Digital Commons Network^™

Tuning The Reactivity Of Nanoenergetic Gas Generators Based On Bismuth And Iodine Oxidizers, Mkhitar A. Hobosyan, Karen S. Martirosyan

Physics & Astronomy Faculty Publications

There is a growing interest on novel energetic materials called Nanoenergetic Gas- Generators (NGGs) which are potential alternatives to traditional energetic materials including pyrotechnics, propellants, primers and solid rocket fuels. NGGs are formulations that utilize metal powders as a fuel and oxides or hydroxides as oxidizers that can rapidly release large amount of heat and gaseous products to generate shock waves. The heat and pressure discharge, impact sensitivity, long term stability and other critical properties depend on the particle size and shape, as well as assembling procedure and intermixing degree between the components. The extremely high energy density and the …

The Near-Peer Mathematical Mentoring Cycle: Studying The Impact Of Outreach On High School Students’ Attitudes Toward Mathematics, Aaron T. Wilson, Sergey Grigorian

School of Mathematical & Statistical Sciences Faculty Publications

College students may be seen as near-peers to high school students and high school students are often able to see themselves in the college students who are but one step ahead. This nearness in maturity and educational level may place college students in a particularly powerful position when it comes to reaching out to high school students to promote higher education in math and science. In this study college students gave dynamic mathematics outreach presentations, MathShows, to minority and low-income high school students in a mid-sized public school district on the U.S. border with Mexico. The study investigated the impacts …

Kinetic Pathways Of Topology Simplification By Type-Ii Topoisomerases In Knotted Supercoiled Dna, Riccardo Ziraldo, Andreas Hanke, Stephen D. Levene

Physics & Astronomy Faculty Publications

The topological state of covalently closed, double-stranded DNA is defined by the knot type $K$ and the linking-number difference $\\Delta Lk$ relative to unknotted relaxed DNA. DNA topoisomerases are essential enzymes that control the topology of DNA in all cells. In particular, type-II topoisomerases change both $K$ and $\\Delta Lk$ by a duplex-strand-passage mechanism and have been shown to simplify the topology of DNA to levels below thermal equilibrium at the expense of ATP hydrolysis. It remains a key question how small enzymes are able to preferentially select strand passages that result in topology simplification in much larger DNA molecules. …

On The Regularity Radius Of Delone Sets In R3, Nikolay Dolbilin, Alexey Garber, Undine Leopold, Egon Schulte

School of Mathematical & Statistical Sciences Faculty Publications

We complete the proof of the upper bound ρ^3≤10R for the regularity radius of Delone sets in three-dimensional Euclidean space. Namely, summing up the results obtained earlier, and adding the missing cases, we show that if all 10R-clusters of a Delone set X with parameters (r,R) are equivalent, then X is a regular system.

Blocks In The Category Of Finite-Dimensional Representations Of Principal W-Algebra For Q(2), Elena Poletaeva

School of Mathematical & Statistical Sciences Faculty Publications

We describe the blocks in the category of finite-dimensional representations of the principal finite W-algebra for the Lie superalgebra Q(2).

Tests Of General Relativity With Gw170817, B. P. Abbott, R. Abbott, Teviet Creighton, Mario C. Diaz, Soma Mukherjee, Volker Quetschke, Malik Rakhmanov, K. E. Ramirez, Robert Stone, D. Tuyenbayev, W. H. Wang

Physics & Astronomy Faculty Publications

The recent discovery by Advanced LIGOand AdvancedVirgo of a gravitational wave signal from a binary neutron star inspiral has enabled tests of general relativity (GR) with this new type of source. This source, for the first time, permits tests of strong-field dynamics of compact binaries in the presence of matter. In this Letter, we place constraints on the dipole radiation and possible deviations from GR in the post-Newtonian coefficients that govern the inspiral regime. Bounds on modified dispersion of gravitational waves are obtained; in combination with information from the observed electromagnetic counterpart we can also constrain effects due to large …

Search For Transient Gravitational-Wave Signals Associated With Magnetar Bursts During Advanced Ligo’S Second Observing Run, B. P. Abbott, R. Abbott, Teviet Creighton, Mario C. Diaz, Soma Mukherjee, Volker Quetschke, K. E. Ramirez, Malik Rakhmanov, Satzhan Sitmukhambetov, Robert Stone

