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Comprehensive Modernization Of Firearm Discharge Residue Analysis; Advanced Analytical Techniques, Complexing Agents, And Tandem Mass Spectrometry, Brittany Louise Stevens Jan 2017

Comprehensive Modernization Of Firearm Discharge Residue Analysis; Advanced Analytical Techniques, Complexing Agents, And Tandem Mass Spectrometry, Brittany Louise Stevens

Graduate Theses, Dissertations, and Problem Reports (ETD)

The use of firearm discharge residue (FDR) evidence has been on the decline as a result of instrumental and analytical limitations and the inability to evaluate and assign evidentiary value. To utilize FDR evidence to its fullest extent, detection methods exploiting modern advancements in instrumentation must be explored and developed. Research has been performed in an effort to modernize FDR analysis but to date nothing has been implemented or found widespread use in forensic laboratories. This research investigated three analytical techniques for the detection of FDR; (1) ion mobility spectrometry (IMS), (2) thermal desorption gas chromatography mass spectrometry (TD-GC/MS), and …

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Biopolitical Cyborgs In Post-1980 North American Critical Dystopias, Valerie Ann Surrett Jan 2017

Biopolitical Cyborgs In Post-1980 North American Critical Dystopias, Valerie Ann Surrett

Graduate Theses, Dissertations, and Problem Reports (ETD)

Stories of babies born from transplanted uteruses, fetuses created from three biological parents, a booming global surrogacy market, and embryonic gene selection have all made national headlines in the past two years. We live in an era of science fictional childbirths. Reproductive technologies that didn't exist a decade ago are now peddled to whomever can afford them, and science fiction has responded. Post-1980 speculative fiction confronts a potent convergence of various sociopolitical and reproductive trends, including the rise of neoliberal conservatism; the "test tube baby" boom; polarized reproductive rights debates; and Diamond v. Chakrabarty (1980), the Supreme Court decision granting …

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A Pedagogical Study Of Selected Piano Music Of Miguel Del Aguila, Sornsuang Tangsinmonkong Jan 2017

A Pedagogical Study Of Selected Piano Music Of Miguel Del Aguila, Sornsuang Tangsinmonkong

Graduate Theses, Dissertations, and Problem Reports (ETD)

Miguel del Aguila (b. 1957) is an Uruguayan American composer who was nominated three times for Grammy Awards. He considers himself a postmodernist composer. His music shows various stylistic traits and strong influence from Latin American folk dances.;This research project focuses on the pedagogical study of eight piano compositions of Miguel del Aguila: "Toccata", Op. 23 (1988) Piano Sonata No.2, Op. 29 (1988) Conga, Op. 39 (1993) "Vals Brutal", Op. 48 (1995) Piano Concerto, Op. 57 (1997) "Nocturne", Op. 62 (1998) "Music in a Bottle", Op. 67 (1999) "Half of Me", Op. 68 (2000).;This study includes a discussion of del …

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Characterization And Flight Test Of A Multi-Antenna Gnss, Multi-Sensor Attitude Determination Algorithm, Nathan Tehrani Jan 2017

Characterization And Flight Test Of A Multi-Antenna Gnss, Multi-Sensor Attitude Determination Algorithm, Nathan Tehrani

Graduate Theses, Dissertations, and Problem Reports (ETD)

A multi-antenna Global Navigation Satellite System (GNSS), multi-sensor attitude estimation algorithm is outlined, and its sensitivity to various error sources is assessed. The attitude estimation algorithm first estimates attitude using multiple GNSS antennas, and then fuses a host of other attitude estimation sensors including tri-axial magnetometers, Sun sensors, and inertial sensors. This work is motivated by the attitude determination needs of the Antarctic Impulse Transient Antenna (ANITA) experiment, a high-altitude balloon-suspended science platform. In order to assess performance trade-offs of various algorithm configurations, the attitude estimation performance of various approaches is tested using a simulation that is based on recorded …

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The Response Of Naturally Regenerating Hardwood Seedlings To Post-Harvest Weed Control And Fertilization, Kevin Andrew Tomlinson Jan 2017

