Digital Commons Network^™

When The Workplace Is On Campus: Learning To Write For A University Speech Language Clinic, Michelle Cox

Doctoral Dissertations

Much of the literature on academic and workplace writing focuses on the differences between these two writing arenas, leading Dias et al. to describe writing for school and work as "worlds apart." Using insights from activity system theory and rhetorical genre theory, this dissertation project investigates the possibility of middle spaces between academic and workplace writing. Set in a Communication Science and Disorders (CSD) master's program, this qualitative study follows five graduate students as they learn workplace writing in a space that physically bridges academia and the workplace, an on-campus speech-language clinic.

Findings indicate that the genres used in the …

Proton Form Factor Ratio Measurement With Blast, Adrian Tiberiu Sindile

Doctoral Dissertations

The proton electric to magnetic form factor ratio ( GPE/GPM ) is related to the underlying electromagnetic structure of the proton. GPE/GPM is studied through elastic scattering using a longitudinally polarized electron beam with 0.85 GeV energy, a polarized internal hydrogen gas target and the BLAST detector at the MIT Bates Lab. Beam-target spin asymmetries are measured in several bins of Q2 for both left and right sector of BLAST, the super-ratio of these left/right asymmetries is formed and GPE/GPM is extracted.

Soil Moisture Dynamics From Satellite Observations, Land Surface Modeling, And Field Data, Minha Choi

Doctoral Dissertations

Knowledge of soil moisture variability is essential to understand hydrologic processes at a range of scales. In this study, spatio-temporal variability of soil moisture and inter-comparison among different soil moisture products were analyzed. The variability patterns were well characterized by negative exponential fitting as function of observed sampling extent scale. The simple physical soil moisture dynamics model was identified as an alternative approach to characterize statistical soil moisture variability. The soil moisture variability was strongly related to physical properties including rainfall and topography.

Normal and log-normal distributions were recognized as the most efficient probability density functions to capture soil moisture …

Modeling Of Diffusional Creep And Stress Relaxation In Copper Grains During Manufacturing Of Microelectronic Integrated Circuits, Vasyl M. Grychanyuk

Doctoral Dissertations

The finite element technique was developed to study diffusional creep and stress relaxation in Cu grains with several atomic monolayers thick grain boundary region of enhanced diffusivity. The model was motivated by the need to study nanoscale back-end interconnect structures of microelectronic circuits. These structures have the length scale that does not conform to the assumptions of classical dimensional theories of diffusional creep.

Both diffusion and elasticity governing equations are considered in the coupled formulation of mass flow and stress analysis. Vacancy concentration field in the grains subjected to external load is coupled to stress field through diffusional creep strains. …

Uptake And Growth Effects Of Polycyclic Aromatic Hydrocarbons In Wetland Plants, Alison Watts

Doctoral Dissertations

Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous contaminants in estuarine environments, but little is known about the distribution and fate of PAHs in wetland sediments and plants. The effect of PAHs on common salt marsh plants, and the PAH distribution within the plants, sediment, and atmosphere were evaluated to determine if PAHs were transported from the sediment into the plants, and if the PAHs affected plant growth. Four salt marsh plant species, Spartina alterniflora, Phragmites australis, Solidago sempervirens and Distichlis spicata were grown in pots of PAH contaminated sediment containing mean total PAH concentrations of 355 mg/kg (ppm). During the growing …

Atmospheric Volatile Organic Compound Measurements: Distributions And Effects On Air Quality In Coastal Marine, Rural And Remote Continental Environments, Yong Zhou

Doctoral Dissertations

A detailed description of the analytical methods employed for whole air sampling and analysis of atmospheric volatile organic compounds is presented. The system described in this thesis produced high precision measurements for a large suite of nonmethane hydrocarbons, halocarbons, and alkyl nitrates, from part per billion by volume (ppbv) to part per trillion by volume (pptv) levels. The measurement precision for most gases ranged from 1-10%.