Physics & Astronomy Faculty Publications

We present the results of a search for short- and intermediate-duration gravitational-wave signals from four magnetar bursts in Advanced LIGO’s second observing run. We find no evidence of a signal and set upper bounds on the root sum squared of the total dimensionless strain (hrss) from incoming intermediate-duration gravitational waves ranging from 1.1 × 10−22 at 150 Hz to 4.4 × 10−22 at 1550 Hz at 50% detection efficiency. From the known distance to the magnetar SGR 1806–20 (8.7 kpc), we can place upper bounds on the isotropic gravitational-wave energy of 3.4 × 10^-44 erg at 150 Hz assuming optimal …

Search For Gravitational Waves From A Long-Lived Remnant Of The Binary Neutron Star Merger Gw170817, B. P. Abbott, B. Abbott, Teviet Creighton, Mario C. Diaz, Volker Quetschke, Malik Rakhmanov, K. E. Ramirez, Robert Stone, D. Tuyenbayev, W. H. Wang

Physics & Astronomy Faculty Publications

One unanswered question about the binary neutron star coalescence GW170817 is the nature of its post-merger remnant. A previous search for post-merger gravitational waves targeted high-frequency signals from a possible neutron star remnant with a maximum signal duration of 500 s. Here, we revisit the neutron star remnant scenario and focus on longer signal durations, up until the end of the second Advanced LIGO-Virgo observing run, which was 8.5 days after the coalescence of GW170817. The main physical scenario for this emission is the power-law spindown of a massive magnetar-like remnant. We use four independent search algorithms with varying degrees …

All-Sky Search For Long-Duration Gravitational-Wave Transients In The Second Advanced Ligo Observing Run, B. P. Abbott, R. Abbott, Teviet Creighton, Mario C. Diaz, Soma Mukherjee, Malik Rakhmanov, K. E. Ramirez, Satzhan Sitmukhambetov, Robert Stone, D. Tuyenbayev, W. H. Wang, A. K. Zadrozny

Physics & Astronomy Faculty Publications

We present the results of a search for long-duration gravitational-wave transients in the data from the Advanced LIGO second observation run; we search for gravitational-wave transients of 2–500 s duration in the 24–2048 Hz frequency band with minimal assumptions about signal properties such as waveform morphologies, polarization, sky location or time of occurrence. Signal families covered by these search algorithms include fallback accretion onto neutron stars, broadband chirps from innermost stable circular orbit waves around rotating black holes, eccentric inspiral-merger-ringdown compact binary coalescence waveforms, and other models. The second observation run totals about 118.3 days of coincident data between November …

Search For Subsolar-Mass Ultracompact Binaries In Advanced Ligo's First Observing Run, B. P. Abbott, Teviet Creighton, Mario C. Diaz, Soma Mukherjee, Volker Quetschke, Malik Rakhmanov, Karla E. Ramirez, Robert Stone, Darkhan Tuyenbayev, Wenhui Wang

Physics & Astronomy Faculty Publications

We present the first Advanced LIGO and Advanced Virgo search for ultracompact binary systems with component masses between 0.2 M-1.0 M using data taken between September 12, 2015 and January 19, 2016. We find no viable gravitational wave candidates. Our null result constrains the coalescence rate of monochromatic (delta function) distributions of nonspinning (0.2 M, 0.2 M) ultracompact binaries to be less than 1.0×106 Gpc-3 yr-1 and the coalescence rate of a similar distribution of (1.0 M, 1.0 M) ultracompact binaries to be less than 1.9×104 Gpc-3 yr-1 (at 90% confidence). Neither black holes nor neutron stars are expected to …

Photocatalytic Degradation Of Simazine Using Zno/Go Composites, Kenneth Ray Flores

Theses and Dissertations

The photocatalytic degradation of simazine (SIM) by Zinc oxide/graphene oxide (ZnO/GO) composites, under visible light irradiation, was investigated to determine various reaction parameters, of initial pH, ZnO loading on GO, and catalyst mass. A pH of 2 was determined to be the optimal reaction pH for all ZnO/GO catalysts. A loading mass of 40mg for the 20 & 30mmol composites; whereas a 10mg mass was determined to be most effective for the 10mmol composite. The reaction followed second order kinetics for the degradation process, the reaction dependence was determined to be on the concentration of SIM in solution. All ZnO/GO …

Contact Numbers For Packing Of Spherical Particles, Eduardo Alejandro Ramirez Martinez

Theses and Dissertations

This thesis covers packings of spherical particles. The main object of this investigation is the contact number of a packing. New bounds for contact numbers of certain families of sphere packings in dimension 3 are obtained as the outcome of this research.

