Digital Commons Network^™

Three Essays On The Economics Of Sustainable Consumer Choices, Muhammad Jawad Khan

Doctoral Dissertations

This dissertation examines consumer preferences and willingness to pay (WTP) within key sustainability contexts, focusing on the remediation of forever chemicals (PFAS) in municipal water systems, forest diversification for climate-resilient maple syrup production, and reduced ecological footprints in farming. The first chapter highlights factors influencing public support for a municipal water filtration system. A contingent valuation survey was conducted in September 2021 among the New England households to estimate their WTP for PFAS filtration in municipal drinking water systems. Health factors are primary: those concerned about water quality show a higher WTP. Income, water expenditures, and filtration status at home …

Rational Design Of Polymers For Specific Interactions With Liquid And Solid-State Water, Nick Mitchell

Doctoral Dissertations

Many plants and animals that live in arctic regions possess biological cryoprotecting agents (CPAs) known as antifreeze proteins (AFPs) which protect them against cryoinjury in their native subfreezing environment. AFPs and their synthetic biomimetics have received increasing attention as potential candidates for various industrial and bio-medical applications. Despite the interest in developing synthetic, macromolecular CPAs; a full understanding of the antifreeze process induced by these remains elusive. To explore this, we have synthesized a series of water- soluble polyol-based polymers with systematic variation of their chain architectures.While AFPs are well-known for their ice nucleation and recrystallization inhibition activity along with …

Natural Laboratories Of The Deep Sea: Linking Community Composition And Environmental Variables On Low-Temperature Venting Outcrops Of Ridge Flank Hydrothermal Systems To Explore Potential Impacts Of Climate Change, Inform Habitat Suitability Models, And To Understand The Impacts Of High Bathymetric Resolution On Seafloor Characterization, Anne Marie Hartwell

Doctoral Dissertations

The deep sea covers over two-thirds of the globe and represents 95% of the ocean. Most life on Earth is suspected to live on or near the seabed. Yet, these ecosystems are the least known on Earth and are important to explore as they are home to a diverse array of species that are currently under threat because of multiple anthropogenic pressures, including warming oceans. Exploration of these systems is critical to further the understanding of species interactions, biodiversity and their overall relationship to environmental and terrain variables. Many of these variables are used in species distribution models and technological …

Semiconductor Physics Based Signal Integrity Analysis For 3d Ic, Ze Sun

Doctoral Dissertations

"Three-dimensional integrated circuits (3DICs) are becoming increasingly popular in high-speed electrical systems. 3DICs are made by stacking multiple dies vertically and connecting them with through-silicon vias (TSVs). In this dissertation, three studies were carried out to model the performance of 3DICs in extreme working conditions and the signal integrity (SI) performance of 3DICs.

First, an in-house Monte Carlo particle simulator was developed to characterize extreme working conditions (ESD/EMP) for ICs at the microscopic level instead of the macroscopic level. The ability of the simulator was demonstrated by modeling a voltage regulator diode under forward and reverse bias. The diode simulation …

Modeling And Analysis Of Dc-Dc Converters For Power Distribution Networks Design, Junho Joo

Doctoral Dissertations

"Accurate modeling of power distribution networks (PDN) including voltage regulator module (VRM) is critical for high-performance digital systems including low- to high-power applications such as laptops and mobile platforms. As a consolidated end-to-end power source, PDN can be divided into several parts: the VRM to regulate the external voltage source, printed circuit board (PCB) PDN, package PDN, and on-chip PDN. A transient current drawn from the on-die circuitry will produce an instantaneous voltage drop at the bump. The time domain behavior of such a drop and the subsequent recovery is called voltage droop which is strongly associated with the VRM …

Modeling And Control For Precision Robotic Machining, Patrick Bazzoli

Doctoral Dissertations

"Robots are used in a wide variety of manufacturing applications, but machining applications in which robots can excel are limited by their lower accuracy and stiffness relative to traditional CNC machines. This work is composed of two parts: one to evaluate a robot’s accuracy and one to compensate for the vibrations of the robot due to its lower stiffness.

