Digital Commons Network^™

Development Of A New Electrodeposition Process For Plating Of Zn-Ni-X (X = Cd, P) Alloys: I. Corrosion Characteristics Of Zn-Ni-Cd Ternary Alloys, Anand Durairajan, Bala S. Haran, Ralph E. White, Branko N. Popov

Faculty Publications

A new Zn-Ni-Cd plating process was developed which offers a unique way of controlling and optimizing the Ni and Cd contents in the final deposit. Zinc-nickel-cadmium alloy was deposited from a 0.5 M NiSO₄ + 0.2 M ZnSO₄ bath in the presence of 0.015 M CdSO₄ and 1 g/L nonyl phenyl polyethylene oxide. Using this process a Zn-Ni-Cd ternary alloy, with a higher nickel content as compared to that obtained from conventional Zn-Ni baths, was synthesized. The Zn-Ni-Cd alloy coatings deposited from an electrolyte containing 0.015 M (0.3%) CdSO₄ has a Zn to Ni ratio of …

Ni-Composite Microencapsulated Graphite As The Negative Electrode In Lithium-Ion Batteries Ii: Electrochemical Impedance And Self-Discharge Studies, P. Yu, James A. Ritter, Ralph E. White, Branko N. Popov

Faculty Publications

Electrochemical impedance and self-discharge studies were carried out to investigate lithium intercalation into bare and Ni-coated KS10 graphite. Values of the charge-transfer resistances, exchange current densities, surface film resistances, and lithium-ion diffusion coefficients as functions of the state of charge (SOC) all favored the 10 wt % Ni composite KS10 graphite over bare KS10 graphite when these materials were used as the negative electrode in a Li-ion cell with mixed organic electrolyte. The charge-transfer resistances were always lower and gave rise to between 26 and 27% larger exchange current densities, which increased from 137 to 614 mA/g as the SOC …

Cardiovascular Disease Prevention By Sports: Myth Or Reality?, Maria João C. A. Almeida, Steven N. Blair

Faculty Publications

Low levels of physical activity and fitness substantially increase risk of several chronic diseases, reduce longevity, and lead to loss of function. The strength and relation of inactivity to health problems and the high prevalence of sedentary habits in most countries of the world make lack of exercise a major public health problem. Fortunately, there is now good consensus regarding public health recommendations for physical activity from many important medical, scientific, and public health organizations. Recent research on physical activity interventions provides additional approaches to helping sedentary adults become more physically active.

A Semianalytical Method For Predicting Primary And Secondary Current Density Distributions: Linear And Nonlinear Boundary Conditions, Dhanwa Thirumalai, Ralph E. White

Faculty Publications

No abstract provided.

Development Of A New Electrodeposition Process For Plating Of Zn‐Ni‐X (X = Cd, P) Alloys: I. Corrosion Characteristics Of Zn‐Ni‐Cd Ternary Alloys, Anand Durairajan, Bala S. Haran, Ralph E. White, Branko Popov

Faculty Publications

No abstract provided.

Computational Fluid Dynamics Modeling Of A Lithium/Thionyl Chloride Battery With Electrolyte Flow, W. B. Gu, C. Y. Wang, John W. Weidner, Rudolph G. Jungst, Ganesan Nagasubramanian

Faculty Publications

A two-dimensional model is developed to simulate discharge of a lithium/thionyl chloride primary battery. As in earlier one-dimensional models, the model accounts for transport of species and charge, and electrode porosity variations and electrolyte flow induced by the volume reduction caused by electrochemical reactions. Numerical simulations are performed using a finite volume method of computational fluid dynamics. The predicted discharge curves for various temperatures show good agreement with published experimental data, and are essentially identical to results published for one-dimensional models. The detailed two-dimensional flow simulations show that the electrolyte is replenished from the cell head space predominantly through the …

