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Decay Of Certain Mercury Lines In Argon, Thallium, And Pure Mercury Atmospheres, Edward E. Stepp

Doctoral Dissertations

"Organization of thesis and Hg-A study, The time decay of the intensity of selected mercury lines was examined under three different conditions, Each section of this thesis i s divided into three parts corresponding to these three different conditions, In each section part A concerns the decay of intensity of the 2537, 4079, 4360, and 5462 A mercury lines, following the excitation of the states from which they originate by an Hg-A de discharge, Part B concerns the decay of intensity of 14 mercury lines following the excitation of the originating state of these lines by an intense r-f discharge …

Stratigraphy Sedimentation And Petroleum Possibilities Of The Middle Ordovician (Kimmswick-Galena) Rocks Of Missouri, Illinois And Iowa, Krishna Kant Misra

Doctoral Dissertations

"Detailed surface and subsurface studies of the Kimmswick Limestone and the Galena Formation of Middle Ordovician age in eastern Missouri, western Illinois, and southeastern Iowa were conducted in order to examine their stratigraphic relations, geological history, environment of deposition, and petroleum possibilities.

The main objective of this study was to seek a stratigraphic subdivision of the Kimmswick Limestone in Missouri, based on its gross lithology and thin section study, and its correlation with the Galena Formation in Illinois and Iowa. As a result of this study, based on the examination of twelve surface sections and 92 thin sections a three-fold …

Mechanism Of Siliconizing Of Molybdenum And Tantalum By Vapor Deposition, Gordon Pu Kong Chu

Doctoral Dissertations

"Molybdenum and tantalum were siliconized in an enclosed system by the hydrogen reduction of silicon tetrachloride with induction heating between 900°C and 1450°C.

The siliconizing process was primarily influenced by the gaseous composition, temperature, time, molar flow ratio (SiCl₄/H₂), geometrical shape and ionization charges. The rate of siliconizing, measured as the weight gain by the fused quartz helix balance, generally follows a parabolic law, y = k t^1/2, where y = weight gain, t = time, and k = rate constant. The activation energy is estimated at 21.6 k cal/mole for siliconizing of molybdenum. …

Petrology And Mineralogy Of Certain Portions Of The Fredericktown Deposits, Farouk El Baz

Doctoral Dissertations

"The Fredericktown area is part of the 'Lead Belt' district of southeastern Missouri, the major lead-producing region in the world for fifty years. The district is a typical example of the Mississippi Valley Type deposits. The ores occur in Upper Cambrian sediments overlying Precambrian rocks.

The Fe-Cu-Pb-Zn (-Co-Ni) - sulphide deposits of Fredericktown occur over a few square kilometers in sediments overlying two 'granite knobs'. The sedimentary units lap upon and pinch-out against these buried basement hills.

The basal sedimentary unit, the Lamotte Formation, is a time-transgressive, marine, submature orthoquartzite. It contains a Boulder Bed at the base or at …

A Study Of The Eddy Diffusivity In Turbulent Heat Transfer, Frank Fu-Kun Tao

Doctoral Dissertations

"The purpose of this investigation was to determine the eddy thermal diffusivity values as a function of radial position at various Reynolds numbers for a fluid flowing turbulently in a pipe. The ratios of the eddy thermal diffusivity and the eddy viscosity were also investigated.

A vertical column of copper tube two inches in diameter was constructed which consisted of an entrance section for the development of the velocity profile and a heating section for the development of the temperature distribution. The heating section was jacketed and maintained at a constant wall temperature at about 103 ° F by the …

Part I: Stereochemistry Of Allenes Part Ii: The Reaction Of Phenyl(Phenylethynyl)-Tert-Butyl Carbinol With Peroxyacids, Eugene William Byrnes

Doctoral Dissertations

No abstract provided.