The Response Of Naturally Regenerating Hardwood Seedlings To Post-Harvest Weed Control And Fertilization, Kevin Andrew Tomlinson

Graduate Theses, Dissertations, and Problem Reports (ETD)

Current models to predict post-harvest success rely upon pre-harvest regeneration assessments, which rarely occur. Furthermore, these models lack management recommendations to improve regeneration success of naturally regenerating desired hardwood species following overstory removal. Factorial combinations of weeding and fertilization were randomly assigned to individual naturally regenerating black cherry (Prunus serotina Ehrh.), chestnut oak (Quercus montana Willd.), white oak (Quercus alba L.), and red oak (Q. rubra L., Q. velutina Lam., and Q. coccinea Muenchh.) seedlings in the spring of 2015, three growing seasons post-harvest. Factorial ANOVA models with size at treatment application as a covariate were developed and showed species-specific …

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Disruptions In Operant Behavior Of Pigeons In Transitions Across Rich And Lean Schedules Of Reinforcement With And Without Advance Notice Of The Lean Schedule, Forrest J. Toegel Jan 2017

Disruptions In Operant Behavior Of Pigeons In Transitions Across Rich And Lean Schedules Of Reinforcement With And Without Advance Notice Of The Lean Schedule, Forrest J. Toegel

Graduate Theses, Dissertations, and Problem Reports (ETD)

"Advance notice" refers to procedures in which a stimulus is provided to signal the end of an ongoing activity and the nature of the upcoming activity. Applied research has considered whether advance notice will reduce the problem behavior that sometimes occurs during transitions. Interpretation of this research is complicated by procedural variations in the type of transitions arranged, the consequences of transition-related problem behavior, the method of providing advance notice, and the measurement of the effects of advance notice. The present experiment investigated effects of advance notice using an animal model of transition-related problem behavior. Key-pecking was maintained on a …

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A Study Of The Correlation Between Static And Dynamic Modulus Of Elasticity On Different Concrete Mixes, Logan Trifone Jan 2017

A Study Of The Correlation Between Static And Dynamic Modulus Of Elasticity On Different Concrete Mixes, Logan Trifone

Graduate Theses, Dissertations, and Problem Reports (ETD)

This study is to determine the relationship between the Static Modulus of Elasticity and the Dynamic Modulus of Elasticity in various concrete mixes. The Static Loading Test was used to measure the strains associated with applied stresses on cylindrical concrete specimens to determine the Static Modulus. An Ultrasonic Pulse Wave Velocity (UPV) technique was utilized to measure the travel time of pulse waves propagating through rectangular prism specimens. The travel times were used to compute the Dynamic Modulus of Elasticity. An Impact Hammer measuring device was also used to measure resonance frequencies of vibrations in rectangular prisms, which also correlate …

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The Effects Of A Six Week Lumbopelvic Control And Balance Training Program In High School Basketball Players, Margaret Long Jan 2017

The Effects Of A Six Week Lumbopelvic Control And Balance Training Program In High School Basketball Players, Margaret Long

Graduate Theses, Dissertations, and Problem Reports (ETD)

Context: Lumbopelvic control (LPC) and balance training programs are popular in the sport of basketball, but there is little research to indicate whether significant improvements in lumbopelvic control and balance are evident after completion of a training program. Objective: The objective of this study is to determine if conducting a six week lumbopelvic control and balance training program will lead to improvement in lumbopelvic control and balance in high school male basketball players. Design: This study will be a repeated measures design. Setting: High School in Western Pennsylvania. Patients and Other participants: This study includes 15 varsity and junior varsity …

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Study Of Parameter Estimation And Model Calibration Using Bayesian Analysis Of Noisy Data For A Virus Model, Alejandro Mejia Jan 2017

Study Of Parameter Estimation And Model Calibration Using Bayesian Analysis Of Noisy Data For A Virus Model, Alejandro Mejia

Graduate Theses, Dissertations, and Problem Reports (ETD)

