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Articles 871 - 900 of 2927
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Carbon Dioxide Measurement In Irish Blanket Peatlands: An Assessment Of Pool-Soil Flux Variability, Mariya Radomski, Alan Gilmer, Vivienne Byers, Eugene Mcgovern
Carbon Dioxide Measurement In Irish Blanket Peatlands: An Assessment Of Pool-Soil Flux Variability, Mariya Radomski, Alan Gilmer, Vivienne Byers, Eugene Mcgovern
Articles
Peatlands have been recognised as having a significant role in the mediation of atmospheric carbon dioxide (CO2) levels with direct implications for global climate change. Longitudinal in situ measurement systems for CO2 concentrations in blanket peatland ecosystems are difficult to implement where the nature of terrestrial–aquatic connectivity and hydrodynamics have a significant effect on the carbon cycle. The need for greater data on CO2 concentrations and flux monitoring in these settings has been well recognised. However, applying the most appropriate monitoring approach presents a special challenge. This paper sets out the development of a direct method for field based longitudinal …
Assessment Of Physicochemical Characteristics, Thermal Stability And Release Profile Of Ascorbic Acid Microcapsules Obtained By Complex Coacervation, Michele Cristina Rodrigues Da Cruz, João Luiz Andreotti Dagostin, Camila Augusto Perussello, Maria Lúcia Masson
Assessment Of Physicochemical Characteristics, Thermal Stability And Release Profile Of Ascorbic Acid Microcapsules Obtained By Complex Coacervation, Michele Cristina Rodrigues Da Cruz, João Luiz Andreotti Dagostin, Camila Augusto Perussello, Maria Lúcia Masson
Articles
The aim of this study was to determine the physicochemical characteristics, thermal stability and release profile of ascorbic acid (AA) microcapsules obtained by complex coacervation. Gelatin and gum arabic were used as wall materials in concentrations of 2.5, 5.0 and 7.5 g% (w/v). The coacervate microcapsules were freeze-dried and assessed for physicochemical characteristics, thermal behavior and stability during 60 days of storage. The release profile was evaluated at different pH values (1.1, 2.2, 5.4, 7.4, 9.6 and 12). The encapsulation efficiency ranged from 27.3 to 93.8%. The microcapsules of AA presented good characteristics for application in food matrices, such as …
Lutein And Zeaxanthin: The Possible Contribution, Mechanisms Of Action And Implications Of Modern Dietary Intake For Cognitive Development In Children. [Version 1; Peer Review: 2 Approved], Ekaterina Loskutova, Kajal Shah, Daniel Ian Flitcroft, Annalisa Setti, John Butler, Yvonne Nolan, Nabin Paudel, James Loughman
Lutein And Zeaxanthin: The Possible Contribution, Mechanisms Of Action And Implications Of Modern Dietary Intake For Cognitive Development In Children. [Version 1; Peer Review: 2 Approved], Ekaterina Loskutova, Kajal Shah, Daniel Ian Flitcroft, Annalisa Setti, John Butler, Yvonne Nolan, Nabin Paudel, James Loughman
Articles
No abstract provided.
Identification Of Surrogate Biomarkers For The Prediction Of Patients At Risk Of Low Macular Pigment In Type 2 Diabetes, Grainne Scanlon, Daniel Mccartney, John Butler, Ekaterina Loskutova, James Loughman
Identification Of Surrogate Biomarkers For The Prediction Of Patients At Risk Of Low Macular Pigment In Type 2 Diabetes, Grainne Scanlon, Daniel Mccartney, John Butler, Ekaterina Loskutova, James Loughman
Articles
Purpose: This cross-sectional study compared macular pigment (MP) levels among persons with Type 2 diabetes relative to healthy controls. Additionally, a range of behavioral, anthropometric, clinical and serum measures were explored as possible predictors of low MP optical density (MPOD) in diabetes.