Lattice Parameters, Thermal Expansion Coefficients, Densities, And Imperfections In Silver And In The Alpha-Phase Of The Silver-Indium System, Samir Moustafa Riad

Doctoral Dissertations

“An investigation of structure insensitive properties (lattice parameters, thermal expansion coefficients, densities, and imperfections) of silver and the α-phase of the silver-indium system was suggested by the desirable uses for silver and its indium alloys.

Both silver and indium used were 99.999 per cent pure. The silver-indium alloys were prepared by melting both metals inside evacuated and sealed fused quartz tubes. The solidified alloys were annealed and then examined by X-ray diffraction for homogeneity.

This experimental work is divided into three main parts:-

I. X-ray diffraction investigation to determine the solid solubility limit of the Ag-In α-phase at 25° C, …

The Origin Of The Bedded Arkansas Barite Deposits (With Special Reference To The Genetic Value Of Sedimentary Features In The Ore), Richard A. Zimmermann

Doctoral Dissertations

"The objective of this study has been to determine the geometric and mineralogic relationships existing between the barite and related sediments in the Stanley Shale in Arkansas and also to establish geometric, mineralogic, petrographic, and geochemical criteria for the interpretation of the origin of the barite and associated minerals. In addition, comparisons with German deposits have been made"--Introduction, Objective and Outline of Study, page [1].

A Thermodynamic Study Of The Zirconium-Sulfur, Titanium-Sulfur And Hafnium-Sulfur Systems In The Disulfide-Trisulfide Region, Norbert Achilles Vermaut

Doctoral Dissertations

"A static method was used to study the equilibria which exist between the higher sulfides of zirconium and sulfur at temperatures from 700° to 1000 °C. Both disulfide and trisulfide have been identified by chemical analysis and X-ray diffraction. There exists a two-phase region of 'ZrS₂' and 'ZrS₃'. The composition limit of the homogeneous disulfide phase appears to exist between ZrS_1.90 and ZrS_2.00. The lower composition limit of the homogeneous region of the trisulfide phase was established as ZrS_2.75.

An experimental method of Blitz and co-workers, i.e., the use of evacuated …

A New Determination Of The Homogeneous Nucleation Rate Of Water In Helium, Edward Francis Allard

Doctoral Dissertations

"The object of this investigation is to apply the best known cloud chamber techniques to the study of condensation phenomena, directed mainly toward the development of a precise method for the determination of homogeneous nucleation rates. A secondary object is to investigate the properties of re-evaporation nuclei so that adequate precautions may be taken to eliminate their detrimental effect in the homogeneous nucleation experiments"--Statement of Problem, page 10.

A Study Of Plane And Spherical Compressional Waves In A Voigt Viscoelastic Medium, Gerald B. Rupert

Doctoral Dissertations

"In investigating the behavior of waves traveling through cohesive solids, two assumptions are usually made: that the propagating medium is either elastic or viscoelastic, and that the wave is either planar or spherical in form. For small distances from the source of the disturbance the medium can be considered elastic and the wave spherical rather than planar. The assumption of elasticity allows considerable simplification of the mathematical analysis, and assuming a spherical wave form is an acceptable approximation if the initial disturbance is essentially a point source and the propagating medium is nearly homogeneous. However, for large distances from the …

A Study Of Turbulent Mass Transfer In A Wetted-Wall Column, David William Bunch

Doctoral Dissertations

"The field of mass transfer is one of great interest to the chemical engineer. An understanding of this field is vital in the design of many types of chemical processing equipment, particularly in the areas of distillation, extraction, absorption, adsorption, and reactor analysis and design.

However, much of the knowledge in this area at the present time is in the form of empirical relationships, and the basic theory is still not well delineated. This lack of understanding leads to expensive and over-sized or under-sized equipment.

A particular area within this field which needs additional investigation is the theory of mass …

A Study Of The Dissolution Of Titanium-Oxygen-Nitrogen Alloys In Hydrofluoric Acid, Arliss V. Martin

Doctoral Dissertations

"The purpose of this investigation was to study the effect of oxygen and nitrogen (in the alpha solid solution range) on the kinetics and electrochemistry of titanium dissolution in hydrofluoric acid. Dissolution rates, activation energies, difference effects, and potential measurements were determined with TiO_XN_Y sintered alloys and sheet metal. Values of x ranged from 0.01 to 0.126 and values of x. from 0.001 to 0.230.