Numerous engineering problems are concerned with the challenge of representing real life systems through mathematical equations: modeling. Properly generated mathematical models can accurately predict the behavior of natural processes. The key objective of model development is to correctly build a set of equations or expressions that can reproduce the results observed from experimental measurements. By following this methodology, sources of error and uncertainty will arise as most natural processes have random factors that make the results stochastic, and therefore can never be exactly reproduced. A model can try to best approximate the actual outcome, but many times assumptions or simplifications …

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Researching History And Performance Practice Regarding Improvisation And Ornamentation In Mozart's Keyboard Works, With Special Attention To Cadenzas, Josiane Merlino Jan 2017

Researching History And Performance Practice Regarding Improvisation And Ornamentation In Mozart's Keyboard Works, With Special Attention To Cadenzas, Josiane Merlino

Graduate Theses, Dissertations, and Problem Reports (ETD)

The purpose of this paper is to examine the history and background of several keyboard works by Wolfgang Amadeus Mozart (1756--1791) and to consider how that research influences interpretation and shapes performance practice, with special attention to the composition of stylistically appropriate and historically informed cadenzas.;First in the paper, I talk about some aspects of performance practice including tempo, pedaling, articulation, and differences between Mozart's piano and modern pianos. Next, I discuss the importance of theoretical analysis and researching biographical events in a composer's life to know historical context of a piece. Ultimately, opportunities that are not notated in the …

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Non-Equilibrium Green's Function Based Calculations Of Spin Voltage In Cobalt Based Spinel Oxides, Anveeksh Koneru Jan 2017

Non-Equilibrium Green's Function Based Calculations Of Spin Voltage In Cobalt Based Spinel Oxides, Anveeksh Koneru

Graduate Theses, Dissertations, and Problem Reports (ETD)

Tougher sanctions on fossil fuel emissions and greater energy demand around the globe is forcing us to rely more on renewable energy resources. Clean energy technologies like thermoelectric power generation provides one solution to ease our dependence on non-renewable energy resources. Thermoelectric materials have the capability of directly converting heat to electricity. However, the efficiency of thermoelectrics has been limited due to the inherent coupling of the electronic and thermal carriers. More recently, an avenue to decouple these interactions has been experimental demonstrated using temperature gradient induced spin currents. With this new discovery comes the need for new transport models …

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On Factors That Influence User Interactions With Social Media Spam: Empirical Exploration Based On A Survey And Experiment, Thomas J. Kyanko Jan 2017

On Factors That Influence User Interactions With Social Media Spam: Empirical Exploration Based On A Survey And Experiment, Thomas J. Kyanko

Graduate Theses, Dissertations, and Problem Reports (ETD)

This thesis explores various factors that influence whether or not users of social media platforms will interact with spam. The research is based on using survey and experimental approaches. The survey looked at several spam related behaviors: ability to identify spam, tendency to interact with spam, and tendency to report spam. In total 256 responses were analyzed, which were collected by an online survey system. Results of the survey show that education about spam did not correlate with changes in behavior, even when users reported that the education had an effect on them. Several other factors, commonly thought to be …

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Bobcat Population Ecology In West Virginia, Stephanie Michelle Landry Jan 2017

Bobcat Population Ecology In West Virginia, Stephanie Michelle Landry

Graduate Theses, Dissertations, and Problem Reports (ETD)

Bobcats (Lynx rufus) are a popular furbearer and game species throughout their range in North America, where they serve as a top predator in many of their ecosystems. However, bobcat populations across their range declined during the 1800s and early 1900s due to overharvest. Overharvest and habitat loss in Europe also affected the Iberian lynx ( L. pardinus), resulting in the listing of all Lynx spp. under the Convention on International Trade in Endangered Species in 1977. Bobcats were listed under Appendix II, which required that state management agencies monitor their bobcat populations for stability. Since their listing, bobcat populations …

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Investigation Of A Neural Network Approach In Modeling And Diagnostics Of An Engine-Out Nox Sensor, Zackery S. Layhew Jan 2017

Investigation Of A Neural Network Approach In Modeling And Diagnostics Of An Engine-Out Nox Sensor, Zackery S. Layhew

Graduate Theses, Dissertations, and Problem Reports (ETD)

