Digital Commons Network^™

The Species Composition, Seasonal Succession, Reproduction And Distribution Of Marine Algae From Scituate To Woods Hole, Massachusetts, Douglas Clifton Coleman

Doctoral Dissertations

No abstract provided.

The Effect Of Copper On Pseudomonas Cuprodurans, Sp Nov, Laurence Ray Mccarthy

Doctoral Dissertations

No abstract provided.

Some Ecological Effects Of Artificial Circulation On A Small Eutrophic New Hampshire Lake, Robert Chester Haynes

Doctoral Dissertations

No abstract provided.

An Investigation Of The Radiation Polymerization Of Methyl Methacrylate-Kaolin Clay Composites, James Jackson Beeson

Doctoral Dissertations

"A kinetic and characterization study has been made on the effects of gamma-rays (Co⁶⁰) on the polymerization of a 50-50 weight mixture methyl methacrylate (MMA) kaolin clay system. The effect of dose rate (7.35 - 24.9 rads per second), temperature (25 to 75ºC) and total dose on the percentage conversion of monomer to polymer was studied. The rate of formation of polymer at 25ºC in the composite system was found to be faster when compared to a bulk MMA system at the same experimental conditions. This acceleration showed that the clay had a catalytic effect on the formation of polymer. …

An Investigation Of Subsequent Yield Phenomena, Joseph George Hoeg

Doctoral Dissertations

"A method utilizing high pressure fluid environments is described whereby a three-dimensional subsequent yield surface was determined for 304 stainless steel. Cylindrical parent specimens of this material were prestrained in axial compression under fluid pressure and then small sub-specimens were sectioned from these parent specimens. Finite element techniques were used to optimize the parent specimen size so that a zone of uniform axial stress would result during the prestraining. Longitudinal strains in this zone were monitored during the prestraining and the sub-specimens were cut from this region in a manner that did not allow the machining to appreciably affect the …

Distribution Of Trace Elements In Olivines And Proxenes - An Experimental Study, Melvin Leroy Bird

Doctoral Dissertations

"Olivine, pyroxene,and spinel were crystallized in the ternary system anorthite-forsterite-silica to which trace amounts of the transition metal ions Cr³⁺, Fe²⁺, Mn²⁺, Co²⁺, Ni²⁺, and Cu²⁺ had been added. The resulting concentrations of the transition metal ions in the liquid and crystalline phases were determined using the electron microprobe. The results, given as free energies and partition functions, indicate the order of substitution of the dipositive ions in all crystals to be Ni²⁺, Co²⁺, Mn²⁺, Cu²⁺, and Fe²⁺ according to the predictions of crystal field theory. The ion Cr³⁺ substituted in greater or lesser quantities depending on the crystalline phase. …

Response Surface Study Of A Characteristic Chemical Plant, John Thomas Mason Iii

Doctoral Dissertations

"Study of the return on investment response surface of a characteristic chemical plant indicates unimodality in the valid region, but the optimum design condition with this response surface is strongly affected by the correlation used for the investment. The method used for the design of this type of chemical plant incorporates the use of a simulation routine for preliminary estimates"--Abstract, page ii.

Structure And Properties Of Silver Borate Glasses, Edward Nashed Boulos

Doctoral Dissertations

"Clear glasses form in the system Ag₂O-B₂O₃ up to about 35 mol.% (65 wt.%) Ag₂O. Infrared absorption, thermal expansion and density data indicated an analogy to the Na₂O-B₂O₃ system. Pentaborate-triborate group pairs appear to be formed upon the addition of Ag₂O to B₂O₃ up to 20 mol.% Ag₂O and diborate groups from 20 to 33 mol.% Ag₂O. This interpretation is supported by the comparison of the infrared absorption spectra of quenched and crystallized glasses. One crystallization product ,Ag₂O.4B₂O₃, has been identified previously. A new compound starts to appear at 28 mol.% Ag₂O. Silver is generally present as a network modifier …

The Thermal Accommodation Coefficients Of Helium, Neon, And Argon On Surfaces, Gerald Lee Zweerink

Doctoral Dissertations

"Measurements of the accommodation coefficients of helium, neon, and argon on an ice surface at 77ºK were accomplished; Measurements of the accommodation coefficients of helium and neon on a clean tungsten surface are also reported here; These data are compared with theoretical calculations of accommodation coefficients as well as with data from other experimental studies"--Abstract, pages iii-iv.

