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Nitrogen-Doped Carbon Fiber Ultramicroelectrodes As Electrochemical Sensors For Detection Of Hydrogen Peroxide, Eric Wornyo
Nitrogen-Doped Carbon Fiber Ultramicroelectrodes As Electrochemical Sensors For Detection Of Hydrogen Peroxide, Eric Wornyo
Electronic Theses and Dissertations
Carbon fiber ultramicroelectrodes (CF-UMEs) are commonly used as electrochemical probes and sensors due to their small size, fast response, and high signal-to-noise ratio. Surface modification strategies are often employed on CF-UMEs to improve their selectivity and sensitivity for desired applications. However, many modification methods are cumbersome and require expensive equipment. In this study, a simple approach known as soft nitriding is used to prepare nitrogen-doped CF-UMEs (N-CF-UMEs). Nitrogen groups introduced via soft nitriding act as electrocatalytic sites for the breakage of O-O bonds during the reduction of peroxides like H2O2, a common target of biosensing strategies. …
Using An Inventory Of Unstable Slopes To Prioritize Probabilistic Rockfall Modeling And Acid Base Accounting In Great Smoky Mountains National Park, Thomas A. O'Shea
Using An Inventory Of Unstable Slopes To Prioritize Probabilistic Rockfall Modeling And Acid Base Accounting In Great Smoky Mountains National Park, Thomas A. O'Shea
Electronic Theses and Dissertations
An inventory of unstable slopes along transportation corridors and performance modeling are important components of geotechnical asset management in Great Smoky Mountains National Park (GRSM). Hazards and risk were assessed for 285 unstable slopes along 151 miles of roadway. A multi-criteria model was created to select fourteen sites for two-dimensional probabilistic rockfall simulations and Acid Base Accounting (ABA) tests. Simulations indicate that rock material would likely enter the roadway at all fourteen sites. ABA test results indicate that influence of significant acid-producing potential is generally confined to slaty rocks of the Anakeesta Formation and graphitic schist of the Wehutty Formation. …
Bilateral Ground Reaction Force Jumping Asymmetry And Performance, Keith Painter
Bilateral Ground Reaction Force Jumping Asymmetry And Performance, Keith Painter
Electronic Theses and Dissertations
The prevalence of asymmetry in performance research has increased in recent years with mixed results. Much of the performance research has focused on unilateral jumping activities attempting to show relationships to other performance variables. However, bilateral ground reaction forces (bGRF) from jumps are more frequently assessed in athlete monitoring programs and the asymmetry from those jumps could be a simple addition to data already being collected. Research into bGRF asymmetries is lacking and no studies have addressed longitudinal changes. Additionally, research into the relationship of asymmetries to performance have infrequently used athletes. For these reasons, this dissertation will focus on …
Manifold Learning With Tensorial Network Laplacians, Scott Sanders
Manifold Learning With Tensorial Network Laplacians, Scott Sanders
Electronic Theses and Dissertations
The interdisciplinary field of machine learning studies algorithms in which functionality is dependent on data sets. This data is often treated as a matrix, and a variety of mathematical methods have been developed to glean information from this data structure such as matrix decomposition. The Laplacian matrix, for example, is commonly used to reconstruct networks, and the eigenpairs of this matrix are used in matrix decomposition. Moreover, concepts such as SVD matrix factorization are closely connected to manifold learning, a subfield of machine learning that assumes the observed data lie on a low-dimensional manifold embedded in a higher-dimensional space. Since …
Response To Intervention 2 Easycbm And Aimsweb Intervention Programs How They Relate To Student Growth, George T. Hopson
Response To Intervention 2 Easycbm And Aimsweb Intervention Programs How They Relate To Student Growth, George T. Hopson
Electronic Theses and Dissertations
This researcher aimed to determine how data collected from computer-based assessment programs, specifically EasyCBM and AIMSweb, was used in data-driven instruction and used to identify risk levels in math and reading areas proficiency. Data from intervention programs were collected from six participating high schools. The data collection included math and reading universal screening scores and levels of risk indicators from Tier 2 and Tier 3 levels of their response to intervention (RTI) programs. Section A included math data within a baseline score and a risk indicator level. Section B had reading scores with a baseline score and a risk indicator …
