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Comparison Of Proton Transfers In (S2h5)+ And (O2h5)+, L. Bigham, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

The energetics and electronic rearrangements associated with proton transfer between S atoms in (H₂S–H–SH₂)⁺ are calculated using ab initio molecular orbital methods and compared with similar data in the first‐row analog (H₂O–H–OH₂)⁺. The full potential energy surface of (S₂H₅)⁺, calculated as a function of the H‐bond length as well as the position of the proton, contains two equivalent minima separated by a small energy barrier, whereas the surface of (O₂H₅)⁺ contains a single minimum corresponding to a symmetric …

Contribution Of Dispersion To The Properties Of H2s‐‐Hf And H2s‐‐Hcl, M. M. Szczesniak, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

Ab initio calculations are carried out using a doubly polarized basis set. Dispersion, evaluated by second‐order Møller–Plesset perturbation theory (MP2), is found to have a profound influence on the stabilities and structures of the H‐bonded complexes. The contribution of dispersion to the H‐bond energies of H₂S‐‐HF and H₂S‐‐HCl is 44% and 69%, respectively, placing this attractive term second in magnitude only to electrostatics. Reductions of the intermolecular distance of 0.17 and 0.34 Å result from inclusion of correlation effects. Nevertheless, the influence of dispersion upon the angular characteristics of the …

Influence Of Basis Set On The Calculated Properties Of (H3n–Hcl), Z. Latajka, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

The structure of (H₃N–HCl) is investigated by ab initio calculations using a number of different basis sets ranging from minimal to split valence. The effects of including a diffuse sp shell and d orbitals on Cl are considered as well. The geometries of the complex and the isolated subunits are fully optimized. Minimal basis sets (STO‐3G, STO‐6G, and MINI‐1) lead to an overestimate of the interaction between the subunits. Addition of d functions produces only a marginal improvement. The 3‐21G, 3‐21+G, MIDI‐1, and LP‐31G split‐valence sets erroneously predict an ion pair …

Final Design Report Of The Design Of A Climate Controlled Sleeping Chamber For Infants And Toddlers, Jennifer Stenger Stevens

Undergraduate Honors Capstone Projects

A climate controlled sleeping chamber, or air crib, for infants and toddlers is an alternative sleeping medium to the conventional crib. It is a chamber that is ventilated with air that is temperature and humidity controlled to provide an optimum sleeping environment for young children, ages 0 to 2 years. Its purpose is to enhance the psychological and physiological development of young children. Because it is easier to heat a small chamber than larger living quarters, the air crib also has economic advantages.

The design o climate controlled sleeping chamber must meet some minimum requirements. The system must provide an …

Development Of Optimal Sustained Yield Groundwater Withdrawal Strategies For The Boeuf‑Tensas Basin In Arkansas, Richard C. Peralta, Bithin Datta, Jamal Solaimanian, Paul J. Killian, Amin Yazdanian

Civil and Environmental Engineering Faculty Publications

No abstract provided.

Optimal Regional Potentiometric Surface Design: Least Cost Water Supply/Sustained Groundwater Yield, Richard C. Peralta, Paul J. Killian

Civil and Environmental Engineering Faculty Publications

A distributed parameter groundwater management model utilizing quadratic programming to develop an optimal regional steady-state potentiometric surface and its sustained groundwater withdrawal strategy is presented. It minimizes the regional cost of attempting to satisfy the water needs of each finite-difference cell (a) from groundwater and diverted surface water or (b) from groundwater and reduction of water needs achieved by reducing production acreages. Groundwater elevations, withdrawal and recharge are constrained, satisfying legal and hydrologic constraints. The technique is applicable for assuring a regional sustained yield of groundwater in a conjunctive water management setting. It represents the first application of optimization in …

Preliminary Identification, Analysis, And Classification Of Odor-Causing Mechanisms Influenced By Decreasing Salinity Of The Great Salt Lake, C. Earl Israelsen, Darwin L. Sorensen, Alberta J. Seierstad, Charlotte Brennard