Development Of A New Electrodeposition Process For Plating Of Zn-Ni-X (X = Cd, P) Alloys: Permeation Characteristics Of Zn-Ni-Cd Ternary Alloys, A. Durairajan, B. S. Haran, Ralph E. White, Branko N. Popov

Faculty Publications

It is shown that an electrodeposited Zn-Ni-Cd alloy coating produced from sulfate electrolyte inhibits the discharge of hydrogen on carbon steel. The newly developed ternary alloys have approximately ten times higher corrosion resistance when compared to a Zn-Ni alloy. Hydrogen permeation characteristics of Zn-Ni-Cd alloy coatings were studied and compared with those of a bare and a Zn-Ni alloy coated steel. The transfer coefficient, a, exchange current density, io, thickness dependent adsorption-absorption rate constant, k0, recombination rate constant, k3, surface hydrogen coverage, θH, were obtained by applying a mathematical model to experimental results. Alloys obtained from baths containing higher concentration …

Modeling Lithium Intercalation Of A Single Spinel Particle Under Potentiodynamic Control, Dong Zhang, Branko N. Popov, Ralph E. White

Faculty Publications

A mathematical model is presented for the lithium intercalation of a single spinel particle as a microelectrode under the stimulus of a cyclic linear potential sweep. The model includes both lithium diffusion within the particle and kinetics at the particle/electrolyte interface. The model is used to predict that peak current densities depend linearly on the scan rate to a certain power with a constant term, which is different from the predicted peak current density for a conventional redox system.

Shrinking Core Model For The Discharge Of A Metal Hydride Electrode, Venkat R. Subramanian, Harry J. Ploehn, Ralph E. White

Faculty Publications

A shrinking core model is presented for the galvanostatic discharge of a metal hydride particle. A quantitative criterion for when the shrinking core can be completely neglected or approximated by a pseudosteady-state solution is presented. The effect of shrinking of the core on the discharge behavior of a metal hydride particle is also studied.

Moderate Intensity Exercise Training Improves Cardiorespiratory Fitness In Women, J. David Branch, Russell R. Pate, Sharon P. Bourque

Faculty Publications

Among women, there is an increased prevalence of sedentary lifestyle and less participation in physical activity at levels recommended by the Surgeon General. As a result, women have been identified as a target group in public health initiatives to increase physical activity. The health-related benefits of habitual, moderate intensity physical activity are well documented in the epidemiological literature, but less is known about the effect of such physical activity on cardiorespiratory fitness. Our hypothesis was that moderate and vigorous exercise training regimens of similar estimated energy expenditure would result in similar changes in cardiorespiratory fitness. Eighteen sedentary premenopausal women with …

Is Malnutrition Declining? An Analysis Of Changes In Levels Of Childhood Malnutrition Since 1980, Mercedes De Onis, Edward A. Frongillo Jr., Monika Blo¨ Ssner

Faculty Publications

Nutritional status is the best global indicator of well-being in children. Although many surveys of children have been conducted since the 1970s, lack of comparability between them has made it difficult to monitor trends in child malnutrition.

Cross-sectional data from 241 nationally representative surveys were analysed in a standard way to produce comparable results of low height-for-age (stunting). Multilevel modelling was applied to estimate regional and global trends from 1980 to 2005.

The prevalence of stunting has fallen in developing countries from 47% in 1980 to 33% in 2000 (i.e. by 40 million), although progress has been uneven according to …

December 1, 1999 Faculty Senate Minutes, University Of South Carolina

Faculty Senate

No abstract provided.

Majority Rule Or Minority Will: Adherence To Precedent On The Us Supreme Court By Harold J. Spaeth And Jeffrey A. Segal, Donald R. Songer

Faculty Publications

No abstract provided.

November 3, 1999 Faculty Senate Minutes, University Of South Carolina

Faculty Senate

No abstract provided.