The Vibrational Modes Of Spheroidal Cavities In Elastic Solids, David Stewart

Doctoral Dissertations

"A general analysis of all possible cavity shapes is given with a discussion of the mathematical difficulties involved for the various cases. Special emphasis is given to cavity shapes describable in terms of the coordinate surfaces of coordinate systems separating the scalar wave equation. 112 such shapes are identified and discussed. Free boundary condition equations for spheres and spheroids are derived in complete generality in terms of potentials. The difference in the vibrations of a solid and those of a cavity of the same shape is discussed and made clear. The impossibility of deriving a frequency equation for uniform radial …

Trace Base Metals, Petrography, Rock Alteration Of The Productive Tres Hermanas Stock, Luna County, New Mexico, Peethambaram Doraibabu

Doctoral Dissertations

"Zinc, lead and minor copper-bearing manto-type and vein- type deposits occur in Paleozoic sedimentary rocks adjoining the Tres Hermanas quartz monzonite stock, Luna County, New Mexico. In an attempt to prove or disprove a possible genetic relationship between these mineral deposits and the stock, 99 half-mile or closer orthogonal grid samples from the stock and 22 soil samples from a connecting alluvial area to the north were analysed by atomic absorption technique for trace contents of zinc, lead and copper. Thirty-two of the rock samples were selected on a wider grid and petrographically studied and modal analyses calculated. Argillic, sericitic …

X-Ray And Neutron Diffraction Study Of The Holmium-Iron System, Michael Fred Simmons

Doctoral Dissertations

"Neutron diffraction and x-ray powder studies have been made of holmium-iron intermetallic compounds. The magnetic moments of Ho and Fe are in good agreement with measured spontaneous magnetization assuming a ferrimagnetic model with the Ho moments antiparallel to the Fe moments. The magnetic moments of the Fe atoms are found to be localized and thus independent of the rare earth content in the alloys. In contrast to HoCo₃, (00ℓ) type magnetic peaks in the neutron diffraction patterns are still prevalent at room temperature and gradually decrease as the Curie temperature is approached. This fact indicates that the easy direction of …

Use Of The Turbulence Kinetic Energy Equation In Analyzing Turbulent Near Wakes, James Edward Auiler

Doctoral Dissertations

"A general method is presented for analyzing turbulent flow fields in the near wake regions of two-dimensional and axisymmetric bodies. The governing partial differential equations of continuity, momentum and turbulence kinetic energy are expressed in elliptic form in terms of the dependent variables stream function, vorticity and turbulence kinetic energy. An iterative finite-difference technique is used to solve the governing equations simultaneously. Numerical solutions are obtained for the following physical problems: 1. Laminar near wake: Only stream function and vorticity are considered for laminar flow. Solutions are compared with available analytical results for uniform flow over a sphere. 2. Turbulent …

Synthesis, X-Ray Characterization, Structural And Magnetic Studies Of A New Class Of Iso-Structural Bimo₃ Compounds, Joseph Donato Bucci

Doctoral Dissertations

"This dissertation consists of four sections. The first part is a temperature dependent X-ray study of the lattice parameters of BiFeo₃. The synthesis and subsequent X-ray characterization of BiCo₃, BiAlO₃, BiMnO₃ , BiScO₃, BiCo₁₋ₓFeₓO₃ , and BiAl₁₋ₓFeₓO₃ are reported in the second part. These compounds all crystallize in the body centered cubic (BCC) structure with a~10.2Å. Single crystal Precession and Weissenberg photographs confirmed the BCC structure. In part three, the results of the magnetic studies on BiCoO₃ and biAl.₉FE.₁ are presented. The magnetic data for BiCoO₃ are substantiated by X-ray thermal expansion studies. In the last part the compound BiCo.₉FE.₁O₃ …

Photoionization Of Photoexcited Cesium, Robert E. Hebner

Doctoral Dissertations

"A new method for obtaining the cross section for photoionization of photoexcited cesium is presented. The salient feature of this experiment is to use three crossed beams, i.e., two light beams intersecting a beam of cesium atoms. The cross section is determined by counting the ions produced by the two step process: Cs (6S) + h[upsilon]₁ --> Cs (6P) ; Cs (6P) + [upsilon]₂ --> Cs⁺ + e⁻ The relative cross section for the second step has been obtained from threshold (5060 Å) to 2500 Å. The excitation light source used in obtaining this cross section was a rf resonance …

Modeling The Visual Pathway For Interactive Diagnosis Of Visual Fields, Chiam Geoffrey Goldbogen

