Digital Commons Network^™

Estimation Of Diffusion Coefficient Of Lithium In Carbon Using Ac Impedance Technique, Qingzhi Guo, Venkat R. Subramanian, John W. Weidner, Ralph E. White

Faculty Publications

The validity of estimating the solid phase diffusion coefficient, D_s, of a lithium intercalation electrode from impedance measurement by a modified electrochemical impedance spectroscopy (EIS) method is studied. A macroscopic porous electrode model and concentrated electrolyte theory are used to simulate the synthetic impedance data. The modified EIS method is applied for estimating D_s. The influence of parameters such as the exchange current density, radius of active material particle, solid phase conductivity, porosity, volume fraction of inert material, and thickness of the porous carbon intercalation electrode, the solution phase diffusion coefficient, and transference number, on the …

Electrochemical Filtering Of Co From Fuel-Cell Reformate, Balasubramanian Lakshmanan, Wayne Huang, John W. Weidner

Faculty Publications

A proton exchange membrane fuel cell was used as a flow reactor for continuous preferential oxidation of CO over H2 from 1.0% CO in H2 under pulse-potential control. By varying the pulse profile ~e.g., on-time, off-time, pulse potential! the CO and H2 oxidation currents were varied independently. The improvement in faradaic selectivity between CO and H2 oxidation results from the promotion of CO adsorption during the off ~i.e., open-circuit! portion of the pulse. Therefore, during the on portion CO oxidation was preferred while the surface was covered with CO.

Anodic Behavior Of Ti In Koh Solutions: Ellipsometric And Micro-Raman Spectroscopy Studies, A. Prusi, Lj. Arsov, Bala Haran, Branko N. Popov

Faculty Publications

Anodic formation of oxide films on titanium surfaces, in various concentrations of aqueous KOH solutions, have been studied using ellipsometry and micro-Raman spectroscopy. By in situ ellipsometric measurements the coefficient of film thickness growth and indexes of refraction of anodic oxide films have been determined. The voltage at which the oxide film breaks down is strongly dependent on the KOH concentration. Further, the solution concentration strongly influences the potential at which the oxide film is transformed from the amorphous state to crystalline form. Using micro-Raman spectroscopy four crystalline forms of titanium oxides, namely, anatase, brookite, corundum, and rutile, have been …

Modeling The Effects Of Electrode Composition And Pore Structure On The Performance Of Electrochemical Capacitors, Changqing Lin, Branko N. Popov, Harry J. Ploehn

Faculty Publications

This work presents a mathematical model for charge/discharge of electrochemical capacitors that explicitly accounts for particle-packing effects in a composite electrochemical capacitor consisting of hydrous RuO₂ nanoparticles dispersed within porous activated carbon. The model is also used to investigate the effect of nonuniform distributions of salt in the electrolyte phase of the electrode in the context of dilute solution theory. We use the model to compare the performance of capacitors with electrodes made from different activated carbons and to investigate the effects of varying carbon content and discharge current density. Even at low discharge current density, concentration polarization in …

Modeling The Effects Of Electrode Composition And Pore Structure On The Performance Of Electrochemical Capacitors, Changqing Lin, Branko N. Popov, Harry J. Ploehn

Faculty Publications

This work presents a mathematical model for charge/discharge of electrochemical capacitors that explicitly accounts for particle-packing effects in a composite electrochemical capacitor consisting of hydrous RuO₂ nanoparticles dispersed within porous activated carbon. The model is also used to investigate the effect of nonuniform distributions of salt in the electrolyte phase of the electrode in the context of dilute solution theory. We use the model to compare the performance of capacitors with electrodes made from different activated carbons and to investigate the effects of varying carbon content and discharge current density. Even at low discharge current density, concentration polarization in …

The Many Uses Of Digitized Oral History Collections: Implications For Design, Dagobert Soergel, Douglas W. Oard, Samuel Gustman, Lydia Fraser, Jinmook Kim, Joan Meyer, Elizabeth Proffen, Theresa Sartori