Isotopic Analysis And Mobility Mapping Of Mammuthus Columbi From The Mammoth Site In South Dakota, Matthew Harrington
Isotopic Analysis And Mobility Mapping Of Mammuthus Columbi From The Mammoth Site In South Dakota, Matthew Harrington
Electronic Theses and Dissertations
The Mammoth Site in Hot Springs, South Dakota preserves a unique death assemblage of sub-adult and adult male Columbian mammoths (Mammuthus columbi). Extensive work on the site has led to a detailed understanding of the taphonomy of the assemblage; yet the life histories and ecology of these mammoths remain relatively unknown. Tooth enamel from four Mammoth Site mammoth individuals were bulk sampled with one of the individuals (MSL 742) also serially micro-sampled for 𝛿13C, 𝛿18O, and 87Sr/86Sr. Isotopic results indicate that MSL 742 remained within the southern and western Black Hills …
Performance Comparison Of Imputation Methods For Mixed Data Missing At Random With Small And Large Sample Data Set With Different Variability, Kyei Afari
Electronic Theses and Dissertations
One of the concerns in the field of statistics is the presence of missing data, which leads to bias in parameter estimation and inaccurate results. However, the multiple imputation procedure is a remedy for handling missing data. This study looked at the best multiple imputation methods used to handle mixed variable datasets with different sample sizes and variability along with different levels of missingness. The study employed the predictive mean matching, classification and regression trees, and the random forest imputation methods. For each dataset, the multiple regression parameter estimates for the complete datasets were compared to the multiple regression parameter …
Partially Oriented 6-Star Decomposition Of Some Complete Mixed Graphs, Kazeem A. Kosebinu
Partially Oriented 6-Star Decomposition Of Some Complete Mixed Graphs, Kazeem A. Kosebinu
Electronic Theses and Dissertations
Let $M_v$ denotes a complete mixed graph on $v$ vertices, and let $S_6^i$ denotes the partial orientation of the 6-star with twice as many arcs as edges. In this work, we state and prove the necessary and sufficient conditions for the existence of $\lambda$-fold decomposition of a complete mixed graph into $S_6^i$ for $i\in\{1,2,3,4\}$. We used the difference method for our proof in some cases. We also give some general sufficient conditions for the existence of $S_6^i$-decomposition of the complete bipartite mixed graph for $i\in\{1,2,3,4\}$. Finally, this work introduces the decomposition of a complete mixed graph with a hole into …
Educator Perceptions Of The Organizational Change Experienced In The Shift From Traditional Grading To A Standards-Based System, Melinda Ford Rainey
Educator Perceptions Of The Organizational Change Experienced In The Shift From Traditional Grading To A Standards-Based System, Melinda Ford Rainey
Electronic Theses and Dissertations
The purpose of this phenomenological study was to examine elementary education teacher perceptions of the change process that occurred in a public-school district during the four-year transition from a traditional grade reporting process to a standards-based system. The director of elementary education and a district leadership team provided oversight as the initial teacher cohort participated in a full school year of planning and designing the new standards-based report card for kindergarten and was executed the following school year. First-grade cohort teachers began their initial year of planning and design the same year kindergarten began implementation. The second-grade teacher cohort followed …
Analysis And Risk Estimation Of High Priority Unstable Rock Slopes In Great Smoky Mountains National Park, Tennessee And North Carolina, Samantha Farmer
Analysis And Risk Estimation Of High Priority Unstable Rock Slopes In Great Smoky Mountains National Park, Tennessee And North Carolina, Samantha Farmer
Electronic Theses and Dissertations
Great Smoky Mountains National Park (GRSM) received 12.5 million visitors in 2020. With a high traffic volume, it is imperative roadways remain open and free from obstruction. Annual unanticipated rockfall events in GRSM often obstruct traffic flow. Using the Unstable Slope Management Program for Federal Land Management Agencies (USMP for FLMA) protocols, this study analyzes high priority unstable rock slopes through 1) creation of an unstable slope geodatabase and 2) generation of a final rockfall risk model using Co-Kriging from a preliminary risk model and susceptibility model. A secondary goal of this study is to provide risk estimation for the …