Addressing Vision Impairment In Mozambique And The Africa Region, Stephen Thompson, Kovin Naidoo, Joel Bambamba, Vanessa Moodley, Diane Van Staden, Amanda Forde, Kajal Shah, Luigi Bilotto, James Loughman
Addressing Vision Impairment In Mozambique And The Africa Region, Stephen Thompson, Kovin Naidoo, Joel Bambamba, Vanessa Moodley, Diane Van Staden, Amanda Forde, Kajal Shah, Luigi Bilotto, James Loughman
Articles
The Mozambique Eyecare Project was an international partnership to implement and research eye health education in Mozambique and the Africa region. An optometry degree was developed at Universidade Lúrio, Mozambique. In addition, existing eye health workers were upskilled with training. Researchers from various disciplines evaluated the project and its potential for impact on eye health in the region. The body of evidence generated from the research provides useful lessons for development programmes in general, as well as specific lessons for delivering eye health education and service delivery models for low income settings.
Third-Order Optical Nonlinearity Properties Of Cdcl2-Modifed Ge–Sb–S Chalcogenide Glasses, Xiaosong Lu, Jianhui Li, Lu Yang, Runan Zhang, Yindong Zhang, Jing Ren, Aurelian Catalin Galca, Mihail Secu, Gerald Farrell, Pengfei Wang
Third-Order Optical Nonlinearity Properties Of Cdcl2-Modifed Ge–Sb–S Chalcogenide Glasses, Xiaosong Lu, Jianhui Li, Lu Yang, Runan Zhang, Yindong Zhang, Jing Ren, Aurelian Catalin Galca, Mihail Secu, Gerald Farrell, Pengfei Wang
Articles
We developed a new type of chalcohalide glasses with physicochemical and nonlinear optical properties that are tunable by composition. It is found that more than 60 mol.% CdCl2 heavy metal halide can be dissolved into the ternary Ge–Sb–S system and forming stable glasses. The visible-light transparency range is extended to shorter wavelengths with the addition of CdCl2, which is beneficial for the optical quality control and infra-red (IR) system alignment. The third-order optical nonlinearity (TONL) is studied using the femtosecond Z-scan method. The results show that both the nonlinear refractive index and two photon absorption co-efficient decrease with CdCl2. Benefiting …
All Fibre Q-Switched Thulium-Doped Fibre Laser Incorporating Thulium–Holmium Co-Doped Fibre As A Saturable Absorber, Shi Li, Elfed Lewis, Gerald Farrell, Ahmad Haziq Aiman Rosol, A.A. Latiff, Sulaiman Wadi Harun, Bingang Guo, Pengfei Wang
All Fibre Q-Switched Thulium-Doped Fibre Laser Incorporating Thulium–Holmium Co-Doped Fibre As A Saturable Absorber, Shi Li, Elfed Lewis, Gerald Farrell, Ahmad Haziq Aiman Rosol, A.A. Latiff, Sulaiman Wadi Harun, Bingang Guo, Pengfei Wang
Articles
A novel all fibre Q-switched Thulium-doped fibre laser (TDFL) is reported which includes a short length of a Thulium–Holmiumco-doped fibre (THDF) as a saturable absorber. A high repetition rate (27.26 kHz) coupled with a low pulse width (19.06μs) is obtained for single wavelength Q-switched pulse operation at an output wavelength of 1911.5 nm using a pump power of 200 mW. Increasing the pump power from 200 mW to 700 mW results in the repetition rate increasing from 27.26 kHz to 99.67 kHz and the pulse width decreasing from 19.06μs to 920 ns. The centre wavelength of the single Q-switched pulse …
Distribution Of Tm 3+ And Ni 2+ In Chalcogenide Glass Ceramics Containing Ga2s3 Nanocrystals: Influence On Photoluminescence Properties, Xiaosong Lu, Zhiqiang Lai, Jing Ren, Lukas Strizik, Tomas Wagner, Yanqiu Du, Gerald Farrell, Pengfei Wang
Distribution Of Tm 3+ And Ni 2+ In Chalcogenide Glass Ceramics Containing Ga2s3 Nanocrystals: Influence On Photoluminescence Properties, Xiaosong Lu, Zhiqiang Lai, Jing Ren, Lukas Strizik, Tomas Wagner, Yanqiu Du, Gerald Farrell, Pengfei Wang
Articles
The distribution of Tm3+ and Ni2+ ions is unambiguously exhibited in 80GeS2-20Ga2S3 chalcogenide glass ceramics (GCs) containing Ga2S3 nanocrystals (NCs) by using advanced analytical transmission electron microscopy. Distinctively different distribution patterns of Tm3+ and Ni2+ ions are observed in the GCs obtained by controlled crystallization. The distribution of the dopants imposes strong influence on their optical properties which are revealed by absorption and photoluminescence (PL) spectra. Detailed discussions are given of the mechanisms of the crystallization-induced PL enhancement and quenching of the Tm3+ mid-infrared and Ni2+ near-infrared emissions, respectively.
