Digital Commons Network^™

Syntheses, Photophysics, & Application Of Porphyrinic Metal-Organic Frameworks, Zachary L. Magnuson

USF Tampa Graduate Theses and Dissertations

Porphyrins are a group of heterocyclic macrocycles that play crucial roles in various biological processes such as electron transfer, catalysis, and sensing. Hemoglobin, which carries oxygen in the blood of mammals, and chlorophyll, which drives photosynthesis in plants and algae, are both porphyrins. The ability of porphyrins to bind metal ions and their unique electronic and photophysical properties make them an excellent platform for designing functional materials for various applications, often drawing inspiration from their function in nature. Metal-organic frameworks (MOFs) are a class of porous materials that have been extensively studied in recent years due to their high surface …

Synthetic Studies Of Potential New Ketogenic Molecules, Mohammad Nazmus Sakib

USF Tampa Graduate Theses and Dissertations

The ketogenic diet has gained popularity in the past few decades among people and physicians due to its various health benefits. A significant amount of research has been done for the modification of the original ketogenic diet and investigation of its potential health benefits. However, synthesis of novel ketogenic compounds as a dietary supplement has not received the same level of attention. That is the primary objective of this research project. The first chapter of this manuscript describes the synthesis of various short and medium chain esters of different polyols that have been done so far, and areas of their …

Saudi Mothers’ Perspectives And Experiences About Family-School Partnership In Early Childhood: A Qualitative Study, Mona Mohsen Alzahrani

USF Tampa Graduate Theses and Dissertations

In this study, I explored Saudi mothers’ perspectives on family-school partnerships, besides understanding the challenges they had faced. I used the ecological theoretical framework, to understand the complexity of the relationships between family and school and the impact of the environment on children's development. The ecological theory allowed me to simplify these relationships and recognize the effect on the children's development by examining Saudi mothers' perspectives. I selected qualitative research to gain a better thoughtful of the complex phenomena. I conducted semi-structured interviews to gain a deeper understanding of mothers’ perspectives. I applied a thematic analysis by Clark and Braun …

Machine Learning For Electronic Design Automation: Specification Mining And High-Level Synthesis, Md Rubel Ahmed

USF Tampa Graduate Theses and Dissertations

The rapid growth of complex system-on-chip (SoC) designs has presented unprecedented opportunities and challenges in electronic design automation (EDA). This dissertation explores two facets of electronic design automation: message flow specification mining using data mining and natural language processing (NLP) and high-level synthesis (HLS) acceleration using different machine learning (ML) methods. It also discusses an ML model co-optimization method for energy-efficient hardware implementation.

Effective SoC design validation relies heavily on message flow specifications. This dissertation presents an efficient technique for synthesizing finite state automaton (FSA) models from SoC execution traces. The synthesized models can provide valuable insights into the on-chip …

Influence Of Thickness And Capping Materials On The Static And Dynamic Properties Of Ferrimagnetic Thin Films, Noha Alzahrani

USF Tampa Graduate Theses and Dissertations

Spintronics traditionally relied on ferromagnetic materials for their strong spin properties but facedissues like large stray magnetic fields. To address these challenges, researchers turned to antiferromagnetic materials with fast spin dynamics, due to their zero net magnetic moment but the lack of a net spin moment complicated operation. In this context, ferrimagnetic materials have emerged as promising alternatives. They combine ferromagnetic and antiferromagnetic traits and feature different magnetic ions in their sublattices. This dissertation explores how film thickness and capping materials affect the properties of ferrimagnetic thin films. Rare-earth transition metal ferrimagnetic amorphous alloys have garnered attention in the realm …

The Contextualization Of Socioscientific Issues In An Age Of Accountability, Karrie A. Wikman

USF Tampa Graduate Theses and Dissertations

The overarching aim of this research was to ultimately support global resiliency through science education, preparing citizens to laudably negotiate the contentious socio-cultural science- and technology-based issues of modern times. Correspondingly, this mixed methods study aimed to move a large, diverse school district toward school environments conducive to contextualized socioscientific issues (SSI)-based learning. Of interest to teachers, administrators, and policymakers, the research investigated the effects of subsuming standards-based objectives within the SSI instructional framework on science achievement. Analysis of variance of multilevel assessment and classroom observation protocol data revealed that students experiencing the SSI intervention showed statistically significant gains in …