Dissolution rates were determined using a gas evolution technique. Temperatures were varied from 5 to 45°C. The hydrogen evolution rates were converted to TiO_XN_Y dissolution rates by means of …

Mineralogy, Petrography, And Ceramic Properties Of Lower Cabaniss Underclays In Western Missouri, Anthony C. Tennissen

Doctoral Dissertations

The mineral and chemical components, the petrography, and the ceramic properties of the Weir-Pittsburg, Tebo, and Mineral underclays In Barton, Vernon, St. Clair, sod Henry Counties of western Missouri have bean Investigated by x-ray diffraction, differential thermal, spectrographic, microscopic, and certain ceramic testing techniques. The underclays are composed principally of little, kaolinite, end mixed-layer illite-montmorillonite. Illite is the dominant mineral. The principal non-phyllosilicate minerals are quarts sad pyrite. The under clays are mineralogically similar to the underlying shales and contain clay pallets which also are mineralogically similar to the underclays and shales in which they are found. The clay appears …

Mineral Paragenesis And Trace Element Distribution In The Tri-State Zinc-Lead District Missouri, Kansas, Oklahoma, Richard D. Hagni

Doctoral Dissertations

"A review of the literature pertaining to the mineral paragenesis and trace element distribution in the Tri-State zinc-lead district of Missouri, Kansas, and Oklahoma revealed inconsistencies in observation and in interpretation and divergent hypotheses regarding the origin of the ores. In an attempt to reconcile the data collected by many investigators over nearly three-quarters of a century, the writer observed working faces in 37 mines, collected over 2,000 specimens for binocular examination and prepared and studied 110 polished surfaces and 60 thin sections of the ores and associated rocks utilizing mineralographic, petrographic, and x-ray techniques. This detailed study resulted in …

A Study Of The Dissolution Of Zr-O Alloys In Hydrofluoric Acid, Wayne Gilbert Custead

Doctoral Dissertations

"The purpose of this investigation was to ascertain and explain, if possible, the effect of oxygen in the metal on the kinetics and electrochemistry of the reaction of zirconium in hydrofluoric acid solutions. This entailed the determination of the effect of oxygen on the dissolution rates, activation energies, dissolution potentials, and difference effect for zirconium in hydrofluoric acid and hydrofluoric-hydrochloric acid mixtures.

The alpha-phase solid solutions of oxygen and zirconium were synthesized by the powder-metallurgy technique. Both the alloy analysis and dissolution rates were obtained by the gas evolution method according to the reaction:

ZrO_x + 4HF → ZrF …

Statistical Analysis Of Fracture Stresses Of Triaxial Porcelain Bodies, Robert E. Moore

Doctoral Dissertations

"Triaxial porcelain bodies containing various forms of silica, quartz, cristobalite and fused silica, were strength tested in bending. Significance tests were employed to discern real differences in the strength sample statistics caused by the various forms of silica. Firings were performed at three temperature levels. The differences in strength sample statistics were correlated to the microstructures of these silica porcelains.

A triaxial alumina porcelain body was employed as a model brittle solid for a study of the effect of flaw density on mean fracture stress. The flaws were introduced in the form of large diameter (d̄ = 115 microns) rounded …

An Investigation Of The Deformation Textures Of Cobalt, Roy Carl Wilcox

Doctoral Dissertations

"Deformation textures of various cobalt structures as a result of cold rolling together with some annealing textures were studied. The textures of cobalt were determined using a modification of the Schulz-Decker Geiger counter technique. Pole figures of the (1011), (0001) and (1010) planes were constructed. Also, a study of the microhardness of cobalt was made.