Self-Cleaning Hydrophobic Nanocoating On Glass: A Scalable Manufacturing Process, Surendra Maharjan, Kang-Shyang Liao, Alexander J. Wang, Killian Barton, Amrita Haldar, Nigel J. Alley, Hugh Byrne, Seamus A. Curran
Self-Cleaning Hydrophobic Nanocoating On Glass: A Scalable Manufacturing Process, Surendra Maharjan, Kang-Shyang Liao, Alexander J. Wang, Killian Barton, Amrita Haldar, Nigel J. Alley, Hugh Byrne, Seamus A. Curran
Articles
A method of forming a self-cleaning hydrophobic coating (SCHN) on glass substrates utilizing a scalable manufacturing process is described. The process initiates with roughening of planar glass surfaces using diamond micro-/nano-particle abrasives, which creates microscopic tortuous grooves. After cleaning the substrates, the roughened surface is vapor deposited with trichloro(1H,1H,2H,2H-perfluorooctyl)silane (TCPFOS) under enclosure with controlled humidity. TCPFOS chemically binds with the substrate via covalent linkage. Due to the greatly reduced surface tension between water and the self-cleaning surface, the water droplet slides down leaving no trail (sliding angle of 14° for 0.1 mL water droplet). Due to the reduced adhesion of …
Raman Spectroscopy As A Potential Tool For Label Free Therapeutic Drug Monitoring In Human Serum: The Case Of Busulfan And Methotrexate, Drishya Parachalil, Franck Bonnier, Deirdre Commerford, Igor Chourpa, Jennifer Mcintyre, Hugh Byrne
Raman Spectroscopy As A Potential Tool For Label Free Therapeutic Drug Monitoring In Human Serum: The Case Of Busulfan And Methotrexate, Drishya Parachalil, Franck Bonnier, Deirdre Commerford, Igor Chourpa, Jennifer Mcintyre, Hugh Byrne
Articles
A methodology is proposed, based on Raman spectroscopy coupled with multivariate analysis, to determine the Limit of Detection (LOD) and Limit of Quantification (LOQ) for therapeutic drug monitoring in human serum, using the examples of Busulfan, a cell cycle non-specific alkylating antineoplastic agent, and, Methotrexate, a chemotherapeutic agent and immune system suppressant. In this study, ultrafiltration is employed to fractionate spiked human pooled serum to efficiently recover the drug in the filtrate prior to performing Raman analysis. The drug concentration ranges were chosen to encompass the recommended therapeutic ranges and toxic levels in patients. Raman spectra were collected from the …
Raman Spectroscopic Analysis Of Saliva For The Diagnosis Of Oral Cancer: A Systematic Review, Genecy Calado, Isha Behl, Amuthachelvi Daniel, Hugh Byrne, Fiona Lyng
Raman Spectroscopic Analysis Of Saliva For The Diagnosis Of Oral Cancer: A Systematic Review, Genecy Calado, Isha Behl, Amuthachelvi Daniel, Hugh Byrne, Fiona Lyng
Articles
Abstract Oral squamous cell carcinoma (OSCC) is one of the most common malignancies worldwide, and new protocols for routine and early detection are required. Raman spectroscopy is an optical based method that can provide sensitive and non-invasive real time detailed information on the biochemical content of a sample like saliva, through the unique vibrations of its constituent molecules and this is sensitive to changes associated with disease. A comprehensive systematic review of the available scientific literature related to Raman spectroscopy of human saliva for diagnosis of OSCC was performed. The 785 nm laser line was most applied wavelength along with …
Principal Components Analysis Of Raman Spectral Data For Screening Of Hepatitis C Infection, A. Dita, H. Nawaz, T. Mahmood, M. Tahir, N. Rashid, Muhammad Mudassar, A.A.H. Alsaadi, Hugh Byrne
Principal Components Analysis Of Raman Spectral Data For Screening Of Hepatitis C Infection, A. Dita, H. Nawaz, T. Mahmood, M. Tahir, N. Rashid, Muhammad Mudassar, A.A.H. Alsaadi, Hugh Byrne
Articles
