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I Preparation Of N-Sulfonylsulfilimines Via Cycloaddition Reactions Of N-Sulfonyl Isothiocyanates And N-Sulfonyl Phosphinimines With Sufoxides Ii Attempt At Preparing (Methylsulfinyl)Alkyl Isothiocyanates Via Optically Active Methanesulfinate Esters, John Butler O'Brien

Doctoral Dissertations

No abstract provided.

Liquid Extraction With Single Droplets-Effect Of Chemical Reaction, William Victor Andoe

Doctoral Dissertations

"The circulating drop mass transport model based on Hadamard's dispersed phase stream function was solved numerically to account for a solute diffusing into a droplet and undergoing a first order irreversible reaction with the drop medium for the case where the continuous phase resistance to solute transport is negligible ... Experimental data were obtained for a system which consisted of 2-chloro-2-methylpropane (t-butyl chloride) diffusing from a benzene continuous phase into falling water droplets and undergoing a first order irreversible reaction with the water droplets ... The experimental solute transport rates were a factor of 7 to 10 greater than those …

An Experimental Determination Of The Homogeneous Nucleation Rate Of Water Vapor In Argon And Helium, Louis Benton Allen

Doctoral Dissertations

"An expansion type cloud chamber was used to measure the nucleation rate of water vapor in an atmosphere of helium and argon. A careful study was made of the thermodynamic characteristics during the expansion so that the nucleation data could be interpreted with reasonable accuracy and consistency. A fine wire thermocouple was used to measure the gas temperature during the course of an isentropic expansion in the dry chamber. When the finite heat capacity of the thermocouple is accounted for, it is found that there is almost perfect agreement with the temperature calculated from the equation of state and the …

Investigation By Neutron Diffraction Utilizing White Neutron Radiation, Arlen Ray Schade

Doctoral Dissertations

"The most probable reactor core neutron velocity was determined by analysis of data obtained from single crystals of copper and lithium fluoride. Derivation of the relationship between the maximum in experimental count rate and the most probable velocity, an error analysis of the method, and the computer routine are given for the method used to obtain the most probable velocity. The most probable velocity was used to index the maxwellian distributions from polycrystalline materials. Investigations were done with white neutron radiation of various silicon steel samples of different preferred orientation. A method is described by which the preferred orientation of …

The Lifetime And Effective Quenching Cross Section Of The 6²P₃/₂ State Of Thallium, Robert Charles Pickett

Doctoral Dissertations

"The measurement of the lifetime of the metastable 6²P₃/₂ state of thallium is discussed. Measurement of time varying optical absorption by time sampling techniques is explained for the study of the decay of the metastable atom concentration following a pulsed radio frequency discharge. The decay of the thallium radiation from optically allowed states terminating on the metastable state is measured at nine different thallium densities in the afterglow of the discharge. This radiation repopulates the metastable state and is displayed on an oscilloscope. The metastable lifetime is measured as a function of the thallium density at three different r-f power …

Deuterium Isotope Effects On The Solvolysis Rates Of Cyclopentyl Brosylates And Tosylates, Jimmie D. Christen

Doctoral Dissertations

"The brosylates and tosylates of cyclopentanol and its 1-d₁, c̲i̲s̲-2-d₁, t̲r̲a̲n̲s̲-2-d₁, and 2,2,5,5-d₄ analogs have been synthesized and their solvolysis rates measured at 25° in 70% vol. ethanol-water. The solvoylsis reactions were monitored by a conductance method. The isotope effects, k_H/k_D, observed for the brosylates and tosylates of each of the isotopically substituted cyclopentyl alcohols are as follows: 1-d₁-brosylate (1.1869) and 1-3₁-tosylate (1l1836); c̲i̲s̲-2-d₁-brosylate (1.1533) and c̲i̲s̲-2-3₁-tosylate (1.1577); t̲r̲a̲n̲s̲-2-d₁-brosylate (1.1803) and t̲r̲a̲n̲s̲-2-d₁-tosylate (1.1765); 2,2,5,5-d₄-brosylate (1.8881) and 2,2,5,5-d₄-tosylate (1.8863). The closeness in magnitude of the isotope effects for the c̲i̲s̲- and t̲r̲a̲n̲s̲-isomers is important in that it …

The Identification And Evaluation Of Toxic Effects Of Organic Micropollutants, John Warren Smith

Doctoral Dissertations

No abstract provided.