In order to evaluate whether a robot has the necessary accuracy to perform a given machining task, Paper 1 discusses a novel Model Invalidation method. This methodology provides a statistical framework as well as a measurement strategy for determining if a …

The Development Of Hard Materials And Fibrous Monolith Composites For Friction Stir Welding, Paul Michael Brune

Doctoral Dissertations

"This research focuses on the development of hard materials and fibrous monolith composites for the purpose of adding to current friction stir welding tool technology. Well studied hard material systems, such as WC-Co, were incorporated and evaluated as cell materials for fibrous monolith composites with ductile cell boundaries of Co, W, and Mo. The indentation behavior of the WC-Co and WC-Co-cBN composites indicated possible crack deflection at the cell/cell boundary interface. Cylindrical pin friction stir welding tools were developed for each of the three fibrous monolith material systems. Welding was achieved on AA1100 aluminum, 260 brass, and AISI 1018 steel …

Paleoecological And Paleoclimatic Reconstructions Based On Holocene Sediment Cores, Lake Izabal, Eastern Guatemala, Erdoo Mongol

Doctoral Dissertations

"The Maya Region in Central America is characterized by pronounced discrepancies in precipitation, resulting in high precipitation gradients that support large-scale differences in vegetation across the region. Several lake deposits and other paleoclimate archives in the region have been studied to reconstruct past climates and palaeoecological conditions. However, actual data from proxy records have not been qualitatively and quantitatively utilized to interpret the behavior of the vegetation in moister areas within the Maya Region, such as the Lake Izabal Basin (LIB). The palynomorphs from two sediment cores in the LIB provided a good opportunity to infer the patterns of past …

In-Depth Characterization Of The Selective Oxidation Products Of Hafnium Carbide, Jonathan Allen Scott

Doctoral Dissertations

"Materials capable of withstanding oxidative environments at temperatures >2000°C are necessary for hypersonic applications. Hafnium carbide (HfC) shows a combination of properties that lends itself toward these applications; however, its oxidation behavior is poorly understood. At 1300°C, HfC was found to oxidize via the following mechanism: 1) Initial oxidation of both C and Hf present in the system, 2) Formation of an interconnected pore network, whose size is related to the volume of gases being generated during the oxidation process, 3) Growth of the oxide scale to become sufficiently protective, 4) Formation of an initially amorphous “HfO₂C” at …

Effect Of Ai–Si Coating Weights On Corrosion And Weldability Of Ultra-High-Strength Steel Usiborr 1500 Used In Automotive Structures, Hilary Anayochukwu Onyishi

Doctoral Dissertations

"There has been increased demand for hot-stamped pre-coated Usibor 1500R in automotive industries due to its excellent properties (ultra-high strength, weight reduction, low spring back and excellent corrosion protection). In this research work, investigation was conducted to better understand the effect of Ai-Si Coating Weights on weldability and corrosion of Ultra-High-Strength Steel Usibor 1500R used in Automotive Structures”. The results show that weld nugget diameter increases with increasing weld current, better spot-weld nugget diameter is recorded at weld currents above 7.5 kA for both AS80 and AS150 and the weld current range decreases as the interdiffusion layer (IDL) thickness increases. …

Deep Reinforcement Learning Based Strategies For Inverter Dominated Microgrids, Oroghene Oboreh-Snapps

Doctoral Dissertations

The integration of inverter-based distributed generators (IBDGs) in modern power systems has ushered in a new era of renewable energy utilization, prompting the rise of Microgrid (MG) architectures. Nevertheless, as IBDG penetration increases, a host of challenges surface. Foremost among these challenges are issues related to frequency stability stemming from the inherent lack of inertia in IBDGs, and inaccurate sharing of reactive and active power, particularly evident in parallel IBDG networks with mismatched feeder impedance. This research presents novel solutions to these challenges by adopting deep reinforcement learning (DRL), specifically, the twin delayed deep deterministic policy gradient (TD3) algorithm, to …

A Structure From Motion Photogrammetric Method For Continuously Measuring And Tracking The Deformations Of Soils During Triaxial Testing, Xiaolong Xia

Doctoral Dissertations

"Measuring soil deformation characteristics during triaxial testing is an important part of characterizing the stress-strain behavior of both saturated and unsaturated soils. The total and local deformations and volume changes of a soil specimen are indispensable parameters that need to be measured and are of great significance for understanding volume change and shear strength characteristics of the soil. Over the past several decades, numerous efforts have been made to measure the soil deformations during triaxial testing. However, it remains a great challenge for researchers to measure the volume-changes of unsaturated soils due to the existence of the air phase.