Results from two subsequent field campaigns (2002 and 2003) conducted in Yellowstone National Park (YNP) are presented. The findings indicate that 2-stroke snowmobile engine emissions furnish large quantities of air toxics to the YNP …

Nanodot-Based Organic Memory Devices, Zhengchun Liu

Doctoral Dissertations

In this study, resistor-type, diode-type, and transistor-type organic memory devices were investigated, aiming at the low-cost plastic integrated circuit applications. A series of solution-processing techniques including spin-coating, inkjet printing, and self-assembly were employed to fabricate these devices.

The organic resistive memory device is based on a novel molecular complex film composed of tetracyanoquinodimethane (TCNQ) and a soluble methanofullerene derivative [6,6]-phenyl C61-butyric acid methyl ester (PCBM). It has an Al/molecules/Al sandwich structure. The molecular layer was formed by spin-coating technique instead of expensive vacuum deposition method. The current-voltage characteristics show that the device switches from the initial 'low' conduction state to …

Worked Examples : Effect Of Modified And Conventional Worked Examples On Assembly Time, Accuracy, And Efficiency In A Manufacturing Environment, James B. Dill

Doctoral Dissertations

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An Exploration Of Adolescent Spirituality In A Single-Gender Urban Catholic High School : A Phenomenological Inquiry, Elizabeth E. O'Donnell

Doctoral Dissertations

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Cupolets: Chaotic Unstable Periodic Orbits Theory And Applications, Kourosh Zarringhalam

Doctoral Dissertations

Recent theoretical work suggests that periodic orbits of chaotic systems are a rich source of qualitative information about the dynamical system. The presence of unstable periodic orbits located densely on the attractor is a typical characteristic of chaotic systems. This abundance of unstable periodic orbits can be utilized in a wide variety of theoretical and practical applications [19]. In particular, chaotic communication techniques and methods of controlling chaos depend on this property of chaotic attractors [12, 13].

In the first part of this thesis, a control scheme for stabilizing the unstable periodic orbits of chaotic systems is presented and the …

Evaluation Of The Effect Of Vehicle Performance On Consumer Satisfaction, Elizabeth A. Cudney

Doctoral Dissertations

"Value is the relationship of functionality or benefit to the cost of a product or service. Consumers appear to seek value, but not all consumers are alike in their needs and wants. Common characteristics that consumers desire in automobiles include a high level of value relative to the product's cost. Consumers measure vehicle performance in terms of twenty-three attributes such as roominess, ride, reliability, handling, brake pedal feel, visibility, interior noise, acceleration, etc. Problems arise when automakers try to translate these characteristics into vehicle performance specifications and capabilities.

Quality is an essential element for both the consumer and producer since …

Designing And Modeling Of A New Continuous Steelmaking Process, Jörg Peter

Doctoral Dissertations

"Continuous steel production has the potential to lower the cost of steelmaking as compared to current batch operations. However, experiences from past attempts to develop and commercialize continuous steelmaking processes show that there are several engineering hurdles to overcome. The objective of this research was the development of a fully continuous steelmaking process that would incorporate the lessons from past experiences, address the foreseen challenges, and meet the requirements to justify the possible replacement of the current EAF-LMF steelmaking route.

The design of the new process consists of five interconnected vessels. Preheated scrap would be continuously charged, melted, and superheated …

An Analysis And Policy Implications Of Comfort Levels Of Diverse Constituents With Reported Units For Blast Vibrations And Limits: Closing The Communication Gap, Braden Lusk

Doctoral Dissertations

"Differences exist between public perception of construction blasting and quarry blasting. In general, people are able to tolerate short term inconveniences much better than long term ones. Quarries and other long term mining operations utilizing blasting are coming under increasing public and legislative pressure in the United States. The question being posed for the blasting industry is, "Has our past haste in adopting complex scientific scales and units been detrimental to us?" In other words, are the most palatable things being reported? The goal of this dissertation is to determine whether current units create an atmosphere of discomfort among neighbors …

Integration Of Micro Nano And Bio Technologies With Layer -By -Layer Self -Assembly, Dinesh Shankar Kommireddy