A Study Of Succinic Dehydrogenase, Indole Acetic Acid Oxidase, Nitrate Reductase And Cytochrome C Reductase In Hygrophorus Conicus, Jagdish M. Mehta

Doctoral Dissertations

"The activity of the enzyme succinic dehydrogenase (succinate : phenazine methosulfate oxidoreductase, EC 1.3.99.1) of Hygrophorus conicus, a member of a class of fungi known as basidiomycetes, was found to be stimulated by nitrate. Two substances were tested as electron acceptors in the measurement of succinic dehydrogenase activity. Of the two substances tried, phenazine methosulfate and brilliant cresyl blue, the former was found to be the best. Nicotinamide adenine dinucleotide (NAD⁺) was a necessary cofactor for the enzyme and could be readily dissociated from the enzyme. The enzyme has the properties of a high molecular weight nucleo- or lipoprotein.

The …

Multiport Synthesis With Multi-Layered Distributed Parameter Rc Networks, Walter Ronald Koenig

Doctoral Dissertations

"Synthesis and design techniques for multiport, multilayered, distributed parameter RC networks are investigated in this dissertation. The basic building block is a network section of uniform width consisting of alternate layers of resistive and dielectric materials on top of a perfectly conducting plane. The resulting network is composed of a cascade of these sections with all access terminals at one end of the cascaded network. The terminals at the other end are either open circuited or short circuited. A method is discussed for synthesizing a network from a prescribed network admittance matrix. An approximation technique is given for obtaining a …

Optical Reflectance Spectra Of Chromium (Iii) In Mgo-Ss, Thomas Spencer Montgomery

Doctoral Dissertations

"The valence state and coordination site of the transition-metal ion, chromium, was investigated in a MgO host lattice. The chromium ion incorporated into poly-crystalline MgO by quenching from elevated temperatures allowed investigation of a single crystalline phase, MgO-solid solution (ss). The chromium ion was confirmed to occur in the trivalent state and to occupy octahedral cation sites in the MgO lattice by the use of optical reflectance spectroscopy. The effect of the concentration of the chromium ion on the crystal field splitting energy, 10 Dq, permitted analysis over a range of Dq/B values. In conjunction, MgO-ss lattice parameters examined as …

Studies Of Toluidine Blue For Inducing Haploidy In Lycopersicon Esculentum And Zea Mays, Salih Aziz Al-Yasiri

Doctoral Dissertations

No abstract provided.

Histochemical And Morphological Analysis Of In Vitro Cultured Embryos Of Pelargonium X Hortorum Bailey, In Comparison To Normal In Vivo Embryology And Seedling Differentiation, Franklin Scott Adams

Doctoral Dissertations

No abstract provided.

Nucleophilic Displacement At The 3-Position Of 1,2,3,6-Tetrahydropyridines, William Ernest Krueger

Doctoral Dissertations

No abstract provided.

Electron Density Measurements In The Lower Ionosphere By A Rocket Borne Radio Propagation Method, Lee Edward Larson

Doctoral Dissertations

No abstract provided.

Resonance Energy Transfer Studies: Dependence Of Transfer Properties On The Structure Of The Donor Molecule, Barton Stephen Solomon

Doctoral Dissertations

No abstract provided.

Physiological Factors In The Etiology And Alleviation Of Salt-Induced Decline Of Roadside Maples And Pines, John Bernard Kotheimer

Doctoral Dissertations

No abstract provided.

The Chemistry Of Vitreoscilla Cell Envelopes, Gerard O'Leary Jr.

Doctoral Dissertations

No abstract provided.

Aspects Of Membrane Structure And Function In Streptococcus Faecium, James Joseph Burke Jr.

Doctoral Dissertations

No abstract provided.

The Stability Constants Of Indium(Iii) Complexes With Chloroacetate, 2-Chloropropionate And 3-Chloropropionate Anions, Edwin Ellison Hach Jr.

Doctoral Dissertations

No abstract provided.

Synthesis And Attempted Resolution Of 4-Hydroxymethyl Cyclohexanone Oxime, Canan Avunduk Bonnice

Doctoral Dissertations

No abstract provided.

Alpha-Arylisoborneols: An Investigation Of The Ord And Cd And A Study Ofthe Ritter Reaction, John Joseph Santos

Doctoral Dissertations

No abstract provided.

The Characterization And Cytochemical Localization Of The Adenosine Phosphate Hydrolases In The Gliding Bacterium Vitreoscilla, Jeffrey Carleton Burnham

Doctoral Dissertations

No abstract provided.

Investigations Into The Synthesis Of Potential Macrocyclic Ring-Chain Tautomers And Model Compounds, Ronald John Panicci

Doctoral Dissertations

No abstract provided.