Measuring Connective Capacity Throughout The Gulf Of Mexico Fishery Management Network, Anthony Rocha Lima

Theses and Dissertations

The Gulf of Mexico provides substantial resources along its 1,680-mile coastline, spanning 5 U.S. states and providing millions of pounds of seafood and hundreds of millions in revenue annually. Continued success of the fishery relies on the ability of a large, complex, multiagency network to find the best solutions to balance the needs of humans, as well as ensure long-term sustainability. Organizations with varying objectives require effective communication when addressing intricate ecosystem-based management topics such as endangered species and regional economies.

To better understand the connectivity within the Gulf fishery management network, an IRB reviewed survey was dispersed to the …

Generalized &Thetas;-Parameter Peakon Solutions For A Cubic Camassa-Holm Model, Michael Rippe

Theses and Dissertations

In this paper we outline a method for obtaining generalized peakon solutions for a cubic Camassa-Holm model originally introduced by Fokas (1995) and recently shown to have a Lax pair representation and bi-Hamiltonian structure by Qiao et al (2012). By considering an amended signum function—denoted sgn &thetas;(x)—where sgn(0) = &thetas; for a constant &thetas;, we explore new generalized peakon solutions for this model. In this context, all previous peakon solutions are of the case &thetas; = 0. Further, we aim to analyze the algebraic quadratic equation resulting from a substitution of the single-peakon ansatz equipped with our amended …

The Mathematical Aspects Of Theoretical Physics, Hassan Kesserwani

Theses and Dissertations

The aim of this thesis is to outline the mathematical machinery of general relativity, quantum gravity, cosmology and an introduction to string theory under one body of work. We will flesh out tensor algebra and the formalism of differential geometry. After deriving the Einstein field equation, we will outline its traditional applications. We then linearize the field equation by a perturbation method and describe the mathematics of gravitational waves and their spherical harmonic analysis. We then transition into the derivation of the Schwarzschild metric and the Kruskal coordinate transformation, in order to set the stage for quantum gravity. This sets …

Use Of The Wilshire Equations To Correlate And Extrapolate Creep Data Of Inconel 617 And Nimonic 105, Vito Cedro Iii, Christian Garcia, Mark Render

Mechanical Engineering Faculty Publications

Advanced power plant alloys must endure high temperatures and pressures for durations at which creep data are often not available, necessitating the extrapolation of creep life. A recently developed creep life extrapolation method is the Wilshire equations, with which multiple approaches can be used to increase the goodness of fit of available experimental data and improve the confidence level of calculating long-term creep strength at times well beyond the available experimental data. In this article, the Wilshire equation is used to extrapolate the creep life of Inconel 617 and Nimonic 105 to 100,000 h. The use of (a) different methods …

Impacts Of Habitat Attributes And Community Gardens On Urban Bird Communities, Samuel Glenn Ortiz

Theses and Dissertations

The Rio Grande Valley of Southern Texas is a major agricultural region yet has some of the highest hunger rates in the USA. Urbanization and agriculture affect biodiversity, which is well studied, but little is known about how agriculture affects biodiversity in urban areas. We investigated how different urban attributes, including those related to urban farming, impact bird communities in Brownsville and Harlingen, TX, and compared sites that have community gardens to those that do not. To study three key urban habitat characteristics, we identified sites that exhibited all possible combinations of these factors, quantified land cover classes related to …

Longitudinal And Temporal Comparison Of Beach Sand On The Rio Grande Delta System, Samantha B. Moore

Theses and Dissertations

The Rio Grande is the 5th longest river in North America and defines a significant extent of the United States-Mexico border. It extends for 2830 km from its headwaters in the Rocky Mountains of Colorado to the Gulf of Mexico. The Rio Grande is fed by streams from the Sangre de Cristo Mountains, the Rio Conchos, the Pecos River, runoff from the Sacramento Mountains area, Devils River, the Rio Salado, and the Rio San Juan. This study addresses how the composition of sand forming the Rio Grande river delta into the Gulf of Mexico at Boca Chica Beach is changed …