Doctoral Dissertations

In the past decade, layer-by-layer (LbL) nanoassembly has been used as a tool for immobilization and surface modification of materials with applications in biology and physical sciences. Often, in such applications, LbL assembly is integrated with various techniques to form functional surface coatings and immobilized matrices. In this work, integration of LbL with microfabrication and microfluidics, and tissue engineering are explored. In an effort to integrate microfabrication with LbL nanoassembly, microchannels were fabricated using soft-lithography and the surface of these channels was used for the immobilization of materials using LbL and laminar flow patterning. Synthesis of poly(dimethyldiallyl ammonium chloride)/poly(styrene sulfonate) …

A Fe-Fd Hybrid Scheme For Solving Parabolic Two-Step Micro Heat Transport Equations In Irregularly Shaped Three Dimensional Double -Layered Thin Films Exposed To Ultrashort -Pulse Lasers, Brian R. Barron

Doctoral Dissertations

Multi-layer thin films are important components in many micro-electronic devices. These films are often used when a single film layer is insufficient to meet devices specifications. The continued reduction in component size has the side effect of increasing the thermal stress on these films and consequently the devices they comprise. Understanding the transfer of heat-energy at the micro-scale is important for thermal processing using a pulse-laser. Often, micro-voids may be found in processed devices. This is due to thermal expansion. Such defects may cause an amplification of neighboring defects resulting in severe damage and consequently the failure of the device. …

Design And Development Of Poly -(3 -Hexylthiophene) Field Effect Transistors, Fengliang Xue

Doctoral Dissertations

Organic field effect transistors (OFETs) with poly(3-hexylthiophene) (P3HT) as the active layer are developed and studied. The device characteristics are significantly affected by source/drain contact resistance, and P3HT-SiO 2 interface and the traps. These results are verified by the numerical device simulations. The temperature dependence of device mobility is studied, which indicates that the carrier transport is either heat-assisted or heat-limited at different temperature ranges. The on/off ratio and threshold voltage are found to be dependent on the temperature. Hysteresis effect due to gate electric stress is investigated. The silanol groups present at the SiO2 surface are thought to be …

Application Of Polyelectrolyte Layer-By-Layer Nano-Assembly For Surface Modification, Encapsulation And Controlled Release, Nikhil Anil Pargaonkar

Doctoral Dissertations

In this study, we applied the traditional Electrostatic layer-by-layer (ELBL) assembly procedure to fabricate nanothin films over flat surfaces, and modify particle surfaces to influence the drug particle size, and drug release. The ELBL assembly has previously been applied to fabricate multilayer nano-scale thin films, but its ability to instantaneously influencing particle size is unique. Other unique observations such as influence on drug release as a result of polymer complexation, and thermal changes occurring during layer fabrication are recorded.

The ELBL self-assembly process was applied to produce dexamethasone particles layered with various polyelectrolyte layer combinations. These combinations were further applied …

Development Of Palladium Nanowires, Chuanding Cheng

Doctoral Dissertations

Inherent limitations of traditional lithography have prompted the search for means of achieving self-assembly of nano-scale structures and networks for the next generation of electronic and photonic devices. The nanowire, the basic building block of a nanocircuit, has recently become the focus of intense research. Reports on nanowire synthesis and assembly have appeared in the scientific literature, which include Vapor-Liquid-Solid mechanism, template-based electrochemical fabrication, solvothermal or wet chemistry, and assembly by fluid alignment or microchannel networks. An ideal approach for practical application of nanowires would circumvent technical and economic constraints of templating. Here we report on the self-assembly of highly-ordered …

Availability Modeling And Evaluation On High Performance Cluster Computing Systems, Hertong Song

Doctoral Dissertations

Cluster computing has been attracting more and more attention from both the industrial and the academic world for its enormous computing power, cost effective, and scalability. Beowulf type cluster, for example, is a typical High Performance Computing (HPC) cluster system. Availability, as a key attribute of the system, needs to be considered at the system design stage and monitored at mission time. Moreover, system monitoring is a must to help identify the defects and ensure the system's availability requirement.