The objective of this study was to develop a method for fault detection of an engine-out oxides of nitrogen (NOx) sensor. The aim of the developed method was not only to isolate a fault with the NOx sensor, but to also diagnose faults in other engine subsystems that may result in higher engine-out NOx production. The developed fault diagnostics are aimed at providing reliable, accurate determinations of sensor output, in-lieu of physical sensors.;The data for the development of numerical models in this study was derived from in-use emissions data of a 2014 Freightliner equipped with a 2013 Cummins ISX15 engine. …

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Microbial Quality And Pathogen Decontamination Strategies For Locally-Grown, Fresh Produce From West Virginia And Kentucky, Ka Wang Li Jan 2017

Microbial Quality And Pathogen Decontamination Strategies For Locally-Grown, Fresh Produce From West Virginia And Kentucky, Ka Wang Li

Graduate Theses, Dissertations, and Problem Reports (ETD)

This study aimed to evaluate the microbiological quality/safety of fresh produce from farmers' markets (FM) and assess the post-harvest washing practice with antimicrobials to inactivate Salmonella and Listeria monocytogenes on fresh produce. In study I, 212 produce samples were tested for the presence of Salmonella and Listeria spp. using modified FDA-BAM methods. Aerobic plate counts (APCs), total coliforms (TCCs), and yeast/molds were analyzed on petri-films. Among the 212 samples, the APCs, TCCs, and yeast/molds were 3.72-5.63, 3.67-5.47, and 3.07-4.13 log CFU/g, respectively, with spinach containing the highest (P<0.05) populations. Among all tested samples, Salmonella enterica spp. enterica was detected on 18.6% of spinach, 10.9% of tomatoes, 18.5% of peppers, and 56.3% of cantaloupes, which is much higher than previous reported. Only 3.78% of the samples were confirmed for Listeria spp., and 50% of them were identified as L. monocytogenes, based on multiplex PCR results. Due to the high percentage of pathogens detected on the farmers' marker produce, an evaluation of post-harvest produce washing with various antimicrobials was conducted in study II. Specifically, spinach, tomatoes, green peppers and cucumbers were inoculated with S. Typhimurium and Tennessee or L. monocytogenes and washed in tap water, vinegar water (10%), lactic acid (5%), a lactic and citric acid blend (2.5%), and sodium hypochlorite (200 ppm) for 30 sec or unwashed. Vinegar water (10%) showed better (P<0.05) reduction of S. Typhimurium and Tennessee on tomatoes and cucumbers, and L. monocytogenes on tomatoes and peppers than tap water. The three antimicrobials reached an additional reduction level of 0.9 to 2.7 (S. Typhimurium and Tennessee) and 0.2 to 1.4 log CFU/g ( L. monocytogenes) compared to tap water. Lactic acid caused the greatest (P<0.05) reduction of S. Typhimurium and Tennessee on spinach and green peppers, and sodium hypochlorite showed the great (P<0.05) reduction of L. monocytogenes on cucumbers. The results supplied important information for FM vendors to develop post-harvest protocols to control foodborne pathogens.

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A Photogrammetry Program For Physical Modeling Of Subsurface Subsidence Process, Yujia Lian Jan 2017

A Photogrammetry Program For Physical Modeling Of Subsurface Subsidence Process, Yujia Lian

Graduate Theses, Dissertations, and Problem Reports (ETD)

Safe and economic longwall coal extraction requires a good knowledge of overburden strata characteristics and understanding of overburden strata movement in response to the full extraction mining. Subsidence induced overburden movement will affect overlying mining, surface and subsurface water bodies, and methane emission and migration in the overburden strata. Therefore, an understanding of subsurface strata movement is essential for optimal layout of multiple seam mining, protecting water resources, and designing of gob hole patterns for longwall degasification.;Physical simulation experiments play an important role in mining engineering research by allowing visual observations of strata movement in the mining process. In recent …

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Student Interview And Preference Assessment As Functional Behavior Assessment Tools In Schools, Gabrielle Mesches Jan 2017

Student Interview And Preference Assessment As Functional Behavior Assessment Tools In Schools, Gabrielle Mesches

Graduate Theses, Dissertations, and Problem Reports (ETD)