Radiative Heat Transfer Analysis Of Railroad Bearings For Wayside Thermal Detector Optimization, James Alexandro Aranda

Theses and Dissertations

Wayside hot-box detectors (HBDs) are devices that are currently used to evaluate the health of railcar components including bearings, axles, and brakes by monitoring their temperatures. While HBDs have been instrumental in reducing some train derailments in the past few decades, the number of non-verified bearing removals has increased significantly. In general, HBDs tend to underestimate bearing temperatures in both field service and in laboratory testing, which is not surprising considering the simple two-point calibration method that is used to calibrate these devices. Because of this, different calibrations were compared and analyzed including two-point, three-point, and multi-point calibrations. Analysis of …

Graduation As A Function Of Mobility, Attendance, Discipline, Math, English Language Arts/Reading, And Parental Educational Attainment Of The Cohort Group 2015 In One South Texas Urban School District In The Rio Grande Valley, Nancy Lopez Castillo

Theses and Dissertations

This study examined the trends and patterns across time over the cohort 2015 on dependent variable, graduation. Aggregated longitudinal data for independent variables, mobility, attendance, discipline, math achievement, reading achievement, and parental educational attainment was collected for 98 students from 2010 to 2018. The independent variables of mobility, attendance, discipline, math achievement, reading achievement, and parental educational attainment were examined to determine whether or not high school completion is dependent on these measures.

The freshmen cohort 2015 in one south Texas urban school district in the Rio Grande Valley was the focus of the study. Exploratory and confirmatory analysis statistical/data …

Green Synthesis/Biosynthesis Of Silver Nanoparticles By Using Orange Peel Extract, Leela Joshi

Theses and Dissertations

Joshi, Leela, Green Synthesis/Biosynthesis of Silver Nanoparticles by Using Orange Peel Extract. Master of Science (MS), December, 2018, 40 pages, 23 figures, references, 36 titles. In this work, we report synthesis of silver nanoparticles (AgNPs) with an average size of ~6 nm. The aqueous solution of Ag+ ions is reduced using an aqueous extract from orange peel (Citrus Sinensis) at varying pHs. Reduction of Ag+ ions in solution was monitored using UV-visible absorption spectroscopy, and the corresponding surface plasmon resonance of AgNPs at 435 nm. The solution changed color from yellow to reddish-brown upon bioreduction of silver nitrate in orange …

Three Dimensional Carbon Nanotube Yarn Based Perovskite Solar Cells, Istiak Hussain

Theses and Dissertations

Perovskite solar cells (PSC) have emerged as a promising photovoltaic technology in lab scale with a short time of research due to their high power conversion efficiency, simple device fabrication, all solid-state structure and the possibility to ingrate the traditional device into fiber format. In this work, a three-dimensional (3D) perovskite solar cell is demonstrated using functionalized carbon nanotube yarn (CNT) as both cathode and anode. TiO2 and 2,2,7,-7-tetrakis(N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (Spiro-OMeTAD) are used as the electron transporting and hole transporting material respectively. The TiO2 oxide layer is deposited on the top of the twisted carbon nanotube yarn and annealed with TiCl4 …

Identities For Partitions Of N With Parts From A Finite Set, Acadia Larsen

Theses and Dissertations

We show for a prime power number of parts m that the first differences of partitions into at most m parts can be expressed as a non-negative linear combination of partitions into at most m – 1 parts. To show this relationship, we combine a quasipolynomial construction of p(n,m) with a new partition identity for a finite number of parts. We prove these results by providing combinatorial interpretations of the quasipolynomial of p(n,m) and the new partition identity. We extend these results by establishing conditions for when partitions of n with parts coming from …

Blow-Up Solutions Of Wave Map Equations With Periodic In Time Speed Of Propagation, Nathalie M. Luna-Rivera

Theses and Dissertations

We study the initial value problem for the wave map equation with time-dependent speed of propagation. In particular, for arbitrary, small, and smooth initial data we construct blow-up solutions of the wave map with coefficients that are periodic in time. For the proof we use Lyapunov-Floquet theory and Borg’s theorem.