Refining The Machine Learning Pipeline For Us-Based Public Transit Systems, Jennifer Adorno

USF Tampa Graduate Theses and Dissertations

According to the Population Division of the United Nations, in the United States, almost 90% of the population will live in urban areas by the year 2050. As the population in a given area increases, higher traffic congestion follows due to an increase of vehicles in the road. A possible way to alleviate congestion could be with widespread use of public transit. However, according to the US Census Bureau, the percentage of individuals commuting through public transportation has been decreasing steadily over time, and the American Community Survey reports that during 2019, only around five percent of the US population …

Optimizing The Dynamic Replacement Of Soft Soils With Sand Using A Fem Tools, Walid Salem A Elsiwi

USF Tampa Graduate Theses and Dissertations

First a dynamic finite element methodology (FEM) was developed to simulate an entire dynamic replacement (DR) program of clay with sand involving multiple poundings. The main objective of this research was to employ FEM and geotechnical test data such as cone penetration test (CPT) data at the site to predict the maximum achievable sand column (SC) depth and the corresponding optimum levels of attributing parameters such as number and height of pounder drops. Another goal was to predict the pore pressure generated in clay due to pounding. A full-scale ground improvement project was used to guide the analytical process. Comparison …

Big Data Analytics For Healthcare Social Media: New Algorithms And Insights, Negar Maleki

USF Tampa Graduate Theses and Dissertations

Over the last two decades, there has been a rapid evolution in information and communication technology, including the emergence of social media. Social media has a significant impact on various fields such as politics, business, culture, education, careers, innovation, and especially healthcare. This influence is not a new phenomenon since a survey from ten years ago showed that up to 78\% of American adults used the internet to look for health-related information for themselves or someone else. With the shift towards on-demand services in society, healthcare is also affected by this trend. Instead of waiting for weeks or months to …

An Empirical Analysis Of Sentiment And Confidence Regarding Interest Rates In Disclosures Of Public Firms In The U.S. Fintech Sector, James J. Farley

USF Tampa Graduate Theses and Dissertations

This dissertation studied the channel of communication of 10-K and 10-Q financial reports and the effectiveness of relaying interest rate sentiment. 10-K financial reports relay information regarding a company’s financials on a yearly basis while 10-Q reports relay information on a quarterly basis. To study a newer industry of Fintech and how it may be affected by interest rates it was necessary to narrow Fintech to the United States and a coordinated public channel of communication using the 10-Q and 10-K financial reports. Fintech emerged as a relevant word and industry coming off the Great Recession of 2009. During the …

Methods And Systems For Determining An Ionic Strength Of A Dilute Aqueous Solution, Robert H. Byrne

USF Patents

Disclosed herein are methods for measuring the ionic strengths of the natural water sources. Also disclosed herein are systems used to measure an ionic strength of the natural water sources. More specifically disclosed herein are methods and systems utilizing spectroscopic pH measurements and calculations of the ionic strength as a function of the measured pH.

Representation And Visualization Of Multivariate Sensory Time Series Data, Ismail Uysal, Alla Abdella

USF Patents

In accordance with some embodiments, systems, methods, and media for processing and representing multivariate sensor information gathered from multiple sources are provided. In some embodiments, the method comprises: receiving a data sequences from respective sources; identifying a shortest data sequence that corresponds to a first interval; calculating, for pairs of data sequences, a similarity value over the first interval; forming a first segment of a representative data sequence that is a weighted combination of the data sequences over the first interval based on similarity values associated with the data sequences; truncating at least a subset of data sequences to exclude …

Anonymity Preserving Data Collection Using Homomorphic Encryption, Jean-Francois Biasse, William Youmans, Sriram Chellappan, Nathan Fisk, Noyem Khan

USF Patents

A public key generated by each user of a plurality of users is used to encrypt the contacts for that user. The results are sent to a server by each user. The key generated by each user is then distributed to every other user in the system, and each recipient encrypts their contacts with the keys. The result of these encryptions for all contacts for all recipients is then received by the server, and the server computes an encrypted computation of equality of two contacts and sends all computations back to the original user. The user can use the homomorphic …