Tracking Of Physical Activity, Physical Inactivity, And Health-Related Physical Fitness In Rural Youth, Russell R. Pate, Stewart G. Trost, Marsha Dowda, Alise E. Ott, Dianne S. Ward, Ruth P. Saunders, Gwen A. Felton

Faculty Publications

This study examined the tracking of selected measures of physical activity, inactivity, and fitness in a cohort of rural youth. Students (N=181, 54.7% female, 63.5% African American) completed test batteries during their fifth- (age=10.7±0.7 years), sixth-, and seventh-grade years. The Previous Day Physical Activity Recall (PDPAR) was used to assess 30-min blocks of vigorous physical activity (VPA), moderate-to-vigorous physical activity (MVPA), TV watching and other sedentary activities, and estimated energy expenditure (EE). Fitness measures included the PWC 170 cycle ergometer test, strength tests, triceps skinfold thickness, and BMI. Intraclass correlation coefficients (ICCs) for VPA, MVPA, and after-school EE …

Piezoelectric Doping In Alingan/Gan Heterostructures, M. Asif Khan, J. W. Yang, Grigory Simin, R. Gaska, M. S. Shur, A. D. Bykovski

Faculty Publications

We report on the piezoelectricdoping and two-dimensional (2D) electron mobility in AlInGaN/GaN heterostructures grown on 6H–SiC substrates. The contribution of piezoelectricdoping to the sheet electron density was determined using an In-controlled built-in strain-modulation technique. Our results demonstrate that in strained AlGaN/GaN heterostructures, the piezoelectric field generates at least 50% of the 2D electrons. The strain modulation changes the potential distribution at the heterointerface, which, in turn, strongly affects the 2D electron mobility, especially at cryogenic temperatures. The obtained results demonstrate the potential of strain engineering and piezoelectricdoping for GaN-based electronics.

Low-Frequency Noise In N-Gan With High Electron Mobility, M. E. Levinshtein, S. L. Rumyantsev, D. C. Look, R. J. Molnar, M. Asif Khan, Grigory Simin, V. Adivarahan, M. S. Shur

Faculty Publications

We report on the results of measurements of low frequency noise in n-type gallium nitride (GaN) grown on sapphire with 300 K electron mobility of 790 cm²/V s. The noise spectra have the form of 1/f noise with a Hooge parameter α of approximately 5×10⁻². This value of α is two orders of magnitude smaller than that observed before in n-GaN. The obtained results show that the level of flicker noise in GaN, just like that in GaAs and Si, strongly depends on the structural perfection of the material (the amplitude of the 1/f …

Intersecting Chains In Finite Vector Spaces, Eva Czabarka

Faculty Publications

We prove an Erdős–Ko–Rado-type theorem for intersecting k-chains of subspaces of a finite vector space. This is the q-generalization of earlier results of Erdős, Seress and Székely for intersecting k-chains of subsets of an underlying set. The proof hinges on the author's proper generalization of the shift technique from extremal set theory to finite vector spaces, which uses a linear map to define the generalized shift operation. The theorem is the following.

For c = 0, 1, consider k-chains of subspaces of an n-dimensional vector space over GF(q), such that the smallest subspace in any chain has dimension at least …

Validity Of The Previous Day Physical Activity Recall (Pdpar) In Fifth-Grade Children, Stewart G. Trost, Dianne S. Ward, Ben Mcgraw, Russell R. Pate

Faculty Publications

This study evaluated the validity of the Previous Day Physical Activity Recall (PDPAR) self-report instrument in quantifying after-school physical activity behavior in fifth-grade children. Thirty-eight fifth-grade students (mean age, 10.8 ± 0.1; 52.6%; female; 26.3% African American) from two urban elementary schools completed the PDPAR after wearing a CSA WAM 7164 accelerometer for a day. The mean within-subject correlation between self-reported MET level and total counts for each 30-min block was 0.57 (95% C.I., 0.51-0.62). Self-reported mean MET level during the after-school period and the number of 30-min blocks with activity rated at > 6 METs were significantly correlated with the …

October 6, 1999 Faculty Senate Minutes, University Of South Carolina

Faculty Senate

No abstract provided.

