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Portable Trace Gas Analysis With Multipass Cavity Raman Scattering, Charuka Muktha Arachchige

USF Tampa Graduate Theses and Dissertations

The continual increase in the production and utilization of chemicals across a growing range of industrial, environmental, and medical applications necessitates accurate and efficient measurement of molecular composition. Trace gas detection is particularly critical in industrialized settings, where the identification of colorless and odorless gases is essential for ensuring operational safety and regulatory compliance. Recent advances in optical instrumentation have positioned spontaneous Raman scattering as a promising analytical technique for trace gas analysis, with multipass cavity enhancement providing a cost-effective pathway to high detection sensitivity. However, existing implementations remain confined to laboratory-scale optical table setups, limiting their applicability in field …

Designing For Fitness And Resilience In Human Artificial Intelligence Systems, Thomas R. Gill

USF Tampa Graduate Theses and Dissertations

Over the last decade, new artificial intelligence models, frameworks, and applications have emerged that have radically changed the socio-technical landscape. These new technologies represent both great opportunities and great potential risks. Due to the recency of their emergence, there is little known about the longevity and long-term repercussions of artifacts powered by new artificial intelligence technology. In this dissertation, I evaluate A.I. and A.I.-based artifacts through the lens of the fitness-utility model, a tool developed by Gill and Hevner (2013) for the evaluation of an artifact's ability to survive and reproduce over long time horizons. In so doing, I also …

Preparing Preservice Teachers: Developing Skills For Working With Students With Disabilities In The Social Studies Classroom, Melissa Waugh

USF Tampa Graduate Theses and Dissertations

This study was aimed towards investigating the extant research, best practices, and teacher preparation standards related to working with students with disabilities in the social studies classroom. The study was guided using three research questions: Are students with disabilities’ learning needs reflected in the National Council for Social Studies National Standards for the Preparation of Social Studies Teachers?; How do preservice social studies teacher programs prepare their candidates for teaching students with disabilities as evidenced by Social Science Education methods course syllabi?; and, What might a college-level course aimed towards social studies teaching methods centering around students with disabilities’ learning …

Photoluminescent Studies Of Metal-Organic Frameworks For Small Molecule Sensing, Julia T. Dematteo

USF Tampa Graduate Theses and Dissertations

Metal–organic frameworks (MOFs) are highly tunable nanoporous materials with broad applications in gas separation, drug delivery, light harvesting, and chemical sensing. The incorporation of photoactive components into MOFs enables the development of optical sensors capable of detecting a wide range of analytes. Porphyrins and metalloporphyrins are particularly attractive for such applications due to their high molar absorptivity, strong emission quantum yields, and versatile interactions with chemical species.

In this work, two porphyrinic MOFs, PCN-222 and MOF1(Cd), are investigated. Both frameworks utilize tetrakis(4-carboxyphenyl)porphyrin (TCPP) as the organic linker, imparting optical functionality to the materials. Integration of TCPP into the framework induces …

Risk-Aware Deep Reinforcement Learning In Portfolio Optimization, Shimin Zhang

USF Tampa Graduate Theses and Dissertations

Portfolio optimization is important in investment, with the purpose of maximizing profit whilemanaging risk. The traditional portfolio optimization method, Modern Portfolio Theory, is based on the assumption that returns are normally distributed, which is always violated in practical financial market settings. In addition, traditional approaches to portfolio optimization are mostly designed as static optimizations and fail to account for the nonlinearity and non-stationarity of contemporary financial markets. Recent developments in deep reinforcement learning have attracted considerable attention for treating portfolio optimization as a sequential decision-making process. Traditional portfolio optimization methods usually evaluate risk based on the variance of the returns. …

Van Der Waals Interactions Through The Lens Of 2d Materials With Emphasis On Many-Body Effects, Thi Xuan Diem Dang

USF Tampa Graduate Theses and Dissertations

This dissertation addresses the long-standing challenge of accurately and efficiently modeling long-range electron correlations, with a particular focus on van der Waals (vdW) interactions. These interactions play an essential role in predicting the structure, stability, and functionality of molecular systems and condensed matter materials. Although Density Functional Theory (DFT) has become a robust cornerstone of computational materials science, traditional formulations of the theory frequently fail to capture dispersive interactions, leading to significant errors in determining interlayer distances, binding energies, and stacking configurations. These limitations become particularly pronounced in layered materials and vdW heterostructures (HSTs), where weak long-range correlations are sensitive …

A Portable Device To Elicit Sensory Trick And Monitor Forearm Muscle Activity In Pianists With Musician’S Dystonia, Josef Franczak

USF Tampa Graduate Theses and Dissertations

Musician’s Dystonia (MD) is a condition that can be acquired in professional musicians,causing involuntary contractions and the loss of fine motor control. The most common pharmaceutical treatment, botulinum toxin injections, has been shown to have side effects of muscle weakness and atrophy. The sensory trick, shown to temporarily relieve symptoms of dystonia, has potential to be used as an alternative or alongside current therapies, allowing patients with MD to return to playing music professionally. To systematically deploy the sensory trick and monitor forearm muscle activity, the first prototype of the Wearable Sensorimotor Integrator (wSMI) has been developed.