Microhardness tests were performed on various cobalt structures, in both the cold rolled and unworked conditions. The microhardness was found to vary with the source of the cobalt, the crystal orientation, and the amount of deformation and twinning. Deformation lines about the hardness impressions diffused …

Lattice Parameters, Densities And Imperfections In Indium And Indium-Cadmium Alloys Rich In Indium, Paluri Bhimeswara Rao

Doctoral Dissertations

"An investigation of perfection of the structure of the indium-cadmium system was suggested by the interesting properties of indium and its cadmium alloys. The lattice of indium, though tetragonal, may be considered as distorted cubic, its axial ratio being 1.0767 at 20°C. Furthermore earlier studies have revealed a transformation of the tetragonal structure to cubic in the presence of cadmium.

To determine the perfection or soundness of the indium and indium-cadmium alloys rich in indium, pure indium (99.999 per cent purity) and eight samples of the indium-cadmium alloys ranging in composition from 2.977 to 10.015 per cent by weight of …

The Geology Of The Eldorado Mining District, Clark County, Nevada, Spenst M. Hansen

Doctoral Dissertations

The rocks of the Eldorado mining district, Clark County, Nevada, are of Precambrian, Tertiary and Quaternary age. Precambrian rocks include a heterogeneous series of gneisses and schists, younger garnetiferous granite gneiss and a youngest group of pegmatites. Paleozoic and Mesozoic rocks present in surrounding areas are absent in the district and Tertiary volcanics lie directly on the Pre- cambrian basement. Tertiary rocks consist of middle to late Tertiary flows and pyroclastic beds of andesite, basalt and rhyolite. These are assigned to three volcanic formations: the Patsy Mine volcanics; the Golden Door volcanics; and the Mount Davis volcanics. The Patsy Mine …

A Study Of The Dissolution Of Hafnium In Hydrofluoric Acid, James W. Johnson

Doctoral Dissertations

"The purpose of this investigation was to obtain kinetic and electrochemical information concerning the reaction of hafnium with hydrofluoric acid in order to establish the mechanism of dissolution. This included the determination of dissolution rates, the difference effect, and dissolution potentials of hafnium in hydrofluoric acid"--Abstract, page 1.

Some Physical, Chemical, And Thermohydrodynamic Parameters Of Explosive Ammonium Nitrate-Fuel Oil Mixtures, Joseph J. Yancik

Doctoral Dissertations

"The explosive properties of ammonium nitrate-fuel blasting agents were investigated by measuring their detonation velocity and sensitivity. Detonation velocity was measured by a pin oscillograph method with a modified pin technique. Five types of tests were used to evaluate the explosive sensitivity of AN-fuel mixtures under varied environmental conditions. These tests measured the confined and unconfined critical diameter, minimum primer for a three inch diameter iron pipe confined charge, for an unconfined charge at the critical diameter, and minimum primacord primer under special conditions.

Properties of ammonium nitrate-fuel blasting agents were evaluated by considering the effects which each component of …

A Thermodynamic Study Of The Zirconium Sulfides, Andrew Hessler Larson

Doctoral Dissertations

"A hydrogen reduction technique was used to determine some thermodynamic properties of various zirconium sulfide phases. The equilibrium H₂S/H₂ ratios were determined as a function of temperature and composition of the condensed sulfide phases. The hydrogen sulfide content of the equilibrated gas mixtures was analyzed by an iodimetric titration procedure.

A detailed description is given for the method and apparatus used both in the preparation of the various sulfide phases and in their equilibration with a hydrogen-hydrogen sulfide gas mixture.

The composition ranger 59 to 67 atomic per cent sulfur was studied over a temperature range of …

Imperfections Within Ti₂O₃ And Tio₂ Phases In The Titanium-Oxygen System, Tatsuhiko Ejima

Doctoral Dissertations

“The hexagonal-rhombohedral Ti₂O₃ phase in the Ti-O system extends from 32.5 to 34.5% oxygen b.w., with the exact composition of Ti₂O₃ nearly in the middle of the phase. Seven samples of different composition within that phase were made, and the lattice constants (a and c) and the density of each sample were determined.

