the cultural influence of historical events on English-language fiction published between 1820 and 1929. Using a corpus of 30,256 digitized books from Project Gutenberg, Latent Dirichlet Allocation (LDA) topic modeling was applied to identify recurring themes across eleven decades. The study sought to determine whether historically significant events could be detected within fictional narratives. One clear instance emerged: Napoleon Bonaparte and the Napoleonic Wars appeared explicitly in the 1820s corpus. Beyond this, several thematic patterns were observed—such as maritime language in the 1840s, national identity in the 1880s, and youth-oriented dialogue in the early 20th century—that plausibly …


Spectroscopic Studies Of Metal Containing Molecules Under Jet-Cooled Conditions Using Laster-Induced Fluoresence (Lif) And Dispersed Fluorescence (Df) Techniques., Md Touhidul Islam Dec 2025

Spectroscopic Studies Of Metal Containing Molecules Under Jet-Cooled Conditions Using Laster-Induced Fluoresence (Lif) And Dispersed Fluorescence (Df) Techniques., Md Touhidul Islam

Electronic Theses and Dissertations

This dissertation examines the jet-cooled spectroscopy of the calcium propoxide radical (CaOC₃H₇) to understand how increasing molecular complexity reshapes symmetry, electronic degeneracy, and vibronic coupling. Moving from Ca–OCH₃ to Ca–OC₃H₇ lowers symmetry (C₃v → Cs → C₁) and exposes effects such as spin–orbit splitting and both Jahn–Teller and pseudo–Jahn–Teller distortions. These features remodel the excited-state potential surfaces and are directly observable with laser-induced fluorescence (LIF) and dispersed fluorescence (DF). A central goal is to evaluate whether CaOC₃H₇ supports the near-diagonal vibronic branching needed for efficient optical cycling, while also highlighting implications for catalysis and astrochemistry, where precise spectral fingerprints guide …


Experiences Of Title Ix Hearing Panel Members., Amanda Gage Stonecipher Dec 2025

Experiences Of Title Ix Hearing Panel Members., Amanda Gage Stonecipher

Electronic Theses and Dissertations

The number of allegations of sexual misconduct on college campuses has been increasing over the past decade and higher education institutions are charged with addressing the misconduct. Addressing student behavior on college campuses through a conduct process is woven into the fabric of higher education, and many institutions use a hearing panel model to determine if institutional policies were violated. My research aims to explore how student conduct hearing panel members process the tension between the emotional management required when hearing intimate and traumatic details of a sexual misconduct case. The data for this research were collected via semi structured …


Optical, Mechanical, And Transport Characterization Of Two-Dimensional Magnetic Materials., Hiruni Weerahennedige Dec 2025

Optical, Mechanical, And Transport Characterization Of Two-Dimensional Magnetic Materials., Hiruni Weerahennedige

Electronic Theses and Dissertations

This work investigates the structural, magnetic, thermoelectric, and optoelectronic behavior of layered two-dimensional (2D) materials, with emphasis on Fe3GeTe2, Ni-substituted Fe3GeTe2 alloys, and GeSe. The study aims to clarify how dimensionality, alloying, and external perturbations influence charge transport, magnetic ordering, and light-matter interactions in van der Waals crystals. Single crystals of Fe3GeTe2 and (NixFe1-x)3GeTe2 (x = 0-1) were synthesized by chemical vapor transport and characterized using X-ray diffraction, Raman spectroscopy, and transmission electron microscopy. Angle-resolved polarized Raman spectroscopy resolved symmetry-dependent phonon modes and …


Symmetry, Stability, And Robust Optimization Strategies For Nonorthogonal Multiconfiguration Self-Consistent Field Wavefunctions., Zihui Song Dec 2025

Symmetry, Stability, And Robust Optimization Strategies For Nonorthogonal Multiconfiguration Self-Consistent Field Wavefunctions., Zihui Song

Electronic Theses and Dissertations

The "different orbital different configuration" (DODC) framework is a general formulation of multireference wavefunctions that allows each configuration (determinant) to possess its own set of optimized molecular orbitals, rather than sharing a common orbital basis as in conventional orthogonal configuration interaction (CI) or Complete Active Space Self-Consistent Field (CASSCF) methods. One prominent example of the DODC framework is the Nonorthogonal Configuration Interaction (NOCI) method, which relaxes the orthogonality constraint between the orbitals of different configurations. This relaxation enables a compact yet flexible description of systems exhibiting strong correlation. By employing multiple nonorthogonal reference determinants, NOCI naturally incorporates orbital relaxation and …