Human Vs Machine: Hyper-Realistic Avatars And Their Efficacy As A Communication Channel, Jill S. Schiefelbein

USF Tampa Graduate Theses and Dissertations

Hyper-realistic avatars (HRAs), a form of synthetic media, are custom-created digital embodiments of a human, created by capturing and combining that person’s video and vocal likeness. This is the first known study of the efficacy of videos delivered by hyper-realistic avatars as a communication channel in comparison to videos delivered by their human counterparts. An experiment testing how information retention, engagement, and trust vary between viewers of videos delivered by a real human, videos delivered by the HRA representing that same human, and videos delivered by the HRA that discloses to viewers that it is a hyper-realistic avatar is presented. …

Utilizing Binding-Based Proteomic Profiling And Mass Spectrometry Imaging As Innovative Tools For Lipid Research, Suzeeta Bhandari

USF Tampa Graduate Theses and Dissertations

Mass spectrometry-based omics research involves global identification and quantification of molecules in the biological system, which can form the basis of the multi-omics approach integrating multiple layers of information to provide a comprehensive overview of systems biology. The investigation of fatty acid amides (FAA) is one such research avenue that benefits significantly from the high-throughput, multi-level, and interdisciplinary approach of integrative omics. Currently, FAA research is dominated by lipidomic-based studies that have successfully identified and quantified >100 different FAAs in different model systems. Few studies are credited with exploring the biological function and evolution of FAA-dependent signaling pathways. Previous literature …

Interdependency Between Water And Road Infrastructures: Cases And Impacts, Shihab Uddin

USF Tampa Graduate Theses and Dissertations

This dissertation studies the interdependency between road and water infrastructures and associated interdependency impact on these two critical infrastructure systems. Critical infrastructures and the interdependency among these infrastructures have gained much attention recently because of its growing complexity, importance, and vulnerability to natural and man-made threats. In response, researchers have spent significant effort to study these infrastructures individually as well as when they are interdependent to understand complex interdependency relationship and to figure out ways to make these infrastructures more reliable, robust, and resilient. However, water and road infrastructure systems have not been studied as vastly as other critical infrastructures …

Social Justice Integration In Stem Content With Early Childhood Education Pre-Service Teachers, Elyse D. Ledford

USF Tampa Graduate Theses and Dissertations

Following the social justice education ideal of building from local sources of knowledge the purpose of this multi-case study was to develop describe and explain the ways pre-service teachers examined how pre-service teachers make use of social justice pedagogies in teaching STEM. The study was guided by the following research questions: In what ways do pre-service teachers make us of social justice pedagogies while planning STEM lessons for young children? In what was do pre-service teachers enact social justice pedagogies in STEM instruction for young children? This study explores the experience of three Early Childhood Education pre-service teachers who were …

Advanced Multiscale Molecular Dynamics Simulations Of Amorphous Polymers, Sahar Zenoozi

USF Tampa Graduate Theses and Dissertations

Polymers are in a wide range of material forms with various resources, including natural to synthetic processes. Polymers consist of covalently bonded monomers to each other. The chain length of polymers varies from a few monomers to thousands of monomers. This wide range of chain length enables polymers with attractive capabilities of chemical and physical properties. Thus, polymers are highly attractive in different scientific and industrial applications such as drug delivery, optical coatings, catalysts, semiconductors and organic photovoltaics. This work has combined updated accurate methods for accurate initial conformations, and modified force field parameters to produce a generalized method for …

Trace Metal Cycling During Phytoplankton Growth In The Southern Ocean, North Pacific, And Tampa Bay, Shannon Michelle Burns

USF Tampa Graduate Theses and Dissertations

The trace metals iron (Fe), manganese (Mn), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), and cadmium (Cd) are essential to primary production in the oceans. They act as micronutrients, used in intracellular enzymes for macronutrient acquisition, light harvesting, and mediation of reactive oxygen species. In some cases, they can also substitute for each other when a primary trace metal micronutrient is depleted. Characterizing the interplay amongst trace metals, macronutrients, and phytoplankton growth is vital for understanding the biogeochemical underpinnings of primary production, and for modelers who develop biological pump frameworks for global carbon cycling.