In the current study, Raman spectroscopy is employed for the identification of the biochemical changes taking place during the development of Hepatitis C. The Raman spectral data acquired from the human blood plasma samples of infected and healthy individuals is analysed by Principal Components Analysis and the Raman spectral markers of the Hepatitis C Virus (HCV) infection are identified. Spectral changes include those associated with nucleic acidsat720 cm−1, 1077 cm−1 1678 (CO stretching mode of dGTP of RNA), 1778 cm−1 (RNA), with proteins at 1641 cm−1(amide-I), 1721 cm−1(CC stretching of proteins) and lipids at 1738 cm−1(CO of ester group in …
On The Use Of Vibrational Spectroscopy And Scanning Electron Microscopy To Study Phenolic Extractability Of Cooperage Byproducts In Wine, Berta Baca‑Bocanegra, Julio Nogales‑Bueno, Brian Gorey, Francisco José Heredia, Hugh Byrne, José Miguel Hernández‑Hierro
On The Use Of Vibrational Spectroscopy And Scanning Electron Microscopy To Study Phenolic Extractability Of Cooperage Byproducts In Wine, Berta Baca‑Bocanegra, Julio Nogales‑Bueno, Brian Gorey, Francisco José Heredia, Hugh Byrne, José Miguel Hernández‑Hierro
Articles
Wood is an important source of phenolic compounds, which can be transferred to wine during aging process, improving its properties, from an organoleptic point of view. Therefore, understanding and optimizing the extractability of phenolic compounds from wood are crucial in the oenological field. The structural composition of oak wood samples has been evaluated using Raman and attenuated total reflectance Fourier transform infrared (ATR–FTIR) spectroscopies, and their main spectral features have been linked to phenolic compound extractabilities, as measured by classic chemical analyses. To support the analysis, microscopic images of the samples were also recorded using scanning electron microscopy (SEM). The …
Traversing States: A Reflection On Digital Technology And Simondon's Critique Of Hylomorphism, Michael O'Hara
Traversing States: A Reflection On Digital Technology And Simondon's Critique Of Hylomorphism, Michael O'Hara
Articles
In this article, I examine Simondon's concept of the technical object reflecting on its analogous relationship to digital technology. Intrinsic to such an analysis is Simondon's distinction between the abstract and concrete and his specific critique of the hylomorphic model. In a deeply rich example, Simondon, contra Aristotle, mobilises the process of mould-making as an exemplar of the modulated ensemble of forces that prefigure any formations of matter through form. I analyse Simondon's paradigmatic criticism while at the same time carving out the potential intersections that emerge through the kinaesthetic awareness of the body. By doing so I highlight the …
Nanostructured Materials For Food Applications: Spectroscopy, Microscopy And Physical Properties, Shubham Sharma, Swana Jaiswal, Brendan Duffy, Amit Jaiswal
Nanostructured Materials For Food Applications: Spectroscopy, Microscopy And Physical Properties, Shubham Sharma, Swana Jaiswal, Brendan Duffy, Amit Jaiswal
Articles
Nanotechnology deals with the matter of atomic or molecular scale. Other factors that define the character of a nanoparticle are its physical and chemical properties, such as surface area, surface charge, hydrophobicity of the surface, the thermal stability of the nanoparticle, and its antimicrobial activity. A nanoparticle is usually characterized by using microscopic and spectroscopic techniques. Microscopic techniques are used to characterize the size, shape, and location of the nanoparticle by producing an image of the individual nanoparticle. Several techniques, such as scanning electron microscopy (SEM), transmission electron microscopy/high resolution transmission electron microscopy (TEM/HRTEM), atomic force microscopy (AFM) and scanning …
On The Determination Of The Number Of Positive And Negative Polynomial Zeros And Their Isolation, Emil Prodanov
On The Determination Of The Number Of Positive And Negative Polynomial Zeros And Their Isolation, Emil Prodanov
Articles