Artificial Intelligence For Cancer Imaging: Integrated Frameworks For Hepatocellular Carcinoma And Pulmonary Nodules., Ahmed Muhammed Sherif Mostafa Alksas Dec 2025

Artificial Intelligence For Cancer Imaging: Integrated Frameworks For Hepatocellular Carcinoma And Pulmonary Nodules., Ahmed Muhammed Sherif Mostafa Alksas

Electronic Theses and Dissertations

Reliable, reproducible, and clinically useful artificial intelligence (AI) for oncologic imaging requires more than high headline metrics: it demands principled pipelines, calibrated predictions, and designs that generalize across anatomy, scanners, and institutions. This dissertation develops such pipelines in two complementary domains— hepatocellular carcinoma (HCC) on multiphase CT/MRI and indeterminate pulmonary nodules on thin-slice CT—while articulating evaluation and reporting practices that support credible clinical translation. The work proceeds in six core chapters. Two focused reviews synthesize the state of the art in (i) radiomics/AI for HCC and (ii) early assessment of lung nodules, mapping common pitfalls (data leakage, class imbalance, kernel …


From 2d To 3d: Multi-Agent Reinforcement Learning For Spectrum-Constrained Urban Air Mobility., Qingyang Li Dec 2025

From 2d To 3d: Multi-Agent Reinforcement Learning For Spectrum-Constrained Urban Air Mobility., Qingyang Li

Electronic Theses and Dissertations

Advanced Air Mobility (AAM) and Urban Air Mobility (UAM) are accelerating a transformation of air transportation but face acute spectrum congestion in dense urban environments. Reliable Control and Non-Payload Communications (CNPC) must be maintained at all times to ensure safe operations, even as fleets of aerial vehicles (AVs) transport passengers and cargo between distributed vertiports. We first develop a 2D formulation that jointly optimizes discrete headings, velocities, and spectrum allocation to minimize total mission time while satisfying quality of service (QoS) and collision-avoidance constraints, and we demonstrate significant gains over non-learning and learning baselines. Building on this 2D framework, we …


Numerical Studies Of Entanglement Entropy In The Fredkin Spin Chain, Joshua Tyler Moore Dec 2025

Numerical Studies Of Entanglement Entropy In The Fredkin Spin Chain, Joshua Tyler Moore

Electronic Theses and Dissertations

In this dissertation, we present work on the entanglement properties of the Fredkin spin chain, a spin one-half chain with local three-body interactions. We focus on the development and use of Monte Carlo techniques to measure the entanglement entropy for bipartitions of the Fredkin spin chain.

In the first chapter, we formally develop an extension to existing Monte Carlo techniques to allow for the calculation of higher-order Rényi entanglement entropies using the replica trick. The method clarifies how multiple systems can be simulated in parallel to calculate the Rényi entanglement entropy at any order.

In the next chapter, we apply …


Postprocessing Gan-Generated Synthetic Time Series Using Dynamic Time Warping, Md Raisul Islam Roni Dec 2025

Postprocessing Gan-Generated Synthetic Time Series Using Dynamic Time Warping, Md Raisul Islam Roni

Electronic Theses and Dissertations

Generative Adversarial Networks (GANs) are a class of deep learning models capable of producing realistic synthetic data that preserve the statistical and temporal characteristics of real datasets. The DoppelGANger (DGAN) framework extends this approach to time series data by jointly modeling temporal dependencies and contextual metadata. However, synthetic sequences generated by GAN may show temporal misalignment, resulting in inconsistencies when compared with real data. This study presents a postprocessing framework based on Dynamic Time Warping (DTW) and its differentiable extension Soft-DTW to improve the temporal alignment of synthetic time series. The framework is evaluated using quantitative measures of alignment and …


Teacher Perceptions Of The Effectiveness Of Voluntary Pre-Kindergarten Attendance, Kimberly Taylor Dec 2025

Teacher Perceptions Of The Effectiveness Of Voluntary Pre-Kindergarten Attendance, Kimberly Taylor

