Digital Commons Network^™

Nitrated Poly(4 -Hydroxystyrene) Microspheres For Optical Ph And Potassium Ion Sensing Based On Turbidity Changes Accompanying Polymer Sweller, Hongming Wang

Doctoral Dissertations

Porous poly(4-acetoxystyrene) swellable microspheres with diameters approximately 1∼2 mum were prepared by seeded emulsion polymerization. Toluene was used as the porogenic solvent and divinylbenzene was used as the crosslinker. The seed particles with diameters approximately 0.5∼1 mum were prepared by dispersion polymerization without adding porogenic solvent and crosslinker. Functionality was introduced by two derivatization reactions, hydrolysis and nitration, to form nitrated poly(4-hydroxystyrene). These polymer microspheres swell at high pH due to the deprotonation of the hydroxyl group on the polymer backbone. Swelling is accompanied by an increase in water content which causes the polymer refractive index to decrease. These microspheres, …

Transition Metal Complexes Of Novel Ligands Derived From The Cis,Cis-1,3,5-Triaminocyclohexane (Tach) Framework: Structural And Biological Studies, Gyungse Park

Doctoral Dissertations

Transition and Group IIB metal complexes of novel ligands derived from cis,cis-1,3,5-triaminocyclohexane (tach) were prepared for structural and biological activity study. Copper(II) complexes of N,N ',N″-trialkylated derivatives of tach [Cu(tach-R3)Cl2] (R = Me, Et, Pr, furanyl, and thiophenyl) were prepared from CuCl2 in MeOH or MeOH/Et2O solvent. The structures of [Cu(tach-R3)Cl2] in the solid and solution (aqueous and methanolic) states were extensively studied by UV-vis and EPR spectroscopies and were consistent to X-ray structure of [Cu(tach-Et 3)Br0.8Cl1.2] which reveals a slightly distorted square-based pyramidal geometry. Displacement of halide ions with water molecules in aqueous media was observed by the band …

Biodiversity And Phytogeography Of Bolivia's Wetland Flora, Nur Paul Ritter

Doctoral Dissertations

The composition, diversity, and phytogeographic affinities of the vascular flora of Bolivia's wetlands were examined and compared with wetland floras from the other Neotropical countries and the New World Temperate region. Forty-six wetlands distributed throughout Bolivia and ranging in elevation from 90 in to >4400 m were established as study sites. Regional and national wetland floras were compiled from field research, the literature, herbarium specimens, and available databases.

Two thousand and sixty species in 149 families and 666 genera were identified as associated with wetlands in Mesoamerica and tropical and subtropical South America. Of these, 1026 species in 126 families …

Swellable Polymer Substrates For Use In Magnetochemical And Optical Chemical Sensing, Stephen Arnold Doherty

Doctoral Dissertations

Lightly cross-linked, animated polymers that swell and shrink with changing pH were prepared and evaluated. At low pHs amine sites protonate causing charge to accumulate along the polymer backbone. The polymer then swells to maximize the charge separation. The swelling of the polymer causes a change in a magnetic or optical property that can be measured and related to pH.

Animated hydrogel membranes were prepared by copolymerizing dimethyl amino ethyl methacrylate(DMAEMA) with various comonomer hydrogels. Experiments were conducted to examine the effect of formulation on the ability of the hydrogel membrane to swell. Factors examined included cross-linker type, cross-linker concentration, …

Remote Sensing Of Forest Damage In The Czech Republic Using Hyperspectral Methods, Petya K. Entcheva

Doctoral Dissertations

The current study assesses the potential of hyperspectral data for monitoring the initial stages of damage in Norway spruce forests characterized by subtle changes in foliar chlorophyll and chemistry. Both field and airborne high spectral resolution reflectance measurements were obtained for selected study sites in the Krusne hory, Czech Republic.

High spectral resolution airborne canopy data and field foliar samples were acquired simultaneously in August 1998 for a total of 51 study sites within the Krusne hory. The sites were selected to represent a full range of damage conditions in even-aged Norway spruce (Picea abies (L.) Karst) stands located between …

Conservation And Ecology Of Fringing Salt Marshes Along The Southern Maine/New Hampshire Coast, Pamela Ann Morgan

Doctoral Dissertations

The small, fringing salt marshes that line the edges of estuaries in southern Maine and New Hampshire were the focus of this research. Although larger meadow marshes in New England have been studied extensively, little is known about the ecology of fringing marshes. Not only are fringing marshes much more numerous than meadow marshes in northern New England, they are often restored or created as mitigation for marsh impacts. Five ecological functions (primary production, soil organic matter accumulation, sediment trapping and binding, wave dampening and maintenance of plant diversity) were compared in meadow marsh and fringing marsh sites, and sometimes …

Disturbance Indicators For Time Series Reconstruction And Marine Ecosystem Health Impact Assessment, Benjamin Harrison Sherman

