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Charge Transfer Between Oˉ Ions And O₂ Molecules In The Ground State And Singlet Delta Excited State, Ronald Floyd Mathis

Doctoral Dissertations

"A crossed-beam apparatus has been built and used to study charge transfer between O⁻ ions and O₂ molecules in the ground state and in the metastable, singlet delta, excited state. The energy of the incident ions ranged from 10 to 10,000 eV.

The cross section for charge transfer between O⁻ and ground state O₂ was found to peak at about 5 keV, as predicted on the basis of the Rapp and Francis theory. At the lower energies there is good agreement with the previous measurements of Snow et al., and Rutherford and Turner, who also used crossed beam techniques. The …

Investigation Of Roof Shales In Illinois Coal Mines, Peter J. Conroy

Doctoral Dissertations

"This thesis describes an investigation of the relationships among the composition, physical properties and the performance of roof shales in Illinois coal mines. The study included cataloging the physical and mineralogical properties of typical roof shales, determining the interrelationships of the properties and defining the factors in the rock which effect deterioration. From the results, a classification system has been developed which may provide a means for evaluating coal mine roof stability.

A coring apparatus was developed for obtaining in situ samples from mine roofs. Five coal mines with varying geologic and roof conditions were sampled. Precautions were taken to …

A Study Of The Pulse-Height Response Of Silicon Surface-Barrier Detectors To High-Energy Heavy Ions, Gregory Dan Smith

Doctoral Dissertations

"The pulse-height defect (PHD) of high-energy heavy ions in silicon surface-barrier detectors can be divided into three components: (1) energy loss in the gold-surface layer, (2) a nuclear-stopping defect, and (3) a defect due to recombination of electron-hole pairs in the plasma created by the heavy ion. The plasma recombination portion of the PHD was the subject of this study using the variation of the PHD with (1) the angle of incidence of incoming heavy ions, and (2) changes in the detector bias. The Tandem Van de Graaff accelerator at Argonne National Laboratory was used to produce scattered beam ions …

Considerations In The Design Of A Network Of Minicomputers, Hardy J. Pottinger

Doctoral Dissertations

"The advantages of a network consisting of a number of minicomputers coupled to a large time shared computer are described. This type of network is very useful in the areas of data acquisition, real time control of experiments, and front-end processing for computer graphics.

Problems associated with the development of a network of this type, various possible solutions, and the trade-offs involved are presented. These problems are classified into two categories: the interface between the network and the central computing facility, and the interface between the remote sites and the rest of the network.

The design constraints, rationale, and implementation …

Convergence Of Material Balance In Mathematical Simulation Of Petroleum Reservoirs, Abdul Rashid Merchant

Doctoral Dissertations

One criterion for determining the precision of pressures calculated by a simulation model is the accuracy of the material balance. A high degree of precision in the calculated pressures is a necessary condition for elimination of error in prediction of fluid migration in the reservoir. However, this condition is not sufficient to guarantee accuracy of the simulation, since inaccuracies are introduced by truncation errors, machine round-off errors, and by the use of finite difference approximations to represent nonlinear partial differential equations.

A new procedure called Error Matrix Technique has been developed for reduction of material balance errors. This reduction is …

Transient State Analysis Of Separated Flow Around A Sphere, Ching-Liang Lin

Doctoral Dissertations

"Transient state solution of the Navier Stokes equation was obtained for incompressible flow around a sphere accelerating from zero initial velocity to its terminal free falling velocity. By assuming rotational symmetry around the axis in the falling direction, the Navier Stokes equation and the continuity equation were simplified in terms of vorticity and stream function. The instantaneous acceleration of the falling sphere was calculated by considering the difference between the gravitational force and the drag force in a transient state. The governing partial differential equations were non-dimensionalized. A set of implicit finite difference equations was developed. In order to obtain …

Stability Of The Developing Laminar Flow In A Circular Tube, Lung-Mau Huang

Doctoral Dissertations

"An investigation is made of the linear stability of the developing laminar flow of an incompressible fluid in the entrance region of a circular tube. Both axisymmetric and non-axisymmetric small disturbances are considered in the analysis. The stability characteristics of the fully developed flow are also re-examined. The main flow velocity distribution used in the stability analysis is that from the solution of the linearized momentum equation. The governing equations for the disturbances and the boundary conditions constitute an eigenvalue problem which is solved by a direct numerical integration scheme along with an iteration technique. The solution starts with a …

Film Boiling Of Freon 113, Normal Pentane, Cyclopentane, And Benzene From Cylindrical Surfaces At Moderate Pressures, Gary Joseph Capone

Doctoral Dissertations

"An investigation of film boiling heat transfer in saturated pools of liquid Freon 113, Normal Pentane, Cyclopentane, and Benzene was made. The fluids were boiled from copper, cylindrical heat transfer surfaces, 3 inches long, and 0.55, 0.75, and 1.00 inch in diameter. The heat transfer elements were positioned horizontally in an autoclave and tested at moderate pressures of up to a pressure of 242.5 psia for Normal Pentane.