Reports

Introduction: The rising level of the Great Salt Lake has received a great deal of attention because of the resulting physical damage to adjoining properties, threatened distruption of major transportation facilities, and environmental damage to feeding and resting areas for migratory waterfowl. Another problem of growing concern is that some zones of the lake are producing odors that are objectionable to nearby populated areas. These odors are most offensive during the warm summer months and appear to be increasing with the rising levels and decreasing salinity of the lake water. This report presents the approach taken and the findings of …

Cataloging Medieval And Renaissance Manuscripts: A Review Article, Richard W. Clement

Library Faculty & Staff Publications

Until recently it could have been argued with much justification that the cataloging of medieval and Renaissance manuscripts in the United States began and ended with Seymour De Ricci's Census of Medieval and Renaissance Manuscripts in the United States and Canada (New York: H. W. Wilson, 1935-40) and Supplement (New York: Bibliographical Society of America, 1962). Of course, many excellent catalogs were produced before the Census and have been produced since (although most are of a specialized nature), yet the Census and its Supplement must be regarded as the one great landmark in cataloging in this country. It was the …

Multiple Shooting, Monique St-Maurice

All Graduate Plan B and other Reports, Spring 1920 to Spring 2023

The purpose of this report was to study the Multiple Shooting method, a numerical method to solve boundary value ordinary differential equation. A FORTRAN program was written to solve the specific problem.

y'' = -y, y(0) = 0, y(π/2) = 1

on a microcomputer, using the microsoft FORTRAN compiler and the 8087 coprocessor.

X-Ray Microanalysis In Cryosections Of Natively Frozen Paramecium Caudatum With Regard To Ion Distribution In Ciliates, M. Schmitz, R. Meyer, K. Zierold

Scanning Electron Microscopy

Cells of Paramecium caudatum were shock-frozen without pretreatment for cryoultramicrotomy and freeze-dried for subsequent X-ray microanalysis. Na, Mg, P, S, Cl, K, and Ca were detected in different amounts in several subcellular compartments. In particular, calcium was localized below the cell surface (pellicle). Trichocysts were found to contain significant amounts of Na in their base but not in the tip. Na, Mg, P, S, Cl, K, Ca were found in electron dense deposits within the lumen of the contractile vacuole. A small K concentration was found in the cytoplasm and in the mitochondria. X-ray microanalysis of the element distribution in …

Scanning Electron Microscopy In Retinal Research, Bessie Borwein

Scanning Electron Microscopy

The literature on scanning electron microscopy (SEM) pertaining to the retina has been surveyed and described.

The first two papers on SEM and retina appeared in 1969. Most of the earlier studies concentrated on descriptions [by SEM alone, or with light microscopy (LM) and transmission electron microscopy (TEM)] of the appearance of various retinae and retinal cells [fish, newt, primates, rodents and rabbits, bullfrog]; or embryology of the chick retina. Two papers dealt with retinal disease. In all there were 25 papers in SEM/retinal research before and in 1974. Since 1975 there have been 111 papers which have used SEM …

A Rapid Technique For Counting Cracks In Rocks, W. B. Durham, J. M. Beiriger, H. C. Weed

Scanning Electron Microscopy

Using a scanning electron microscope (SEM) and an image analyzer, we have developed a technique for counting and measuring cracks in rocks which is more efficient than traditional techniques in which an operator performs all image analysis functions. The key aspect of the technique is that black-on-white tracings of fresh cracks, which can be made rather rapidly by an operator, are measured and digitized by an image analyzer. The most time-consuming step in the process has now become the generation of SEM micrographs and pertinent chemical (mineralogical) information, not the quantification of crack structure. The technique has been applied to …

Surface Roughness Contribution To The Auger Electron Emission, D. Wehbi, C. Roques-Carmes

Scanning Electron Microscopy

Scanning Auger Microscopy (SAM) experiments have shown that z height and θ slope relative to the analysed spot are parameters that contribute to the measured Auger intensity I(z, θ). For greater analysed areas specific to Auger Electron Spectroscopy (AES), the knowledge of height and slope statistical distributions P(z) and P(θ) is required. These functions have been determined by means of profilometric data. The spatial resolution of the used tactile profilometer is similar to that which characterizes AES. A mathematical relationship I { P(z), P(θ) } has been set up for Si samples whose roughness is well defined. On the other …