Doctoral Dissertations

A systematic reconstruction of Multiple Marine Ecological Disturbances (MMEDs) involving disease occurrence, morbidity and mortality events has been undertaken so that a taxonomy of globally distributed marine disturbance types can be better quantified and common forcing factors identified. Combined disturbance data include indices of morbidity, mortality and disease events affecting humans, marine invertebrates, flora and wildlife populations. In the search for the best disturbance indicators of ecosystem change, the unifying solution for joining data from disparate fields is to organize data into space/time/topic hierarchies that permit convergence of data due to shared and appropriate scaling. The scale of the data …

Impacts Of Wildlife Viewing: A Case Study Of Dixville Notch Wildlife Viewing Area, Judith Kay Anderson Silverberg

Doctoral Dissertations

Major objectives of this study were to examine the motivations, knowledge level and attitudes of wildlife viewers as well as the response of moose to observation and other human caused stimuli at a designated wildlife viewing site. Moose and other wildlife are attracted to areas where road salt runoffs and pools in low areas around culverts and ditches creating wildlife viewing opportunities.

This study examined whether moose behaviors such as visitation time and rate of use of the salt lick changed from preconstruction (1996) of a wildlife blind to wildlife viewing establishment (1999). Trailmaster monitors strategically located on trails entering …

Soil Hydraulic Controls Over Nitrogen Oxide Emissions And Nitrogen Cycling In Tropical Agriculture, Antje M. Weitz

Doctoral Dissertations

Soils are the major natural source of nitrous oxide (N2O). Intensive land use increased atmospheric concentrations of this greenhouse gas. Soil microbes produce and consume nitrogen oxides (NO, N2O) during the processes of nitrification (aerobic) and denitrification (anaerobic). Micro-scale variability of controlling factors cause nitrification and denitrification to occur simultaneously in soils, resulting in high spatial variability of nitrogen oxide emissions. Fertilization increases nutrient availability and thus N2O fluxes. Forest soils in the humid tropics account for 20--50% of all N2O sources. Expansion and intensification of tropical agriculture is expected to increase atmospheric N2O concentrations.

We measured N2O fluxes from …

One Solution For Managing Risks During Cutbacks In Residency Training Programs, Patrick Knott, Kathleen Ruroede

RISK: Health, Safety & Environment (1990-2002)

Professors Knott and Ruroede examine the risks associated with downsizing and elimination of physician residency training programs.

Normalizing Novelty: Regulating Biotechnological Risk At The U.S. Epa, Les Levidow, Susan Carr

RISK: Health, Safety & Environment (1990-2002)

Drs. Levidow and Carr examine EPA's regulation of biotechnology in the field of genetically modified organisms.

Looking Back: Unneeded X-Rays, Allan Mazur

RISK: Health, Safety & Environment (1990-2002)

From the discovery of x-rays in 1896 to the present, Dr. Mazur explores the history of risk management of radiation exposure from x-rays and nuclear fallout.

The Effects Of Forest Fragment Size, Isolation, And Microhabitat Variables On Nest Box Use By Southern Flying Squirrels (Glaucomys Volans) In Southern Illinois, Catherine Wong, Eric K. Bollinger, Thomas A. Nelson

Faculty Publications

We studied the effects of forest fragmentation on southern flying squirrels (Glaucomys volans) in southern Illinois, and examined factors influencing nest box use. Ten nest boxes were placed in each of 30 oak-hickory forest fragments. Nest boxes were checked monthly after installation. We measured habitat variables that described the nest box tree, the microhabitat surrounding the nest box tree, and landscape level characteristics of the fragments (isolation and area). Overall, 78% of the 300 nest boxes were used. Glaucomys volans was captured in 24 of the 30 forest fragments, and evidence of squirrel use was found in 4 additional fragments. …

Sensitivity Of A High‐Elevation Rocky Mountain Watershed To Altered Climate And Co2, Jill S. Baron, Melannie D. Hartman, L. E. Band, Richard B. Lammers

Faculty Publications

We explored the hydrologic and ecological responses of a headwater mountain catchment, Loch Vale watershed, to climate change and doubling of atmospheric CO2 scenarios using the Regional Hydro‐Ecological Simulation System (RHESSys). A slight (2°C) cooling, comparable to conditions observed over the past 40 years, led to greater snowpack and slightly less runoff, evaporation, transpiration, and plant productivity. An increase of 2°C yielded the opposite response, but model output for an increase of 4°C showed dramatic changes in timing of hydrologic responses. The snowpack was reduced by 50%, and runoff and soil water increased and occurred 4–5 weeks earlier with 4°C …

Food Resources Of Stream Macroinvertebrates Determined By Natural-Abundance Stable C And N Isotopes And A 15n Tracer Addition, Patrick J. Mulholland, Jennifer L. Tank, Diane M. Sanzone, Wilfred M. Wollheim, Bruce J. Peterson, Jackson R. Webster, Judy L. Meyer

Faculty Publications

Trophic relationships were examined using natural-abundance 13C and 15N analyses and a 15N-tracer addition experiment in Walker Branch, a 1st-order forested stream in eastern Tennessee. In the 15N-tracer addition experiment, we added 15NH4, to stream water over a 6-wk period In early spring, and measured 15N:14N ratios in different taxa and biomass compartments over distance and time. Samples collected from a station upstream from the 15N addition provided data on natural-abundance 13C:12C and 15N:14N ratios. The natural-abundance 15N analysis proved to be of limited value in identifying food resources of macroinvertebrates because 15N values were not greatly different among food …

The New Hampshire, Vol. 89 [90], No. 27-28 (Dec. 10, 1999), The New Hampshire

The New Hampshire Print Edition

An independent student produced newspaper from the University of New Hampshire. This volume was printed as 89, but it is the 90th volume in the series. This was corrected in pencil.