The experimental data are discussed and compared with known film boiling correlations. The known correlations were found to be inadequate in predicting heat transfer coefficients as a function of pressure, temperature difference …

Film Boiling Of Benzene, Freon 113, Freon 11, And Normal Pentane From Horizontal Surfaces At Atmospheric Pressure, Richard Stanley Kistler

Doctoral Dissertations

"A film boiling study was conducted with five different area flat plates at atmospheric pressure for benzene, Freon 113, Freon 11, and n-pentane. The heat transfer surface was horizontal for all tests.

The data were compared to the correlations commonly used for heat transfer. The common correlations were found to be in error for small surface sizes, but adequate for all fluids except benzene for the largest surface, a semi-empirical equation which correlates the available data as a function of surface diameter was derived and discussed"--Abstract, page iii.

Measurement Of Molecular Diffusivities Of Liquid Alkane Systems, James W. Moore

Doctoral Dissertations

"An unsteady-state porous frit method of diffusion coefficient measurement, recently developed in this laboratory, was improved and expanded upon. The experimental technique has been refined and documented. The unsteady-state diffusion of an initially 0.5 N NaCl solution into pure water (effective diffusivity -1.480 x 10^-5 cm²/sec) was employed as the calibration standard. An overall calibration precision of ±4% was obtained. Diffusion times of two hours or less were used for the non-aqueous diffusivity measurements. The validity of this measurement technique was confirmed by the agreement of the measured self-diffusion coefficient of n-heptane (25⁰C) with literature values.

A …

Parameter Identification Applied To Linear Quadratic Differential Games, John D. Corrigan

Doctoral Dissertations

"A two player zero-sum linear quadratic differential game is investigated for the case in which one of the players has incomplete a priori knowledge of the parameters of his opponent's dynamic system. This incomplete system parameter information game is shown to be playable since the ignorant player can make limiting estimates of the unknown parameters from the relative controllability condition for the game. Performance from the ignorant player's point of view is suboptimal.

It is also shown that parameter identification techniques can be applied by the ignorant player in order to directly identify the smart player's closed-loop parameters in the …

Numerical Simulation Of Heat, Mass, And Momentum Transfer In An Atmospheric Boundary Layer, Darrell W. Pepper

Doctoral Dissertations

"Considerable interest has developed in recent years to understand transport phenomena in thermally stratified boundary layers. More complete knowledge in this field is needed to improve the prediction of the diffusion of air pollutants in the lower atmosphere as well as in forecasting air-water circulation for weather conditions.

The atmospheric boundary layer is modeled using the equations of continuity, momentum, energy, and concentration. Closure of this set of partial differential equations is hindered by the turbulence terms. Using turbulence kinetic energy, the system of equations is closed by internally determining the exchange coefficients of heat, mass, and momentum along with …

Paleozoic Stratigraphy As An Ore Control Of Hydrothermal, Base-Metal, Sulfide Deposits In New Mexico, John Samuel Sullivan Jr.

Doctoral Dissertations

"Until now the concept or regional stratigraphic control of hydrothermal ore deposits has not received much attention in the literature as a possible exploration guide for locating additional ore bodies. This concept is applied on a regional scale to Paleozoic strata in thirteen mining districts with hydrothermal base-metal deposits in a 35,300 square mile area or southwest New Mexico.

The rocks at the stratigraphic position of the ore-zones are characterized as massive- to thick-bedded with less than 5 percent chert present. The rocks are abundantly to moderately fractured. Fine- to medium-grained dolomite is the dominant host-rock in the lower Paleozoic …

Premartensitic Elasticity Of Fe-Ni Invars, Bryce Linn Shriver

Doctoral Dissertations

"The premartensitic temperature dependence of ultrasonic wave propagation in Fe-30 pct Ni polycrystals and Fe-32 pct Ni single crystals was measured by using a continuous wave technique. As the temperature was lowered to within 10°C of the M_s, a nonlinear decrease of the relative shear velocity was observed. This effect is related to dislocation stacking fault instabilities which may trigger the martensitic phase transformation. In addition, the single crystals show a frequency dependence of the shear elastic constant C' well above the M_s. The dispersion is believed to be caused by fluctuations in the anisotropic molecular …

Tchebycheff Approximation On A Discrete Point Set: Algorithms Old And New, William Edward Mcbride

Doctoral Dissertations

"Several linear and nonlinear algorithms for solving the discrete Tchebycheff problem are compared in this study. The Lawson algorithm is compared with two more well-known methods of linear Tchebycheff approximation. A new acceleration scheme for the Lawson algorithm is introduced and its performance is tested with an already existing acceleration technique. The new version is found to be better than the previous one but not as effective as the traditional Exchange method.