An Integrated Gis/Remote Sensing Data Base In North Cache Soil Conservation District, Utah: A Pilot Project For The Utah Department Of Agricultures Rims (Resource Inventory And Monitoring System), Douglas J. Wheeler, Merrill K. Ridd, John A. Merola

All U.S. Government Documents (Utah Regional Depository)

The RIMS program is designed "To provide SCD (Soil Conservation District) supervisory with adequate data about agriculture and related natural resources of their district and to use this data for district responsibilities" (Utah Department of Agriculture 1984). The department's guidelines for RIMS go on to describe SCD responsibilities for short and long-term conservation inputs into various state resource plans, giving direction to Agriculture Resource Development Loan fund programs, and giving direction to SCD programs. The guidelines emphasize the established institutional role of the SCD as a local body to deal with local resource issues in the context of a regional …

Assessment Of Landsat For Rangeland Mapping, Rush Valley, Utah, United States, National Aeronautics And Space Administration

Range Management

The objective of this investigation is to assess the feasibility of using Landsat MSS (multispectral scanner) data to identify and map cover types for rangeland, and to determine comparative condition of the ecotypes. A supporting objective is to assess the utility of various forms of aerial photography in the process.

If rangeland can be efficiently mapped with Landsat data, as supported by appropriate aerial photography and field data, then uniform standards of cover classification and condition may be applied across the rangelands of the state. Further, a foundation may be established for long-term monitoring of range trend, using the same …

High Recovery Desalting Of Brackish Water By Electrodialysis: Field Tests At Yuma Desalting Test Facility & At La Verkin Springs, United States Department Of The Interior, Bureau Of Reclamation

Water

An ED (electrodialysis pilot plant achieved high desalting recoveries of nearly 95 percent at the YDTF (Yuma Desalting Test Facility, Arizona) and 92 percent at LVS (La Verkin Springs, Utah) during over 4000 hours of operation. Brine TDS (total dissolved solids) concentrations of nearly 100 000 g/m³ were obtained at LVS, which is a greater brine concentration than is possible using RO (reverse osmosis). The LVS required ED energy (while producing a product TDS concentration of about 1000 g/m³) is estimated to be about one-third the energy requirements of a commercially available distillation brine concentrator. Lowering product …

The Economic Impact Of The Apple Maggot And Western Cherry Fruit Fly On Utah's Fruit Industry, Larry K. Bond, T. F. Glover, Clive D. Jorgensen, Anthony H. Hatch

Economic Research Institute Study Papers

Until just recently, the apple maggot (Rhagoletis pomonella) has not been a serious pest in Utah fruit crops. It was first discovered in 1967, but was remote from existing orchards. The first recorded findings in Utah orchards did not occur until 1983 while the Utah Department of Agriculture was conducting survey studies of the western cherry fruit fly (Rhagoletis indifferens).

Utah Science Vol. 45 No. 4, Winter 1984

Utah Science

97 PHOSPHORUS NEEDS OF BEEF CATTLE J. W. Call, J. E. Butcher, J. L. Shupe, A. E. Olson, and J. T. Blake Levels of phosphorus, suggested for normal growth and reproduction, are outlined. Symptoms and lesions of phosphorus deficiency in beef cattle are discussed.

100 FAT CATTLE D. Bailey and B. W. Brorsen The price differences by month and year between Utah and other regional markets for fat cattle were charted and analyzed to help the producer to make effective marketing decisions.

104 THE MALNUTRITION/DIARRHEA CONNECTION R. W. Sidwell, B. B. Barnett, and A. W. Mahoney Using pregnant and newborn …

Twenty-Five Years Of Bonjour, Alfred N. Smith

Faculty Honor Lectures

While considering topics appropriate for this lecture, I became encouraged by the thought that my quarter of a century of experience in foreign language teaching would surely suggest some interesting possibilities. Up until this moment, I had never consciously counted my years of service, and frankly when I realized that I had spent two and one-half decades in front of the blackboard teaching French as a second language mainly to Anglo adults, I began to feel within the rumblings of a need to mark this anniversary in some significant way. Several days later in an amusing conversation with a friend, …