Applying Deep Learning To The Ice Cream Vendor Problem: An Extension Of The Newsvendor Problem, Gaffar Solihu
Applying Deep Learning To The Ice Cream Vendor Problem: An Extension Of The Newsvendor Problem, Gaffar Solihu
Electronic Theses and Dissertations
The Newsvendor problem is a classical supply chain problem used to develop strategies for inventory optimization. The goal of the newsvendor problem is to predict the optimal order quantity of a product to meet an uncertain demand in the future, given that the demand distribution itself is known. The Ice Cream Vendor Problem extends the classical newsvendor problem to an uncertain demand with unknown distribution, albeit a distribution that is known to depend on exogenous features. The goal is thus to estimate the order quantity that minimizes the total cost when demand does not follow any known statistical distribution. The …
Prediction Intervals: The Effects And Identification Of Sparse Regions For Nonparametric Regression Methods, Jackson Faires
Prediction Intervals: The Effects And Identification Of Sparse Regions For Nonparametric Regression Methods, Jackson Faires
Electronic Theses and Dissertations
In this work, we provide an overview of different nonparametric methods for prediction interval estimation and investigate how well they perform when making predictions in sparse regions of the predictor space. This sparsity is an extension to the more common concept of extrapolation in linear regression settings. Using simulation studies, we show that coverage probabilities using prediction intervals from quantile k-nearest neighbors and quantile random forest can be biased to low or too high from the nominal level under various situations of sparsity. We also introduce a test that can be used to see if a new data point lies …
Is Being Respectable Enough?: A Critical Investigation Of Code-Switching And The Lived Experiences Of Black Leaders Who Work At Nonprofits In Bridgertown, Ramona Crawford
Is Being Respectable Enough?: A Critical Investigation Of Code-Switching And The Lived Experiences Of Black Leaders Who Work At Nonprofits In Bridgertown, Ramona Crawford
Electronic Theses and Dissertations
The current literature on Black nonprofit leaders is scarce, causing little to be known about the experiences that they have encountered when navigating their roles and responsibilities. Even less literature is available on these Black leaders and their usage of code-switching strategies when attempting to navigate those same nonprofits. Based on themes uncovered during the literature review this study employs an in-depth narrative inquiry qualitative methodology. While using theories such as critical race theory (Delgado & Stefancic, 200; Ladson-Billings,1998), the politics of respectability (Higginbotham, 1993) and the theory of capital (Bourdieu, 1985; 1996) the researcher examines the leadership experiences of …
Mass Spectrometry Based Metabolomics And Lipidomics., Fang Yuan
Mass Spectrometry Based Metabolomics And Lipidomics., Fang Yuan
Electronic Theses and Dissertations
Metabolomics and lipidomics studies are important to understand living organisms at the molecular level. In this dissertation, I conducted various untargeted and targeted metabolomics and lipidomics studies using mass spectrometry based analytical platforms. Firstly, I investigated the androgen depletion effects on fecal metabolites in a mouse model of systemic lupus erythematosus and metabolite biomarkers for colorectal cancer using two-dimensional gas and liquid chromatography-mass spectrometry. Secondly, I investigated the relationship between gut microbiota-mediated resistance and susceptibility to malaria and the production of short-chain fatty acids using gas chromatography-mass spectrometry. Thirdly, I developed a high-throughput liquid chromatography-mass spectrometry method to profile long-chain …
Biometric Features Modeling To Measure Students Engagement., Islam Mohamed Ahmed Mohamed Mahmoud Alkabbany
Biometric Features Modeling To Measure Students Engagement., Islam Mohamed Ahmed Mohamed Mahmoud Alkabbany
Electronic Theses and Dissertations
The ability to measure students’ engagement in an educational setting may improve student retention and academic success, revealing which students are disinterested, or which segments of a lesson are causing difficulties. This ability will facilitate timely intervention in both the learning and the teaching process in a variety of classroom settings. In this dissertation, an automatic students engagement measure is proposed through investigating three main engagement components of the engagement: the behavioural engagement, the emotional engagement and the cognitive engagement. The main goal of the proposed technology is to provide the instructors with a tool that could help them estimating …