A nonlinear version of Lawson's algorithm is proposed for the solution of problems having approximating functions which are varisolvent. Some linear theorems of Lawson are extended to the …

Hall Effect Measurements Of The Net Ionic Mobility In Nacl, Nabr And Nai, Suman Kumar Hukku

Doctoral Dissertations

"Ac Hall effect measurements of the net ionic mobility, µ_H, in "pure" NaCl, NaBr and Nal were made over their intrinsic temperature ranges extending up to about 250⁰ C below the crystal melting point. A well characterized detector system was employed which provided a mobility sensitivity ≥ 2 x 10^-4 cm² · V^-1 · s^-1. Complementary electrical conductivity, σ, data was also collected. The charge transport was assumed to be due to Schottky defects and both cation and anion contributions were considered. The high temperature anion contribution to mobility was clearly demonstrated by …

Scavenging Of Atmospheric Particles By Water Drops, Ming-Shian Wu

Doctoral Dissertations

"In the first paper, the mechanisms of particle capture and coalescence of aerosols by a moving water drop in the atmosphere are studied using the boundary-layer flow approximation. The particle trajectory is computed by solving the equations of motion of the particle both outside and inside the boundary layer using the Adams-Moulton method. The grazing trajectory is found by a trial-and-error technique. The collision and collection efficiencies of scavenging due to particle inertia and to the velocity gradient of the flow field are then computed for water drops ranging from 0.1 to 1.0 mm in radius and for particle of …

The Effect And Compensation Of Time-Base Perturbations In Analog Recording Systems, Clifford D. Skouby

Doctoral Dissertations

"The mean square error between recorded and reproduced signals is used as an error measure to determine the effects of time-base perturbations on an analog singal. The mean square error caused by time-base perturbations is shown to be proportional to the product of the square of the signal bandwidth and the time-base error variance for the case of low pass signal. When the signal is band pass, there is shown to be an additional error term which is proportional to the square of the signal center frequency and the time-base error variance.

Calculations are also carried out to determine the …

Trend Surface Analysis As An Aid In Exploration For Mississippi Valley Type Ore Deposits, John Siegfried Trapp

Doctoral Dissertations

"The conditions necessary for emplacement of Mississippi Valley-type mineral deposits can be expressed using mathematical symbols as a function of the pre-depositional topography of the host formation and post-depositional structure. These conditions can be observed and analyzed in the Missouri region from residual maps of trend surface analysis of the Precambrian surface. In areas where the topography prior to deposition of the ore bearing horizon has been strongly altered by the deposition of the basal Paleozoic formation the Lamotte Formation residual maps from trend surface analysis of the top of the Lamotte better illustrate these conditions. The Lamotte Formation in …

Early Extracellular Events In Sp82g Dna Infection Of Competent Bacillus Subtilis, Gordon Lee Williams

Doctoral Dissertations

No abstract provided.

Characterization Of Several Thymine-Requiring Mutants Of Escherichia Coliy Mel, James Howard Maryanski

Doctoral Dissertations

No abstract provided.

Electromagnetic Cavity Resonances In Rotating Systems, Barbaros Celikkol

Doctoral Dissertations

No abstract provided.

Patterns Of Conversational Interaction As Factors Of Attraction And Compliance Within Dyads, Kenneth Gavin Stuart

Doctoral Dissertations

No abstract provided.

General Exponential-Type Functions In Atomic Calculations, Robert H. Carrier

Doctoral Dissertations

No abstract provided.

Interactions Between The Short-Tailed Shrew, Blarina Brevicauda, And The Meadow Vole, Microtus Pennsylvanicus, Daniel Hugh Hubbard

Doctoral Dissertations

No abstract provided.

Chemical Studies On Toxins From Gymnodinium Breve And Aphanizomenon Flos-Aquae, Maktoob Alam

Doctoral Dissertations

No abstract provided.

Tryptophan Analog Effects And Nuclease Secretion In Staphylococcus Aureus, David F. Carpenter

Doctoral Dissertations

No abstract provided.

The Analysis Of Trace Organics In Fresh Water By Gas Chromatography - Mass Spectroscopy, Gary John Dean Anemaet

Doctoral Dissertations

No abstract provided.

Studies On The Quantitative Enumeration Of Viruses In Water, Frederick Carlton Pearson Iii.

Doctoral Dissertations

No abstract provided.

Observation Of Pulsed Gamma-Rays With Energies Greater Than 250 Kev From The Crab Nebula Pulsar Np 0532, Larry Eugene Orwig

Doctoral Dissertations

No abstract provided.