In this study, novel solutions which provide availability modeling, model evaluation, and data analysis as a single framework have been investigated. …

Microcapsule Biosensors Based On Competitive Binding And Fluorescence Resonance Energy Transfer Assays, Swetha Chinnayelka

Doctoral Dissertations

Fluorescent sensing systems offer the potential for minimally invasive monitoring with implantable devices, but they require carrier technologies that provide suitable immobilization, accessibility, and biocompatibility while maintaining adequate response characteristics. Towards the development of this goal, a general design of a biosensor with the capability of detecting different metabolites was investigated. The approach is based on the encapsulation of a competitive binding assay in microcapsules and monitoring the changes in fluorescence resonance energy transfer (FRET) in the presence of analyte. To experimentally demonstrate this type of sensing system, glucose was chosen as the model target analyte. The design, fabrication, and …

Study On Poly[2-Methoxy-5-(2'-Ethylhexyloxy)-1,4-Phenylenevinylene] Polymer Based Photodetectors, Difei Qi

Doctoral Dissertations

This thesis is dedicated to the development of novel and efficient polymer photodetectors based on MEH-PPV conjugated polymers. The polymer-based photodetectors have the advantages of easy processing, low weight, and low cost, and thus are promising candidates for future generations of photodetectors. At present, the quantum efficiency of polymer photodetectors is still low and not comparable to inorganic photodetectors. Therefore, in this thesis we explore ways to enhance the quantum efficiency of polymer photodetectors by using different electron donors, configurations, and implementation of the diffraction optical grating into photodetector structure. We designed, fabricated, and characterized several original types of devices: …

Organization And Signal Processing Of The Descending Tracts In The Cervical Spinal Cord, Yanmei Tie

Doctoral Dissertations

This dissertation addresses the research for the development of spinal cord-computer interface (SCCI). The main objective of SCCI is to generate voluntary motor control signals for individuals with spinal cord injury (SCI).

In the neuroscience aspect, organization of the fibers in the descending tracts of the dorsolateral funiculus of the cervical spinal cord was investigated in cats. The spinal cord was penetrated with silicon substrate microelectrodes at 400 μm intervals in the medio-lateral direction at the C5/C6 and C6/C7 segmental borders. The stimulus consisted of a 20 ms train of charge-balanced biphasic pulses at 330 Hz. The evoked activities from …

An Empirical Investigation To Detect The Presence Of Confirmation Bias In The Decision-Making Strategies Used By Litigants In Tax Court Memorandum Cases, Mary M. Anderson

Doctoral Dissertations

Normative decision theory describes the judgment and decision-making process as a cost/benefit analysis based upon maximum utility. One assumption of the theory is full rationality for choices made throughout the process. Due to bounded rationality, however, mental shortcuts become necessary. Use of these shortcuts does not necessarily diminish the quality of the decision. However, a suboptimal use of a heuristic results in a biased decision.

Kahneman and Tversky (1979) identify three basic heuristics: availability, representativeness, and anchoring and adjusting. One suboptimal use of the anchoring and adjusting heuristic, confirmation bias, is the unconscious search for and evaluation of information that …

Modeling, Design, And Validation Of Fluorescent Spherical Enzymatic Glucose Microsensors Using Nanoengineered Polyelectrolyte Coatings, Jonathan Quincy Brown

Doctoral Dissertations

In this dissertation, the modeling, design, and function of fluorescent spherical enzymatic microsensors for minimally-invasive diabetic monitoring are described. The devices reported herein are novel and their experimental construction and theoretical analysis have not been previously reported, thus laying the foundation for an intensive set of studies. These sensors are based on the encapsulation of an enzymatic fluorescent assay for glucose within hydrogel alginate microspheres with diameters on the order of tens of microns, which are of the appropriate size for intradermal implantation. A novel feature of these sensors is the use of multifunctional nanoengineered ultrathin multilayer polyelectrolyte coatings on …

Dna-Templated Assembly Of Metallic Nanowires, Qun Gu

Doctoral Dissertations

Nanowires are widely recognized as key elements in the development of futuristic nanoscale devices of nanoelectronics, optoelectronics and nano-electro-mechanic systems. Lithographic fabrication, however, faces increasing difficulties in the realization of continuously miniaturized features. The “Bottom-up” approach is a promising successor to lithography for fabrication of nanostructures. DNA is a natural template for nanowire assembly. The linear polynucleotide chain has a width of 2 nm and a length of 0.34 run per nucleoside subunit.