The wSMI is …

Photophysical Behavior Of Ruthenium-Based Complexes: A Study Of Ligand Variation And Encapsulation In Metal-Organic Frameworks, Delaney S. Sellers

USF Tampa Graduate Theses and Dissertations

Ruthenium (II) polypyridyl complexes have emerged as a prominent class of compounds in inorganic photochemistry due to their structural robustness, reversible redox chemistry, and tunable excited-state dynamics. Central to the investigation of these systems is the ability to manipulate the triplet metal-to-ligand charge transfer state (3MLCT). In the context of photoactivated chemotherapy (PACT), the strategic deactivation of this MLCT state to populate a dissociative triplet ligand field state (3LF) can enable the controlled, light-triggered release of caged cytotoxic agents. This work focuses on understanding the caging mechanism of various ligands to optimize the eventual delivery of cytotoxic ligands. In this …

Development Of A Coupled Hydrological-Nitrogen Modeling Framework For Urban Stormwater Pond Analysis, Tione Grant

USF Tampa Graduate Theses and Dissertations

Urbanization impacts the hydrological and biogeochemical processes that regulate water quality in downstream ecosystems, leading to increased stormwater volume and nitrogen loads in receiving aquatic environments. Although stormwater ponds are designed as simple hydraulic storage basins, they function more like managed ecosystems within urban drainage systems, offering both hydraulic attenuation and passive nutrient treatment. However, nitrogen removal efficiency varies significantly and depends on interactions between hydrological and biogeochemical factors. This thesis details the development, calibration, validation, and sensitivity analysis of a coupled hydrological-nitrogen model framework for Aaran’s Pond, an urban stormwater pond in Hillsborough County, Florida.

A process-based water budget …

Trophic Structure Of Reef-Fish Assemblages In The Eastern Gulf Of Mexico Varies By Depth And Reef Type, Jessica L. Van Vaerenbergh

USF Tampa Graduate Theses and Dissertations

Globally, marine ecosystems are increasingly threatened by anthropogenic stressors, leading to reef degradation, changes in reef-fish assemblages, and altered trophic structure. In this study, I investigated reef-fish underwater visual survey data collected over a decade (2013-2023) from paired natural and artificial reefs in the eastern Gulf of Mexico. I applied the novel Normalized Reef Status Index (NRSI) to evaluate how biomass was distributed across the three trophic categories (i.e., Lower Trophic Position (LTP; 2.0-2.9), Central Trophic Position (CTP; 3.0-3.9), and Upper Trophic Position (UTP; ≥4.0). This index is a metric to assess the ecological status of reef systems by investigating …

Development And Evaluation Of The East Florida Coastal Ocean Model (Efcom), Orion B. Scharton-Witmer

USF Tampa Graduate Theses and Dissertations

Florida’s Atlantic coast has abundant resources in beaches, state parks, aquatic preserves, and wildlife refuges as well as densely populated coastal cities in low lying areas that are all subjected to natural disaster threats from the oceans. There is an urgent need for a high-resolution coastal ocean circulation model for this region. Based on the application of the Finite Volume Community Ocean Model (FVCOM), an East Florida Coastal Ocean Model (EFCOM) is developed, downscaling from the deep ocean, across the continental shelf, and into the estuaries. It employs an unstructured grid with horizontal resolution varying from 3 kilometers at the …

A System Dynamics Perspective Of User Adaptation: The Case Of Exoskeleton Technology, Enzo Novi Migliano

USF Tampa Graduate Theses and Dissertations

Technology implementation is a common occurrence in organizations to which workers must adapt. Although research on workers' technology acceptance is widely spread, research on the workers' technology adaptation process is less represented in the literature. The discrepancy in the literature permeates research on new technologies currently being implemented in organizations, such as occupational exoskeletons. As in other technologies, the variance research perspective dominates the literature on exoskeleton implementations. The current thesis aims to foster process research by formalizing the coping model of user adaptation (Beaudry & Pinsonneault, 2005) and exploring research questions regarding workers' adaptation to general technology and exoskeletons. …