Functional behavior assessments (FBA) identify the consequences that maintain challenging behavior. Much of the current literature suggests that functional analyses are the most effective component of an FBA. However, functional analyses are most commonly used with children with developmental and intellectual disabilities. For children with complex verbal repertoires, other types of assessment may identify consequences maintaining behavior that can be subsequently manipulated as part of a classroom-based intervention. In the current study, we compared a student-completed interview and preference assessment to the outcomes of a functional analysis, and used the outcomes of all three assessments to evaluate classroom-based interventions to …

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Three Essays On Monetary Policy, Income Inequality, And Capital Flows, John Meszaros Jan 2017

Three Essays On Monetary Policy, Income Inequality, And Capital Flows, John Meszaros

Graduate Theses, Dissertations, and Problem Reports (ETD)

This dissertation is a collection of essays centered on monetary policy and central bank institutions and how they affect capital flows and income inequality. The first chapter concerns household debt and income inequality, which are both effected by the interest rate environment. As such, the high leverage ratio of households outside the top end of the income distribution has led many economists to assert that household debt has been an important component of the increase in income inequality in the United States. Mason and Jayadev (2014) define 3 variables that may affect household debt: an effective interest rate measure, inflation, …

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The Assessment Of Fingerprint Quality For A More Effective Match Score In Minutiae-Based Matching Performers, Alyshia Meyers Jan 2017

The Assessment Of Fingerprint Quality For A More Effective Match Score In Minutiae-Based Matching Performers, Alyshia Meyers

Graduate Theses, Dissertations, and Problem Reports (ETD)

One of the most common types of evidence recovered from a crime scene are latent fingerprints, however these impressions are often of low quality. The quality of a latent fingerprint is described as the degree to which the ridge details can be observed. If the quality of the latent fingerprint is very clear, a minutiae-based matching algorithm with automatic extraction may detect and utilize the minutiae that are truly present in the fingerprint. However, if the impression is of poor quality, the minutiae-based matching algorithm's automatic extraction may detect fewer features and could completely miss features resulting in the return …

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On Some Parabolic Type Problems From Thin Film Theory And Chemical Reaction-Diffusion Networks, Fatma Naser Ali Mohamed Jan 2017

On Some Parabolic Type Problems From Thin Film Theory And Chemical Reaction-Diffusion Networks, Fatma Naser Ali Mohamed

Graduate Theses, Dissertations, and Problem Reports (ETD)

This dissertation considers some parabolic type problems from thin film theory and chemical reaction-diffusion networks. The dissertation consists of two parts:;In the first part, we study the evolution of a thin film of fluid modeled by the lubrication approximation for thin viscous films. We prove an existence of (dissipative) strong solutions for the Cauchy problem when the sub-diffusive exponent ranges between 3/8 and 2; then we show that these solutions tend to zero at rates matching the decay of the source-type self-similar solutions with zero contact angle. We introduce the weaker concept of dissipative mild solutions and we show that, …

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Examining Diabetes, Depression And Suicide In Middle-Aged And Older Adults, Kimberly Morton Jan 2017

Examining Diabetes, Depression And Suicide In Middle-Aged And Older Adults, Kimberly Morton

Graduate Theses, Dissertations, and Problem Reports (ETD)

Rates of suicide in the United States are highest in middle-aged and older adults compared to younger age groups. These rates are alarming and point to the need for suicide prevention research in middle-aged and older adult populations. Depression is the most well-established independent risk factor for death by suicide. Some health conditions are also associated with risk of suicide above and beyond depression. Diabetes is often co-morbid with depression (clinical and subclinical depression). However, research examining diabetes and risk of suicide is less clear. In the current study, the first aim was to examine diabetes, vision impairment and depressive …

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Inhibiting The Cannabinoid Catabolic Enzyme Magl To Potentiate The Anti-Arthritic Properties Of The Synthetic Glucocorticoid Dexamethasone, Sara R. Nass Jan 2017

Inhibiting The Cannabinoid Catabolic Enzyme Magl To Potentiate The Anti-Arthritic Properties Of The Synthetic Glucocorticoid Dexamethasone, Sara R. Nass