This …

Sustainable Cementitious Materials For Building And Sorption Applications, Sukanta Kumar Mondal

Doctoral Dissertations

"Ordinary Portland Cement (OPC) is the most widely used cement material, but it contributes over 8% of the global CO₂ emission and the process is energy intensive. Moreover, OPC faces durability challenges, particularly in aggressive environments. Hence, there is rapidly increasing interest in sustainable alternative cements with lower carbon footprint, lower energy consumption, and those that offer superior properties that are beneficial for specific applications. Two sustainable cementitious materials that are frequently researched as an alternative to OPC are calcium sulfoaluminate (CSA) cement and alkali-activated materials (AAMs). CSA cement lowers CO₂ emission by over 40% compared to OPC, …

Characterization Of The Acquisition Parameters Of A Submersible Gamma-Ray Computed Tomography System, Zhongmin Jin

Doctoral Dissertations

"The purpose of this work is to study a component of a submersible gamma-ray computed tomography (CT) system used in the non-destructive testing of irradiated nuclear fuels. The first section of this study proposes two acceleration approaches for rapidly modeling a transmission-type gamma-ray tomography system. The first relies on Monte Carlo simulations with a monodirectionally biased source sampled from a sub-volume of the whole source volume. This method estimates the real count rate using analytical correction factors. The second way of acceleration is based on deterministic calculations that use the Beer-Lambert law and detector response characteristics. It shows that both …

Novel Uses Of Distributed Optical Fiber Sensing For Geo-Mechanical Monitoring, Samuel Vincent Nowak

Doctoral Dissertations

"Rock mass monitoring in underground excavations is crucial for ensuring workplace safety and efficiency. As mines become deeper and more complex, the need to monitor larger volumes of rock during mining becomes impractical with existing instruments due to high costs. Distributed Optical Fiber Sensing (DOFS) is a powerful technology with advantages like long sensor length, real-time measurement capabilities, ease of installation, low cost, and distributed measurement. However, its application in rock mass monitoring is limited, especially in the mining industry. This study addresses a major gap in DOFS technology, specifically the inability of long-range distributed optical fiber strain sensors to …

Monitoring And Control Of Coal Dust Exposure Using Low-Cost Pm Sensors And Computational Fluid Dynamics, Nana Kobina Amoako Amoah

Doctoral Dissertations

"Overexposure to respirable coal mine dust has been linked to causing serious health problems including coal workers pneumoconiosis (CWP) and chronic massive fibrosis. The prevalence of these health problems has been on the increase since the 2000s due to increased exposure levels with roof bolter operators having the highest exposure levels. The currently used PDM3700 is too expensive, heavy and bulky which limits their use only for regulatory monitoring failing to measure miners’ personal exposure levels. Also, since roof bolter operators are more prone to elevated coal dust levels, the canopy air curtain (CAC) was developed to protect then high …

Melt Pool Feature Extraction, A State-Space Model And Spatial Layer-To-Layer Control For Powder Bed Fusion, Xin Wang

Doctoral Dissertations

"Powder Bed Fusion (PBF) is an Additive Manufacturing (AM) technique which can reduce material waste and is a fast-prototyping technique for complex geometries. However, the lack of consistent quality is a major problem in industrial applications. An InfraRed (IR) camera is a common tool to monitor a surface temperature field and melt pool morphology in PBF. With melt pool features from camera videos, manufacturing researchers use spatial feature maps to visualize defect locations and control researchers use layer-to-layer control to achieve more uniform melt pools and less defects.

Paper I presents a simulation method to characterize the effect of down-sampling …

Additive Manufacturing Of Steel And Aluminum Structures: Modeling And Experiments, Manoj Kumar Reddy Rangapuram

Doctoral Dissertations

"Additive manufacturing (AM) is defined as the process of joining materials to make objects from three-dimensional model data. Complex geometries can be easily manufactured compared to conventional subtractive methods with more freedom and flexibility in the design process. As the demand for AM process increased, it has become critical to understand the process and various parameters that constitute in affecting the quality of the manufactured part. Conducting experiments can be time intensive and costly to optimize a process. Modeling can be used as an aid to optimize, examine, and predict the process outcome.