Electronic Theses and Dissertations

The purpose of this study was to identify the perceptions of educators with respect to student enrollment in voluntary pre-kindergarten classes provided through the Tennessee Department of Education in public schools. The data collection strategy used to gain teacher perspectives was through conducting one-on-one interviews with 15 educators in three Tennessee school districts. To qualify for the study, teachers must have been teaching in kindergarten classrooms that receive students who had previously been enrolled in the school’s pre-kindergarten program. Data collection and analysis were based on the Grounded Theory approach which uses data that is systematically gained and analyzed to …


A Leslie System For A Demographic Simulation: From An Actuarial Point Of View, David Kings Dec 2025

A Leslie System For A Demographic Simulation: From An Actuarial Point Of View, David Kings

Electronic Theses and Dissertations

This thesis develops a discrete stochastic linear systems interpretation of age–stage demographic evolution grounded in Leslie operators and realized in a discrete-event simulation implemented with salabim. The central claim is that one annual cycle of the simulation constitutes a cone-preserving, stochastic affine transformation on a high- dimensional population state vector indexed by age, sex, marital status, household type, employment, and education, and that the composition of yearly operators yields a random matrix product whose top Lyapunov exponent is the stochastic counterpart of the Perron–Frobenius growth rate (Caswell, 2001; Tuljapurkar, 1997)[1, 2]. The actuarial bridge is constructed by mapping simulated survival …


Isolation, Chemical Characterization, And In-Vitro Cytotoxic Evaluation Of Novel Polar Flavonoids From Chromolaena Leivensis, Matthew Tohatsu Tetteh Dec 2025

Isolation, Chemical Characterization, And In-Vitro Cytotoxic Evaluation Of Novel Polar Flavonoids From Chromolaena Leivensis, Matthew Tohatsu Tetteh

Electronic Theses and Dissertations

This study focuses on isolation, chemical characterization, and in-vitro cytotoxic evaluation of novel polar flavonoids from chromolaena leivensis. A 95% ethanolic extract of c. leivensis shipped by Prof. Ruben Torrenegra from University of Applied and Environmental Sciences, Bogota, Colombia, was dissolved in 1:1 methanol/chloroform mixture and its purity analyzed by TLC. The sample was eluted with toluene/methanol in an increasing order of polarity on silica gel, resulting in 49 fractions labelled CLA1 to CLA49. Among these fractions, CLA10 (1) and CLA19 (2) obtained yellow and white crystals. They were analyzed by GCMS, IR, and …


Grokking Applied To Chaotic Iterates Of The Logistic Map, Felix Donkoh Dec 2025

Grokking Applied To Chaotic Iterates Of The Logistic Map, Felix Donkoh

Electronic Theses and Dissertations

This thesis investigates grokking, the delayed transition from memorization to generalization in neural networks trained on deterministic chaotic data. Using an integer–arithmetic discretization of the logistic map, yn+1 =( a yn(p − yn))/ p 2 , bounded aperiodic sequences were generated across control parameters α ranging from 3.0 to 4.0. Transformer-based models displayed characteristic grokking curves. In periodic and chaotic regimes, validation accuracy rose suddenly after long plateaus, while at the Feigenbaum boundary (α ≈ 3.57) generalization failed completely. Increasing data diversity restored learning in chaotic domains, and explicit α–conditioning enabled a single network to generalize across all regimes. A …


An Income Subsystem As A Discrete Stochastic Leslie System: A Simulation-Based Approach, Fahd Nii Okantah Cobblah Dec 2025

An Income Subsystem As A Discrete Stochastic Leslie System: A Simulation-Based Approach, Fahd Nii Okantah Cobblah

Electronic Theses and Dissertations

This thesis formulates the household-income engine of an integrated population sim- ulator as a Discrete Stochastic Leslie System (DSLS). The nonnegative state vector nt ∈ Rk + aggregates income, savings, debt, employment, and transfers. (Here, the subscript + denotes the positive cone, i.e., vectors with nonnegative components). Annual evolution is linear in state, stochastic in coefficients: nt+1 = Ttnt + εt, with Tt : Rk + → Rk + cone-preserving. Exogenous macro drivers (inflation, employment, tax, salary inflation, mortgage) are forecast via ARIMA; forecasts multiply entries of Tt, preserving linearity in expectation while introducing realistic temporal correlation. The discrete-event implemented …