A novel method with two variations is proposed with which the number of positive and negative zeros of a polynomial with real co-efficients and degree $n$ can be restricted with significantly better determinacy than that provided by the Descartes' rule of signs and also isolate quite successfully the zeros of the polynomial. The method relies on solving equations of degree smaller than that of the given polynomial. One can determine analytically the exact number of positive and negative zeros of a polynomial of degree up to and including five and also fully isolate the zeros of the polynomial analytically and …
Van Der Waals Universe With Adiabatic Matter Creation, Emil Prodanov, Rossen Ivanov
Van Der Waals Universe With Adiabatic Matter Creation, Emil Prodanov, Rossen Ivanov
Articles
A FRWL cosmological model with perfect fluid comprising of van der Waals gas and dust has been studied in the context of dynamical analysis of a three-component autonomous non-linear dynamical system for the particle number density $n$, the Hubble parameter $H$, and the temperature $T$. Perfect fluid isentropic particle creation at rate proportional to an integer power $\alpha$ of $H$ has been incorporated. The existence of a global first integral allows the determination of the temperature evolution law and hence the reduction of the dynamical system to a two-component one. Special attention is paid to the cases of $\alpha = …
Injective Tensor Products Of Tree Spaces, Milena Venkova, Christopher Boyd, Costas Poulios
Injective Tensor Products Of Tree Spaces, Milena Venkova, Christopher Boyd, Costas Poulios
Articles
We study tensor products on tree spaces; in particular, we give necessary and sufficient conditions for the n-fold injective tensor product of tree spaces to contain a copy of l_1.
Equatorial Wave–Current Interactions, Adrian Constantin, Rossen Ivanov
Equatorial Wave–Current Interactions, Adrian Constantin, Rossen Ivanov
Articles
We study the nonlinear equations of motion for equatorial wave–current interactions in the physically realistic setting of azimuthal two-dimensional inviscid flows with piecewise constant vorticity in a two-layer fluid with a flat bed and a free surface. We derive a Hamiltonian formulation for the nonlinear governing equations that is adequate for structure-preserving perturbations, at the linear and at the nonlinear level. Linear theory reveals some important features of the dynamics, highlighting differences between the short- and long-wave regimes. The fact that ocean energy is concentrated in the long-wave propagation modes motivates the pursuit of in-depth nonlinear analysis in the long-wave …
A Multilayer Exponential Random Graph Modelling Approach For Weighted Networks, Alberto Caimo, Isabella Gollini
A Multilayer Exponential Random Graph Modelling Approach For Weighted Networks, Alberto Caimo, Isabella Gollini
Articles
A new modelling approach for the analysis of weighted networks with ordinal/polytomous dyadic values is introduced. Specifically, it is proposed to model the weighted network connectivity structure using a hierarchical multilayer exponential random graph model (ERGM) generative process where each network layer represents a different ordinal dyadic category. The network layers are assumed to be generated by an ERGM process conditional on their closest lower network layers. A crucial advantage of the proposed method is the possibility of adopting the binary network statistics specification to describe both the between-layer and across-layer network processes and thus facilitating the interpretation of the …
Current Source Density Approaches Improve Spatial Resolution In Event Related Potential Analysis In People With Parkinson's Disease, Conor Fearon, John Butler, Saskia M. Waechter, Isabelle Killane, Richard B. Reilly, Timothy Lynch
Current Source Density Approaches Improve Spatial Resolution In Event Related Potential Analysis In People With Parkinson's Disease, Conor Fearon, John Butler, Saskia M. Waechter, Isabelle Killane, Richard B. Reilly, Timothy Lynch
Articles
No abstract provided.