Graduate Theses, Dissertations, and Problem Reports (ETD)

Rheumatoid arthritis (RA, Table 1) is the most common type of inflammatory arthritis, and is characterized by swelling, inflammation, pain, and destruction of the synovial joints (i.e., knees, elbows, wrists, hips, and fingers). Glucocorticoid receptor agonists are a type of steroid hormone and are among the most common treatments for inflammatory arthritis because of their powerful anti-inflammatory effects. However, harmful side effects are associated with these glucocorticoids (GCs), including increasing patients' vulnerability to infections. Cannabinoids (i.e., cannabis-like signaling molecules) exert anti-inflammatory and analgesic effects with limited side effects compared to traditional immunosuppressants making them excellent targets for the development of …

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Deep Features Based Hierarchical Classification Scheme For Face Recognition In Heterogeneous Environments, Neeru Narang Jan 2017

Deep Features Based Hierarchical Classification Scheme For Face Recognition In Heterogeneous Environments, Neeru Narang

Graduate Theses, Dissertations, and Problem Reports (ETD)

This dissertation investigates the advantages and limitations of the heterogeneous problem of matching infrared long-range, night time face images against their visible counterparts. The contributions of the thesis are three-fold. First, a multifeature scenario dependent fusion scheme is developed, where Gabor Wavelets, Histogram of gradients (HOG) and Local binary patterns (LBP) feature descriptors are empirically selected. Next, a set of fusion score level schemes are developed and applied before face matching. The developed fusion scheme results in 54 percent point (pp) higher recognition performance than the baseline established using a commercial and a set of academic face matchers. Second, to …

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Narrow Representation? The Impact Of Implicitly And Explicitly Racial Issues On Opinion And Representation, Franchesca V. Nestor Jan 2017

Narrow Representation? The Impact Of Implicitly And Explicitly Racial Issues On Opinion And Representation, Franchesca V. Nestor

Graduate Theses, Dissertations, and Problem Reports (ETD)

My dissertation combines knowledge from the opinion, racial and ethnic politics, and representation literatures to examine Black and Latino opinion and representation on racially salient issues. I theorize that representation of Blacks and Latinos is a "narrow" representation, much more in line with Black and Latino opinion on issues that are explicitly, rather than implicitly, racial. To test this theory, I build upon the literature by considering intersectional identity and multiple methods of representation. In Chapter 2, I examine two questions: when do income and racial group differences occur on racially salient issues, and if splits occur between respondents of …

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Using A Species Distribution Model And Site-Specific Microclimatic Variables To Model Presence Of Spodic Soil Properties And Relative Occurrence Rate Of Picea Rubens (Red Spruce) To Inform Red Spruce Management, Adrienne Nottingham Jan 2017

Using A Species Distribution Model And Site-Specific Microclimatic Variables To Model Presence Of Spodic Soil Properties And Relative Occurrence Rate Of Picea Rubens (Red Spruce) To Inform Red Spruce Management, Adrienne Nottingham

Graduate Theses, Dissertations, and Problem Reports (ETD)

Red spruce restoration efforts in the central Appalachians are of interest to land managers because of the reduced current extent and the numerous ecosystem services provided by red spruce forests. These land managers require information regarding the best places to focus restoration efforts. Studies attempting to locate optimal locations for red spruce restoration have been conducted to in the central Appalachians, most of which utilize modeling. In particular, podzolization, a soil formation pathway present under conifer vegetation in the central Appalachians has been used to help select areas for red spruce restoration. The effectiveness of using recent podzolization (as evidenced …

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Chronic Illness And Physicians' Referrals To Psychologists: A Pilot Study, Nicole O'Barto-Trainer Jan 2017

Chronic Illness And Physicians' Referrals To Psychologists: A Pilot Study, Nicole O'Barto-Trainer

Graduate Theses, Dissertations, and Problem Reports (ETD)