In Chapter two, I investigated …

Investigating Mobility In The Northern Balkans During The Fifth Millenium Bc Through Strontium Analysis Of Human Tooth Enamel, Aurélien Tafani

USF Tampa Graduate Theses and Dissertations

This research investigates how individual mobility among ancient populations in Romania during the Eneolithic, between 5000 and 4000 BC, may be related to the spread of the material culture known as Kodjadermen-Gumelniţa-Karonovo VI (KGK VI) that extended over most of southern Romania and Bulgaria. This work seeks to combine results on individual mobility with other lines of archaeological evidence to provide a better understanding of the social context and kinship relationships that were in place when these events took place.

Strontium isotopic analyses were performed on 130 individuals from two sites located in the southern Romania: 49 from Sultana and …

Using Social Network Analysis To Measure And Visualize Student Clustering Within Middle And High Schools, Geoffrey David West

USF Tampa Graduate Theses and Dissertations

The dominant philosophy of American public schools has been to group students together based on similar characteristics. Known as tracking, high achieving students would take courses on the “college track” while others would take “career track” courses. It was not long until advocates noticed that this process unfairly advantaged affluent and White student over poor and minoritized groups. A new process called “ability grouping” took over where tracking left off, but to the same effect. It is difficult to measure the degree students are grouped together by a certain characteristic, and while a few research papers aim to do so, …

Deciphering Trends And Tactics: Data-Driven Techniques For Forecasting Information Spread And Detecting Coordinated Campaigns In Social Media, Kin Wai Ng Lugo

USF Tampa Graduate Theses and Dissertations

The main objective of this dissertation is to develop models that predict and investigate the spread of information in social media over time. In this context, we consider topics of discussions as the information that spreads. Thus, we are interested in forecasting the number of messages per day in a future interval of time. We take a data-driven approach, in which we compare our results with real datasets from a multitude of socio-political contexts and from multiple social media platforms, specifically, Twitter and YouTube.

We identified a number of challenges related to forecasting social media time series per topic. First, …

Coupling Chemical And Genomic Data Of Marine Sediment-Associated Bacteria For Metabolite Profiling, Stephanie P. Suarez

USF Tampa Graduate Theses and Dissertations

Marine sediment-associated bacteria house many new and exciting novel secondary metabolites. These metabolites can be tested for bioactivity against various types of cancer and fungal, bacterial, and viral infections. In this thesis, we investigated the combination of biosynthetic gene cluster information with mass spectra to perform a chemical profiling of sediment- associated bacteria. Furthermore, we utilized a scoring technique to provide an identification and confidence score to each annotated compound. The sediment was collected from east Arthur Harbor, Palmer Station, Antarctica, at depths of 20 ft and 60 ft. After plating on agar, 52 unique bacterial strains were isolated, with …

Procedures For Assessment Of The Marine Carbon System And Evaluation Of Access And Ocean Acidification Literacy In The Deaf Community, Loraine Martell-Bonet

USF Tampa Graduate Theses and Dissertations

One major goal of this dissertation addresses the need for improved laboratory procedures to measure chemical changes in seawater caused by the uptake of atmospheric CO2, especially in coastal environments. Due to the proximity of anthropogenic stressors in the coastal zone, the biogeochemical complexity of the CO2 system is more dynamic than the open ocean. My principal research objectives were addressed by developing methods for (1) improving the accuracy of pH measurements over a wide range of salinities and (2) investigating the acid-base properties of natural organics in the coastal ocean.