On The Reidemeister Spectrum Of An Abelian Group, Brendan Goldsmith, Fatemeh Karimi, Noel White
On The Reidemeister Spectrum Of An Abelian Group, Brendan Goldsmith, Fatemeh Karimi, Noel White
Articles
The Reidemeister number of an automorphism ϕ of an Abelian group G is calculated by determining the cardinality of the quotient group G/(ϕ − 1G)(G), and the Reidemeister spectrum of G is precisely the set of Reidemeister numbers of the automorphisms of G. In this work we determine the full spectrum of several types of group, paying particular attention to groups of torsion-free rank 1 and to direct sums and products. We show how to make use of strong realization results for Abelian groups to exhibit many groups where the Reidemeister number is infinite for all automorphisms; such groups then …
Interpreting And Reporting Principal Component Analysis In Food Science Analysis And Beyond, D. Cozzolino, A. Power, J. Chapman
Interpreting And Reporting Principal Component Analysis In Food Science Analysis And Beyond, D. Cozzolino, A. Power, J. Chapman
Articles
Principal component analysis (PCA) is one of the most widely used data mining techniques in sciences and applied to a wide type of datasets (e.g. sensory, instrumental methods, chemical data). However, several questions and doubts on how to interpret and report the results are still asked every day from students and researchers. This brief communication is inspired in relation to those questions asked by colleagues and students. Please note that this article is a focus on the practical aspects, use and interpretation of the PCA to analyse multiple or varied data sets. In summary, the application of the PCA provides …
Ex-Post Service Contract Performance Management, Brian Forbes, Malcolm Brady
Ex-Post Service Contract Performance Management, Brian Forbes, Malcolm Brady
Articles
This paper highlights how contract incompleteness can threaten the performance of public procurement facilities management contracts during their implementation stages, based on a multiple case study comprising five public procurement services contracts. The paper takes a principle-agent view and with the unit of analysis being the contract itself. The paper shows that contract contingencies are almost inevitable and may stem from the written contract or from the participating organisations. Written and unwritten contract management mechanisms were used in practice to deal with contingencies as they arose in the services case studies examined. The paper found that written contracts do not …
Ionic Liquid Based Polymer Gel Electrolytes For Use With Germanium Thin Film Anodes In Lithium Ion Batteries, Louise M. Mcgrath, John Jones, Edwin Carey, James F. Rohan
Ionic Liquid Based Polymer Gel Electrolytes For Use With Germanium Thin Film Anodes In Lithium Ion Batteries, Louise M. Mcgrath, John Jones, Edwin Carey, James F. Rohan
Articles
Thermally stable, flexible polymer gel electrolytes with high ionic conductivity are prepared by mixing the ionic liquid 1‐butyl‐1‐methylpyrrolidinium bis(trifluoromethylsulfonyl)imide (C4mpyrTFSI), LiTFSI and poly(vinylidene difluoride‐co‐hexafluoropropylene (PVDF‐HFP). FT‐IR and Raman spectroscopy show that an amorphous film is obtained for high (60 %) C4mpyrTFSI contents. Thermogravimetric analysis (TGA) confirms that the polymer gels are stable below ∼300 °C in both nitrogen and air environments. Ionic conductivity of 1.9×10−3 S cm−2 at room temperature is achieved for the 60 % ionic liquid loaded gel. Germanium (Ge) anodes maintain a coulombic efficiency above 95 % after 90 cycles in …
Fluorescence Quenching-Based Mechanism For Determination Of Hypochlorite By Coumarin-Derived Sensors, Karolina Starzak, Arkadiusz Matwijczuk, Bernadette Creaven, Alicja Matwijczuk, Sławomir Wybraniec, Dariusz Karcz
Fluorescence Quenching-Based Mechanism For Determination Of Hypochlorite By Coumarin-Derived Sensors, Karolina Starzak, Arkadiusz Matwijczuk, Bernadette Creaven, Alicja Matwijczuk, Sławomir Wybraniec, Dariusz Karcz
Articles
A fluorescence quenching-based mechanism for the determination of hypochlorite was proposed based on spectroscopic and chromatographic studies on the hypochlorite-sensing potency of three structurally similar and highly fluorescent coumarins. The mode of action was found to rely upon a chlorination of the coumarin-based probes resulting from their reaction with sodium hypochlorite. Importantly, the formation of chlorinated derivatives was accompanied by a linear decrease in the fluorescence intensities of the probes tested. The results obtained suggest the applicability of a coumarin-dependent hypochlorite recognition mechanism for the detection of, as well as for quantitative determination of, hypochlorite species in vitro.