The objective of this study is (i) …

Design And Development Of Biocompatible Mofs And Silica-Based Nanocarriers With Controlled Pharmacokinetics For Drug Delivery Applications, Neila Pederneira

Doctoral Dissertations

"In the past decade, a big interest has drawn into nanoporous metal-organic frameworks (MOFs) and silica-based materials as nanocarriers for drug delivery applications, owing to their exceptionally high surface area and highly structured porous network. The overall goal of this research was to optimize the pharmacokinetic behavior of several highly porous biocompatible drug carriers that have the potential to carry Ibuprofen, 5-Fluorouracil, and Curcumin to the desired tissue without creating a burst effect and minimizing the amount of dosage and size that conventional capsules require. The specific objectives of this study are to (i) assess the effect of drug solubility …

Development Of Uas And Geophysical Techniques For Agriculture And Environmental Site Characterization, Yunyi Guan

Doctoral Dissertations

"Soil properties are critical for agricultural management. Geophysical techniques such as ground penetrating radar (GPR) and electromagnetic induction have been used to measure soil properties for agricultural applications. However, their measurements are only acquired along select traverses within a field, and the data processing can be time-consuming, the instruments can also be expensive. Unmanned aerial vehicles (UAVs) are a recent advancement used for precision agriculture. Compared with geophysical data, UAVs have higher resolution and wider coverage and can quickly collect data across the whole field. The operation is also relatively simpler with a more economical acquisition cost. This research investigates …

Mission-Driven Inverse-Design Of Conventional And Unconventional Airplane Configurations Using Machine Learning, Rohan Srinivas Sharma

Doctoral Dissertations

"A key challenge in airplane design has been the long-desired ability to quickly create an airplane design with specific performance properties. To tackle this problem, researchers have traditionally leveraged design space exploration methodologies to iteratively explore a design space via surrogate models. On the other hand, inverse design is a process wherein performance objectives are fixed while a suitable design for satisfying these requirements is calculated. In recent years, artificial neural networks (ANNs) have been explored as viable surrogate models because traditional surrogate models struggle with the large number of output to input mapping needed for inverse design problems. In …

Lithospheric Drip And Mantle Thermal Upwelling Beneath Central Asia And The Southern Great Plains Of North America: Evidence From Receiver Function Imaging, Yangyang Liao

Doctoral Dissertations

"Investigating the depth of mantle transition zone (MTZ) discontinuities provides insights into mantle dynamics, including regional-scale downwelling of mantle lithosphere (i.e., lithospheric drip) and upwelling of thermal materials (i.e., mantle plume). In our study, we employ receiver functions to image the 410 km (d410) and 660 km (d660) mantle discontinuities and to ascertain thickness of the MTZ beneath Central Asia and the Great Plains in United States. The findings unveil a significantly thickened transition zone, exhibiting an average thickness of 284 km beneath East Sayan. When considered alongside geochemical observations, our results indicate that the descent of the lithosphere is …

Exploring Seismic Anisotropy In The Crust And Mantle Of The Tibetan Plateau And Analyzing Seismic Velocity Variations In Yellowstone, Cong Shen

Doctoral Dissertations

"Seismology is a scientific discipline that utilizes seismic waves to investigate the deep structures within the Earth's interior, which are otherwise inaccessible to direct observation by humans. These seismic waves can be categorized into two types: body waves and surface waves, each with distinct propagation modes and behaviors, carrying valuable information about their travel paths. The first paper concentrates on the analysis and inversion of body waves produced by large seismic events. It employs shear wave splitting and receiver function methods to explore the geodynamic structure of the south-central Tibetan Plateau, near the plate boundary. The investigation covers the depth …

Improving Syngas Quality In A Downdraft Biomass Gasifier With Blended Feedstocks, Rania Almusafir

Doctoral Dissertations

"Biomass gasification is the greatest potential renewable energy source and will play an important role in the energy mix of the future. To achieve a high quality of produced synthesis gas (syngas) in the gasification system, the syngas cleaning and cooling processes pose challenges. The main objectives of the present work are advancing the knowledge of the gasification process and producing syngas in the studied pilot-scale downdraft biomass gasifier.