The Effects Of Prescribed Burning On Soil Water Infiltration Rates And Other Select Soil Physical And Chemical Properties In East Texas, Cassady Pennington Dunson, Brian P. Oswald, Kenneth Farrish, Tyson Hart
The Effects Of Prescribed Burning On Soil Water Infiltration Rates And Other Select Soil Physical And Chemical Properties In East Texas, Cassady Pennington Dunson, Brian P. Oswald, Kenneth Farrish, Tyson Hart
Electronic Theses and Dissertations
This study focused on whether prescribed burning affects soil physical and chemical properties, especially water infiltration, in Western Gulf Coast forests. Soil water infiltration rates were measured 1) pre-burn (before the fire), 2) post-burn (one month after the fire), and 3) at vegetation green-up (three months after the fire). Soil samples were also collected to determine the effects of prescribed burning on soil pH, bulk density, particle density, pore space, soil strength, O-horizon weight and depth (organic matter), water stable aggregates, and soil fertility. This project was conducted on two different burn intervals. The National Forests and Grasslands of Texas …
Data Science And The Ice-Cream Vendor Problem, Makafui Azasoo
Data Science And The Ice-Cream Vendor Problem, Makafui Azasoo
Electronic Theses and Dissertations
Newsvendor problems in Operations Research predict the optimal inventory levels necessary to meet uncertain demands. This thesis examines an extended version of a single period multi-product newsvendor problem known as the ice cream vendor problem. In the ice cream vendor problem, there are two products – ice cream and hot chocolate – which may be substituted for one another if the outside temperature is no too hot or not too cold. In particular, the ice cream vendor problem is a data-driven extension of the conventional newsvendor problem which does not require the assumption of a specific demand distribution, thus allowing …
An Electrochemical Immunoassay System For Measuring Circulating Protein Biomarkers Of Pediatric Soft Tissue Sarcoma, Ivy Antwi
Electronic Theses and Dissertations
Measurement of circulating protein biomarkers associated with disease can facilitate early detection, help guide treatment strategies and improve patient outcomes beyond current standards of care. The combination of inexpensive 3D-printed flow cells and electrochemical biosensors has recently emerged as a viable platform for low-cost, reliable biomarker measurements. Here, we report an electrochemical immunoassay system based on simple graphite electrode arrays, 3D-printed flow cells, and signal-generating magnetic bead bioconjugates for simultaneous detection of three biomarker proteins (cancer antigen 125 (CA-125), midkine (MK) and osteopontin (OPN)) associated with pediatric soft tissue sarcomas (PSTS). Magnetic bead bioconjugates are functionalized with large amounts of …
Implementing Of Phase Potentiation Program With College Triathletes, David Fish
Implementing Of Phase Potentiation Program With College Triathletes, David Fish
Electronic Theses and Dissertations
The purpose of this study is to determine the effectiveness of an in-season resistance training program on improving measures of strength in female collegiate triathletes. Nine females (age = 19.2 ± 1.1 years, height = 166.5 ± 12.5 cm, body mass = 61.1 ± 9 kg) with limited resistance training experience were examined for this study. Formal RT intervention was monitored for 7 weeks with the athletes being assigned 6 weeks of independent RT prior to the pre-test. Athletes completed a standardized athlete monitoring program pre and post resistance training intervention. Paired sample t-tests were used to determine differences …
Synthesis Of The Diazonium Zwitterionic Polymer/Monomer For Use As The Electrolyte In Polymer Electrolyte Membrane (Pem) Fuel Cells, Josiah Marshall
Synthesis Of The Diazonium Zwitterionic Polymer/Monomer For Use As The Electrolyte In Polymer Electrolyte Membrane (Pem) Fuel Cells, Josiah Marshall
Electronic Theses and Dissertations
My research goals are to synthesize new zwitterionic perfluorosulfonimide (PFSI) monomer/polymers. They are expected to replace traditionally used perfluorosulfonic acid (PFSA) polymers as the electrolyte in PEM fuel cells. For the PFSI monomer preparation, we designed a nine-step synthesis route. Thus far, I have successfully completed the synthesis of 4- (2-bromotetrafluoroethoxy)-benzenesulfonyl amide, 4-acetoxybenzenesulfonic acid sodium salt, and 4-chlorosulfonyl phenyl acetate. The coupling reaction of 4-(2-bromotetrafluoroethoxy)- benzenesulfonyl amide with 4-chlorosulfonyl phenyl acetate, was troublesome due to slow reaction kinetics and byproducts. Additionally, I did a methodology study for the homopolymerziation of the perfluoro 3(oxapent-4-ene) sulfonyl fluoride monomer. We compared the weight …