One-dimensional magnetic Co and Ni nanoparticles have been assembled in-situ for the first time by use of single DNA molecules as templates. Target metallic nanowires that are …

Evaluating Online Trust Using Machine Learning Methods, Weihua Song

Doctoral Dissertations

Trust plays an important role in e-commerce, P2P networks, and information filtering. Current challenges in trust evaluations include: (1) fnding trustworthy recommenders, (2) aggregating heterogeneous trust recommendations of different trust standards based on correlated observations and different evaluation processes, and (3) managing efficiently large trust systems where users may be sparsely connected and have multiple local reputations. The purpose of this dissertation is to provide solutions to these three challenges by applying ordered depth-first search, neural network, and hidden Markov model techniques. It designs an opinion filtered recommendation trust model to derive personal trust from heterogeneous recommendations; develops a reputation …

Numerical Simulation Of Nanopulse Penetration Of Biological Matter Using The Z -Transform, Shengjun Su

Doctoral Dissertations

Short duration, fast rise time ultra-wide-band (UWB) electromagnetic pulses (“nanopulses”) are generated by numerous electronic devices in use today. Moreover, many novel technologies involving nanopulses are under development and expected to become widely used soon. Study of nanopulse bioeffects is needed to probe their useful range in possible biomedical and biotechnological applications, and to ensure human safety.

Based on the well-known dispersive properties of biological matter and their expression as a summation of terms corresponding to the main polarization mechanisms, the Cole-Cole expression is commonly employed to describe the frequency dependence of the dielectric properties of a tissue. Solving the …

Sleep Habits And Patterns Of College Students And Their Relationship To Selected Personality Characteristics, Steve M. Jenkins

Doctoral Dissertations

College is a time of adjustment when many students have a newfound responsibility for many aspects of their lives, including sleep habits and patterns. College students often have sleep schedules that vary greatly, which can result in sleep disturbances. Previous research indicates that college students report significantly more sleep disturbances than the general population. Poor sleep quality has been linked to myriad psychological, physiological, and cognitive difficulties, including mood and anxiety disorders, cardiovascular disease, and poor academic performance. Oftentimes, sleep disturbances can be corrected with basic psychological interventions. Considering the deleterious effects that poor sleep can have on college students, …

Application Of Self -Assembled Ultrathin Film Coatings To Stabilize Enzyme Encapsulation And Activity In Alginate Microspheres, Rohit Srivastava

Doctoral Dissertations

Alginate-based hydrogels have been used for the encapsulation of a variety of materials, including enzymes, proteins, and cells for a wide range of applications from drug delivery to biosensors and bioreactors. However, due to the high porosity of the matrix, it has been increasingly difficult to retain macromolecules inside the alginate matrix, leading to loss in functionality over time. In an effort to improve the stability for long-term biosensor use, this work investigated layer-by-layer self-assembly as a potential technique to provide a diffusion barrier to an encapsulated macromolecule. Alginate microspheres (∼2–50μm radius) were fabricated using an emulsification technique, and were …

Developing A B -Tagging Algorithm Using Soft Muons At Level-3 For The Dø Detector At Fermilab, Mayukh Das

Doctoral Dissertations

The current data-taking phase of the DØ detector at Fermilab, called Run II, is designed to aid the search for the Higgs Boson. The neutral Higgs is postulated to have a mass of 117 GeV. One of the channels promising the presence of this hypothetical particle is through the decay of b-quark into a muon. The process of identifying a b-quark in a jet using muon as a reference is b-tagging with a muon tag.

At the current data taking and analysis rate, it will take long to reach the process of identifying valid events. The triggering mechanism of the …