Amending Planting Media With Typha-Derived Biochar For Sustainable Horticulture, Elissa Touma

USF Tampa Graduate Theses and Dissertations

Constructed wetlands are widely used to improve water quality by removing excess nutrients from wastewater and stormwater. Nutrients are stored within wetland vegetation, particularly in fast-growing plants such as Typha. Harvesting vegetation provides an opportunity to permanently remove these nutrients while generating biomass suitable for beneficial reuse. Converting harvested biomass into value-added products such as compost and biochar can support nutrient recovery and sustainable biomass management. In addition, increasing concerns regarding the environmental impacts of peat extraction have created interest in renewable alternatives for horticultural growing media. Therefore, the objective of this study was to evaluate the potential of harvested …

Exploring Culturally Responsive Leadership Practices Among Female Leaders In Title I Schools: Strategies For Enhancing Student Success, Tara K. Indar

USF Tampa Graduate Theses and Dissertations

The academic achievement gap between White students and diverse student populations remains a persistent and prominent disparity in schools across the United States. While this issue affects schools nationwide, it is particularly significant in Title I schools, where many students from diverse, lower-socioeconomic-status backgrounds are served. Although a substantial body of literature examines this gap and highlights the positive impact of culturally responsive leadership, there remains a limited understanding of which specific practices are most effective in improving students’ academic outcomes. This study explores the perceptions of female school leaders in Title I schools regarding the strategies they believe contribute …

Modeling And Mitigating Stale Hardcoded Secrets In Version Control History, Katarina Valentine Capalbo

USF Tampa Graduate Theses and Dissertations

Hardcoded secret vulnerabilities remain a growing and persistent problem that can be difficult to mitigate once exposed. While there has been significant research and advancements in identifying and preventing hardcoded secrets, less attention has been given to understanding the risks of leaving these secrets behind in version control history, as well as analyzing the sanitization of hardcoded secrets. These challenges present a growing gap between the risk and ability to mitigate and sanitize existing secret exposures. This thesis begins to address this gap by formalizing a threat model for hardcoded secrets that persist in Git version control history after the …

Morphodynamic Evolution Of Midnight Pass, West-Central Florida, Sydney C. Scott

USF Tampa Graduate Theses and Dissertations

This study takes advantage of a rare opportunity provided by the reopening of Midnight Pass due to two consecutive hurricanes in 2024, to examine the morphologic evolution of a newly reopened inlet and subsequent beach-inlet interactions. Historical aerial photos since the 1940s were collected and analyzed to understand the last closure of Midnight Pass, and to gain knowledge on the future of the newly reopened inlet. Time-series topography and bathymetry survey of the beach-inlet system were conducted bimonthly to quarterly for the first year and a half after the reopening, with the goals of quantifying the morphologic changes and understanding …

Quantitative Determination Of Nano Delivered Kras Sirna, Axel S. Deraspe

USF Tampa Graduate Theses and Dissertations

This study focuses on the development and validation of analytical methods for the detection of therapeutic KRAS-targeting siRNA in biological systems. Physicochemical characterization showed that p5RHH-formulated siRNA nanoparticles exhibit a controlled nanoscale size distribution, moderate polydispersity, and a negative zeta potential, suggesting colloidal stability and potential suitability for cellular uptake. Scanning electron microscopy confirmed a predominantly spherical morphology with a relatively uniform size distribution, consistent with dynamic light scattering measurements.

To enable accurate siRNA quantification, stem–loop reverse transcription (SL-RT) coupled with SYBR Green–based quantitative Polymerase Chain Reaction (qPCR) was optimized. Key parameters, including a primer concentration of 100 nM and …

Students In Motion: How Educators Enact Movement In Elementary Mathematics, Katherine E. Nash

USF Tampa Graduate Theses and Dissertations

This study used an exploratory sequential mixed-methods design to examine how elementary mathematics teachers report using physical activity in their instructional practice. The purpose of the study was to develop, provide evidence of validity, and implement a questionnaire to document the types of movement teachers use and when these practices occur in relation to mathematics instruction. In Phase 1, qualitative interviews were conducted with eight elementary mathematics teachers to identify common movement types and inform instrument development. The eight movement types that were identified are non-academic fine-motor, non-academic gross-motor, non-academic music-elicited, non-academic environmental, academic fine-motor, academic gross-motor, academic music-elicited, and …

Measures Of Linguistic Complexity And Vocabulary Diversity As Indicators Of Oral Language Production Growth Of 4th Grade Spanish-Speaking Els, Carla T. Zayas-Santiago