Educator And Administrator Perceptions Of Sheltered Instruction In Stem Courses, Tommy D. Duncan Ii
Educator And Administrator Perceptions Of Sheltered Instruction In Stem Courses, Tommy D. Duncan Ii
Electronic Theses and Dissertations
The purpose of this qualitative case study was to explore the perceptions held by educators and administrators regarding sheltered instruction of English Language Learners (ELLs) in science, technology, engineering, and mathematics (STEM) classrooms; relevant professional development; and the use of the English Language Proficiency Standards (ELPS) within lesson plans. ELLs represent a subpopulation of students with significant achievement gaps in STEM, ultimately affecting student engagement and career interest in STEM. Ten STEM teachers and two administrators from a midsized middle school in west Texas participated in the study. Online semistructured one-on-one interviews and document analysis of submitted lesson plans from …
Student Perceptions Of The Effects Of The Modern Educational Reform Movement On The Concept Of The Whole Child, Edward Theodore Knight
Student Perceptions Of The Effects Of The Modern Educational Reform Movement On The Concept Of The Whole Child, Edward Theodore Knight
Electronic Theses and Dissertations
As a robust public education system is critical to the future of the U.S. democracy, efforts to improve or reform education have been prominent since its inception. Unfortunately, recent strategies to improve academic achievement have not been successful, and unintended consequences were noted for both students and staff. A specific issue related to modern reform was the construct that the focus on the whole child was disappearing as educators focused solely on the cognitive aspects of their students. The purpose of this study was to examine the perceptions of recently graduated high school students in an effort to determine if …
Servant Leadership And Conflict Adaptivity In Local Government Leaders, June F. Mighty
Servant Leadership And Conflict Adaptivity In Local Government Leaders, June F. Mighty
Electronic Theses and Dissertations
Government organizations’ focus on public service provides a fertile ground for conflict due to competing interests and goals. Conflicts exist and persist because of workplace pressures such as unstable political climates, budget restrictions, technological advances, a diverse workforce, disruptive change, and organizational transformation. Although typically risk-averse, these organizations need flexible and adaptive leaders who exhibit the appropriate behaviors in the best interests of the organization and the community. Servant-leaders seem likely to demonstrate conflict adaptivity due to their focus on serving the needs of followers and other stakeholders, which may require different conflict styles at different times and in different …
Investigations Of Elastin Recoil On Molecular And Macroscopic Levels., Nour Mohammad Jamhawi
Investigations Of Elastin Recoil On Molecular And Macroscopic Levels., Nour Mohammad Jamhawi
Electronic Theses and Dissertations
Elastin is one of the most hydrophobic proteins, and it is extremely flexible when hydrated. The driving force for recoil is the decrease in entropy of the protein and/or the hydrating solvent. This dissertation is a study of both mechanisms. Following an introduction (Chapter 1), Chapters 2 and 3 investigate the recoil mechanism on the molecular level in the hydrating solvent and in the protein, respectively. Chapter 4 examines macroscopic properties of recoil by thermomechanics. Conclusions are discussed in Chapter 5. Using double quantum NMR, the deuterated water ordering at the elastin surface was studied quantitatively as a function of …
High-Density Parking For Autonomous Vehicles., Parag J. Siddique
High-Density Parking For Autonomous Vehicles., Parag J. Siddique
Electronic Theses and Dissertations
In a common parking lot, much of the space is devoted to lanes. Lanes must not be blocked for one simple reason: a blocked car might need to leave before the car that blocks it. However, the advent of autonomous vehicles gives us an opportunity to overcome this constraint, and to achieve a higher storage capacity of cars. Taking advantage of self-parking and intelligent communication systems of autonomous vehicles, we propose puzzle-based parking, a high-density design for a parking lot. We introduce a novel method of vehicle parking, which leads to maximum parking density. We then propose a heuristic method …