Mountain Communities During A Time Of War: A Case Study Of The Hutsul Region In The Carpathian Mountains Of Ukraine, Pavlo Rybaruk Dec 2025

Mountain Communities During A Time Of War: A Case Study Of The Hutsul Region In The Carpathian Mountains Of Ukraine, Pavlo Rybaruk

Electronic Theses and Dissertations

This thesis investigates the ethno-ecological technologies employed by the Hutsul people within the highland agrarian economy of the Carpathian Mountains. Over centuries, the Hutsuls have developed ethno-ecological technologies that maintain ecological integrity while supporting community livelihoods.

The study addresses three primary research questions: What are the most important ethno-ecological technologies of the Hutsul highland economy? How might these traditional ethno-ecological practices be applied to economic, agricultural, and tourism development in the Hutsul region? How might these traditional ethno-ecological practices be combined with contemporary approaches to encourage sustainable development in the region?

The research explores the devastating impact of the Russian …


Synthesis Of Phenyl-Substituted Zinc Dipyrrin Photosensitizer For Carbon Dioxide Reduction, Stephen Ankomah Dec 2025

Synthesis Of Phenyl-Substituted Zinc Dipyrrin Photosensitizer For Carbon Dioxide Reduction, Stephen Ankomah

Electronic Theses and Dissertations

The release of CO₂ from fossil fuel combustion drives the need for its conversion into more sustainable options like CO and CH₄ via photocatalytic reduction. This process requires a catalyst, sensitizer, and electron donor. Zinc dipyrrin-based complexes are promising photosensitizers, offering an alternative to expensive, rare-metal-based systems. Most first-row transition metal dipyrrin compounds have short excited-state lifetimes due to rapid nonradiative decay, but Zn(II) dipyrrin complexes stand out. With a d¹⁰ configuration, they lack deactivating ligand field states and can access long-lived triplet states through a charge-separated intermediate. A phenyl-substituted Zn(II) dipyrrin complex was synthesized and studied using NMR to …


Divergent Responses Of Branched-Chain And Straight-Chain Lipid Membranes To Butanol Stress Revealed By All-Atom Molecular Dynamics Simulations, Joshua Olaf Aggrey Dec 2025

Divergent Responses Of Branched-Chain And Straight-Chain Lipid Membranes To Butanol Stress Revealed By All-Atom Molecular Dynamics Simulations, Joshua Olaf Aggrey

Electronic Theses and Dissertations

Membrane integrity under chemical stress is critical to cellular survival and industrial microbial bioproduction, yet the molecular basis of bilayer resilience remains poorly understood. Using all-atom molecular dynamics simulation, we compare the effect of increasing concentrations of 1‑butanol on membranes composed of straight-chain (1,2-dipalmitoyl-sn-glycero-3-phosphocholine, DPPC) and branched-chain (1-anteiso-palmitoyl-2-palmitoyl-sn-glycero-3-phosphocholine, APPC) lipids, which differ in the point of attachment of a single methyl group. In the absence of butanol, both membranes exhibit well-ordered architectures consistent with experimental benchmarks; however, under increasing solvent stress, their behaviors diverge markedly. DPPC membranes display gradual thinning, modest area per lipid …


Reservoir Characterization Of The Clarksville Formation In Red River County, Texas, Matthew Allen Parker Dec 2025

Reservoir Characterization Of The Clarksville Formation In Red River County, Texas, Matthew Allen Parker

Electronic Theses and Dissertations

The Upper Jurassic Clarksville Formation in northern Texas and southern Oklahoma is a productive but poorly understood sandstone–conglomerate unit with unresolved questions regarding its depositional environment and sediment provenance. This study evaluates the depositional setting, spatial distribution, and diagenetic controls of the Clarksville Formation using integrated core and well log analyses in Red River County, Texas. Three cores (Lennox Unit #1, Reeder Oil Unit #2, and Reeder Oil Unit #7) were analyzed for lithology, mineralogy, porosity, permeability, and fluid saturation, and correlated with 137 well logs to map formation thickness and regional trends.

Four lithofacies were identified based on core …