USF Tampa Graduate Theses and Dissertations

As fourth-grade students transition from learning to read to reading to learn, their ability to use language for academic purposes becomes increasingly important, particularly for Spanish-speaking English Learners (ELs). However, students often have limited opportunities to produce extended oral language during instruction. Students’ oral language production reflects both structural aspects of language use, captured through measures of linguistic complexity, and lexical aspects of language use, captured through measures of vocabulary diversity. Although prior studies have examined transcript-derived measures of oral language production, limited research has examined how these measures predict English proficiency, capture growth over time, and respond to different …

The Architecture Of Chemical Understanding: How Representation Selection, Ordering, And Feature Salience Shape Students' Conceptions In Chemistry, Isaiah Nelsen

USF Tampa Graduate Theses and Dissertations

Chemical representations play a central role in how students learn and reason aboutchemistry. While representations are routinely used in chemistry classrooms, students often struggle to extract relevant information, connect representations to underlying chemical principles, and apply this information to problem-solving. This dissertation investigates the role of representations in supporting students’ conceptual understanding and reasoning across general and organic chemistry through three qualitative studies.

The first study in this work explores how variation in chemical representation influences how students understand foundational chemistry principles. This study sought to characterize how second semester general chemistry students approach dipole–dipole interaction tasks with four distinct …

New Developments In Space-Filling Designs, Xiankui Yang

USF Tampa Graduate Theses and Dissertations

This dissertation presents three methodological advancements to improve the construction of space-filling designs for meeting different needs of computer experiments. Traditional space-filling designs focus on achieving uniform coverage in the input space, ensuring that design points are spread evenly throughout. However, in some scientific and engineering applications, varied density of design points may be desired for more efficient data collection when prior knowledge implies different emphases. In other cases, ensuring good coverage and/or spread of the response values allows better performance of fitted models in the next stage of applications. Many processes involve variation in response values. Therefore, incorporating variation …

Unquaint Pigs’ Stakeholder Perspectives On Wild Swine In Central Western Florida, Tyler Koerner

USF Tampa Graduate Theses and Dissertations

The Anthropocene presents important questions for how to address the continuous transferal of new species into new spaces and the cascading impacts of environmental transformations. Novel ecosystems present one such outline for conservation that acknowledges the modification of historic ecosystems and the social entanglements that arrive with new species. I argue that novel ecosystems can benefit from further anthropological integrations that aid in describing the entanglements of introduced species and the pursuit of best managerial outcomes. For wild swine in Florida, the adoption of a novel approach is especially relevant because of entanglements with historic and modern Floridian stakeholders and …

The Heterogeneous Response Of Astrocytes In Different Brain Regions Under Metabolic Stress, Pawan Kumar Thapaliya

USF Tampa Graduate Theses and Dissertations

Astrocytes play a central role in maintaining ionic homeostasis, neurotransmitter clearance, and brain en-ergy metabolism. Their excitability, reflected in activity-evoked intracellular sodium (Na+, [Na+]i) and calcium (Ca2+,[Ca+]i) dynamics, is increasingly recognized as a critical determinant of neuronal function and vulnerability, particularly under metabolic stress. Despite their importance, the mechanisms underlying astrocytic ionic signaling and its regional heterogeneity remain incompletely understood. In this thesis, I developed detailed computational and biophysical models to investigate astrocytic Na+ and Ca2+ dynamics, their bioenergetic consequences, and the roles of key ion transporters under physiological and metabolically stressed conditions, validating the models against experi- mental data. …

Riki&Dolphin: Real Time Data Transmission From The Bottom Of A Cave To A Website, Luca Tringali, Giacomo Canciani Dr., Tecla Tripari, Alexander Debenjak, Caterina Bearzotti

International Journal of Speleology

Coming from over 10 years of experience in cave monitoring in northeast Italy, Gruppo Speleologico Talpe del Carso, has designed Riki and Dolphin: customizable, low cost, and easy to assemble tools for getting real time data transmission from the bottom of a cave, even underwater, to a webserver. Their use has been tested to monitor air temperature inside the Abisso Bonetti Cave (Classical Karst, Italy), proving for the first time that a cave in Gorizian Karst can systematically be colder than the outdoor temperature even in winter, recording an internal temperature even lower than 0°C. The Dolphin device can be …

Investigating The Effect Of Input Modality On Reasoning In Vlms Using Zero-Shot Evaluation, Rodela Ghosh, Aviral Gupta, Ocean Monjur, Shrestha Datta, Anshuman Chhabra