Structural, Vibrational And Transport Properties Of Novel Complex Systems., Bhupendra Man Shing Karki
Structural, Vibrational And Transport Properties Of Novel Complex Systems., Bhupendra Man Shing Karki
Electronic Theses and Dissertations
Electron correlation effects in quantum materials are very strong. It is critical to investigate the structure of quantum materials to better understand and manipulate their physical properties. Quantum effects are prominent at the atomic microscopic length scale, which can not be examined by average long range structural measurements using traditional diffraction methods. Instead, pair distribution function (PDF) analysis, a local structure probe, can effectively unveil the mystery of local structure, which is more sensitive to local behavior than bulk average features. The first section of my dissertation will concentrate on the local structural study of the Iron oxy-chalcogenides, {\cSSe}, which …
Engineering Performance And Teamwork Perceptions Shaped By Structured Learning Experiences In A Makerspace., Teresa Lee Tinnell
Engineering Performance And Teamwork Perceptions Shaped By Structured Learning Experiences In A Makerspace., Teresa Lee Tinnell
Electronic Theses and Dissertations
The ability to work on teams is of critical importance to the field of engineering and a critical competency for future engineers. Fostering performance of effective teamwork through the education of engineers emphasizes the humanistic dimension of the engineering profession and engages future engineering professionals in complex and dynamic team experiences. Team performance and effectiveness of student teams is strongly influenced by individual student perceptions of teamwork as a learning mechanism for successful collective learning experiences. Initial perceptions of teamwork among first year engineering students are often negative due to prior adverse or unproductive team performance. Makerspace learning environments are …
Intercalation And High Pressure Studies Of Black Phosphorous - Pathways To Novel Materials And Physics., Manthila Chathurange Rajapakse
Intercalation And High Pressure Studies Of Black Phosphorous - Pathways To Novel Materials And Physics., Manthila Chathurange Rajapakse
Electronic Theses and Dissertations
Discovery of graphene in 2004 initiated a new trend of materials known as two-dimensional (2D) materials which have exciting surface properties and anisotropies than their bulk counterparts. Phosphorene, which is the layered version of black phosphorous (BP) is one of the top 2D materials in terms of research interests and applications of the present day. Moving a step further, our interest is to understand the possibilities for structural modifications of phosphorene, by means of stimuli such as intercalation and high-pressure. It has been predicted by theoretical studies that these stimuli may lead to the formation of new structures and phases …
Approaching Trans Debates As Fascistic Sites Of Engagement., Sarah Jump
Approaching Trans Debates As Fascistic Sites Of Engagement., Sarah Jump
Electronic Theses and Dissertations
For the past decade, trans rights issues have been a legal topic of discussion and are still discussed publicly in 2021. This thesis researched how arguments surrounding anti-trans issues were successful in the United States. The arguments surrounding these issues are important to study to see how they pass within society and if traditional rules of argumentation are changing. This thesis proposes that traditional dialectical argument is no longer occurring and has taken a post-dialectical turn. The purpose of this thesis is to describe the kinds of arguments used in these issues and build the case that they are evidence …
Bayesian Variable Selection Strategies In Longitudinal Mixture Models And Categorical Regression Problems., Md Nazir Uddin
Bayesian Variable Selection Strategies In Longitudinal Mixture Models And Categorical Regression Problems., Md Nazir Uddin
Electronic Theses and Dissertations
In this work, we seek to develop a variable screening and selection method for Bayesian mixture models with longitudinal data. To develop this method, we consider data from the Health and Retirement Survey (HRS) conducted by University of Michigan. Considering yearly out-of-pocket expenditures as the longitudinal response variable, we consider a Bayesian mixture model with $K$ components. The data consist of a large collection of demographic, financial, and health-related baseline characteristics, and we wish to find a subset of these that impact cluster membership. An initial mixture model without any cluster-level predictors is fit to the data through an MCMC …