Spheroid-3d And Monolayer-2d Intestinal Electrochemical Biosensor For Toxicity/Viability Testing: Applications In Drug Screening, Food Safety, And Environmental Pollutant Analysis, Evangelia Flampouri, Shahzad Imar, Kieran O'Connell, Baljit Singh
Spheroid-3d And Monolayer-2d Intestinal Electrochemical Biosensor For Toxicity/Viability Testing: Applications In Drug Screening, Food Safety, And Environmental Pollutant Analysis, Evangelia Flampouri, Shahzad Imar, Kieran O'Connell, Baljit Singh
Articles
The rise of three-dimensional cell culture systems that provide in vivo-like environments for pharmaco-toxicological models has prompted the need for simple and robust viability assays suitable for complex cell architectural structures. This study addresses that challenge with the development of an in vitro enzyme based electrochemical sensor for viability/cytotoxicity assessment of two-dimensional (2D) monolayer and three-dimensional (3D) spheroid culture formats. The biosensor measures the cell viability/toxicity via electrochemical monitoring of the enzymatic activity of nonspecific esterases of viable cells, through the hydrolysis of 1-naphthyl acetate to 1-naphthol. The proposed sensor demonstrated strong correlation (r = 0.979) with viable …
Electrochemical Enzyme-Linked Immunosorbent Assay (E-Elisa) For Parasitic Nematode: Ostertagia Ostertagi (Brown Stomach Worm) Infections In Dairy Cattle, Baljit Singh, Evangelia Flampouri, Eithne Dempsey
Electrochemical Enzyme-Linked Immunosorbent Assay (E-Elisa) For Parasitic Nematode: Ostertagia Ostertagi (Brown Stomach Worm) Infections In Dairy Cattle, Baljit Singh, Evangelia Flampouri, Eithne Dempsey
Articles
A sensitive electrochemical immunoassay (e-ELISA) has been developed for the detection of the gastrointestinal parasitic nematode Ostertagia ostertagi (brown stomach worm) in infected and control serum samples. An antigen-indirect immunoassay format was employed to detect the presence of O. ostertagi antibodies, coupled with an anti-species monoclonal horseradish peroxidase (HRP) conjugate. ABTS (2,2'-azino-bis(3-ethylbenzothiazoline-6-sulphonic acid)) and TMB (3,3',5,5'-tetramethylbenzidine/hydrogen peroxide) were investigated as both chromogenic visualising reagents for optical ELISA and electroactive substrates for electrochemical ELISA in the HRP catalysed oxidation reaction. Coulometry was applied for the detection of O. ostertagi antibodies (via TMB electrochemistry) and compared with the commercial optical ELISA (ABTS …
Three Against Two: On The Difference Between Property And Contract And The Example Of Deposit Accounts In Bankruptcy, Jeanne L. Schroeder, David G. Carlson
Three Against Two: On The Difference Between Property And Contract And The Example Of Deposit Accounts In Bankruptcy, Jeanne L. Schroeder, David G. Carlson
Articles
In Citizen's Bank v. Strumpf (1995), Justice Scalia announced that deposit accounts are not "property". Five years later, the Uniform Commercial Code was amended to make deposit accounts collateral for the depositary bank maintaining the account, thereby crowding the field previously occupied by the common law right of setoff. Security interests attach to personal "property." Security interests attach to deposit accounts. Deposit accounts, by syllogistic logic, are property. Does this mean that the UCC has overruled the Supreme Court? We argue not. A deposit account is a mere contract in the two-person universe that contract law presupposes. A deposit account …
Double Deadbeat Plus Repetitive Control Scheme For Microgrid System, Sreedhar Madichetty, Malabika Basu, Sukumar Mishra, Josep M. Guerrero
Double Deadbeat Plus Repetitive Control Scheme For Microgrid System, Sreedhar Madichetty, Malabika Basu, Sukumar Mishra, Josep M. Guerrero
Articles
Parallel connection of converters is a convenient choice when system capacity is to be increased. Parallel-connected voltage source converters, especially neutral point clamped converters, are one of the best choices for its range. However, with the parallel connectivity, the converter possesses a circulating current in its legs, which consequently threatens the safe operation of the system. To alleviate this circulating current problem, in this paper, a double deadbeat (DD) plus repetitive control (RC) scheme is proposed. The RC scheme is employed to mitigate the circulating currents and the DD loop control scheme is employed to achieve a high operating bandwidth …