Bellini College REU Symposium (BCREUS)

This project investigates how input modality affects mathematical reasoning in vision-language models (VLMs). Using 100 samples from the GSM8K benchmark, we evaluate Qwen2-VL-2B-Instruct and LLaVA-v1.6-Mistral-7B across three conditions: text-only, rendered image, and a modality mismatch condition where image and text describe different problems. Both models show substantial accuracy drops under visual input — Qwen2 falls from 55% to 30% and LLaVA from 40% to 21%. In the mismatch condition, both models follow the text modality in over 75% of cases, revealing strong text dominance when modalities conflict. These findings suggest that rendering math problems as images meaningfully impairs reasoning in …

Modality-Specific Confidence And Uncertainty Metrics For Vision-Language Models, Sahasra Kondapalli, Poyraz An, Trung Dong, Lara Radovanovic, Xiaomin Lin

Bellini College REU Symposium (BCREUS)

Introduction and Problem Statement

Vision-Language Models (VLMs) are increasingly being integrated into high-stakes environments, such as autonomous robotics used in shared workspaces and as multimodal medical assistant systems. However, current models still have inherent uncertainties, often producing errors or false confidence in responses [1]. Such errors, when passed undetected, can cause serious issues in medical implementations. In shared workspaces, false confidence can lead to safety hazards, or disruption. Du et al. present an evaluation of uncertainty, specifically in the field of human-robot interaction [2]. Such faults are only magnified with the addition of the vision modality, thus highlighting the need …

Teacher Candidates’ Reflective Practices Of Mathematics Curriculum From The Lens Of Universal Design For Learning, Weichen Zhao

Journal of Practitioner Research

The Universal Design for Learning (UDL) framework encourages educators to proactively remove barriers in curriculum and instruction to increase accessibility for all learners. While UDL is often applied during lesson planning, it can also serve as a powerful tool for critically examining and revising existing mathematics curricula. Drawing on qualitative data from teacher candidates’ reflective journals and curriculum artifacts collected over two semesters, this study examines how guided reflection supported teacher candidates in identifying barriers, proposing inclusive adaptations, and deepening their understanding of equity-oriented mathematics instructional design. As a self-study grounded in participatory action research, the findings also informed the …

Exploring Researcher-Practitioner Authorship Collaboration In English, Foreign Language, And Mathematics Education, Rachel Cullen, Joseph Taylor, Matthew Laney, Mohamed Nouri

Journal of Practitioner Research

This study examined collaboration and bidirectional relationships between researchers and practitioners in the context of journal publications. Through exploration of research and practitioner journals in the areas of English, Foreign Languages, and Mathematics, we aimed to understand how authorship patterns and types of references illustrate the gap between research and practice. Findings indicate that collaboration between researchers and practitioners in the context of journal publications is minimal, and practitioner presence is scarce in research. The types of references included in publications are high quality regardless of authorship, but there is a problem of exposure that limits the research from reaching …

Numeracy-Based Civic Education Model: Needs Analysis Through An Explanatory Sequential Design, Sulkipani Sulkipani, Kokom Komalasari, Sapriya Sapriya, Susan Fitriasari, Vina Amilia Suganda Makenun

Numeracy

The United Nations Sustainable Development Goals emphasize numeracy as essential for quality education, and require its integration across the curriculum, including into civic education (CE). However, the integration of numeracy in CE in Indonesian universities has not yet been clearly mapped out. This study aims to analyze the need for numeracy integration in CE as a basis for developing a numeracy-based CE learning model. Using a mixed method with an explanatory sequential design, the study involved a convenience sample of 225 students and 10 lecturers from various universities through surveys, interviews, observations, and documentation studies. Quantitative findings show that numeracy …

Drainage Proximity And Sinkhole Occurrence In Sivrihisar (Central Turkey): A Comparative Analysis Of Linear, Poisson, And Negative Binomial Regression Models, Bilge Bingül, Emrah Pekkan, Resul Çömert

International Journal of Speleology

This study investigates the relationship between sinkhole occurrence and distance to drainage in the Sivrihisar region (Central Turkey) and evaluates the suitability of different regression approaches for modeling clustered count data in karst terrains. A comprehensive inventory of 104 sinkholes developed within the Neogene lacustrine limestones of the Akpınar Formation was compiled using official records, remote sensing analyses, and detailed field surveys. Sinkhole occurrences were analyzed relative to a drainage network derived from a high-resolution Digital Surface Model and grouped by proximity to drainage lines. Linear Regression (LM), Poisson Regression (PR), and Negative Binomial Regression (NBR) models were comparatively applied …