Doctoral Dissertations

"Visual fields are an important tool for the ophthalmologist in the detection, diagnosis, and monitoring of certain diseases and maladies of the visual pathway. The aim of the present research is to build a computer system which utilizes a learning machine to develop a mathematical model of the visual pathway. It is hoped that this system may be used in the field of ophthalmology as a teaching aid, or may assist in various aspects of diagnosis. Faults corresponding to blind or impaired areas of visual fields are extracted from medical records of a patient's condition. The structure of the model …

Dynamic Behavior Of Eccentrically Stiffened Plates, Charles Stuart Ferrell

Doctoral Dissertations

"The dynamic behavior of eccentrically stiffened rectangular plates is studied by the finite element method. The addition of stiffeners to a plate structure is a common method of increasing the rigidity of the structure with a minimum of weight increase. However, this stiffened plate configuration does not easily lend itself to analysis. This study is an approach to finding a rational method by which the dynamic behavior of such a stiffened plate structure may be determined. The governing differential equations for the finite element model are derived and the stiffness and mass matrices for the plate and stiffener elements are …

Metal Salt Catalyzed Carbenoids, Billy W. Peace

Doctoral Dissertations

"The interaction of diazomalonic esters with olefins in the presence of homogeneous copper(I) and copper(II) catalyst has been examined as a function of olefin structure, solvent media, ionic strength, catalyst structure and catalyst concentration, using partial rate data. It has been possible to determine the fine mechanistic details of the cycloproponation, C-H insertion and "dimer" forming reactions. The initial step is displacement of a ligand from copper by diazo compound in a pre-equilibrium, loss of nitrogen in the rate determining step, return of the ligand, displacement of metal from the carbenoid by olefin, followed by collapse to products. Studies revealed …

Noble Gases Anomalies In Terrestrial Ores And Meteorites, B. Srinivasan

Doctoral Dissertations

"Analyses of the content and isotopic composition of xenon and krypton in terrestiral ores containing tellurium, selenium or iodine resulted in the following conclusions: 1. The double beta-decay half-life for ¹³⁰Te is 2.51 x 10²¹ years from analysis of tellurobismuthite from Boliden, Sweden and 2.83 x 10²¹ years from analysis of tellurides from Kalgoorlie, Australia. 2. The ratio of the double beta-decay half-life of ¹²⁸Te relative to that of ¹³⁰Te is ≥ 108 and ≥ 293 for Boliden tellurobismuthite and Kalgoorlie tellurides, respectively. 3. Selenium minerals and tellurium ores containing selenium exhibit ⁸²Kr excess attributed to the double beta-decay of …

Surface Reactions Of Boron With Clean Tungsten Substrates, Thomas A. Flaim

Doctoral Dissertations

"A model developed to predict adsorbate-induced work-function changes for thermionic emitters is shown here to apply to a more general class of electron emission phenomena and a much broader range of adsorbates. This model predicts that chemically, vapor-deposited boron will increase the work function of a clean tungsten substrate at coverages between 0 and 1 monolayer. This is the first time that a single model has been shown to predict both positive and negative work function changes for different adsorbates. The reactions of chemically, vapor-deposited (CVD) boron with clean tungsten substrates were studied using field emission microscopy (FEM) and low …

The Ecology Of A New Hampshire Estuarine Tidal Rapid, Norman B. Reynolds

Doctoral Dissertations

No abstract provided.

Internal Friction Of Ion Exchanged Li₂O•Al₂O₃•2sio₂ Glasses, A. Ismail A. Abdel-Latif

Doctoral Dissertations

"Li₂O•Al₂O₂•2SiO₂ glass fibers were ion-exchanged from 1 to 300 minutes in a sodium nitrate bath at 366ºC. The internal friction was measured along with the lithium and sodium concentration profiles. As sodium progressively replaced lithium, the alkali internal friction peak became smaller while a new peak (mixed alkali peak) appeared and increased in magnitude. These changes in the internal friction are similar to those that occur upon the addition of a second alkali to glasses prepared by conventional melting. The magnitude of both internal friction peaks in ion exchanged glasses was dependent on the overall glass composition. The magnitude of …

Characterizing Topologies By Classes Of Functions And Multifunctions, Alexander Hamlin Cramer

Doctoral Dissertations

"Topological spaces are characterized by the algebraic and topological structures of their classes of continuous selfmaps. The problem of determining the topology of a set given certain classes of multifunctions or relations is considered. The algebraic structure of the upper semicontinuous multifunctions is shown to determine the topology of T₁ spaces. A partial order for classes of topologies for the real numbers is defined and relationships between various classes are established"--Abstract, page ii.