Sputtered Thermal Ion Mass Spectrometry As A New Quantitative Method For In-Depth Analysis, G. Blaise

Scanning Electron Microscopy

The Sputtered Thermal Ion Mass Spectrometry method (STIMS) consists of collecting a part of the matter sputtered from a solid by ion bombardment into a heated cell where it is reduced into atoms. A thermal ionization process or an electron impact process taking place in the cell yields ions which are extracted and mass analyzed. The composition of the solid is determined from ion intensities after calibration of ionization coefficients. It has been demonstrated that the method has an absolute quantitative character. Applications to elemental quantitative analysis (identification of new compounds in diffusion couples, dust particle analysis) and in-depth analysis …

Wave-Length Dispersive Microprobe Analysis Of Coated Samples Of Bulk Tissues, C. Ward Kischer, Thomas M. Teska

Scanning Electron Microscopy

Hypertrophic scars contain highly pleomorphic cells, including many from the erythrocytic series which have been extravasated. The conventional visual mode of SEM cannot distinguish the cell types with certainty except in the case of typical biconcave disc-shaped erythrocytes. Microprobe elemental analysis might be used to differentiate one type from another on the basis of iron and possibly phosphorus (for nucleated cells). Using coated specimens (gold or gold-palladium) precludes simultaneous visual mode SEM with EDX because of energy line interference with phosphorus and other elements. However, wave-length dispersive analysis offers minimal or no interference, and a coated specimen offers the use …

Progress In Element Analysis On A High-Voltage Electron Microscope, W. F. Tivol, D. Barnard, T. Guha

Scanning Electron Microscopy

X-Ray microprobe (XMA) and electron energy-loss (EELS) spectrometers have been installed on the high-voltage electron microscope (HVEM). The probe size has been measured and background reduction is in progress for XMA and EELS as are improvements in electron optics for EELS and sensitivity measurements.

XMA is currently useful for qualitative analysis and has been used by several investigators from our laboratory and outside laboratories. However, EELS background levels are still too high for meaningful results to be obtained. Standards suitable for biological specimens are being measured, and a library for quantitative analysis is being compiled.

Oxidation Of Aluminum Studied By Ion Scattering Spectroscopy (I.S.S) In A Scanning Auger Microscope, M. Gautier, J. P. Duraud, J. P. Vigouroux, C. Le Gressus, R. Shimizu

Scanning Electron Microscopy

The set up of an ion gun, producing a focused beam in the analysis chamber of a Scanning Auger Microscope permits ion scattering experiments: surface studies performed by electron spectroscopies can then be enlarged by Ion Scattering Spectroscopy (I.S.S.) to get additional information.

I.S.S. appears to be very sensitive to the cleanliness of the surface: comparison between Electron Energy Loss Spectroscopy (E.E.L.S.) and I.S.S. studies on clean samples show that I.S.S. can still detect oxygen even when it is not detectable by E.E.L.S.

Preliminary results on oxidation of Al (111) and Al (100) give oxidation curves in good agreement with …

Cross-Sectional Analysis Of Silicon Metal Oxide Semiconductor Devices Using The Scanning Electron Microscope, Daniel S. Koellen, David I. Saxon, Kenneth E. Wendel

Scanning Electron Microscopy

A technique has been developed which enables one to cross-section specific devices or features for examination with the scanning electron microscope (SEM). This method is used for investigation of all facets of microelectronic circuit manufacture from research and development to failure analysis of the finished product.

Selective etching is used to provide contrast to each processed layer. Etch type and sequence, used for delineation, are important to understand since they may add artifacts to the cross-section, leading to erroneous analysis conclusions. The etchant and etch conditions used will be dictated by the information needed from a particular sample.