Legal Implications For Teacher Selection As Defined By The Ada And The Adea, Phillip I. Young, Arthur L. Prince

The Journal of Law and Education

No abstract provided.

Prosecutorial Misconduct In Grand Jury Investigations, Peter J. Henning

South Carolina Law Review

No abstract provided.

The Premature Belatedness Of Victorianism's Boyhood: Clough And The Rugby Magazine, 1835-1837, Patrick G. Scott

Faculty Publications

Explores the attitudes and pressures on early Victorian teenagers through an examination of contributions by the poet Arthur Hugh Clough and other students at Rugby School to a short-lived quarterly, the Rugby Magazine (1835-1837). Originally presented at the Victorians Institute conference, Richmond, VA, 1999.

Writing Contracts In The Client's Interest, James P. Nehf

South Carolina Law Review

No abstract provided.

Caroliniana Columns - Fall 1999, University Libraries--University Of South Carolina

University South Caroliniana Society Newsletter - Columns

Contents:

The 1999 University South Caroliniana Society Annual Meeting..... p.1
A Chronicle of Extraordinary Service: the Military Career of Gen. William Childs Westmoreland..... p.1
South Caroliniana Library Receives Papers of Dr. George E. Meetze..... p.3
USC Archives Collections Used in Bicentennial Programs..... p.3
"Count Basie's Left Hand" Comes to the Caroliniana..... p.4
Summer Scholars Complete Research Projects..... p.8
From Humans to Amazons: Acquiring Materials at the South Caroliniana Library..... p.8
Mystery Images..... p.9
Library Receives Grant for Photograph Preservation and Access..... p.10
64th Annual Meeting..... p.10
Society Names Regional Representatives..... p.11
Memorials..... p.11
Unsigned and undated Poem..... p.12
New Old …

Manufacturing Ideology: Scientific Management In Twentieth-Century Japan, By William M. Tsutsui, William Dean Kinzley

Faculty Publications

A review of Manufacturing Ideology: Scientific Management in Twentieth-Century Japan, by William M. Tsutsui

Extended Stratification: Immigrant And Native Differences In Individual And Family Labor., Pidi Zhang, Jimy M. Sanders

Faculty Publications

The article outlines a theoretical system of extended stratification in order to account for differences between immigrants and natives in the amount of time individuals devote to paid work and the number of family members participating in paid work. The extended stratification theory contends that because people have different socio-economic frames of reference, they vary in their willingness to work long hours in an effort to achieve modest improvements in their current socioeconomic circumstances. Thus, immigrants from relatively poor societies tend to see their richer host society as abundant in opportunities for getting ahead through hard work. Immigrants will often …

September 1, 1999 Faculty Senate Minutes, University Of South Carolina

Faculty Senate

No abstract provided.

An Ellam Scheme For Advection-Diffusion Equations In Two Dimensions, Hong Wang, Helge K. Dahle, Richard E. Ewing, Magne S. Espedal, Robert Sharpley, Shushuang Man

Faculty Publications

We develop an Eulerian--Lagrangian localized adjoint method (ELLAM) to solve two-dimensional advection-diffusion equations with all combinations of inflow and outflow Dirichlet, Neumann, and flux boundary conditions. The ELLAM formalism provides a systematic framework for implementation of general boundary conditions, leading to mass-conservative numerical schemes. The computational advantages of the ELLAM approximation have been demonstrated for a number of one-dimensional transport systems; practical implementations of ELLAM schemes in multiple spatial dimensions that require careful algorithm development are discussed in detail in this paper. Extensive numerical results are presented to compare the ELLAM scheme with many widely used numerical methods and to …

Religious Education In Canadian Public Schools Foreign Developments, Anwar N. Khan

The Journal of Law and Education

No abstract provided.