A Thermogravimetric analysis (TGA) has been developed and utilized to experimentally investigate the impact of biomass feedstock diversity on the performance of the gasification process of hardwood (HW), softwood (SW) pellets, …

Highly Dipole-Parallel Aligned Nonlinear Optical Organic Molecular Crystalline Materials: Rational Design, Experimental And Theoretical Studies Of Supramolecular Structures And Non-Covalent Interactions, Harmeet Singh Bhoday

Doctoral Dissertations

Highly dipole-parallel aligned donor-acceptor substituted organic molecules are attractive for a wide array of applications, including nonlinear optics. However, only a limited number of crystals are known to adopt polar non-centrosymmetric space groups. The concepts guiding the fabrication of these polar materials have been described. The study focused on unsymmetrical donor-acceptor substituted azines and butadiene's. An improved design over (MeO, Y)-azines led to the realization of three crystals perfectly aligned in dipole parallel orientation for (PhO, Y)-azines with Y = Cl, Br, I, and one nearly perfectly aligned crystal for Y = F (Paper I). The unique bonding properties associated …

Comprehensive Investigation Of Using Tire-Derived Aggregate In Chip Seal Subjected To Various Traffic And Environmental Conditions, Alireza Pourhassan

Doctoral Dissertations

"Chip seal is one of the most cost- and performance-effective pavement preservation treatments commonly used in the United States. Using crumb rubber obtained from scrap tires as a partial or full replacement for mineral aggregate has been proposed as a sustainable solution to reduce the negative environmental impacts of scrap tire accumulation and excessive consumption of natural resources. However, there was no data available regarding the performance of rubberized chip seal under traffic loads and environmental conditions. An extensive study using laboratory specimens and conditioning as well as field implementation and assessments were conducted to bridge this gap. Different traffic …

Novel Supercritical Biodiesel Plant Design & Process Scale-Up, Ghana Shyam Paudel

Doctoral Dissertations

"Current energy prices, national energy security, and global climate change fuel our momentum to find efficient advanced fuels choices. In this study, biodiesel processing, and a novel design for next generation biodiesel plants are explored. During a National Science Foundation (NSF) I-Corps project we identified three creative and profitable improvements to the process: 1. Incorporating Energy intensive separations and reactions 2. Utilizing Low commodity glycerol and 3. Applying process intensification principles.

Current biodiesel processes are catalyzed processes using continuous stir reactors with distillation systems to separate material constituents. We tested a lab-scale nocatalyst supercritical biodiesel process using waste cooking oil …

Advanced Manufacturing Of Nanomaterials For Energy Storage And Biomedical Applications, Hiep Pham

Doctoral Dissertations

"Nanomaterials have emerged as an important component to the advancement of many fields, ranging from advanced energy materials in the energy field to highly sophisticated treatment vehicles in the biomedical field. Understanding the physical behavior of nanomaterials is critical to design materials with excellent properties and performance for the many disciplines in which they are utilized and is necessary to master the various manufacturing processes that influence nanomaterial properties and behavior. This research focused on a fundamental study into the behaviors of newly developed nanomaterials under both conventional and new manufacturing processes for high performance lithium-ion batteries and for advanced …

Modeling And Analysis Methods For Esd And Emi Problems, Xin Yan

Doctoral Dissertations

"Electrostatic discharge (ESD) failures and Electromagnetic interference (EMI) problems are becoming more critical in electronic devices and large systems. In this work, four studies are presented to model and analyze ESD and EMI problems.

First, a simplified physical-based model for deep-snapback transient voltage suppressors (TVS) is developed. While based on physics, the number of parameters and components is minimized. Results show that the proposed model captures the most important behaviors of the TVS response using a limited number of parameters, allowing the model to be tuned relatively easily using data obtained only from package-level transient and quasi-static measurements. Second, a …

A Human-Centered Framework For Oncological Healthcare System Modeling Applied To Mobile Radiation Delivery, Alex Price

Doctoral Dissertations

"Healthcare systems engineering is challenging due to the complexity, geographic expansiveness, inertial properties, and the heterogeneous sub-systems, with varying vested interests. Additionally, humans comprise many of the forms and functions, and are independent, with resistance and uncertainty in their decision-making that adds complexity. Human-centered systems modeling approaches are therefore needed to capture this unique aspect of a healthcare system and to enhance understanding of emergent healthcare properties. This dissertation focuses on integrating systems modeling within healthcare and emphasizes the importance of incorporating human decision-making. Moreover, the incorporation of a human-centered approach yields particularly valuable insights into the decision-making processes that …