Faculty Senate - December 6, 1999 Minutes Summary, Faculty Senate

Faculty Senate Agendas & Minutes

No abstract provided.

Faculty Senate - December 6, 1999 Minutes Summary, Faculty Senate

Faculty Senate Agendas & Minutes

No abstract provided.

The New Hampshire, Vol. 89 [90], No. 24 (Nov. 23, 1999), The New Hampshire

The New Hampshire Print Edition

An independent student produced newspaper from the University of New Hampshire. This volume was printed as 89, but it is the 90th volume in the series. This was corrected in pencil.

The New Hampshire, Vol. 89 [90], No. 20 (Nov. 9, 1999), The New Hampshire

The New Hampshire Print Edition

An independent student produced newspaper from the University of New Hampshire. This volume was printed as 89, but it is the 90th volume in the series. This was corrected in pencil.

The New Hampshire, Vol. 89 [90], No. 18 (Nov. 2, 1999), The New Hampshire

The New Hampshire Print Edition

An independent student produced newspaper from the University of New Hampshire. This volume was printed as 89, but it is the 90th volume in the series. This was corrected in pencil.

The New Hampshire, Vol. 89 [90], No. 17 (Oct. 29, 1999), The New Hampshire

The New Hampshire Print Edition

An independent student produced newspaper from the University of New Hampshire. This volume was printed as 89, but it is the 90th volume in the series. This was corrected in pencil.

The New Hampshire, Vol. 89 [90], No. 15 (Oct. 22, 1999), The New Hampshire

The New Hampshire Print Edition

An independent student produced newspaper from the University of New Hampshire. This volume was printed as 89, but it is the 90th volume in the series. This was corrected in pencil.

The New Hampshire, Vol. 89 [90], No. 14 (Oct. 19, 1999), The New Hampshire

The New Hampshire Print Edition

An independent student produced newspaper from the University of New Hampshire. This volume was printed as 89, but it is the 90th volume in the series. This was corrected in pencil.

The New Hampshire, Vol. 89 [90], No. 12 (Oct. 12, 1999), The New Hampshire

The New Hampshire Print Edition

An independent student produced newspaper from the University of New Hampshire. This volume was printed as 89, but it is the 90th volume in the series. This was corrected in pencil.

The New Hampshire, Vol. 89 [90], No. 11 (Oct. 8, 1999), The New Hampshire

The New Hampshire Print Edition

An independent student produced newspaper from the University of New Hampshire. This volume was printed as 89, but it is the 90th volume in the series. This was corrected in pencil.

The New Hampshire, Vol. 89 [90], No. 10 (Oct. 5, 1999), The New Hampshire

The New Hampshire Print Edition

An independent student produced newspaper from the University of New Hampshire. This volume was printed as 89, but it is the 90th volume in the series. This was corrected in pencil.

Bioavailability And Trophic Transfer Of Humic-Bound Copper From Bacteria To Zooplankton, Emile M. Lores, Jonathan Pennock

School of Marine Science and Ocean Engineering

ABSTRACT:

The effect of humic acid (HA) on uptake and transfer of Cu by selected marine organisms from the microbial loop was determined. Bacteria grown with and without 15 µg Cu l^-1 and with and without 10 mg Suwannee River Humic Acid (SRHA) l^-1 were fed to Uronema sp. The Uronema were subsequently fed to Acartia tonsa to determine the effect of humic acid on the uptake and transfer of Cu from bacteria to copepods. The presence of 10 mg SRHA l^-1 reduced Cu uptake in A. tonsa by an average of 54% and significantly reduced the …

Regulation And Management Of New Hampshire Estuaries: A Base Programs Analysis, Nh Department Of Fish And Game, Great Bay National Estuarine Research Reserve

PREP Reports & Publications

This report is designed to provide a snapshot of the local, state and federal management framework for the estuaries of the state. Natural resource management, land use regulation, research, education and funding are all important pieces of this framework, and each is reviewed in relation to specific problems of the estuaries. The report first summarizes the issues and potential issues confronting the estuaries and then reviews the existing policies and programs aimed at dealing with these issues.

The New Hampshire, Vol. 89 [90], No. 9 (Oct. 1, 1999), The New Hampshire

The New Hampshire Print Edition

An independent student produced newspaper from the University of New Hampshire. This volume was printed as 89, but it is the 90th volume in the series. This was corrected in pencil.