Theory Of Nucleation Of Water Properties Of Some Clathrate Like Cluster Structures, Mehdi Daee

Doctoral Dissertations

"The tranquility of classical homogeneous nucleation theory has been disturbed by the introduction of statistical mechanical correction factors to a basically thermodynamic theory. These factors, which appear to be essential, destroy much of the agreement with experiment in the case of water vapor. A molecular model for the pre-nucleation water clusters is proposed with a view toward resolving some of these difficulties. As a first step, the Properties of a few specific cluster configurations have been examined. Clathrate-like structures containing 16 to 57 water molecules are discussed. The hydrogen bonds were treated as simple harmonic oscillators for the purpose of …

Homogeneous Nucleation Of Water Vapor In Inert Gas Atmospheres, Arthur Henry Biermann

Doctoral Dissertations

"The homogeneous nucleation of water vapor in atmospheres of helium, neon, argon, krypton, and xenon was studied using an expansion type cloud chamber. A strong dependence of the nucleation rate on the particular inert carrier gas was observed. At present the only dependence upon the nature of the carrier gas included in classical nucleation theories is a small factor arising from kinetic considerations which is in the wrong direction to explain the observations. To explain the dependence of the rate on the nature of the carrier gas, a molecular cluster model is assumed allowing inert gas atoms to occupy the …

Surface Plasmon-Longitudinal Optical Phonon Contribution To The Reflectivity Of N-Type Insb, William Eugene Anderson

Doctoral Dissertations

"The reflectivity of n-type InSb has been measured in the far infrared. The doping of the samples was such that the free-carrier plasma frequency was near the longitudinal optical phonon frequency. The results suggest that samples with a sufficiently thick damage layer show effects due to surface plasmons. The results also indicate that the surface plasma excitations are coupled to the phonons. A simple model of this coupling is presented which agrees qualitatively with the observed reflectivity. A somewhat more rigorous theory of the coupling is also presented"--Abstract, page ii.

Statistical Study Of Rock Drilling By Hypervelocity Jets From Explosive Shaped Charges, John William Brown

Doctoral Dissertations

"The drilling effect in rock of hypervelocity jets from explosive shaped charges was investigated experimentally to supplement a rapid excavation concept. The effects of the design factors of the charge and the mechanical properties of eight rock types were studied. Experiments were both designed and analyzed upon statistical principles. A full factorial experimental design was used for each of seven rock types. An analysis of variance and the k-ratio least significant-difference test were applied to the results.

The optimum design of shaped charges for drilling was found to be independent of rock type and rock properties. For composition C-4 charges …

Absolute Cross Sections For Excitation Of Neon By Impact Of 20-180 Kev H , H₂ And He Ions, George William York

Doctoral Dissertations

"The technique of heavy-ion energy-loss spectrometry has been used to measure excitation cross sections for the (2p⁵)3s and (2p⁵)3p electronic configurations of Neon. The incident particles used were H⁺ , H⁺₂ and He⁺ at impact energies from 20-180 keV. The results are compared with previous optical measurements of the emission cross sections of lines from these levels as excited by H⁺ and He⁺ impact. Agreement is not good, either in shape or in absolute magnitude for excitation of the (2p⁵)3s configuration. However, agreement is surprisingly good for excitation of the (2p⁵)3p configuration. A curve fitting technique has been applied to …

Activation Volumes Of Carbon Diffusion In F.C.C. Iron-Nickel Alloys, James Raymond Keiser

Doctoral Dissertations

"The disaccommodation technique was used to determine the activation volume of carbon diffusion, ΔV, in six fcc iron-nickel alloys. Measurements were made at temperatures ranging from 68ºC to 90ºC and pressures up to six kilobars on samples having a nickel content between 31 and 63 at. %. A maximum activation volume of 3.9 cm³/mole was found at 34 at. % nickel. The compositional dependence of ΔV is satisfactorily reproduced by a magnetic energy continuum model in which it is assumed that the activation free energy of diffusion is essentially ferromagnetic in origin "--Abstract, page iii.

On-Line Economic Optimization Of A Chemical Reactor, Jesse Daniel Bennett

Doctoral Dissertations

"An economic optimizing control system for a continuous flow stirred tank chemical reactor is designed, simulated, and installed on a pilot scale reactor. The control scheme utilizes a reaction and reactor model to predict on-line the economic optimum of a reactant concentration. In this manner the control system manipulates the reactant flow rate to maintain the optimum concentration during changes in reaction-reactor parameters with time. Typical parameter changes include the decay of reaction catalyst activity. The optimizing controller will function in conjunction with various operating policies including control to maintain a specified production rate"--Abstract, page ii.