The Chronic Care Model (CCM) is an evidenced based healthcare management system that encompasses a multidimensional approach to healthcare for the treatment of patients with chronic conditions. A component of this model is collaborative care. The tenets of the biopsychosocial model are central to collaborative care and evidenced-based health care interventions. These interventions provide integrated, patient-centered healthcare delivered by a multidisciplinary healthcare team. Recent research has indicated that psychologists can play a vital role on such teams. The purpose of this exploratory pilot study was to subject the Biopsychosocial Endorsement Questionnaire (BEQ) to preliminary statistical analysis and to pilot its …

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Syntheses Of Functionalized Cycloparaphenylenes, Furan-Containing Cycloparaphenylenes, And Related Thiophene-Containing Fused Carbon Nanohoop, Behzad Farajidizaji Jan 2017

Syntheses Of Functionalized Cycloparaphenylenes, Furan-Containing Cycloparaphenylenes, And Related Thiophene-Containing Fused Carbon Nanohoop, Behzad Farajidizaji

Graduate Theses, Dissertations, and Problem Reports (ETD)

Synthetic pathways for preparing furan-containing cycloparaphenylenes (CPPs) bearing 10, 12, and 15 aromatic units in the macrocyclic ring structures were developed. Several important steps used in these syntheses are the Suzuki--Miyaura cross-coupling reaction between the L-shaped building block and 2-furanylboronic ester the nickel-mediated homocoupling reaction to incorporate two and three 2,2'-bifuran-5,5'-diyl units into functionalized [6]- and [9]cycloparaphenylene (CPP) precursors. Oxidative aromatization of the precursors with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) under mild conditions led to the formation of fully aromatized furan-containing cycloparaphenylenes (CPPs).;The Diels--Alder reaction between the parent benzyne or 3,6-dimethoxybenzyne with furan-2,5-diyl units incorporated into functionalized [8]CPP macrocycle followed by reductive deoxygenation …

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Evaluating Treatment Integrity Failures During Timeout From Play, Apral P. Foreman Jan 2017

Evaluating Treatment Integrity Failures During Timeout From Play, Apral P. Foreman

Graduate Theses, Dissertations, and Problem Reports (ETD)

Timeout is an effective behavior-reduction strategy with considerable generality. There are several recommendations about how to implement timeout. However, little research has investigated how timeout is implemented under natural conditions, or how timeout-implementation errors impact its effectiveness. Thus, our study attempted to address two aims. The first aim was to observe how teachers implemented timeout with their students. To address this aim (Experiment 1), we completed naturalistic observations of teachers who were implementing timeout during play. We collected data on how frequently the teachers implemented timeout following problem behavior (omission integrity), and how frequently teachers implemented timeout following responses not …

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Information Centric Strategies For Scalable Data Transport In Cyber Physical Systems (Cpss), Ajay Krishna Teja Kavuri Jan 2017

Information Centric Strategies For Scalable Data Transport In Cyber Physical Systems (Cpss), Ajay Krishna Teja Kavuri

Graduate Theses, Dissertations, and Problem Reports (ETD)

Cyber-Physical Systems (CPSs) represent the next generation of computing that is ubiquitous, wireless and intelligent. These networked sens- ing systems are at the intersection of sensing, communication, control, and computing [16]. Such systems will have applications in numerous elds such as vehicular systems and transportation, medical and health care systems, smart homes and buildings, etc. The proliferation of such sensing systems will trigger an exponential increase in the computational devices that exchange data over existing network infrastructure.;Transporting data at scale in such systems is a challenge [21] mainly due to the underlying network infrastructure which is still resource con- strained …

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Revolutionary Pedagogy: A Historical Perspective On Improvising In Beethoven, Julia Kinderknecht Jan 2017

Revolutionary Pedagogy: A Historical Perspective On Improvising In Beethoven, Julia Kinderknecht

Graduate Theses, Dissertations, and Problem Reports (ETD)

This dissertation will investigate the historical significance and modern application of Beethoven's improvisations in performance, first by observing what we know through primary sources and eye-witness accounts, then by considering the reasons for the absence of improvisation in modern performance practice and the steps that could be taken towards reincorporating classical improvisation into modern pedagogy, and finally by offering historically-based improvisation exercises and written-out examples of improvisations in Beethoven's works to benefit modern pianists.

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