Faculty Publications

Oral history - and spoken word collections generally - are assuming increasing importance in digital libraries as the storage, transmission and reproduction infrastructure improves. This paper describes three synergistic approaches to user needs analysis, explains how they are being applied to guide the design of systems to provide access oral history collections (using a s test bed the Shoah Foundations collection of over 50,000 videotaped oral history interviews), presents preliminary results from so -called “discount requirements analysis” and an analysis of “early access” requests, and draws some design implications. The results show a wide variety of users and uses of …

Making Agents Secure On The Semantic Web, Csilla Farkas, Michael N. Huhns

Faculty Publications

Agents were designed to collaborate and share information. While highly desirable for interoperability, this feature is scary from the security perspective. Illegal inferences, supported by semantic Web technology and ontologies, might enable users to access unauthorized information. In addition to semantic associations and replicated data with different sensitivity, malicious agents could also exploit statistical inferences. Although each agent in a system might behave in a desired and secure way, their combined knowledge could be used to disclose sensitive data. The research community must therefore develop and implement techniques that allow control over released data. To answer the questions related to …

“[Cu(Pyrazine-2-Carboxylate)2]2Cd4I8: Unprecedented 1-D Serpentine Chains And Regular 2-D Regular Metal-Organic Square Grids In A 3-D Framework., Delia M. Ciurtin, Mark D. Smith, Hans Conrad Zur Loye

Faculty Publications

A novel three-dimensional coordination polymer containing
an unprecedented one-dimensional serpentine motif conjoined
with a two-dimensional square grid motif is presented.

Development Of Cfl-Free, Explicit Schemes For Multidimensional Advection-Reaction Equations, Hong Wang, Jiangguo Liu

Faculty Publications

We combine an Eulerian–Lagrangian approach and multiresolution analysis to develop unconditionally stable, explicit, multilevel methods for multidimensional linear hyperbolic equations. The derived schemes generate accurate numerical solutions even if large time steps are used. Furthermore, these schemes have the capability of carrying out adaptive compression without introducing mass balance error. Computational results are presented to show the strong potential of the numerical methods developed.

December 5, 2001 Faculty Senate Minutes, University Of South Carolina

Faculty Senate

No abstract provided.

November 7, 2001 Faculty Senate Minutes, University Of South Carolina

Faculty Senate

No abstract provided.

Ca4Iro6, Ca3Mgiro6 And Ca3Zniro6, Matthew J. Davis, Mark D. Smith, Hans Conrad Zur Loye

Faculty Publications

Single crystals of tetracalcium iridium hexaoxide, Ca₄IrO₆, tricalcium magnesium iridium hexaoxide, Ca₃MgIrO₆, and tricalcium zinc iridium hexaoxide, Ca₃ZnIrO₆, were prepared via high-temperature flux growth and structurally characterized by single-crystal X-ray diffraction. The three compounds are isostructural and adopt the K₄CdCl₆ structure type, comprised of chains of alternating face-shared [CaO₆], [MgO₆] or [ZnO₆] trigonal prisms and [IrO₆] octahedra, surrounded by columns of Ca²⁺ ions.

Formula: Ca₄IrO₆, Ca_3.34Mg_0.66IrO₆ and …

A Dipolar Coupling Based Strategy For Simultaneous Resonance Assignment And Structure Determination Of Protein Backbones, Fang Tian, Homayoun Valafar, James H. Prestegard

Faculty Publications

A new approach for simultaneous protein backbone resonance assignment and structure determination by NMR is introduced. This approach relies on recent advances in high-resolution NMR spectroscopy that allow observation of anisotropic interactions, such as dipolar couplings, from proteins partially aligned in field ordered media. Residual dipolar couplings are used for both geometric information and a filter in the assembly of residues in a sequential manner. Experimental data were collected in less than one week on a small redox protein, rubredoxin, that was 15N enriched but not enriched above 1% natural abundance in 13C. Given the acceleration possible with partial 13C …

Transcendentalists & Friends, University Libraries--University Of South Carolina

Rare Books & Special Collections Publications

This catalog accompanied the exhibit which displays a portion of the Joel Myerson Collection of Nineteenth-century American Literature. It brings to the library comprehensive collections of first editions for Ralph Waldo Emerson (1803-1882), Margaret Fuller (1810-1850), Theodore Parker (1810-1860), Walt Whitman (1819-1892), and Emily Dickinson (1830-1886), along with manuscripts, letters, proofs, later and posthumous editions, and associated scholarship. With these core collections are smaller collections for lesser-known writers of the Transcendentalist movement, such as Christopher Pearse Cranch (1813-1892), significant groups of early editions from other writers of the period such as Nathaniel Hawthorne, Henry David Thoreau, Bronson and Louisa May …

October 3, 2001 Faculty Senate Minutes, University Of South Carolina

Faculty Senate

No abstract provided.