The accuracy of pH electrode calibrations is affected when …

Examining Paleoshorelines In The Eastern Gulf Of Mexico: Insights On Sea Level History And Potential Areas Of Interest For Habitat Management, Catalina Rubiano

USF Tampa Graduate Theses and Dissertations

An inventory of multibeam bathymetry containing relict drowned and lithified paleoshorelines has been compiled and analyzed in the first ever shelf-wide investigation of paleo sea level indicators on the west Florida shelf (WFS). On the largest scale, the WFS is a wide and gently sloping terrain that is characterized by a carbonate-rich sediment regime. This framework coupled with the region’s tectonic stability provided a setting in which sea level changes since ~ 20 ka have been recorded to a remarkable degree of resolution in the form of paleoshorelines which formed at sea level and were subsequently drowned and preserved in …

Deep Learning-Based Automatic Stereology For High- And Low-Magnification Images, Hunter Morera

USF Tampa Graduate Theses and Dissertations

Quantification of the true number of stained cells in specific brain regions is an important metric in many fields of biomedical research involving cell degeneration, cytotoxicology, cellular inflammation, and drug development for a wide range of neurological disorders and mental illnesses. Unbiased stereology is the current state-of-the-art method for collecting the cell count data from tissue sections. These studies require trained experts to manually focus through a z-stack of microscopy images and count (click) on a hundred or more cells per case, making this approach time consuming (~1 hour per case) and prone to human error (i.e., inter-rater variability). Thus, …

Automated Stereology For Determining Tissue Characteristics, Peter Randolph Mouton, Hady Ahmady Phoulady, Dmitry Goldgof, Lawrence O. Hall

USF Patents

Systems and methods for automated stereology are provided. A method can include providing an imager for capturing a Z-stack of images of a three-dimensional (3D) object; constructing extended depth of field (EDF) images from the Z-stack of images; performing a segmentation method on the EDF images including estimating a Gaussian Mixture Model (GMM), performing morphological operations, performing watershed segmentation, constructing Voronoi diagrams and performing boundary smoothing; and determining one or more stereology parameters such as number of cells in a region.

Developing New Strategy Toward Ruthenium And Gold Redox Catalysis, Chenhuan Wang

USF Tampa Graduate Theses and Dissertations

This dissertation mainly contains three parts: 1) The discovery of triazole-modified Ru carbene catalysts for alkene metathesis and dynamic covalent chemistry; 2) The study of ligand assisted gold oxidative addition toward aryl iodide to achieve the alkene difunctionalization; 3) Gold redox catalysis via chiral P,N-chelating ligands. In the first part, the 1,2,3-triazole coordinated ruthenium carbene complexes (TA-Ru) were reported for the first time as a new class of modified Grubbs catalyst to achieve challenging olefin metathesis at higher temperatures without catalyst decomposition. With this new TA-Ru catalyst, cross-metathesis (CM), ring-closing metathesis (RCM) and dynamic covalent chemistry (DCvC) were achieved. The …

Booker Creek: Wet Season Water Quality Trends In A Florida Urban Stream, Alexandra M. Shostak

USF Tampa Graduate Theses and Dissertations

Booker Creek, a 1.9-mile stream with a 4.9-mi2 watershed, flows southeast through highly urbanized St. Petersburg, Florida, and empties into Bayboro Harbor, which connects with Tampa Bay. This study collected and analyzed water quality data for several parameters (TN, TP, nitrate-nitrite, ammonia, orthophosphate, chl-a, fecal coliform, dissolved oxygen, pH, turbidity, temperature, and salinity) every two weeks, at four different sites, during the 2022 wet season to characterize the current state and geographic variability of Booker Creek. Current creek sampling regimes, though consistent, do not sample at multiple sites along the creek. Urban streams do not display uniform water quality along …

Water Chemistry Variability In Peacock Springs Cave System And Spring Basin: Impacts On Continuous Monitoring Of Karst Aquifers, Mahnoor Kamal

USF Tampa Graduate Theses and Dissertations

The Upper Floridan Aquifer (UFA) is a highly transmissive and heterogeneous karst aquifer that makes it acutely susceptible to pollution. Rapid and extensive water quality changes in nutrients at springs draining the UFA have prompted intensive monitoring at several priority springs, including continuous and discrete water quality sampling. Springs, however, are a discrete discharge point of an often-expansive phreatic cave network that can intersect different land uses and thus drain distinct geographic areas of a springshed. The extensive network contains convergent passages from deep and shallow aquifer regions and may contribute to varying water chemistry across passages resulting in water …