The plots of the constants against the composition of the samples revealed a deviation from Vegard’s rule when approaching the exact composition of Ti₂O₃. The lattice constants of this compound, obtained by graphical interpolation were; a_{25 …}

A Study Of The Recrystallization And The Mechanical Properties Of Indium, Louis John Reitsma Jr.

Doctoral Dissertations

"The recrystallization temperature and the mechanical properties of tensile strength, elongation, reduction in area and hardness were determined for 99.97% indium. Metallographic techniques were developed and stress rupture data were obtained.

Single crystals of indium were grown in a horizontal furnace with a traveling temperature zone, and sectioned in a strain-free manner, with an etch-cutter. Because of the low recrystallization temperature of indium, no further work was done on the single crystals.

The effect of recrystallization on electrical resistance, thermoelectric force, hardness, bending strength, crystallographic orientation and microstructure was studied. The range of recrystallization temperature for small amounts of cold …

An Experimental And Theoretical Investigation Of The Preferred Orientation In Deformed And Recrystallized Hafnium, David S. Gould

Doctoral Dissertations

"The research problem, as presented, therefore became two-fold; first to investigate and determine the feasibility of fabrication of hafnium and secondly to study the deformation characteristics of the material in light of the overall study of hexagonal metals aimed at the development of an overall general theory of plastic deformation. This appeared to envolve a study of the operating deformation systems in hafnium and the theoretical and experimental study of the textures resulting from plastic deformation. These were to be analyzed in comparison with the other hexagonal metals.

It became evident immediately that the research techniques which must be evolved …

A Thermodynamic Study Of The Titanium Sulfides, Reinhard Paul Abendroth

Doctoral Dissertations

"The determination of the thermodynamic properties of chemical compounds is in essence an experimental one. The purpose of this investigation was (1) to make an experimental determination of the thermodynamic properties of the titanium sulfides (2) to determine what sulfide phases are present in the titanium-sulfur system (3) to show the relationships between the various phases present"--The Problem, Statement of the Problem, page 3.

Phase Relationships In The Quaternary System Lime-Titania-Zirconia-Silica, Robert Martin Gruver

Doctoral Dissertations

"The phase compatibility relationships for the quaternary system lime-titania-zirconia-silica have been determined by a solid-phase-reaction technique.

Preliminary division of the system into Alkemade tetrahedra was based on the phases found in samples by X-ray diffraction analysis. These samples covered the entire volume of the tetrahedron in a systematic fashion. When the quaternary system had been divided into regions or compatible phases, an analytical method was used to calculate the phase composition of each sample. The relative amounts of each phase in a sample determined by X-ray analysis were compared with the calculated quantities, and agreement between the two methods verified …

Nanbo₃ - Batio₃ - Basno₃ Ceramic Dielectrics, William Dean Mckee

Doctoral Dissertations

"A. The Problem.

The purpose of this investigation was to form by ceramic processes a number of compositions in the ternary system NaNbO₃ - BaSnO₃ - BaTiO₃, to determine certain dielectric properties of these, to study them by means or x-ray diffraction, and to determine the extent or correlation possible between the compositional variation of dielectric properties and the x-ray results.

Compositions investigated contained 50 mole percent or less BaSnO₃. Materials and methods of forming were chosen with the intent that the final bodies should be pure oxide compositions as represented in the ternary …

Preparation And Separation Of Metallic Chlorides, Norbert Felix Neumann

Doctoral Dissertations

"The use of chlorine and chlorine compounds as metallurgical reagents has long been known to the metallurgical industry. Recent developments in corrosion resistant metals and alloys as well as new equipment and techniques have led to a revival of chlorine processes. Many of the objections to the use of chlorine in metallurgical operations have been overcome and many are being reconsidered, as evidenced by the new processes in which chlorine and chlorides are the primary reagents. The Betterton process employs chlorine or lead chloride for the dezincing of lead. Ductile zirconium and titanium have been made by reducing their chlorides …