Etching systems …

Digital Processing Of Electron Energy Loss Spectra And Images, R. D. Leapman, K. E. Gorlen, C. R. Swyt

Scanning Electron Microscopy

Processing in electron energy loss spectroscopy involves both data acquisition and analysis. The interface of an analytical electron microscope to a laboratory computer with a satellite microcomputer dedicated to data acquisition results in a system with a high degree of flexibility. In spectrum acquisition, channels may be selected around specific core edges, or dwell times may be varied continuously as a function of energy loss to reduce the dynamic range of the signal. Data transfer to the host computer allows further analysis such as the removal of plural scattering by spectral deconvolution. Elemental maps and line-scans can be recorded with …

Alterations Of The Intracellular Water And Ion Concentrations In Brain And Liver Cells During Aging As Revealed By Energy Dispersive X-Ray Microanalysis Of Bulk Specimens, Gy. Lustyik, I. Zs.-Nagy

Scanning Electron Microscopy

Age dependence of the intracellular concentrations of monovalent ions (Na+, K+ and Cl-) was examined in 1, 11 and 25-month-old rat brain and liver cells by using energy dispersive X-ray microanalysis. The in vivo concentrations of Na+, K+ and Cl- ions were calculated from two different measurements: The elemental concentrations were measured in freeze-dried tissue pieces, and the intracellular water content was determined by means of a recently developed X-ray microanalytic method, using frozen-hydrated and fractured bulk specimens as well as subsequent freeze-drying.

All the single monovalent ion concentrations and consequently, also the total monovalent ion content showed statistically significant …

Intracellular Localization Of Heavy Metals In Yeast By X-Ray Microanalysis, Ljerka Kunst, Godfried M. Roomans

Scanning Electron Microscopy

The intracellular localization of heavy metals in yeast cells was studied by means of energy-dispersive X-ray microanalysis. The yeast, Saccharomyces cerevisiae, was pretreated with phosphate and then loaded with different metal ions, by suspending the cells in salt solutions (Ni, Zn, Cd, Pb, Al and Cr). For the analysis, the cells were embedded in gelatin, rapidly frozen, and thin cryosections were cut on a dry knife.

A considerable uptake of divalent cations by the yeast cells was found to occur. The cations were bound to the polyphosphate granules localized in or close to the cell vacuoles. Immediately after phosphate …

Study By Scanning Electron Microscopy And Electron Spectroscopy Of The Cascade Of Electron Multiplication In An Insulator Submitted To An Electric Field, J. P. Vigouroux, J. P. Duraud, C. Le Gressus, G. Petite, P. Agostini, C. Boiziau

Scanning Electron Microscopy

An original method for revealing the dielectric heterogeneities on an insulating surface has been developed on creation of an electron multiplication cascade inside the insulator placed in an electric field. The steps of the physical process are: (i) excitation of electrons into the conduction band, (ii) electric field acceleration of the conduction electrons, (iii) ionization of the valence levels, (iv) creation of many more new defects in the vicinity of dielectric heterogeneities, (v) charge localization on defects and appearance of a local residual potential. The potential map is observable by scanning electron microscopy after propagation of the ionizing cascade, but …

String Induced Space Compactification, P. G. Freund, P. Oh, James Thomas Wheeler

All Physics Faculty Publications

Motivated by the possibility of a finite theory of gravity provided by superstrings in ten space-time dimensions, we analyze the problem of space compactification in the context of string dynamics. Such an analysis is hampered by conceptual and technical problems, stemming from the existence of the quantum string's own graviton mode on the one hand, and from Witten's observation of anomalies in a not specially chosen curves space-time on the other hand. Still, in the context of a classical local field presentation of string theory à la Nambu and Hosotani, supplemented by gravitational and Kalb-Ramond interactions, we are able to …

High Accuracy And Automatic Measurement Of The Pattern Linewidth On Very Large Scale Integrated Circuits, H. Yamaji, M. Miyoshi, M. Kano, K. Okumura

Scanning Electron Microscopy

High accuracy measurement of pattern linewidth is particularly important in Very Large Scale Integrated Circuits (VLSI) manufacturing.

The measurement of pattern linewidth has been done by optical methods. However, the optical methods have several problems: as the measured value depends on slope angle at pattern edge, thickness and optical property of film and also substrate, there exists a large difference in size (0.3 μm) between the defined edge and the true edge in case of photoresist linewidth measurements. Especially, the optical methods have severe problems to measure bottom of pattern edge and are unsuitable to measure pattern linewidth in VLSI's …