Johnny Saw My Test Score, So I'M Suing My Teacher: Falvo V. Owasso Independent School District, Peer Grading, And A Student's Right To Privacy Under The Family Education Rights And Privacy Act, Daniel R. Dinger

The Journal of Law and Education

No abstract provided.

Recent Developments In The Law

The Journal of Law and Education

No abstract provided.

Law Review Digests

The Journal of Law and Education

No abstract provided.

Fixing Up Fair Housing Laws: Are We Ready For Reform, David A. Thomas

South Carolina Law Review

No abstract provided.

An Ivy League Mystery: The Lost Papers Of Arthur Linton Corbin, Scott D. Gerber

South Carolina Law Review

No abstract provided.

A Comment On Justice O'Connor's Quest For Power And Its Impact On African American Wealth, Joan Tarpley

South Carolina Law Review

No abstract provided.

Effective Community Policing Performance Measures, Geoffrey P. Alpert, Daniel Flynn, Alex R. Piquero

Faculty Publications

As the philosophy of policing moves from a traditional to a community-oriented approach, performance measures must shift as well. Unlike the typical police performance measures of arrest and crime rates found in traditional police philosophies, community-oriented policing performance measures are more general and tend to measure the extent to which police affect the quality of life in the communities they serve as well as the problems they solve. This manuscript begins the process of developing effective community policing performance measures and presents three case studies through which objectives and performance measures are conceptualized.

Reconstruction Corruption And The Redeemers' Prosecution Of Francis Lewis Cardozo, W. Lewis Burke

Faculty Publications

No abstract provided.

Bush V. Gore And Equal Protection, Martin D. Carcieri

South Carolina Law Review

No abstract provided.

God Bless The Kickoff: School Prayer In South Carolina In The Wake Of Santa Fe V. Doe, Richele Keel Taylor

South Carolina Law Review

No abstract provided.

The Biographer’S Tale By A. S. Byatt. New York: Alfred A. Knopf, 2001. 305 Pp. $24.00. Isbn 0-375- 41114-3., Jennifer A. Marshall

Faculty Publications

No abstract provided.

Validation Of Land Surface Models Using Satellite-Derived Surface Temperature, Joshua Rhoads, Ralph Dubayah, Dennis Lettenmaier, Greg O'Donnell, Venkataraman Lakshmi

Faculty Publications

This research examines the feasibility of using remotely sensed surface temperature for validation and updating of land surface hydrologic models. Surface temperature simulated by the Variable Infiltration Capacity (VIC) hydrologie model is compared over the Arkansas-Red River basin with surface temperature retrievals from TOVS and GOES. The results show that modeled and satellite-derived surface temperatures agree well when aggregated in space or time. In particular, monthly mean temperatures agree on the pixel scale, and basin mean temperatures agree instantaneously. At the pixel scale, however, surface temperatures from both satellites were found to have higher spatial and temporal variabilities than the …

September 6, 2001 Faculty Senate Minutes, University Of South Carolina

Faculty Senate

No abstract provided.

Crystal Growth, Structure Determination And Magnetism Of A New Hexagonal Rhodate: Ba9rh8o24, Katharine E. Stitzer, M. D. Smith, J. Darriet, Hans Conrad Zur Loye

Faculty Publications

Single crystals of Ba9Rh8O24, grown from a molten potassium carbonate flux, crystallize in the spacegroup R¯3c with lattice parameters of a = 10.0899(4) and c = 41.462(2) Å. Magnetic measurements on oriented single crystals reveal the existence of magnetic anisotropy

Primary And Secondary Education - Recent Decisions

The Journal of Law and Education

No abstract provided.