The Relationship Between The Distance Of An External Focus Of Attention And Lower Body Power In Rugby Athletes, Donald Pump

Theses and Dissertations

The purpose of this investigation is to examine the relationship between the distance effect on power output during countermovement jumps in Rugby athletes. Hypothesis Testing was conducted utilizing a Repeated Measures Analysis of Variance (RM ANOVA) at a .05 significance level. A Pairwise comparison was conducted to determine if one variable had a greater amount of quantitative property. Statistical insignificance was determined after all data was analyzed Results were unable to show a positive relationship between the distance of an external focus of attention and lower body power output in rugby athletes.

Asymptotic Quantization For A Condensation System Associated With A Discrete Distribution, Shankar Parajulee

Theses and Dissertations

Let P := (1/3)P ○ S1–1 + (1/3)P ○ S2–1 + (1/3)v be a condensation measure on R, where S1(x) = (1/5)x, S2(x) = (1/5)x + 4/5 for all x ∈ R , and v is a discrete distribution on R with the support of v equals C := {(2/5), (3/5)}. For such a measure P we determine the optimal sets of n–means and the nth quantization errors for all n ≥ 2. In addition, we show that the quantization dimension of the condensation measure P exists and equals …

Effects On Altering Reaction Conditions In Suzuki Cross Coupling Reactions Using The Microwave, Javier Alejandro Perez

Theses and Dissertations

Over the last few decades, Suzuki coupling has become a common process for the synthesis of intermediates in pharmaceutical and industrial applications. It is well known that palladium is an effective catalyst for the formation of cross-coupled products. Therefore, this catalyst was tested in a series of reactions. Also, it is believed that other catalyst with similar properties to palladium can work, for example cerium. Therefore, a cerium hydroxide catalyst was synthesized in lab and used as a potential catalyst for the Suzuki reaction. For this study, some bases were investigated (NaOH, Na2CO 3, K3PO4, NaNO3, NaHCO3, etc) for the …

Design, Synthesis And Microbiological Evaluation Of Novel Compounds As Potential Staphylococcus Aureus Phenylalanine Trna Synthetase Inhibitors, Samar S. Elbaramawi, Casey Hughes, Jennifer Richards, Arya Gupta, Samy M. Ibrahim, El Sayed M. Lashine, Mohamed E. El-Sadek, Alex J. O’Neill, Mandy Wootton, James M. Bullard

School of Integrative Biological & Chemical Sciences Faculty Publications

AS THE RESISTANCE of Staphylococcus aureus to antibiotics represents a major threat to global health, anti-infectives with novel mechanisms must be developed. Novel compounds were generated as potential phenylalanine tRNA synthetase (PheRS) inhibitors based on the published homology model of S. aureus PheRS to aid the design process using Molecular Operating Environment (MOE) software. PheRS was selected as it is structurally unique enzyme among the aminoacyl-tRNA synthetases (aaRS), it is considerably different from human cytosolic and human mitochondrial aaRS and it is essential and conserved across bacterial species. The designed compounds were synthesized according to different clear schemes. The compounds …

Chemical Treatment To Reduce Turbidity In Pumped Construction Site Water, James Jihoon Kang, Joshua W. Vetter, Richard A. Mclaughlin

School of Earth, Environmental, & Marine Sciences Faculty Publications

Many construction projects need to pump turbid water from borrow pits or other excavations into stilling basins or sediment filter bags prior to discharge. This study evaluated the effectiveness of these devices with polyacrylamide (PAM) injection to reduce effluent turbidity. Results from laboratory jar tests using two coastal plain sediments of North Carolina suggested that a cationic PAM was the most effective in reducing turbidity, followed by a nonionic PAM. Anionic PAM was effective in whole-soil jar tests but not when turbid supernatant was tested. A stilling basin was not effective in reducing the turbidity of the pumped water without …

The Role Of Teaching Presence On Academic Achievement In Fully Online Asynchronous And Hybrid Undergraduate Mathematics Courses, Shaghayegh Azadi Setayesh

Theses and Dissertations

This study was designed to investigate how mathematics student perceptions of teaching presence differ by course delivery mode and student achievement. Online learning has had a steady growth in higher education, and mathematics courses are also offered in fully online and hybrid modes, but the research on online mathematics learning and academic achievement is limited. In order to contribute to the body of research in this field, the focus of this study was on teaching presence and academic achievement in two delivery modes: fully online asynchronous, and hybrid.

The Community of Inquiry was the theoretical framework of this study, where …