A Kinetic Study Of The Gas Phase Photobromination Of Trichlorosilane, Bernard Launcelot Mahoney Jr.

Doctoral Dissertations

No abstract provided.

A Theoretical Investigation Of Elastic And Voigt Transient Spherical Waves, And Plane Three-Element Viscoelastic Waves, Edward Hornsey

Doctoral Dissertations

"A mathematical model of explosive generated waves in rock is needed in many areas of engineering endeavor. Investigations to date have been unsuccessful in obtaining a model that satisfactorily represents real wave phenomena at all radial distances and in all of the important characteristics.

In this investigation, spherical waves in elastic and Voigt media were investigated. Series solutions for plane waves in a three-element viscoelastic medium were obtained. A dual exponential pressure pulse, P(t) = P_o (e^-αt-e^-ßt) was assumed because it can exhibit significant features of real pressure pulses while avoiding instantaneous rise time, which …

A Structural Investigation Of Bismuth Ferrate And The Bifeo₃-Pbzro₃-Pbtio₃ Ternary System, Gary D. Achenbach

Doctoral Dissertations

"Solid state reaction of Bi₂O₃ · Fe₂O₃ mixtures was shown to yield impure bismuth ferrate, BiFeO₃, containing Bi₂Fe₄O₉ and residual Bi₂O₃; this places the results of much of the literature based on BiFeO₃ prepared by this technique in suspect. Single phase polycrystalline BiFeO₃ was prepared by multiple nitric acid leaching of sintered samples which contained excess Bi₂O₃ to prevent the formation of Bi₂Fe₄O₉ during sintering. X-ray and neutron powder diffraction data indicate that …

An Investigation Of The Creep Characteristics Of Portland Cement Mortar Under Static And Dynamic Strain, Ikram-Ul-Haq Dar

Doctoral Dissertations

"The combined effect of static and dynamic loads on design of underground openings is currently receiving much attention. It is known that the time-dependent behavior of rock is considerably different when a dynamic load is superimposed on prestressed rock. The shape of an underground opening has a definite influence on the magnitude of the local stresses and these may be significantly larger than those due to the weight of the overlying rock alone. Under these conditions, even a small dynamic load in the form of vibrations caused by blasting, drilling and related operations may increase the stress beyond a critical …

Numerical Approximation To Performance Predictions Of Gas-Drive Reservoir With Or Without Gas-Cap And Gas Injection, Jagannath Rao Ghole

Doctoral Dissertations

"The pressure-saturation transient history for a hydrocarbon reservoir is solved for solution-gas, gas-cap and injected-gas drives assuming the saturation-pressure variations depicted by Muskat, under specific restrictive assumptions. A prototype reservoir system and its transient pressure saturation distribution under production is systemized on an IBM 360-Model 40 Computer which allows the definition of the transient behavior of saturation with pressure declination and fluid withdrawal for preassigned initial saturations of the oil, water and gas phases. This analysis is then modified for the existence of a gas-cap and for the re-injection of produced gas volumes for pressure maintenance considerations and the ensuing …

Magnetic Properties Of The Bifeo₃-Pbtio₃-Pbzro₃ Ternary System, James Ivan Latham

Doctoral Dissertations

"The magnetic susceptibility and spontaneous magnetic moment of the perovskitic, polycrystalline solid solutions of BiFeO₃ with PbTiO₃, PbZrO₃, and [50PbZrO₃·50PbTiO₃] were determined using the Faraday method. Pure BiFeO₃ has a G-type antiferromagnetic structure. Although the perovskite BiFeO₃ exhibits a sharp peak in the susceptibility at the Néel temperature, it does not possess a spontaneous magnetic moment. The solid solutions investigated possessed a spontaneous magnetic moment throughout the multiple cell rhombohedral region of the BiFeO₃-PbTiO₃-PbZrO₃ ternary phase diagram, which extends from pure BiFeO₃ to …

High Frequency Ferroelectric Properties Of The Bifeo₃-Pbtio₃-Pbzro₃ Ternary System, Robert Travis Smith

Doctoral Dissertations

"High temperature dielectric measurements have been performed on the ferroelectric and antiferroelectric perovskitic polycrystalline solid solutions in the BiFeO₃-PbTiO₃-PbZrO₃ ternary system. The data were taken in the UHF frequency range with the use of a slotted line and specially constructed sample holder capable of operation at temperatures in excess of 800°C.

The Curie points have been found to occur at progressively higher temperatures with the increase of BiFeO₃ content in the solutions except in phase transition regions where minima can occur. The dielectric constants at the Curie temperatures have been found to decrease with …